Article pubs.acs.org/Macromolecules
Polymer Actuators Using Ion-Gel Electrolytes Prepared by SelfAssembly of ABA-Triblock Copolymers Satoru Imaizumi, Hisashi Kokubo, and Masayoshi Watanabe* Department of Chemistry and Biotechnology, Yokohama National University, Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan S Supporting Information *
ABSTRACT: Well-defined ABA-triblock copolymers, polystyreneblock-poly(methyl methacrylate)-block-polystyrene (SMS), which have two different polystyrene (PSt) weight fractions (f PSt), were synthesized by successive atom-transfer radical polymerizations. Ion gels consisting of SMS and an ionic liquid, (1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide [C2mim][NTf2]), were prepared using the cosolvent evaporation method with tetrahydrofuran. Atomic force microscope images of the ion gels indicated that PSt is phase-separated to form sphere domains that serve as physical cross-linking points because PSt is not compatible with [C2mim][NTf2], while a continuous poly(methyl methacrylate) (PMMA) phase with dissolved [C2mim][NTf2] is formed to serve as ion conduction paths. Accordingly, the ion gels are formed by the self-assembly of SMS and the preferential dissolution of [C2mim][NTf2] into the PMMA phase. The viscoelastic properties of the gels can be easily controlled by changing f PSt in SMS and [C2mim][NTf2] concentration in the ion gels. The ion gels that exhibit high ionic conductivities (>10−3 S cm−1) at room temperature were used as an electrolyte of an ionic polymer actuator, which has a trilaminar structure consisting of the ion-gel electrolyte sandwiched between two composite carbon electrodes containing high-surface-area activated carbon powders. By applying low voltages (
