J. G. Smith, and George F. Wright. J. Org. Chem. , 1952, 17 (8), ... Donald Bethell, Philip C. Bulman Page, and Hooshang Vahedi. The Journal of Organi...
Chemistry, University of. Toronto]. THE DIÃSTEREOMERIC MENTHYL CHLORIDES OBTAINED. FROM (-) MENTHOL. J. G. SMITH and. GEORGE F WRIGHT.
Modulation of Thermoreceptor TRPM8 by Cooling Compounds. Sonali S. Bharate and Sandip B. Bharate. ACS Chemical Neuroscience 2012 3 (4), 248-267.
SANITARIUM]. MENTHOL STUDIES. 11. MENTHYL ESTERS OF THE &NITRO-. 4-CARBOXYPHENYLARSONIC AND PHENYLARSENIOUS. ACIDS.
MENTHOL STUDIES. II. MENTHYL ESTERS OF THE 2-NITRO-4-CARBOXYPHENYLARSONIC AND PHENYLARSENIOUS ACIDS. K. Lucille McCluskey.
insolubility in water caused by the menthol,the menthyl esters of the aminocinnamic acids could not be made wrater-soluble through their hydro- chlorides.
I. MENTHYL ESTERS OF THE NITRO-AND AMINOCINNAMIC ACIDS. K. Lucille McCluskey, and Ben C. Sher. J. Am. Chem. Soc. , 1927, 49 (2), pp 452â457.
MENTHOL STUDIES. I. MENTHYL ESTERS OF THE NITRO-AND AMINOCINNAMIC ACIDS. K. Lucille McCluskey, Ben C. Sher. J. Am. Chem. Soc. , 1927, 49 (2) ...
Suspension cultures of Mentha canadensis and Mentha piperita transformed added /-(-)-menthyl acetate andc/-(+)-menthyl acetate such as d-(+)-neomenthyl ...
Within 24 h most of the I-(-)-menthol was converted into 1-(-)-menthyl glucoside. Small amounts of d-(+)-menthol and d-(+)-neomenthol were also transformed ...
Conversion of menthyl acetate or neomenthyl acetate into menthol or neomenthol by cell suspension cultures of Mentha canadensis and Mentha piperita. Ute.
[CONTRIBUTION FROM TEI3 DBPT. OF G E M I S T R Y , UNIVERSITY OF TORONTO]
T H E DIASTEREORIERIC JtENTHYL CHLORIDES OBTAIKED FROlVX (-) MENTHOL J. G. SMITH
AND
GEORGE F WRIGHT
Received February 66, 1966
When (- f menthol (I) reacts with phosphorus pentachloride (1-4) a mixture (31, [a]:' -5" to - lo", of two diastereomers is obtained. If this mixture of menthyl (11) and neomenthyl (111) chlorides is treated with a dehydrohalogenating agent the less stable dextrorotatory isomer (111)is converted to menthelie more rapidly than the levorotatory isomer (11).
