Synthetic Resins and Rubbers - C&EN Global Enterprise (ACS

Many of the new developments in this field are used principally in materials of war, and their composition cannot be revealed now. Some of the trade m...
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Synthetic Resins and Rubbers P A U L O . P O W E R S , Armstrong C o r k C o . , Lancaster, P a .

are listed. For brevity, no attempt has been made to include all of these nor company trade marks ordinarily associated with more than one type of resin. The formulas of the polymers are abbreviated and are not neces­ sarily entirely accurate. They are believed to represent the most characteristic unit of their structure.

T H I S chart is a revision of an earlier chart [CHEM. E N G . N E W S , 20,

536 (1942)] but resins from natural products have not been included. Many of the new developments in this field are used principally in materials of war, and their composition cannot be revealed now. Some of the trade marks or trade names designating the resins

CONDENSATION

POLYMERS

CI H C-O H-

NaOH„ or H 2 0 CHLOROBENZENE

BENZENE

PHENOL •NH

NH, CARBON

AMMONIA

DIOXIDE

C o=c:

CARBIDE

C«°

NAPHTHALENE

PHTHAL1C

ANHYDRIOE

c=o

Ir-NH

H

» > H C-C-o MALEIC

C YC LOPE Ν Τ A D Ι Ε Ν Ε

A Ν HYO RI DE

0 /

C3H5i00CCf7H320HJ3

->

CASTOR OIL

HOC\CH^ SEBACIC

Να O H

l-UNC ^ C N H2^ 1 1 | N.C,N HNH ME L A M I N E H HCOH HCOH HCOH H GLYCEROL

m

HC-C'°

Ρ 4c

"AD D U C T "

Jn

ACID

LfNOLEIC

H HCOH HÇOH HCOH H GLYCEROL

Nv

Ν

Η



I η

Ρ f? H H H — c c-o-c-c- c - o - l / ~ \ HφΗ LfNOLEIC

_K£L7

ACID

O:CCI7H3(

η

CARB1C -'•

RfCHj8.O-li-Ç.8.0 8,tB.o—1 RlCTNOLEfC

H Ο Η 0:CCl7H32OHjn

-

PARAPLEX

ACID

Ο

HH HH

Ί

J n

PARAC Ο Ν

Ο

Γ"θ Ο HA H~I Η2Ν(0Η2)^ΝΗ2-> R C H ^ C - N [ c f ^ N ^

+-

ACID

,9 2ô

GLYCOL

«OC(CH^COH ADIPIC

ι

— Ç _ Ç - 0 O C - C- O — W Ο Η .~ 0:CC|7H3, j n GLYPTAL. ReZYL. OURAPLEX.

ACID

C,7H32OHCOOH

εTHYLENε

ADIPAMIDE

ι)

M E W C , RES1MENE Ρ HH H

°

9f

^NClc^^CN^

CYCLOHEXANOL

H FORMALDEHYDE

L

OH

^

e*o

-f

εεβΑοιο ACID >I J

H jgvN H H -NC CN-C

H +

H rfÇOH HÇOH HCOH H GLYCEROL

Ο COH+

(cHgJpCOOH 2' 8

CASTOR OIL

PHENOL

D U R E Z , RES INOX Ν—C 1 QIC «

H

2

UREA

C5N NH2 CYANAMIDE

N,

Hg

n

FQRMALDEHYDE

FORMALDEHYDE

oo

8

C-

H E X A M E T H Y L E N E DCAMfNE

NYLON

Η HOCH ETHYLENE

IO

Η

2

CH CI 2

Η Η -^» C I C Η ETHYLEΗ NE

Η

c=c

Η ETHYLENE

CHLOROHYDRIN



DfCHLORfDE

VINYL H

12

0 BENZENE

GASES

SODIUM

TETRASULFIDE

POLYMERS L H H_jn POLYTHENE H H " CH

H

ETHYLENE

në-cS

8=8 H

H

ETHYLENE

1992

CARBOWAX Ν«2 S+

-c cr

Η Η ETHYLENE

CRACKED

B-U-^n OXIDE

-

0"

ETHYL

COPYfMGHT,

ë=ë -> BENZENE

STYRENE

194 4~ By Ρ Q

Π S T Y R O N . LUST R O N

POWERS

CHEMICAL

A N D ENGINEERING

Ν ΕW S

13

f-i^s—ι

HCH

L0

Θ

yS P I N E NE

TURPENTINE

P1CCQLYTE

CH3

.

