William S. Ferguson. Organic Nitrogen by Sealed-Tube Kjeldahl.
ASSOCIATIONS
Southwest Regional Meeting The 20th Southwest Regional Meeting of ACS local sections will be held Dec. 3 to 5 at the Captain Shreve and Wash ington-Youree Hotels in Shreveport, La. Ark-La-Tex Section is host.
Reiser
Milligan
A program of 184 papers has been planned, with general sessions and symposiums in the fields of analytical chemistry, biochemistry, chemical education, computers in industrial chemistry, corrosion, industrial and engineering chemistry, inorganic chemistry, organic chemistry, and in the student affiliate program. At the Southwest Awards banquet Dr. Raymond Reiser, professor of bio chemistry and nutrition at Texas A&M University, will be recipient and prin cipal speaker. A feature of the meeting will be plenary lectures by Dr. W. O. Milligan of Texas Christian University (Recent
Noyes
Conkle
Electronmicroscopic Studies on the Hydrous Oxides), Dr. W. Albert Noyes, Jr., of University of Texas (Photochemistry, Present and Future), and Dr. James P. Conkle of Brooks Air Force Base (Contaminants in Sealed Environments). The meeting will feature an em ployment clearinghouse. The ladies' 100
C&EN
NOV. 9, 196 4
FRIDAY MORNING
program includes a luncheon, tours, and a tea. General chairman of the meeting is Dr. Edward C. Greco of United Gas Corp. Dr. Alan H. Crosby of North-
Greco
Crosby
western State College at Natchitoches, La., is chairman of the technical pro gram committee. Advance registration is urged; the coupon on page 102 should be ac companied by a check made out to Robert E. Pitts, United Gas Corp., P.O. Box 1407, Shreveport, La. 71102.
Ray E. Humphrey, Lloyd M. McCrary, Rodney C. Webb. Reduction of Selected Alkyl Disulfides with Triphenvlphosphine. F . J . Miller, H. E. Zittel. Voltammetry of Iodide, iodine, and Iodate with the Pyrolytic Graphite Indicating Electrode. K. V. Wise, T. J. Lemoine, L. H. Holmes, Jr. Simple Room Tempera ture Gas Chromatography. John Q. Walker. Special Tech niques of Trace Analysis by Gas Chromatography. Edgar D. Smith, J. M. Oathout. A Statistical Evaluation of Some Im portant Parameters in the Preparation of Gas Chromatographic Packings. B. W. Dixon, J. F. Slowey, D. W. Hood. A Method for Activation Analysis of Ruthenium in Sea Water. H. M. Klein, A. Max Bryant. Mass Spectrometric Ionization Sensitivity for Positive and Negative Halogen Ions. A. Gene Collins. Emission Spec trometric Determination of Barium, Strontium, Boron, Manganese, and Iron in Oilfield Waters Using Plasma Arc. Biochemistry
Program Analytical Chemistry
T i l l " RS DA Υ ΝIORNING
Symposium: Amino Acids, Peptides, and Analogs
THURSDAY AFTERNOON
Lester C. Howick, Tony Rihs. Kinetic Study of the Precipitation of Copper 8-Quinolate from AcetoneWater Mixed Solvents. Hans A. S liter. The Aluminum Salt of 8-Hydroxyquinaldine. Harold F. Schaeffer. Chemical Microscopy of the Platinum Metals: Reactions with 1,5-Naphthvridine. Robert E. McCoy. The Validity of the Cobaltinitrite Test for Potassium Ion and the "Confirmatory Flame Test." Suresh Srivastava, Mary L. Good. Spectrophotometric Study of 2-Mercaptoacetanilide Carbamate as a Colorimetric Reagent for Rhodium (III) and Palladium(II). David Miller, Suresh Srivastava, Mary L. Good. 1-Nitroso 2-NaphthoI 3:6 Disulfonic Acid (Disodium Salt) as a New Reagent for the Spectro photometric Determination of Ruthe nium (III ). Michael E. Mason, Bobby Johnson, Mynard Hamming. Procedures for the Identification of Small Quantities of Carbonyl Compounds by Way of Their 2,4-Dmitrophenylhydrazones. Paul Lynas, E. A. Eads, D. A. Payne, Jr. Copper-Copper Oxide Flame Reactions of Selected Organohalogens in the Presence of Air and Methane.
Charles G. Skinner. Use of Struc turally Defined Amino Acid Analogs in the Study of Biochemical Processes. Paul F. Kruse, Jr. Amino Acid Metabolism in Proliferating vs. Nonproliferating Animal Cell Cultures. Robert Gipson, C. G. Skinner, William Sftrive. Biological Specifici ties of Some Cyclopentyl Glycines. Tommy J. McCord, Alvie L. Davis. Biological Activities of o-Aminophenylalanine. 2-Aminotyrosine, and Related Compounds. Floyd W. Dunn. Microbial Growth Inhibition Studies Employing Peptides of β-2-Thienylalanine. Ellen A. Young, Sydney Turner, Jo Etta Shelby, Anna Grace Stewart. Transport of Unnatural Peptides by Lactobacillus casei 7469. Thomas R. Henderson. Effects of Heavy Water on Growth and Enzyme Formation in Microorganisms. THURSDAY AFTERNOON
William Garner, Boyce C. Williams, J. Wayne Whitworth. Biochemical Oxygen Demand as a Parameter in Evaluating Soils. Edgar D. Smith, Howard Sheppard. Gas Chromatographic Analysis of Amino Acids as the Trim ethyl silyl Derivatives.
