Subscriber access provided by UNIV OF WATERLOO
Policy Analysis
Viability of Carbon Capture and Sequestration Retrofits for Existing Coal-fired Power Plants under an Emission Trading Scheme Shuchi K. Talati, Haibo Zhai, and M. Granger Morgan Environ. Sci. Technol., Just Accepted Manuscript • DOI: 10.1021/acs.est.6b03175 • Publication Date (Web): 28 Oct 2016 Downloaded from http://pubs.acs.org on November 3, 2016
Just Accepted “Just Accepted” manuscripts have been peer-reviewed and accepted for publication. They are posted online prior to technical editing, formatting for publication and author proofing. The American Chemical Society provides “Just Accepted” as a free service to the research community to expedite the dissemination of scientific material as soon as possible after acceptance. “Just Accepted” manuscripts appear in full in PDF format accompanied by an HTML abstract. “Just Accepted” manuscripts have been fully peer reviewed, but should not be considered the official version of record. They are accessible to all readers and citable by the Digital Object Identifier (DOI®). “Just Accepted” is an optional service offered to authors. Therefore, the “Just Accepted” Web site may not include all articles that will be published in the journal. After a manuscript is technically edited and formatted, it will be removed from the “Just Accepted” Web site and published as an ASAP article. Note that technical editing may introduce minor changes to the manuscript text and/or graphics which could affect content, and all legal disclaimers and ethical guidelines that apply to the journal pertain. ACS cannot be held responsible for errors or consequences arising from the use of information contained in these “Just Accepted” manuscripts.
Environmental Science & Technology is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Published by American Chemical Society. Copyright © American Chemical Society. However, no copyright claim is made to original U.S. Government works, or works produced by employees of any Commonwealth realm Crown government in the course of their duties.
Page 1 of 30
Environmental Science & Technology
1 2
Viability of Carbon Capture and Sequestration Retrofits for
3
Existing Coal-fired Power Plants under an Emission Trading Scheme
4 5 6
Shuchi Talati, Haibo Zhai,* and M. Granger Morgan
7
Department of Engineering and Public Policy
8
Carnegie Mellon University, Pittsburgh, PA15213, United States
9
* Corresponding author. Tel.: +1 412 268 1088; Fax: +1 412 268 3757; Email address:
[email protected] 10 11
Prepared for publication in Environmental Science & Technology
12 13 14 15
5,095 text words + 1 table+ 6 figures = 7,195 word equivalents
16 17 18 19 20 21 22 23
ACS Paragon Plus Environment
Environmental Science & Technology
24
ABSTRACT
25
Using data on the coal-fired electric generating units (EGUs) in Texas we assess the economic
26
feasibility of retrofitting existing units with carbon capture and sequestration (CCS) in order to
27
comply with the Clean Power Plan's rate-based emission standards under an emission trading
28
scheme. CCS with 90% capture is shown to be more economically attractive for a range of
29
existing units than purchasing emission rate credits (ERCs) from a trading market at an average
30
credit price above $28 per MWh under the final state standard and $35 per MWh under the final
31
national standard. The breakeven ERC trading prices would decrease significantly if the captured
32
CO2 were sold for use in enhanced oil recovery, making CCS retrofits viable at lower trading
33
prices. The combination of ERC trading and CO2 use can greatly reinforce economic incentives
34
and market demands for CCS and hence accelerate large-scale deployment, even under scenarios
35
with high retrofit costs. Comparing the levelized costs of electricity generation between CCS
36
retrofits and new renewable plants under the ERC trading scheme, retrofitting coal-fired EGUs
37
with CCS may be significantly cheaper than new solar plants under some market conditions.
38 39
ACS Paragon Plus Environment
Page 2 of 30
Page 3 of 30
Environmental Science & Technology
40
INTRODUCTION AND RESEARCH OBJECTIVES
41
In December 2015, an historic agreement to take action against climate change was reached by
42
195 nations in Paris with the objective of keeping the average increase in global temperature at
43
or below 2 degrees Celsius this century.1 Given that a reliance on fossil fuels will likely continue
44
for decades, carbon capture and sequestration (CCS) will be essential if deep reductions in
45
carbon dioxide (CO2) emissions are to be achieved. The Intergovernmental Panel on Climate
46
Change's Fifth Assessment Report emphasized that while stabilizing the greenhouse gas
47
concentrations below 450 ppm CO2-equivalent is necessary to meet this goal, the cost of
48
mitigation could increase by roughly 140% in the absence of CCS.2 However, today's CCS cost
49
is a major barrier to its large-scale deployment. Regulations and policies are needed to provide
50
economic incentives for CCS.
