%Selective Decoration of a Phase-Separated Diblock Copolymer with

Robert W. Zehner, Ward A. Lopes, Terry L. Morkved, Heinrich Jaeger, and Lawrence R. Sita*. Langmuir , 1998, 14 (7), pp 1942–1942. DOI: 10.1021/la980...
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Langmuir 1998, 14, 1942-1942

Additions and Corrections Selective Decoration of a Phase-Separated Diblock Copolymer with Thiol-Passivated Gold Nanocrystals Robert W. Zehner, Ward A. Lopes, Terry L. Morkved, Heinrich Jaeger, and Lawrence R. Sita* Langmuir 1998, 14, 241.

Figures 1 and 2 did not reproduce well in the printed issue of the journal. Images that show more detail are presented below. LA9801108

Figure 1. (a) TEM micrograph of a phase-separated 600 Å thick, PS-b-PMMA copolymer film. The light areas correspond to the PMMA phase. Image dimensions were 1.7 µm × 1.75 µm. (b) TEM micrograph of dodecanethiol-coated gold nanocrystals on a microphase-separated PS-b-PMMA substrate, deposited form a dilute solution in toluene/ethanol. Image dimensions were 360 nm × 350 nm.

Figure 2. TEM micrographs of dodecanethiol-coated gold nanocrystals deposited on a phase-separated PS-b-PMMA block copolymer film. (a) Disperse coverage observed for deposition from dilute solution. Image dimensions 615 nm × 690 nm. (b) Dense coverage resulting from deposition from a more concentrated solution. Note the presence of nanocrystals on the PMMA phases. Image dimensions 205 nm × 230 nm. S0743-7463(98)00110-3 CCC: $15.00 © 1998 American Chemical Society Published on Web 02/24/1998