Zhongping Shi , Susanne Kiau , Paul Lobben , John Hynes , Jr. , Hong Wu , Luca Parlanti , Robert Discordia , Wendel W. Doubleday , Katerina Leftheris ...
How to Succeed at Scientific Collaboration | Part 1: A Cross-Disciplinary Collaboration. Late last year @ACS4Authors surveyed over 1,500 researchers on Twitter and found that 30% .
April, 1928 formation of primary amines. [Contribution from the Chemical Laboratory of the State University of Iowa]. THE FORMATION OF PRIMARY AMINES ...
April, 1028. FORMATION OF PRIMARY AMINES. 1193. [CONTRIBUTION FROM THE CHEMICAL LABORATORY. OF THE STATE UNIVERSITY OF IOWA].
THE PREPARATION OF PRIMARY AMINES FROM ALDEHYDES AND MONOCHLORO-AMINE. Charles R. Hauser. J. Am. Chem. Soc. , 1930, 52 (3), pp 1108â ...
same way as in dimethylglycol ether except for the changes ... When this method was applied to mixtures of methyl ... From the mixtures cited above there was.
Jan 1, 1993 - Chemical Research in Toxicology 2007 20 (6), 887-895. Abstract | Full Text ... Quan Yuan, Xiaochun Zhu, and Lawrence M. Sayre. Chemical ...
Aaron T. Jacobs and Lawrence J. Marnett. Accounts of Chemical Research 2010 ... Quan Yuan, Xiaochun Zhu, and Lawrence M. Sayre. Chemical Research in ...
ride, m. p. 247°, whose aqueous solution was ex- tremely bitter. Since I had prepared a desoxycholamine which differed from that described by Dr. Vanghelovici.
alternative explanations of thehydro- peroxide effect. 1. Cumene hydroperoxide generated by oxidation before addition of inhibitor had exactly the same effect.
April, 1028
FORMATION OF PRIMARY AMINES
[CONTRIBUTION FROM THE CHEMICAL
1193
LABORATORY OF THE STATE UNIVERSITY OF IOWA]
THE FORMATION OF PRIMARY AMINES FROM GRIGNARD REAGENTS AND MONOCHLORO-AMINE BY GEORGEH. COLEMAN AND C. R. HA USER^ RECEIVEDDECEMBER19, 1927
PUBLISHEDAPRIL 6, 1928
Comparatively few reactions of Grignard reagents with halogen compounds in which the halogen atom is attached to nitrogen have been studied. Oddo2 prepared nitrosobenzene from nitrosyl chloride (NOC1) and phenylmagnesium bromide. Zuskine3 has reported, however, that nitroxyl chloride (N02C1) does not form nitro compounds with either phenylmagnesium bromide or ethylmagnesium bromide. Strecker4 isolated only ammonium salts from the reaction mixtures of nitrogen trichloride with phenylmagnesium bromide and ethylmagnesium bromide. Buylla5 failed in an attempt to prepare triethylamine by the action of iododiethylamine on ethylmagnesium bromide, the iododiethylamine being recovered almost quantitatively. Grignard6 and his co-workers have studied the reactions of cyanogen chloride, bromide and iodide with a variety of organomagnesium halides. With cyanogen chloride the principal product is in many cases the nitrile. In such reactions the authors regard the cyanogen chloride as reacting in that form in which the chlorWith cyanogen bromide and ine is attached to carbon iCl-C=N). iodide the principal product is the corresponding halogen derivative instead of the nitrile. The halogen atoms are here regarded as being attached to nitrogen (I-N=C or I-N=C
