Synthetic Resins and Rubbers P A U L O . P O W E R S , Armstrong C o r k C o . , Lancaster, P a .
are listed. For brevity, no attempt has been made to include all of these nor company trade marks ordinarily associated with more than one type of resin. The formulas of the polymers are abbreviated and are not neces sarily entirely accurate. They are believed to represent the most characteristic unit of their structure.
T H I S chart is a revision of an earlier chart [CHEM. E N G . N E W S , 20,
536 (1942)] but resins from natural products have not been included. Many of the new developments in this field are used principally in materials of war, and their composition cannot be revealed now. Some of the trade marks or trade names designating the resins
CONDENSATION
POLYMERS
CI H C-O H-
NaOH„ or H 2 0 CHLOROBENZENE
BENZENE
PHENOL •NH
NH, CARBON
AMMONIA
DIOXIDE
C o=c:
CARBIDE
C«°
NAPHTHALENE
PHTHAL1C
ANHYDRIOE
c=o
Ir-NH
H
» > H C-C-o MALEIC
C YC LOPE Ν Τ A D Ι Ε Ν Ε
A Ν HYO RI DE
0 /
C3H5i00CCf7H320HJ3
->
CASTOR OIL
HOC\CH^ SEBACIC
Να O H
l-UNC ^ C N H2^ 1 1 | N.C,N HNH ME L A M I N E H HCOH HCOH HCOH H GLYCEROL
m
HC-C'°
Ρ 4c
"AD D U C T "
Jn
ACID
LfNOLEIC
H HCOH HÇOH HCOH H GLYCEROL
Nv
Ν
Η
—
I η
Ρ f? H H H — c c-o-c-c- c - o - l / ~ \ HφΗ LfNOLEIC
_K£L7
ACID
O:CCI7H3(
η
CARB1C -'•
RfCHj8.O-li-Ç.8.0 8,tB.o—1 RlCTNOLEfC
H Ο Η 0:CCl7H32OHjn
-
PARAPLEX
ACID
Ο
HH HH
Ί
J n
PARAC Ο Ν
Ο
Γ"θ Ο HA H~I Η2Ν(0Η2)^ΝΗ2-> R C H ^ C - N [ c f ^ N ^
+-
ACID
,9 2ô
GLYCOL
«OC(CH^COH ADIPIC
ι
— Ç _ Ç - 0 O C - C- O — W Ο Η .~ 0:CC|7H3, j n GLYPTAL. ReZYL. OURAPLEX.
ACID
C,7H32OHCOOH
εTHYLENε
ADIPAMIDE
ι)
M E W C , RES1MENE Ρ HH H
°
9f
^NClc^^CN^
CYCLOHEXANOL
H FORMALDEHYDE
L
OH
^
e*o
-f
εεβΑοιο ACID >I J
H jgvN H H -NC CN-C
H +
H rfÇOH HÇOH HCOH H GLYCEROL
Ο COH+
(cHgJpCOOH 2' 8
CASTOR OIL
PHENOL
D U R E Z , RES INOX Ν—C 1 QIC «
H
2
UREA
C5N NH2 CYANAMIDE
N,
Hg
n
FQRMALDEHYDE
FORMALDEHYDE
oo
8
C-
H E X A M E T H Y L E N E DCAMfNE
NYLON
Η HOCH ETHYLENE
IO
Η
2
CH CI 2
Η Η -^» C I C Η ETHYLEΗ NE
Η
c=c
Η ETHYLENE
CHLOROHYDRIN
+·
DfCHLORfDE
VINYL H
12
0 BENZENE
GASES
SODIUM
TETRASULFIDE
POLYMERS L H H_jn POLYTHENE H H " CH
H
ETHYLENE
në-cS
8=8 H
H
ETHYLENE
1992
CARBOWAX Ν«2 S+
-c cr
Η Η ETHYLENE
CRACKED
B-U-^n OXIDE
-
0"
ETHYL
COPYfMGHT,
ë=ë -> BENZENE
STYRENE
194 4~ By Ρ Q
Π S T Y R O N . LUST R O N
POWERS
CHEMICAL
A N D ENGINEERING
Ν ΕW S
13
f-i^s—ι
HCH
L0
Θ
yS P I N E NE
TURPENTINE
P1CCQLYTE
CH3
.