Leon S. Ciereszko, Mary A. W. Johnson, Robert W. Schmidt, C. B. Koons. Gorgosterol, a C 3 0 Sterol Oc curring in Zooxanthellae. J. B. Middlebrook, R. O. Bowman. C 1 4 Incorporation into Amino Acids from Urea by Chlorella. S. S. Patton, B. Shelby, R. Lee, S. S. Kilgore. Serum Proteins in Peromyscus. S. S. Patton, B. Hewett, J. Kendall, S. S. Kilgore. Hemoglobins in Peromyscus. B. C. Shirley, Donald E. Kizer. Relationships Between Increases in Hepatic Nuclear RNA Content, Nuclear-Nucleolar Morphology, and Adenylic Acid Deaminase Activity of the Rat Following Thioacetamide In jections. Boyd A. Howell, Donald E. Kizer. The Relationship Between Hepatic Protein and RNA Biosynthesis and the Increase in Adenylic Acid Deaminase Activity of the Rat Following Thioacet amide Injections. F. de Balbian Verster, O. Z. Sellinger, J. C. Harkin. Morphology and Characterization of Cerebral Lysosomes. F. de Balbian Verster, R. GuerreroFigueroa. Effect of Amino Oxyacetic Acid on y-Aminobutyric Acid Uptake by the Rat Brain. George Gorin, Chang-Chen Chin. Urease. V. Assay, Specific Activity, and Other Properties. Sister Mary Daniel Healy. NMethyl-Pyridoxal-5-Phosphate: A Vitamin Bfi Analog.
FRIDAY MORNING
Symposium: Nucleic Acid Biosyn thesis—Nucleotide Chemistry Rogene F. Henderson, T. R. Hen derson. Vitamin B 1 2 and DNA Bio synthesis. E. Colleen Moore. Deoxyribonucleotide Biosynthesis by an Enzyme System from Rat Tumor. Robert B. Hurlbert, Ming C. Liau. RNA Polymerase Reaction in Isolated Nuclei and Nucleoli from Rat Liver and Tumor. Harris Busch. Controls on Nucleo lar RNA Synthesis. L. S. Hnilica, D . Billen. The Ef fect of DNA-Histone Interactions on the Biosynthesis of DNA in Vitro. Carlos L. Krumdieck, Elliott N. Shaw, Charles M. Baugh. The Origin of Carbon-6, -7, and -9 in Folic Acid.
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FRIDAY AFTERNOON
Symposium: Protein Biosynthesis, Structure, Active Sites
Statham Instruments, Inc. 12401 West'Olympic Blvd. Los Angeles 64, Calif.
Virgil L. Koenig. Physicochemical Properties of the Proteins of the Crys talline Lens. Willette Y. Libano, Virginia R. Wil liams. Studies on the Active Site of β-Methylaspartase. NOV. 9, 196 4 C & E N 101
Scientists and Engineers
Rocketdyne's Research Division has the following openings in the Chemistry Section
Franklin R. Leach, Thomas F. Dunn, Semih Erham. Studies of Poly ribonucleotide Coding in Protein Syn thesis.
Elliott Shaw, William Cohen, Mar cos Mares-Guia. A Hydrophobic Binding Region of the Active Center of Trypsin. Richard R. Fritz, Donald A. Rappoport. Influence of Age and Hormones on Rat Brain Ribosomal Activity. Boyd A. Hardesty. The Origin and Role of the Small Polysomes in Rabbit Reticulocytes. A. Clark Griffin. Effect of Ribo nucleic Acid on Mammalian in Vitro Amino Acid Incorporating Systems.
C. Hedgcoth, J. M. Ravel, W. Shive. Selective Inactivation of Acceptor Ribonucleic Acids by Chemical Re agents. S. J. Norton, M. D. Key, S. W. Scholes. The Association of Some Amino Acid Activating Enzymes with Isolated Microsomes of Chick Embryo.
Registration Card
ACS Southwest Regional Meeting Dec. 3 to 5, 1964
Shreveport, La.
SENIOR ANALYTICAL RESEARCH CHEMIST
To develop and apply instrumental and gas chromatic graphic methods to problems associated with current, near-term, and exotic propellants and materials.
(Last Name) Technical Session Registration for Men and Women:
SENIOR CHEMIST
To perform synthesis, with particular emphasis in the areas of organic, organometallic, fluorine chemistry, polymers, and hydrides.
(First Name or Initial)
(Please Print)
Ladies' Registration Π
Member$7.50
Π
Foreign; or Nonchemist or Nonchemical Engineer $7.50
Π
Ladies'Program
$2.00
Π
Social only
Π
Student
$2.00
Π
Saturday only
$2.00
Π
Secondary School $2.00 Teachers
1.00
SENIOR PHYSICAL CHEMIST
To perform nuclear magnetic reso nance spectrometry on the structures of new compounds. SENIOR CHEMICAL THERMODYNAMICS
To study high-temperature equilib rium and nonequilibrium processes.
Π
U.S. Nonmember Chemist or Chemical Engineer $10.00
Local Hotel Address Business Affiliation
CHEMICAL ENGINEER OR CHEMIST
To perform theoretical calculations and programming related to molecu lar structure of propellants. SENIOR CHEMICAL ENGINEER
To perform studies of ignition and detonation, materials compatibility, stability, and storage processes. Positions require an MS or Ph.D de gree with demonstrated ability to carry out applied research assignments. Qualified individuals are invited to write:
(Street Address)
(City)
(State)
(Zip Code)
Tours and Function Ticket Order (Indicate number of tickets in space at left) TOURS (complimentary tickets available at registration desk on a first come, first served basis) A.
United Gas Corp. Research Lab Thursday, Dec. 3, 1:30-4 P.M. (limit 40) Β Bird & Son Roofing Co. Friday, Dec. 4, 1:15-4 P.M. (Limit 40) C. Ladies' tour of Louisiana State Exhibit Building Thursday, Dec. 3, 1:30 P.M. D. Ladies' conducted tour of Shreveport with tea at Centenary College Faculty Lounge Friday, Dec. 4, 1:30 P.M.
Mr. K. L. Stoetzel Professional Employment Office 6 6 3 3 Canoga Avenue Canoga Park, California All qualified applicants will receive consideration for employment without regard to race, creed, color, or national origin.
