Reaction of B-methoxydialkylboranes with lithium aluminum hydride in

Herbert Charles Brown, Eiichi Negishi, and Shyam Kirti Gupta. J. Am. Chem. Soc. , 1970, 92 (22), pp 6648–6649. DOI: 10.1021/ja00725a050. Publication...
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6648

The Reaction of B-Methoxydialkylboranes with Lithium Aluminum Hydride in the Presence of Olefins. A New and General Synthesis of Acyclic and Cyclic Mixed Trialkylboranes and Their Conversion into the Corresponding Trialkylcarbinols cia Carbonylation-Oxidation

readily converted into the corresponding trialkylcarbinols cia carbonylation-oxidation (eq 1). 3R2’BOCH3

+ LiAlH,

olefln

3R,’BR

+

LihlHtOCH (

0

1

((

)