UNITED SCIENTIFIC - Analytical Chemistry (ACS Publications)

May 31, 2012 - UNITED SCIENTIFIC. Anal. Chem. , 1979, 51 (2), pp 190A–190A. DOI: 10.1021/ac50038a756. Publication Date: February 1979. ACS Legacy ...
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Peak separation you've never seen before.

in their infancy. Both look quite promising. One or both of these vari­ ants of coherent R a m a n spectroscopy may give analytical chemists the means to obtain Raman spectra of flu­ orescent materials at trace concentra­ tions within the next year or two.

Acknowledgment T h e authors thank G. Patrick Ritz and Jeanne Haushalter who have been extensively involved in the develop­ ment and applications of our coherent R a m a n system.

References

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New from this X-ray fluorescence analyzer.

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UNITED SCIENTIFIC ANALYTICAL INSTRUMENTS DIVISION CIRCLE 212 O N READER SERVICE CARD

190 A · ANALYTICAL CHEMISTRY, VOL. 5 1 , NO. 2, FEBRUARY 1979

(1) C.-W. Tsai and M. D. Morris, Anal. Chim. Acta, 76,193 (1975). (2) L. C. Hoskins and U. Alexander, Anal. Chem., 49, 695 (1977). (3) J. Behringer, in "Molecular Spectros­ copy, Specialist Periodic Reports," R. F. Barrow, D. A. Long, and D. J. Millen, Eds., The Chemical Society, pp 170-3, London, England, 1974. (4) J. Behringer, ibid., Vol. 3, pp 163-280, 1975. (5) B. B. Johnson and W. L. Peticolas, Ann. Rev. Phys. Chem., 27, 465 (1977). (6) T. G. Spiro and P. Stein, ibid., 28,501 (1977). (7) A. Warshel, Ann. Rev. Biophys. Bioeng., 6, 273 (1977). (8) T. G. Spiro, in "Vibrational Spectra and Structure," J. R. Durig, Ed., pp 101-20, Elsevier, Amsterdam, The Neth­ erlands, 1976. (9) J. Brandmiiller, Z. Anal. Chem., 170, 29 (1959). (10) R.J.H. Clark, in "Advances in InfraRed and Raman Spectroscopy," R.J.H. Clark and R. E. Hester, Eds., Vol. 1, pp 143-72, Heyden, London, England, 1975. (11) C. W. Brown and P. F. Lynch, J. Food Sci., 41,1231 (1976). (12) L. VanHaverbeke, P. F. Lynch, and C. W. Brown, Anal. Chem., 50, 315 (1978). (13) R. J. Thibeau, L. VanHaverbeke, and C. W. Brown, Appl. Spectrosc, 32, 98 (1978). (14) M. D. Morris, Anal. Chem., 47, 2453 (1975). (15) M. S. Rahaman and M. D. Morris, Talanta, 23, 65 (1976). (16) M. D. Morris, Anal. Lett., 9, 469 (1976). (17) D. L. Jeanmaire, M. R. Suchanski, and R. P. Van Duyne, J. Am. Chem. Soc, 97,1699 (1975). (18) J. L. Anderson and J. R. Kincaid, Appl. Spectrosc, 32, 356 (1978). (19) W. H. Woodruff and G. H. Atkinson, Anal. Chem., 48,186 (1976). (20) W. H. Woodruff and S. Farquharson, ibid., 50,1389 (1978). (21) P. J. Trotter, J. Phys. Chem., 82, 2396 (1978). (22) H. Yamada, Y. Amamiya, and H. Tsubomura, Chem. Phys. Lett., 56, 591 (1978). (23) P. P. Yaney, J. Opt. Soc. Am., 62, 1297 (1972). (24) R. P. Van Duyne, D. L. Jeanmaire, and D. F. Shriver, Anal. Chem., 46, 213 (1974). (25) F. E. Lytle and M. S. Kelsey, ibid., ρ 855. (26) J. M. Harris, R. W. Chrisman, F. E. Lytle, and R. S. Tobias, ibid., 48,1937 (1976). (27) S. Burgess and I. W. Shepherd, J. Phys., E, 10,617 (1977). (28) A. B. Harvey, Anal. Chem., 50,905A (1978).