ROCKETDYNE I t A Division of North American Aviation
102
C&Ε Ν
N O V . 9, 19 6 4
FUNCTIONS Ladies' Luncheon, Petroleum Club of Shreveport (included in registration fee) Thursday, Dec. 3, 12 noon Social Hour (admission by complimentary tickets furnished registrants) Thursday» Dec. 3, 5:30 P.M. Awards Banquet, Friday, Dec. 4, 7 P.M. $3.50 Total value of registration fees and tickets $_ (Please attach check or money order for advance registration)
Return with check or money order to: Robert E. Pitts, United Gas Corp., Research Department, P.O. Box 1407, Shreveport, La. 71102
SATURDAY MORNING
Symposium: Multicomponent En zyme Systems and Special Topics W. Orme-Johnson, F . F . Sun. Sub strate Specificity of the Microsomal Alkylarylamine Dealkyase. D. M. Ziegler, F . H. Pettit, C. A. Haddox. Properties of a Mammalian Alkylarylamine Oxygenase. K. Kiritani, S. Narise, R. P. Wagner. In Vitro Biosynthesis of Valine from Pyruvate in Neurospora Crassa. Peter Jurtshuk, Jr., E. Pinia Norrod, Charles H. Denton, William T. Swift III. Particulate Dehydrogenases of Azotobacter Vinelandii. G. W. Brown, Jr. Evolution of Urea-Forming Reactions. Robert L. Wixon. Comparative As pects of Biosynthesis of Amino Acids. Walter N. Thomas, G. W. Brown, Jr. Liver and Kidney Uricase in Poikilothermic Vertebrates.
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Chemical Education FRIDAY AFTERNOON
Horace H . Bliss, Ralph G. Benham. The Organic Chemistry Content In cluded in High School Chemistry. G. F . Reynolds. The Electron Spin Resonance at Radio-frequencies. James C. Cox, Jr. Formula for Suc cess in Teaching Organic Chemistry. Willis W. Floyd. A Modular Rela tion for the Number of the Group in Which an Element Is Listed in the Periodic Table. Hans A. Suter, Patricia H. Suter. Special Problems in Teaching General Chemistry at a Community Junior Col lege. Buddhadev Sen. An Analytical Chemistry Course for Undergraduate Chemistry Majors. M. F . Stubbs. The Use of Short Historical Sketches as a Means of En riching the Modern General Chemistry Course. Robert L. Holt, William K. Easley. Determination of Iron (III) by Com bination of Liquid/Liquid Extraction and Colorimetry in the Quantitative Analysis Course. William J. Diamond. Simulated Projects for Teaching Experimental Strategies and Methods of Data Analy sis.
2-chloro-5-trifluormethyl-aniIine Amber colored oil of 99% minimum purity used as an intermediate in dyes and other chemicals. 2,5-dimethoxy-mtrobenzene Gray or tan powder for use in dyestuff intermediates and other organic chemicals.
SATURDAY MORNING
Symposium: What the Colleges and Universities Are Doing to Meet the New ACS Minimum Standards for Accreditation Arthur Fry, Edward Lewis. Discussion.
Samples are available in the U. & Specifications and price list of these and other intermediates available on request. Phone 201 - WE 5-5400 or write:
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Computers in Industrial Chemistry ( Joint with Industrial and Engineer ing Chemistry) FRIDAY MORNING
Irving L. Kinney, Marvin D. Misak. The Use of the IBM 1620 in Routine Laboratory Operations.
I liiStOr
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CHEMICAL WORKS, m. Ridge field, New Jersey NOV. 9, 1964 C&EN
103
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T. M. Nartker, C. D. Holland. A Generalized Convergence Method for Systems Containing Various Types of Interconnected Units. Gregor H. Riesser, Jack C. Fritz. Use of Statistical Design and Kinetics for Process Simulation. Thomas E. Short, John H. Erbar. A Short-Cut Method for Predicting Minimum Reflux for Multifeed Fractionator. Corrosion (Joint with Industrial and Engineering Chemistry )
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R. de Le vie. The Influence of Surface Roughness of Solid Electrodes on Electrochemical Measurements. Lester D. Hulett, Jr.? F. W. Young, Jr. Application of Kinematic Theory to a Study of the Dissolution of Metal Crystal. J. S. Payne, Jr., E. S. Snavely, Jr., Norman Hackerman. Corrosion of Mild Steel in Phosphoric Acid. J. B. Sardisco, R. E. Pitts, W. B. Wright, E. C. Greco. Environmental Effects upon the Sulfide Films Formed During the Corrosion of Iron bv HoSCO.,-H>0. John D. Sudbury, W. P. Banks. Anodic Protection in the Chemical Industry.
Industrial and Engineering Chemistry
38 in the Advances in Chemistry Series SALINE WATER CONVERSION-II
FRIDAY AFTERNOON
No.
Three years of important work in this active research area are represented in this new volume on saline water conversion. The 14 papers it offers were based on symposia sponsored by the Division of Water and Waste Chemistry at the 139th and 141st National Meetings of the ACS in March 1961 and March 1962, respectively. Different methods reported here include: spray evaporation . . . phosphate precipitation . . . vibration . . . wiped thin-film distillation . . . the use of the diffusion s t i l l . . . the use of the osmotic membrane . . . flash evaporation utilizing solar energy.
Cost prob-
lems are fully covered. There are abundant charts and illustrations. Authors are drawn from universities and industry, research institutes,
government.
They provide experimental data and discussion from work in the U. S., Canada, Australia, South Africa and Israel.
Both basic and applied research is covered.
All those concerned with technical aspects of saline water conversion will want this up-to-date compilation of significant papers on the subject. 199 pages.
Paper bound.
Kenneth F. Federico, Frank R. Groves, Jr. Computer Study of the Design of a Continuous Flow Stirred Tank Reactor with External Heat Transfer Loop. Paul W. Murrill, Jesse Coates. Degrees of Freedom in the Automatic Control of Fractionators. Robert L. Rule, R. N. Maddox. A Study of Chromatographic Distillation. A. Adler Hirsch. A Reflective Protractor for Determining Slopes of Curves. Hamdi Ali El-Banbi, Harvey T. Kennedy. Equations of State for Various Pure Hydrocarbon and Nonhydrocarbon Systems and Their Mixtures. Joe E. Gilliland, Wayne E. White, John B. West. Phase Equilibria in the Stannous Fluoride-Hydrogen Fluoride System. J. C. Burleson. A Multiple Differential Thermal Analysis Apparatus. James E. Pritchard, F. W. Bailey, D. R. Witt. A New Cross-Linked High-Density Polyethylene.
Price: $6.00 Inorganic Chemistry THURSDAY
Order from: Special Issues Sales/American Chemical Society 1155 Sixteenth Street, N. W./Washington 6, D. C.
104
C&EN
NOV.
9f
196 4
MORNING
Norman Fogel, Wyman Grindstaff. Thermodynamics of the Stepwise Dissociation of Cobalt ( II ) Chloride Hexahydrate.
