Subscriber access provided by UNIV OF DURHAM
Comment
Reply to Comment on "The Mayonnaise Effect" Klaas Wynne J. Phys. Chem. B, Just Accepted Manuscript • DOI: 10.1021/acs.jpcb.8b01428 • Publication Date (Web): 12 Feb 2018 Downloaded from http://pubs.acs.org on February 18, 2018
Just Accepted “Just Accepted” manuscripts have been peer-reviewed and accepted for publication. They are posted online prior to technical editing, formatting for publication and author proofing. The American Chemical Society provides “Just Accepted” as a service to the research community to expedite the dissemination of scientific material as soon as possible after acceptance. “Just Accepted” manuscripts appear in full in PDF format accompanied by an HTML abstract. “Just Accepted” manuscripts have been fully peer reviewed, but should not be considered the official version of record. They are citable by the Digital Object Identifier (DOI®). “Just Accepted” is an optional service offered to authors. Therefore, the “Just Accepted” Web site may not include all articles that will be published in the journal. After a manuscript is technically edited and formatted, it will be removed from the “Just Accepted” Web site and published as an ASAP article. Note that technical editing may introduce minor changes to the manuscript text and/or graphics which could affect content, and all legal disclaimers and ethical guidelines that apply to the journal pertain. ACS cannot be held responsible for errors or consequences arising from the use of information contained in these “Just Accepted” manuscripts.
The Journal of Physical Chemistry B is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Published by American Chemical Society. Copyright © American Chemical Society. However, no copyright claim is made to original U.S. Government works, or works produced by employees of any Commonwealth realm Crown government in the course of their duties.
Page 1 of 3 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
The Journal of Physical Chemistry
Reply to “comment on ‘The Mayonnaise Effect’” Klaas Wynne School of Chemistry, University of Glasgow, UK Recently I described how the structuring of a liquid caused by the addition of solutes causes the viscosity to increase according to a Vogel-Fulcher-Tammann type expression.1 The rapid viscosity increase as a function of concentration can be understood in terms of a jamming transition at a critical concentration. This effect was referred to as “the Mayonnaise Effect” (see Figure 1). In the comment by Wessling,2 it is pointed out that mayonnaise is an emulsion and not a solution. It is true that solutions are at equilibrium whereas emulsions such as mayonnaise are not. However, consistent with the comment by Wessling, emulsions do attain their high viscosity because of the jamming (or gel formation) of a three-dimensional network of irregularly sized droplets. This can be seen clearly in figures 1 and 2 of the comment.
Figure 1. The large viscosity of concentrated solutions is caused by the Mayonnaise Effect.1
AUTHOR INFORMATION Corresponding Author
*
[email protected] ACS Paragon Plus Environment
1
The Journal of Physical Chemistry 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Page 2 of 3
Notes
The author declares no competing financial interest.
ACKNOWLEDGMENT I thank the Engineering and Physical Sciences Research Council (EPSRC) for support through grants EP/E046541/2, EP/F06926X/2, EP/J009733/1, and EP/K034995/1.
REFERENCES 1. 2.
Wynne, K. The Mayonnaise Effect. J. Phys. Chem. Lett. 2017, 8, 6189-6192. Wessling, B. Comment on “The Mayonnaise Effect”. J. Phys. Chem. Lett. submitted.
ACS Paragon Plus Environment
2
Page 3 of 3 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58
The Journal of Physical Chemistry
ACS Paragon Plus Environment
