Electrochemistry of nitrite reductase model compounds. 3. Formation

Laser Photoinitiated Nitrosylation of 3-Electron Reduced Nm europaea Hydroxylamine Oxidoreductase: Kinetic and Thermodynamic Properties of the ...
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Inorg. Chem. 1987, 26, 2480-2483

2480

Contribution from the Chemistry Department, Marquette University, Milwaukee, Wisconsin 53233

Electrochemistry of Nitrite Reductase Model Compounds. 3. Formation and Characterization of a Bis( hydroxylamine) (tetraphenylporphyrinato)iron(II) Complex DiWei Feng and Michael D. Ryan* Received July 1, 1986 The reaction of hydroxylamine with Fe"'(TPP)CI and Fe"(TPP) (TPP = tetraphenylprphyrinate(2-)) at room temperature and at lower temperatures (