Joel Selbin, Laura Morpurgo. Spec tral Studies of Low Symmetry Vanadyl(IV) Complexes. Mark M. Jones. Ligand Replace ment Reactions of Nontransition Ele ment Complexes. Dale A. Johnson. Transition Metal Complexes of Unsaturated Ligands. Mary L. Good, Stiresh Srivastava. Spectral Studies on Some New Rhodium Halide Complexes. Richard J. Thompson, Phillip W. Grayson. Some Reactions of Potas sium Hexaiodorhenate(IV) in Liquid Ammonia. Richard J. Thompson, James L. Booker. The Ammonolysis of Rhe nium (III) Chloride in Liquid Am monia.
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THURSDAY AFTERNOON
Katheryn E. Lawson, Bruno Morosin. The Configuration and Electronic Absorption Spectra of Tetrachloroand Tetrabromocuprate Ions. F. H. Kruse, Katheryn E. Lawson, Bruno Morosin. Vibrational Analysis of Trivalent Metal Acetylacetonates. Jacob A. Seaton, Charles R. Gates. The Behavior of Some Transition Metal Acetates in Acetic Acid. Robert F. Krug. Ion-Ion Interac tions in Aqueous Solution. B. Zane Egan, Ralph A. Zingaro. Extraction of Alkali Metals by Sub stituted Phenols. Buddhadev Sen, David C. Shuman. Ligational Thermodynamics of Some Metal (II) Phenyl 2-Pyridyl Ketoximates.
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FRIDAY AFTERNOON
Symposium: Recent Developments in Inorganic Chemistry John H. Burns. Recent Develop ments in the Chemistry of Noble Gases. R. N. Meals. Recent Developments in the Chemistry of OrganosiHcon Compounds. R. A. Laudise. Recent Develop ments in Crystal Growing Techniques. R. V. Harrington. Recent Develop ments in the Chemistry of Glass.
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PHOSGENE
FRIDAY MORNING
A. H. Cowley, S. T. Cohen. Reac tions of Phosphorus Iodides. A. H. Cowley, W. Dexter White. The Chemistry of the Diphosphine Di sulfides. Peter L. Timms, D. D. Stump, Thomas C. Ehlert, R. A. Kent, John L. Margrave. The Chemistry of Sili con Difluoride. A. W. Cordes, Bi-Cheng Wang. The Role of the Lone Pair of Electrons in the Stereochemistry of -j-4 Selenium. Louis C. Cusachs, Barbara B. Cusachs. Molecular Orbitals for General Polyatomic Molecules. Richard J. Thompson, Ronald H. Gore. Some Influences of Ligand Sub stitution on Absorption Spectra.
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Aubrey R. McKinney. Oxidation Protective Coatings for Carbon Structures for Service in Air to 4000° F . Claude P. Béguin, D. G. Vickroy, Adli S. Kana'an, John L. Margrave. Chemical Svnthesis in Plasma Arcs. William C. McGavock, Robert W. Martin. Cede Sulfate Oxidation of Hypophosphite in the Presence of Phosphite. R. C. Compton, J. J. Lagowski. Metal Derivatives of the Borazines. T. D . George, W. W. Wendlandt, M. W. Nathans. The Nonisothermal Kinetics of the Thermal Dissociation of Polyhalite. W. W. Wendlandt, C. H. Stembridge. The Solid-State Reaction Between [Cr(en) 3 ] X 3 and MX and NH 4 X.
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Organic Chemistry THURSDAY AFTERNOON
Symposium: Heterocyclic Chemistry A. I. Meyer, J. C. Getson, G. GarciaMunoz. Reduction of 5,6-Dihydro-l,3-Thiazines to m-Thiazines with Sodium Borohydride. Manfred G. Reinecke, Louis R. Kray. C-Methylation of Pyridines by Primary Alcohols and Raney Nickel. K. D . Berlin, M. Khayat, L. A. Wilson, D . E. Gibbs. Reaction of Phosphorus Azides with Electron-Rich Olefins. J. H. Stephenson. Preparation and Reactions of Some Tris-N-Acyl Aziridines. M. W. Hanson, Ε. Ν. McElrath. Transmission of Substituent Effects in Benzo ( b ) thiophene and Benzofuran. Raymond N. Castle. Nitrogen Heterocycles with Two Nitrogen Atoms Adjacent in a Heterocyclic Ring.
FRIDAY MORNING
A. C. Oehlschlager, L. H. Zalkow. The Reactions of Bicyclo (2.2.1) Heptene and Bicyclo (2.2.2) Octene with Ν, Ν-DibiOmobenzenesulfonamide. G. W. Griffin, J. Covell, R. C. Petterson. The Photochemistry of Cyclo propane Derivatives. E. S. Lewis, J. M. MacDonald, K. Witte. Transition State Polarity in Some Gas Phase Ester Reactions. K. D. Berlin, Robert Hanson, M. H. Cooper. Reactions of the Dianion Ketone with 2 ? 2,4-Trimethyl-3-hydroxy-3-pentenoic Acid ^-Lactone. Adam M. Aguiar, Harriet Aguiar, Donald Daigle, Robert Farmer, Keith Hansen. Vinyl Tertiary Phosphines: Reactions Demonstrating Electron Delocalization. William B. Smith, Ben A. Shoulders. The NMR Spectra of a Series of 9,10Bridged Anthracenes.
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FRIDAY AFTERNOON
John Schneller, James G. Traynliam. Solvolyses of Some Medium Ring Halohy drins. Meiling T. Yang, James G. Traynham. An NMR Study of Some A7-Nitrosoamines. William C. Herndon, Charles R. Grayson. Retro-Diels-Alder Reaction of e-ncZo-Dicyclopentadiene. Walter H. Corkern, Arthur Fry. Rearrangement of Aliphatic Ketones on Supported Acidic Catalysts. W. H. Starnes, Jr. Concurrent Carbon-to-Oxygen Rearrangement Cyclization and Decarboxylation in the Re action of 3,3,3-Triarylpropionic Acids with Lead Tetraacetate. James E. Kmiecik. The Reductive Coupling of Aromatic Nitro Com pounds by Carbon Monoxide.