>CH

2

Π COAL

TAR

15

DISTILLATES

I H;C-CH

3

H C= H

C H3,

/

^ 33 Η I C—C Η I CH3

I

Η

C H 3 C2N CYANOHVDAW CM3COOH

CH, AC HE CTrO CNHE ^

ACETIC

ACETYLENE

I8

t

Η Η -C— CH Ο

H

H

H

Ο

- c - c -

L Q-C-CH3 Iη POLYVINYL Η Η C=C Η Η ETHYLENE

POLYVINYL

ACETATE

(>o OCH,

oc

,L

METHANOL

ACID

Π

_

VISTANEX

X

c=o \

19

C H .3 -C I CH3

I.SOBUTYLENE

ISOBUTANE

17

CUMAR,NEVINDENE, P i C C O

COUMARONE

^Jn

METHYL METHCRYLATE H H CH3C-0-C=g

"PLEXIGLAS, LUCITE

VINYL

GELVA.VINYLITE A

Η

Η

Π

-s-H

ACETATE

H H H H

Ί +.

"n

-c-c-c-c— I H Ο HO Ι

C3H7C=0

H>cc3H7Jn ALCOHOL

Η Η C Ι C—C C Ι Η Η ETHYLENE DfCHLORIDE

BUTYRALDEH YOE

SAP LEX, Β UTACÎ T E , VINYLÎ TE X

Η Η C= C Η α V I N Y L CHLORIDE

GEON,

KOROSEAL

20 Η

HCFCH

Η Η

VINYL

ACETYLENE

Η Η C=C-C=C H CI H H



c=c-c-c ACETYLENE

P-C^C-CC] L_H α Η H_Jh

CHLOROPRENE

NEOPRENE,

GR-M

VINYL COPOLYMERS Η Η C=rC. Η Η

Cl H H C—C H Cl Cl

-^ l,f,2

ETHYLENE

H Cf C= C H - CI

TRfCHLOROETHANE

22

VINYLIDENE

H H C=C H Cl

SEE

VINYL

C 7 Α. 19

CHLORfDE

VINYL

H CI H H i C-C-C-CH CI H C j j n

VINYL CHLORIDE

fr

H H H H H H - C - C - •C CC -- C Ç— - CC-- C Ci H ο H Cl 0 = C C H .'3 —1 VINYLITE V

H H C=C H Ο O-CCH3

CHLORIDE

E

H H C= C H CI

ACETATE

23 H H H O C — C CÎ 4 ·

NdCN — *

H HOC H

H CCSN H

HYDRACRYLIC

CHLOROHYDRIN

-4-

CH3OH

N1TRILE

H H C= C H Ç>0 O-CH3 METHYlT ACRTLATE

£=^ 3 ç-o Ô-CH3 METHYL METHACRYLATE

t

H H H C«3 C - Ç — C— Ç - = » ÇxQ Ç-O

2^

-c-o*c-c-c-

H H H H HC-C-C-Cl· H H H H

H

H H H H C=C C=C H H

H H H H HC- C-C=C H H H

STYRENE

BUTADIENE

BUTENE

BUTANE

25

ÔCH3 OCH3|n ACRYLOiD " ^ H H H H H

H HCV

H H H H C=C-C-C H H

H

GR-S

[

H

H H

H

H H

H

H

c-c=c-c-c-c— H

Τ

CSNjn

H ETHYLENE

26

BUTADIENE

ACRYLONITRILE

OXIDE

CH,

0

H

H

CH, I H

H

c=c I H

c=c-c-c

CH-

CH^CH2

ISOBUTYLENE

ISOPRENE

DfPENTENE

COPYR/GHT, 1944,

V Ο LUME

2 2, N O .

22*NOVEMBER

2 5,

HYCAR O. R., C HE M l GUM PERBUNAN, RJ TAP RE NE

ÇR 3

H H H ' H - C - C = C - C - G- C H CH, î H CH3_ BUTYL,

,

GR- ί

BY Ρ Ο. POWERS.

1944

19-93