THE ELECTRIC MOMENT OF n-BUTYLLITHIUM AND THE NATURE

Publication Date: December 1946. ACS Legacy Archive. Cite this:J. Am. Chem. Soc. 68, 12, 2748-2748. Note: In lieu of an abstract, this is the article'...
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2748

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mycin, 0 ; dihydrostreptomycin hydrolyzate, 1. The presence of a t least two aldehyde groups and a terminal methyl group in the central moiety, C6HBOr.< , of streptomycin, together with the lack of chemical evidence for a hydroxyl group, indicates that this portion probably possesses two carbon chains linked in a polyacetal type of structure.

character of the Li-C bond being about equal in magnitude to that of the C-F bond. n-Butyllithium was prepared by stirring a benzene solution of n-butyl chloride with an excess of lithium sand for two days. The solution was filtered and transferred to the dielectric constant cell for measurement; the apparatus and technique have been described5 previously. The R. U. LEMIEUX density was determined, and aliquots withdrawn DEPARTMENT OF CHEMISTRY W. J. POLCLASE and analyzed acidimetrically. All handling was THEOmo STATE UXIVERSITY C. W. DEWALT done in a carefully dried, all-glass apparatus, COLUMBUS, OHIO M. L. WOLFROV through which dry, oxygen-free nitrogen was conl