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AMERICAN CHEMICAL SOCIETY ANNOUNCES 3 NEW TITLES IN THE
ADVANCES IN CHEMISTRY SERIES HO. 4 2 / BORON-NITROGEN CHEMISTRY contains thirty-two papers presented at the BoronNitrogen Chemistry Symposium sponsored by the U. S. Army Research Office—Durham. These papers contain contributions from many subdisciplines of chemistry and emphasize the close collaboration of classical chemistry with advanced techniques and modern theoretical treatments. Laubengayer's synthesis of B-trichloroborazine, which tended to replace high vacuum techniques by more classical approaches, and the use of spectroscopy as a tool for explaining structures and mechanisms, stimulated by the work of Goubeau and his school, are two major advances which have influenced the growth of research in boron-nitrogen chemistry. Both of these leaders along with M. F. Lappert, W. N. Lipscomb, M. Kubo, and M. J. S. Dewar are represented. 330 Pages, cloth bound $7.50
study of wettability, and other areas. 389 Pages, cloth bound $8.00 No. 44/AMINO ACIDS AND SERUM PROTEINS Perhaps more individuals are concerned with amino acid and protein research than any other area of biochemistry not only from the standpoint of nutrition and nutritional and physiological effects, but the growing evidence of a possible link to the senetic code AMINO ACIDS ANDSERUMPROTEINSisbased on the Richard J. Block Memorial Symposium, organized by the Division of Biological Chemistry of the American Chemical Society. The 10 papers by 20 contributors reflect work at the frontier of today's research activity in amino acids and protein chemistry. 154 Pages, cloth bound $5.50 AMERICAN CHEMICAL SOCIETY Special Issue Sales 1155 Sixteenth Street, N.W. Washington, D.C. 20036
No. 43/CONTACT ANGLE, WETTABILITY, AND ADHESION This is the largest and best collection of up-to-date papers giving both theoretical and practical ap proaches to wettability and adhesion—a subject important to many areas of science and technology. Papers report the latest work, survey progress, and suggest new directions for research and application. Moreover, the papers are sufficiently current and broad in scope so as to include thoughtprovoking, controversial points of view. Some papers deal with the chemical structure of solid surfaces, solid-fluid interfacial tensions, and flow in capillaries as related to contact angle discussed in other papers. Still others explore adhesion theories, thermodynamics of wettability, chemisorption, coadsorption on metals, spreading of oils on surfaces and its prevention, a computer 108
C & ΕΝ
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Please send me copies of the books in the Advances in Chemistry Series which I have checked below: copies of BORON-NITROGEN CHEMISTRY, Number 42, at $7.50 each. copies of CONTACT ANGLE, WETTABILITY, AND ADHESION, Number 43, at $8.00 each. copies of AMINO ACIDS AND SERUM PROTEINS, Number 44, at $5.50 each. Additional for postage per copy: PUAS $0.10; foreign $0.15. My payment in the amount of $ is enclosed. Π Bill me. Π Bill company.
I I I I
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William T. Brady, Hubert R. O'Neal. Synthesis and Structure of Polyglyoxal. Donald R. Larkin. The Vapor Phase Catalytic Dehydrogenation of 1,6Hexanediol. Donald B. Miller. Reaction of Trialkylaluminums with Halohydrocarbons. Replacement of Halogens by Alkyl Groups. David E. Hoiness, Virgil Tweedie. The Behavior of Certain Organic Com pounds in the Presence of Tita nium (II) Chloride. John B. Daffin. A New Procedure in the Preparation of Alkyl £-Butyl Sulfides. James C. Cox, Jr. A Study of the Reaction of Nitrosyl Chloride with Amines. Lyman R. Caswell. Acylation of Amines with Thiolacids and Acyl Sul fides. Physical Chemistry THURSDAY AFTERNOON
James R. Johnson, Sherril D. Chris tian, Harold E. Affsprung. SelfAssociation and Hydration of Phenol in Benzene and in 1,2-Dichloroethane. George W. Murphy, Bill B. Arnold. Studies on the Electrochemistry of Carbon. J. T. Truemper. The Adsorption of Aromatic Compounds from the Aqueous Solution by Activated Car bon. William H. Wade, Shiichiro Teranishi, Jack L. Durham. The De hydration of Ethanol on Aluminas of Various Particle Sizes. William H. Wade, Shiichiro Teranishi, Jack L. Durham. Surface Acidity of Aluminas by Microcalorimetric Method. James L. Pauley, T. Chen, A. Ghodstinat. Ion Exchange Processes in Aqueous Dimethylformamide Mix tures. Lee G. Pedersen, Richard N. Porter. Nondiatomic Contributions to the Po tential Energy of H 3 and H 3 + .
Richard M. Hedges. SCF MO Cal culations. Owen C. Hofer, R. M. Hedges. The Electronic Spectrum and Struc ture of the Bis(2,2'-biphenylene) Methane. FRIDAY MORNING
Aubrey J. Serewicz, B. Ken Robert son, Edward A. Meyers. Crystal Struc ture of Pyridine Hydrogen Nitrate. Richard F. Copeland, Edward A. Meyers. The Application of Various Weighting Schemes to the Least Squares Refinement of Crystal Struc tures. W. Gant McPherson, B. K. Robert son, Edward A. Meyers. The Crystal Structure of Some Halogenobismuthate Complex Compounds. L. Μ. Trefonas, Richard Majesté. Crystal and Molecular Structure of 7- ( p-Iodobenzene-sulf onyl ) -7 - A z a b i cyclo (4.1.0.) heptane. D. F. Burow, J. J. Lagowski. Some Spectrophotometric Observations on Dilute Metal-Ammonia Solutions. Rudolph A. Schroeder, Edward J. Adam. An Infrared Absorption Study of Several Metal Chelates of 1-Nitroso2-naphthol and 2-Nitroso-l-naphthol. Rudolph A. Schroeder, Lyman L. Lyons. An Infrared Absorption Study of Inorganic Aluminates.
