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Apr 30, 1976 - Mechanisms of Racemization of M(phen)32+ Ions. AIC60316P. Sir: A fewyears ago Sutter and Hunt1 reported that Cr-. (phen)32+ (phen =.
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Electronic Spectra of Tris(2,2â²-bipyridine)-M(II) Complex Ions in Vacuo (M = Fe and Os) ... Stephanie Bellinger-Buckley , Tse-Cing Chang , Seema Bag , David Schweinfurth ... The Journal of Physical Chemistry B 2013 117 (12), 3428-3438 ... Benjamin
Chandima Abeywickrama and Arthur David Baker. The Journal of Organic Chemistry 2004 69 (22), 7741-7744. Abstract | Full Text HTML | PDF | PDF w/ Links.
Jan 22, 2010 - The Stöber method,(16) in which tetraethoxysilane (TEOS) was used as silica source and ammonia as catalyst, is the most widely adopted ...
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Correspondence Table I. R a t e Parameters for Ligand Dissociation and Racemization of M(phen)," Ions at 25 "C
Mechanisms of Racemization of M(phen)3?+ Ions AIC603 16P
Sir: A few years ago Sutter and Hunt' reported that Cr( ~ h e n ) 3 ~ "(phen = 1,lo-phenanthroline) reacted with ( + ) ~ - C o ( p h e n ) 3 ~to+ yield (-)~-Cr(phen)3~+ and that when (-)~-Co(phen)3~+ was the reactant (+)~-Cr(phen)3~+ resulted. There was thus indicated a substantial (84%) stereospecificity in this outer-sphere redox reaction. The observations demanded additionally that the (rapid) redox reaction must be much slower than the inversion of C r ( ~ h e n ) 3 ~so + , as to allow the optical form of C r ( ~ h e n ) 3 ~which + is oxidized more rapidly by C0(phen)3~+to be continuously regenerated. This required a racemization half-life