Nitrogen Scheme Is Changing - C&EN Global Enterprise (ACS

Nov 6, 2010 - DOI: 10.1021/cen-v037n008.p032. Publication Date: February 23, 1959. Copyright © 1959 AMERICAN CHEMICAL SOCIETY. ACS Chem...
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Nitrogen Scheme Is Changing Ammonium sulfate giving ground fo solutions, but gaining as t o p dressing; exports rising COKE

OVEN a m m o n i u m

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result of curtailed coking operations in the steel industry. Steel operations d r o p p e d to as low as 4 8 % of capacity in April, recover­ ing to 7 3 % at year's e n d . Currently die rate is a r o u n d 8 3 . 5 % . As a nitrogen fertilizer material, am­ monium sulfate ( 2 1 % N ) is slowly yielding ground t o other nitrogen prod­ ucts of higher analysis, especially ni­ trogen solutions. Synthetic ammonium sulfate output was stepped up in 1958 b u t not enough to compensate for production losses at the coke ovens. T h e outputs, based on data supplied b y the Bureau of Mines a n d t h e Bureau of t h e Census, with

December 1 9 5 S estimated, w e r e a b o u t like this: Amtiioniztin Coke Ovens Synthetic Imports

Siufais Su 1958

640,000 1,100,000 140,000 (Est.)

1957 910,000 1,070,000 120,000

• E x p o r t s H e a v y . Exports a s s u m e an important v o l u m e in ammonium sul­ fate. I t is e s t i m a t e d i n the t r a d e t h a t the greater p a r t o f t h e synthetic p r o ­ duced in 1 9 5 7 a n d 1958 was exported. A good share of t h e coke oven sulfate in 1957 was also sent abroad, b u t out­ puts from this source i n 1958 p r o v i d e d little surplus for t h i s purpose. D u e in a m e a s u r e t o inroads by ni­

More Use Made of Chemical Nitrogen Materials

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t r o g e n solutions, d i r e c t appKcatio*n o f a m m o n i u m sulfate to crops ESS slipping, says Chester E d w a r d s of Niteogen P r o d u c t s . O n t h e other Iiaed» jfcs u s e a s t o p dressing «material is Sncreatsing.. D i r e c t application of siiîfaîae remains q u i t e large in California, T h e changing nitrogen picture flavoring higher analysis materials is sliown in another w a y b y t h e Depsart!ne*st €»f Agriculture^ s u m m a r y of ct»eniicad n i trogen materials «consumed «during; t h e fertilizer year e n d e d last Juane (MS571958). tTjjj. »jk«; «^««Λ*^! t h e coiissHnotsoQ of all chemical nitrogen materials for «di­ rect application a m o u n t e d tea 3.BM mil­ lion tons, a n increase of 1S5,€(HB t o n s over d i e 1 9 5 6 - 1 9 5 7 period. T h i s report d o e s n o t cower tfcue e n ­ tire nitrogen consunipuon «niclurae b u t it contains some pertinent details- Use of a m m o n i u m sulfate increased S7,(J0O tons to 573,000 tons, but imitrogtsn s o ­ lutions gained 7 1 , 0 0 0 tons t o 3E7,O00 tons- A n h y d r o u s ammonia* consump­ tion expanded 1 2 4 , 0 0 0 t o n s to a . total of 5 7 7 , 0 0 0 tons, a n d this pmobably will surprise n o one- Anln/dirmis novw a c ­ counts for some 15S& of atîl cli*onïeal nitrogen materials used in agricnalture• P e r c e n t a g e U s e s . Heme's th*e p e r centage b r e a k d o w n for 185*7-58= Product Anhydrous a m m o n i a Ammonium n i t r a t e Aqua a m m o n i a Ammonium sulfate Nitrogen solutions Sodium nitrate

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T h e small p°*-centage for usrea J»>es n o t show its much g r e a t e r user in soiutsons «^^3 Ajkor fertilizer fonQ?^ ÂSiso. îite sodium nitrate figures re^resemt B o t h Chilean a n d U- S. p r o d u c t s . In its Chemical Eeon&mfcs Newsletter for J a n u a r y , Stanfcwrd R e s e a r c h Institute says t h a t fertilizer usses c o n tinue t o take a n increasing sliare o f t o tal ammonia production. The? rise is primarily t h r o u g h direct application a n d in the form of nitrate and s*ii*»teAnd while industrial omtiets for a n hydrous ammonia a r e decreasing in p e r c e n t a g e of t h e market, dbey a r e continuing their g r a d u a l expsansioio, a i d e d b v d i e ûicreasin 0 " aecep!b?incc of a m m o n i u m n i t r a t e a s an explosive a n d u s e of a m m o n i a in bisulfilte pulping of wood.

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PAS Meets Competition Temporary price reductions have b e e n effected b y Sumner Chemical, M e w York, In « - a m i n o s a l i c y l i c a c i d . Sumner, a division of Miles Laborat o r i e s , m a d e t h e m o v e to m e e t import competition. S o d i u m p - a m i n o s a l i c y l a t e , U S P ^ is n o w q u o t e d at $ 1 . 9 0 p e r p o u n d ; p - a m i n o s a l i c y l i c a c i d , U S P , is S 3 . 4 0 ; a n d calciuni p-aminosalicylate, U S P , § 3 . 1 0 p e r pound. T h e prices a p p l y to iTîiïimiiirri orders o f 1 0 0 p o u n d s .

*> C o m m e r c i a l S o l v e n t s . N e w Yorlc. i s s u e d a n e w s c h e d u l e s h o w i n g price reductions for dibuty! phthaiaie. N e w t a n k c a r b a s e is £ G c e n t s per p o u n d , E a s t . N e w s c h e d u l e s w e r e also i s s u e d o n £ - n i t r o p r o p a n e , n i t r o m e t h a n e , nitroethane, I-nitropropane, anhydrous a m monia, butyl alcohol, butyl acetate, e t h y l a c e t a t e , a m y ! acetaute, a c e t o n e , and S B A N o . 4 0 alcohol. *> W . R- G r a c e , c h e m i c a l d i v i s i o n , M e m p h i s , T e n n . , issued a n e w p r i c e s c h e d u l e for urea q u o t i n g prills of 4 6 % Ν ( t r e e - f l o w i n g b e a d s ) a t S I 15 p e r s h o r t t o n , freight e q u a l i z e d , carloads or trucîdoads, f.o.b. Woodstock, Tenn. W h i t e c r y s t a l l i n e s o l i d u r e a is q u o t e d o n t h e s a m e basis, and b o t h products a r e s h i p p e d Li 1 0 0 - p o u n d m u l t i w a l l p a p e r b a g s w i t h m o i s t u r e barrier.

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