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Edward A. Boudreaux. The Reflectance Spectrum and Electronic Structure of Solid Anhydrous C u ( N 0 3 ) 2 . Norman D . Heitkamp, Alfred Danti. Far-Infrared Spectroscopy and Hindered Rotation. Dale K. Cabbiness, Edward S. Amis. A Spectrophotometric Study of the Ferric and Nickelous Chloranilate Complexes. W. E. Wentworth, Edward Chen. Detailed Investigation of a Pulse Sampling Technique for the Measurement of Molecular Electron Affinities. W. E. Wentworth, Walter Hirsch. Possible Correlation Between Η Bond ing of Alcohols, Phenols, and Naphthols and Electron Attachment Meas urements with Thermal Energies. A. Ray Hilton, Charlie E. Jones, Maurice J. Brau. Ternary Nonoxide Glasses Containing Group IVA, VA, and VIA Elements. Charlie E. Jones, A. Ray Hilton. Mechanical Damage to Gallium Arsen ide Surfaces as Determined by In frared Reflection. SATURDAY MORNING
J. O. Wear, Ν. Κ. Shastri, Edward S. Amis. The Kinetics of the Oxida tion of U(IV) by N p ( V ) in AqueousChloride Medium. W. C. Gardiner, Jr. Ignition Delay in the High-Temperature HydrogenOxygen Reaction. M. S. B. Munson. Mass Spectrom etry and Mechanisms of Ionic Reac tions.
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Will M. Oillison, Robbin C. Anderson. Thermal Reactions of an Octatriyne. George Gorin, Gavin Doughty. Equilibria in Some Mercaptan-Disulfide Interchange Reactions. George Gorin, Avinash K. Rangra. Restricted Diffusion Through Membranes. Richard A. Kent, Thomas C. Ehlert, John L. Margrave. The Stabilities of Transition Element Monofluorides and Difluorides. Student Affiliate SATURDAY MORNING
Rex L. Bunkley, Alfred Danti. Nuclear Magnetic Resonance Studies of Hydrocarbons. Ralph W. Harker, John B. Entrikin. Investigation of Benzyl Amine as a Derivatizing Agent for Carboxylic Acids. Ross C. Ahlstrom, James C. Cox, Jr. The Leuckart Reaction: Reactivities of Cyclic Amines with Cyclohexanone. Kamie Law, T. J. Bond. Comparison of the Endosuccinate Derivatives of 1,2-Benzanthracene as Inhibitors of Growth of L. casei. Fred Tibbals, Thomas C. Franklin. Effect of Organic Additives on Cadmium Deposition. Diane Willenbrock. The Solubility of Calcium Sulfate in Ionic Solutions of Varying Strengths. Evangelina Zubiate. The Isolation of DNA from a Lymphatic Leukemia Tumor. Mary Ann Vering. The Isolation and Detection of Aflatoxin in Peanuts. Frances King. The Reduction of the Permanganate Ion with Calcium Hydride. Ariadne Thomas, Sister Mary Daniel. A Study of Some Chemical Properties of p-Aminophenylmercaptoacetic Acid. Doretha Rainey. The Separation of Lipides by Silicic Acid Chromatography. Julia Tung, Mary Ann Gelder. Qualitative Analysis of Steroids by Thin-Layer Chromatography. Sister M. Albert, Maria' Hinojosa. The Extraction of Vacuolar Flower Pigments. Diane Willenbrock. A Qualitative Separation of Rare Earth Salts.
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C&EN
NOV. 9, 196 4
Applications of Fundamental Thermodynamics to Metallurgical Processes is the topic of a conference to be held at the Center for the Study of Thermodynamic Properties of Materials at University of Pittsburgh, Nov. 29 to Dec. 1. A program of about 21 papers will be given. The conference address will be given by Dr. O. Kubaschewski of National Physical Laboratory in England.
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New York Academy of Sciences will sponsor a conference on Antiviral Substances at the Waldorf-Astoria, New York City, Dec. 9 to 11.
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The Third Caribbean Chemical Symposium will be held in Caracas, Venezuela, Jan. 4 to 9. The meeting will feature a series of plenary lectures by invited eminent speakers, and sessions of other papers under the headings of analytical, inorganic, organic, and physical chemistry and biochemistry. If enough papers are received in a more specialized field—for example, natural products, mechanisms, polymer chemistry, or radiochemistry— these will be grouped into separate sessions. Abstracts of papers will be available to participants at the time of registration. Official languages of the symposium will be Spanish and English. Write the Secretary, Third Caribbean Chemical Symposium, Department of Chemistry, IVIC, Apartado 1827, Caracas, Venezuela, for further details. CALENDAR OF EVENTS
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American Chemical Society 149th National Meeting. Detroit, Mich. April 4-9,1965. 150th National Meeting. Atlantic City, N.J. Sept. 12-17, 1965. 151st National Meeting. Pittsburgh, Pa. March 22-31, 1966. Eastern Analytical Symposium and Instrument Exhibit. Statler Hilton Hotel, New York, N.Y. Nov. 11-13 (C&EN, Oct. 5, page 74). ACS Division of Industrial and Engineering Chemistry. 31st Annual Chemical Engineering Symposium. Ann Arbor, Mich. Nov. 12-13. (C&EN, Oct. 12, page 86). ACS 20th Annual Southwest Regional Meeting. Captain Shreve Hotel, Shreveport, La. Dec. 3-5. ACS Pacific Southwest Regional Meeting. Orange Coast College, Costa Mesa, Calif. Dec. 5.
NOVEMBER 9,1964 these items were added to the famous list of
EASTMAN 9171
Cyanogen Iodide
25 g. $ 7.60
ICN . . . MW 152.92
8951
100 g.
1,4-Diethoxybutane BP 163-164°
P6740
5483
6.75
100 g.
24.35
Diethyl Methyloxalacetate (Pract.) BP 103-105*75 mm
10 g.
4.45
C 2 H 5 OCOCH(CH3)COCOOC 2 H 3 . . . MW 202.21
25 g.
9.60
Dimethyl Fumarate MP 104-105° CH 3 OCOCH:CHCOOCH 3 . . . MW 144.13
9225
Octylamine Hydrochloride CH 3 (CH 2 ) 7 NH 2 -HC1... MW 165.71
9036
27.80
25 g.