>CH
2
Π COAL
TAR
15
DISTILLATES
I H;C-CH
3
H C= H
C H3,
/
^ 33 Η I C—C Η I CH3
I
Η
C H 3 C2N CYANOHVDAW CM3COOH
CH, AC HE CTrO CNHE ^
ACETIC
ACETYLENE
I8
t
Η Η -C— CH Ο
H
H
H
Ο
- c - c -
L Q-C-CH3 Iη POLYVINYL Η Η C=C Η Η ETHYLENE
POLYVINYL
ACETATE
(>o OCH,
oc
,L
METHANOL
ACID
Π
_
VISTANEX
X
c=o \
19
C H .3 -C I CH3
I.SOBUTYLENE
ISOBUTANE
17
CUMAR,NEVINDENE, P i C C O
COUMARONE
^Jn
METHYL METHCRYLATE H H CH3C-0-C=g
"PLEXIGLAS, LUCITE
VINYL
GELVA.VINYLITE A
Η
Η
Π
-s-H
ACETATE
H H H H
Ί +.
"n
-c-c-c-c— I H Ο HO Ι
C3H7C=0
H>cc3H7Jn ALCOHOL
Η Η C Ι C—C C Ι Η Η ETHYLENE DfCHLORIDE
BUTYRALDEH YOE
SAP LEX, Β UTACÎ T E , VINYLÎ TE X
Η Η C= C Η α V I N Y L CHLORIDE
GEON,
KOROSEAL
20 Η
HCFCH
Η Η
VINYL
ACETYLENE
Η Η C=C-C=C H CI H H
•
c=c-c-c ACETYLENE
P-C^C-CC] L_H α Η H_Jh
CHLOROPRENE
NEOPRENE,
GR-M
VINYL COPOLYMERS Η Η C=rC. Η Η
Cl H H C—C H Cl Cl
-^ l,f,2
ETHYLENE
H Cf C= C H - CI
TRfCHLOROETHANE
22
VINYLIDENE
H H C=C H Cl
SEE
VINYL
C 7 Α. 19
CHLORfDE
VINYL
H CI H H i C-C-C-CH CI H C j j n
VINYL CHLORIDE
fr
H H H H H H - C - C - •C CC -- C Ç— - CC-- C Ci H ο H Cl 0 = C C H .'3 —1 VINYLITE V
H H C=C H Ο O-CCH3
CHLORIDE
E
H H C= C H CI
ACETATE
23 H H H O C — C CÎ 4 ·
NdCN — *
H HOC H
H CCSN H
HYDRACRYLIC
CHLOROHYDRIN
-4-
CH3OH
N1TRILE
H H C= C H Ç>0 O-CH3 METHYlT ACRTLATE
£=^ 3 ç-o Ô-CH3 METHYL METHACRYLATE
t
H H H C«3 C - Ç — C— Ç - = » ÇxQ Ç-O
2^
-c-o*c-c-c-
H H H H HC-C-C-Cl· H H H H
H
H H H H C=C C=C H H
H H H H HC- C-C=C H H H
STYRENE
BUTADIENE
BUTENE
BUTANE
25
ÔCH3 OCH3|n ACRYLOiD " ^ H H H H H
H HCV
H H H H C=C-C-C H H
H
GR-S
[
H
H H
H
H H
H
H
c-c=c-c-c-c— H
Τ
CSNjn
H ETHYLENE
26
BUTADIENE
ACRYLONITRILE
OXIDE
CH,
0
H
H
CH, I H
H
c=c I H
c=c-c-c
CH-
CH^CH2
ISOBUTYLENE
ISOPRENE
DfPENTENE
COPYR/GHT, 1944,
V Ο LUME
2 2, N O .
22*NOVEMBER
2 5,
HYCAR O. R., C HE M l GUM PERBUNAN, RJ TAP RE NE
ÇR 3
H H H ' H - C - C = C - C - G- C H CH, î H CH3_ BUTYL,
,
GR- ί
BY Ρ Ο. POWERS.
1944
19-93