Exploring Digital Signals and Noise in Instrumental Analysis

Mathcad in the Chemistry Curriculum edited by. Theresa Julia Zielinski. Monmouth University. West Long Branch, NJ 07764-1898. Exploring Digital Signal...
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Mathcad in the Chemistry Curriculum

edited by

Theresa Julia Zielinski Monmouth University West Long Branch, NJ 07764-1898

Exploring Digital Signals and Noise W in Instrumental Analysis: SignalsNoise.mcd Augustus W. Fountain III, Department of Chemistry and Photonics Research Center, United States Military Academy, West Point, NY 10996; [email protected]

The fundamental concepts of noise and signal-to-noise ratio are central to the discipline of analytical chemistry. Since chemical instrumentation dominates the modern laboratory, it is critical that students understand the role noise plays in limiting the precision of a measurement. It is equally important that they understand how to implement active and passive means to mitigate noise. The purpose of this Mathcad document is to allow the student to gain a familiarity with the concepts of signal-to-noise ratios and to explore the advantages of ensemble averaging and digital filtering analyti-

Figure 1. Ensemble averaged signal and original signal.

cal signals. Simulated noisy signals are used to guide the student through a series of individual exercises (Fig. 1). These exercises culminate in a capstone experience in which they simultaneously apply all of the concepts.

JChemEd.chem.wisc.edu • Vol. 78 No. 2 February 2001 • Journal of Chemical Education

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