C 2 H r ) 0(CH 2 ) 4 OC 2 H 5 . . . MW 146.23
Other Organizations Chemical Market Research Association and Chemical Institute of Canada. Queen Elizabeth Hotel, Montreal, Que. Nov. 17-18. Manufacturing Chemists' Association. Semiannual Meeting and Midyear Conference. New York, N.Y. Nov. 24. Synthetic Organic Chemical Manufacturers Association. Annual Meeting. Hotel Roosevelt, New York, N.Y. Dec. 3. American Institute of Chemical Engineers. 55th National Meeting. Statler Hotel, Boston, Mass. Dec. 6-10. Chemical Specialties Manufacturers Association. 51st Annual Meeting. Chalfonte-Haddon Hall, Atlantic City, N.J. Dec. 7-9. American Association for the Advancement of Science. Queen Elizabeth Hotel, Montreal, Que. Dec. 26-30.
Organic Chemicals:
Silver Cyanide A g C N . . . MW 133.89
25 g.
4.50
100 g.
15.35
25 g.
2.90
100 g.
8.95
5 g.
2.55
25 g.
8.20
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NOV.
9, 1 9 6 4
C&EN
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Men and Molecules... . . . released for broadcast after Nov. 6 is titled "A Superconductor Called Niobium 3 T i n " and features Dr. J. E. Kunzler of Bell Laboratories. See "ACS on the Air" listings beginning on page 129 of C&EN for Oct. 26 for stations broadcasting in your area. Each week C&EN announces here the "Men and Molecules" program to be released the following Friday. This may not be the specific program to be carried on your station at the time listed, however; a number of different programs are constantly in circulation. Call your local station to find out when specific programs you are interested in will be broadcast.
Society of Chemical Industry (road and building materials group) will sponsor an International Symposium on Autoclaved Calcium Silicate Building Products in London, May 18 to 21, 1965. Topics will include chemical, physical, and mechanical properties of the hydrous calcium silicates; manufacture of calcium silicate building products; and design, properties, and behavior of building structures (including industrialized unit construction) in these materials.
The 11th German Synthetic Products Conference will be held May 4 to 6, 1965, at Lubeck-Travemunde, Germany. Write Arbeitsgemeinschaft, Deutsche Kunststoff-Industrie, Karlstrasse 21, 6 Frankfurt am Main, Germany, for further information.
The 13th Annual Conference on Mass Spectrometry and Allied Topics, arranged by officers of Committee E-14 on Mass Spectrometry of the American Society for Testing and Materials, will be held at the Sheraton-Jefferson Hotel in St. Louis, Mo., May 16 to 21, 1965.
American Association for Contamination Control will hold its fourth annual technical meeting and exhibits at Miami Beach, Fla., May 25 to 28, 1965. The meeting will be open to all interested in the technology of the control of contaminants in closed systems of gases and liquids. Open forums will be presented daily. 114
C&EN
NOV. 9r 196 4
The Properties and Uses of Plasma is the subject of a conference to be held July 19 to 21, 1965, in Moscow, U.S.S.R. Sponsor is the International Union of Pure and Applied Chemistry. The program of technical papers will be roughly divided into the physics and chemistry of plasma and the potential ways in which plasma can serve mankind. Titles of proposed papers should be received by the corresponding secretary for one's country by Dec.
15, abstracts by Feb. 1, and final papers by May 15. The corresponding secretary for the U.S. is Dr. E. S. Starkman, College of Engineering, University of California, Berkeley, Calif. Scope of the papers is intended to cover plasma above the normal flame temperature range so that for the purposes of the conference a working definition of plasma would be when there is substantial ionization, for example more than 1%.
ACS LOCAL SECTIONS PLACE
Akron. Dining Hall, Student Center Bldg., University of Akron Central Arkansas. Officers' Club, Pine Bluff Arsenal, Little Rock Central North Carolina. A&T College, Greensboro Central Pennsylvania. Pennsylvania State University, University Park Central Texas. Faculty Lounge, Student Bldg., Southwestern University, Georgetown Chattanooga. Du Pont Co. (Ladies' Night and Plant Tour) Chicago. Furniture Club of America ( Chemical Literature Group )
Nov.
Hampton Roads. Science Bldg., Old Dominion College. Norfolk, Va. Idaho. Bov Scout Headquarters Bldg., Idaho Falls Indiana. Medical Science Bldg., Indiana University Medical Center, Indianapolis Louisville. Stouffer's Inn, Louisville, Ky. Inland Empire. Plantation Restaurant, Spokane, Wash. Joliet. East Junior High, Kankakee, 111. Maryland. Eudowood Gardens, Eudowood Plaza Shopping Center (Third Annual Maryland Chemist Award) Michigan State University. Kedzie Chemical Laboratory, East Lansing Midland. Auditorium, Dow Chemical Co. Milwaukee. Elks Club ( Milwaukee Section Award ) Montana. Room 216, Metallurgy Bldg., Montana School of Mines, Butte New York (Westchester Chemical Society Subsection). Boyce Thompson Institute, Yonkers North Jersey (Central Subsection ). Elizabeth Carteret Hotel, Elizabeth, N.J.
SUBJECT
Herman R. Felton
Preparative Scale Gas Chromatography
17
Jack Wood Sears
Biological Individuality
19
Donald D. DeFord
18
Philip S. Skell
Column Efficiency in Gas Chromatography Bridged Free Radicals
18
W. A. Noyes, Jr.
Photochemical Sensitization
19
C. H. Rutledgc
20
Gilford W. Crosby
Fibers, Fabrics, Females—and Other Factors, if Any Chemicals in the Automobile Industry A Universal Approach to Computer Processing of Patent Records Developing a Marketing Program
Frank Liska John J. Pétrie
(Chemical Marketing and Economics Group) ( Education Group ) ( Organic Group ) Cincinnati. Cleveland. Cleveland Engineering and Scientific Center Colorado. Olin Hall, Colorado College, Colorado Springs Columbus. New Chemical Abstracts Bldg., Columbus, Ohio Dallas-Fort Worth. Detroit (Blue Water Subsection). Room 219, Port Huron Junior College, Port Huron, Mich. Detroit (Flint Subsection). Gorman Bldg., Flint Community Junior College, Flint, Mich. Eastern New York. New York State University, Albany Erie. Room 209, Mercyhurst College, Erie, Pa. Florida (Miami Subsection). Richter Memorial Library, University of Miami, Coral Gables Florida (Tampa-Bay Subsection). Florida Presbyterian College, St. Petersburg Georgia. Cox Hall, Emory University, Atlanta
SPEAKER
19
Robert A. Alberty Ernest L. Eliel 17 10
New Trends in Education Recent Advances in Conformative Analysis ACS ^ YOU Education and the ChemistToday and Tomorrow Materials Problems in Energy Conversion ACS τ* YOU
