Titanium(IV) Chloride and the Amine-Promoted Baylis−Hillman Reaction

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Titanium(IV) Chloride and the Amine-Promoted Baylis−Hillman Reaction

2000 Vol. 2, No. 16 2397-2400

Min Shi,* Jian-Kang Jiang, and Yan-Shu Feng Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China [email protected] Received March 2, 2000 (Revised Manuscript Received July 5, 2000)

ABSTRACT

In the Baylis−Hillman reaction, we found that, when the reactions of arylaldehydes with methyl vinyl ketone were carried out at