19
M. H. Arveson J. S. xMillis Louis Gordon Clinton M. Kelley
16
M. H. Arveson
19
W. A. Noyes, Jr.
17
J. Arthur Campbell
18
J. Arthur Campbell
18 19
G. L. Closs Nathaniel Brenner
19
Donald E. Andrews
17
Phillip Fergusen
20
Eugene C. Ashby
18
Donald D. DeFord
20
Philip S. Gentile
19
M. H. Arveson
18
M. H. Arveson
ACS
18
Philip S. Gentile
17
Joseph Richardson
Dissociation and Stability stants in Mixed Solvents Mathematics Today
18
Alsoph H. Corwin
Colors of Life
19
J. Arthur Campbell
The New Science Progress and/or Change in Col lege Chemistry The Problems and Perils of a Chemist in Business Dissociation and Stability Con stants in Mixed Solvents
Progress and/or Change in Col lege Chemistry The New Science Synthesis and Properties of Some Unusually Strained Compounds Analytical Applications of Dif ferential Scanning Calorimetry Symmetry Properties of Organic Molecules The Chemistry of Aryl N-NitrosoAmides The Composition of Grignard Compounds and the Mech anisms of Their Reaction with Ketones Column Efficiency in Gas Chro matography Complexes via Solid-Solid Inter action ACS ^ YOU ^
YOU Con
16
J. Arthur Campbell
20
H. A. Pinkalla
19
Philip S. Gentile
19
Elliott N. Shaw
A New Approach to the Study of Enzyme Active Centers
17
Samuel S. Ristich
Insect Sterilants—Recent Chemical and Biological Advances
Continued on page 144
ANALYTICAL CITEMTST: Ph.D. STRONG in physical a n d electrochemistry. F i v e years managing modern industrial instrumental labora t o r y characterizing high t e m p e r a t u r e o r g a n i c a n d inorganic m a t e r i a l s . T e n years professor a n a l y tical c h e m i s t r y and i n s t r u m e n t a l m e t h o d s of analysis. P u b l i c a t i o n s . N o r t h e a s t IT. S. Box 3 1 6 - F - l l , C. & Ε . Ν . . E a s t o n , P a , LITERATURE SCIENTIST: M.A., P h . D . organic c h e m i s t r y . Courses in information science. Experience in l a b o r a t o r y . L i t e r a t u r e searching, report writing, t r a n s l a t i o n s F r e n c h a n d G e r m a n , a b s t r a c t i n g , indexing. Box'307-F-ll, C. & Ε . N., Easton, P a . ITALIAN CHEMIST (DOCTOR DEGREE U n i v e r s i t y of M i l a n ) . Six y e a r s l a b o r a t o r y e x perience r a d i o c h e m i s t r y - i n o r g a n i c c h e m i s t r y , seeks a t e a c h i n g a n d / o r research position in U.S.A. or C a n a d a . Good knowledge of English a n d F r e n c h . P u b l i c a t i o n s and references. Box 3 0 2 - F - l l , C . & Ε . Ν . , E a s t o n , P a . O R G A N T C T C H E I M I S T T Ph.rTT E X T E N S I V E experience in synthesis, isolation a n d s t r u c t u r e d e t e r m i n a t i o n of steroids, o t h e r n a t u r a l p r o d u c t s and p h a r m a c e u t i c a l s . G r o u p leader. M e m b e r of university faculty. I m a g i n a t i v e , s t i m u l a t i n g , e n e r getic, resourceful and p r o d u c t i v e . Desires r e sponsible position in. research i n s t i t u t i o n , u n i versity or i n d u s l r y . Box 312-L-10, C . & Ε . Ν . . E a s t o n , P a .
SITUATIONS WANTED Retired Chemists and Chemical Engineers R E T I R E E A G E 65: C H E M I S T , M E M B E R New Y o r k B a r , registered p a t e n t a t t o r n e y ; m a n y y e a r s supervisor large l a b o r a t o r y d e p a r t m e n t ; p a s t t e n years principal, liaison, officer between research a n d p a t e n t d e p a r t m e n t m a j o r oil c o m p a n y . Excellent h e a l t h a n d vigor. Box 3 0 7 - H - l l , C. & E . N . , E a s t o n , P a .
ACS LOCAL SECTIONS (Continued from page 114) North Jersey (Lackawanna Sub section), Warner Lambert Pharmaceutical Co., Morris Plains, N J . N o r t h J e r s e y ( P a s s a i c Valley S u b section). R o o m 1 5 5 . Mallory H a l l , M o n t c l a i r S t a t e College, Upper Montclair, N.J. Northeast Oklahoma. Audito r i u m , U . S . B u r e a u of M i n e s , Bartlesville Northeast Tennessee. Ridgefields Country Club, Kingsport ( Ladies' Night) N o r t h e a s t W i s c o n s i n . St. N o r b e r t College, W e s t D e P o r e Northeastern (Analytical G r o u p ) . Room 2 - 1 3 1 , M I T , C a m b r i d g e , ^ Mass. Northeastern (Elastomer and Plastics G r o u p ) . Hornblower Room, Museum of Science, Boston, M a s s . Northeastern (Medicinal Chem istry Group). Auditorium, Arthur D . Little, Inc., Acorn Park, Mass. Northeastern Indiana. IUPU Regional Campus. Fort W a y n e Northeastern Ohio. Mentor Lounge Restaurant, Route 20, Mentor O k l a h o m a . Central State College, Edmond Orange County. Coda's Restau r a n t , B u e n a P a r k , Calif. Panhandle Plains. Penn-Ohio Border. Chemistry Bldg., Grove Citv College, G r o v e City, P a . P h i l a d e l p h i a . University Museum
16
F. T. Manheim
Chemistry a n d Oceanography
19
Arnold Brassi
I s o q u i n o l i n e C a c t u s Alkaloids
17
S. I . W e i s s m a n
17
A . B. G a r r e t t
S t u d i e s of Rates a n d M e c h a n i s m s of C h e m i c a l Processes by M a g netic Resonance Spectroscopy F l a s h of G e n i u s
17
Jacob Shapiro
18
Evan H. Appelman
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