51
To combat anthropogenic climate change domestically, the U.S. Environmental Protection
52
Agency (EPA) established the Clean Power Plan (CPP) in August 2015, which would reduce
53
national CO2 emissions from existing electric generating units (EGUs) by 32% from 2005 levels
54
by 2030.3 The CPP established uniform national emission performance standards for existing
55
fossil fuel-fired EGUs. Reflecting each state’s energy mix, the final rule also presented state-
56
specific rate- and mass-based emission standards. The CPP established three "building blocks" to
57
achieve compliance: heat rate improvements; increased electricity generation from existing
58
natural gas combined cycle (NGCC) plants; and, increased electricity generation from new
59
renewable plants.3 CCS was not included in the building blocks due to concerns about the
60
availability of space in plants, cost, and system integration, if applied broadly to the overall
61
source fleet.3 However, retrofit of CCS can be a viable option for some existing coal-fired EGUs
62
depending on the unit attributes.3-4 The CPP provides states with the flexibility to decide whether
ACS Paragon Plus Environment
Environmental Science & Technology
63
to implement a rate- or mass-based standard and to choose the compliance measures, including
64
market-based mechanisms.
65
Emission trading programs have been increasingly used for cost-effective management of
66
emissions in national and global environmental and climate policy. They have encouraged
67
innovation, incentivized further pollutant reduction, and lowered compliance costs when
68
compared with strategies based on command-and-control.5-7 For example, under the U.S. acid
69
rain trading program sulfur dioxide (SO2) emission reductions were achieved faster than
70
expected due the flexibility afforded by the trading scheme.7 Innovation in and diffusion of SO2
71
reduction technology has grown while costs have declined.7 Prior estimates of the cost of
72
compliance ranged from $2.7 −$8.7 billion/year, while realized costs proved to be a much lower
73
$1.9 billion/year.8
74
In the U.S., trading programs, such as the Regional Greenhouse Gas Initiative and the
75
California Cap-and-Trade Program, have demonstrated the viability of carbon trading at the state
76
and multi-state level.9 Multi-State auctions for carbon allowances have been run since 2008 and
77
state-level auctions have been run since 2012 respectively.9-11 In addition, under the European
78
Union Emission Trading System, multiple survey studies found innovation and investment from
79
industry related to CO2 abatement motivated by the policy.12
80
Under a rate-based emission standard, a state or group of states can develop an emission
81
trading program or participate in a federal program. This would allow EGUs with emissions
82
below the standard to create and sell emission rate credits (ERCs). Retrofits of CCS at suitable
83
coal-fired EGUs have the potential to not only meet the emission standards, but also to generate
84
ERCs to trade with other affected EGUs, thus providing income to offset some of the cost of
85
retrofits.
ACS Paragon Plus Environment
Page 4 of 30
Page 5 of 30
86
Environmental Science & Technology
Using data on the coal-fired EGUs in Texas the objectives of this paper are: 1) to investigate
87
the viability of retrofitting CCS to existing coal-fired EGUs as a measure to comply with the
88
CPP under a rate-based emission standard; 2) to examine how emission reduction trading would
89
affect the viability of CCS retrofits; and 3) to compare the costs of electricity generation between
90
CCS and renewable technology as compliance measures under the emission trading scheme. This
91
study will reveal the viability of CCS retrofits under the emission trading scheme outlined by the
92
CPP in conjunction with CO2 use for oil recovery operations.
93 94
RETROFITTING CCS FOR RATE-BASED STANDARD COMPLIANCE UNDER AN
95
EMISSION TRADING SCHEME
96
The CPP established uniform national interim and final CO2 emission standards of 1534 and
97
1305 lbs CO2/MWh respectively for existing fossil-fuel-fired steam EGUs over the compliance
98
period from 2022 to 2030.3 The CPP also presented state-specific interim and final emission
99
standards, which are 1188 and 1042 lbs CO2/MWh for Texas, respectively. States using a rate-
100
based standard may implement a market-based emission trading program that employs an
101
administratively created tradable compliance instrument called an emission rate credit (ERC),
102
defined as one MWh of electric generation with zero-associated CO2 emissions. ERCs can be
103
generated by numerous sources, including new renewable plants (e.g. wind and solar), demand-
104
side energy efficiency programs, or existing EGUs with an emission rate less than the rate-based
105
standard. The amount of ERCs that an EGU must buy or can sell is estimated as the product of
106
the annual electricity generation and the normalized difference between the emission rate
107
standard and the actual emission rate.3 ERCs can be traded between EGUs under the same
108
compliance pathway. Further details about the CPP are available in the Federal Register.3
ACS Paragon Plus Environment
Environmental Science & Technology
109
A recent study found that the implementation of CO2 capture appears feasible for some
110
existing coal-fired EGUs that already have environmental systems for controlling major
111
traditional air pollutants, are fully or substantially amortized, relatively efficient, have net
112
capacities of more than 300 MW with high utilization, and can operate for 20 years or more.4
113
CCS deployment becomes more cost effective when the captured CO2 can be used for enhanced
114
oil recovery (EOR).4 However, as elaborated below, since EOR results in a net increase in CO2
115
emissions it is not a sustainable long term strategy.
116
Texas has 18 such EGUs, resulting in a total summer capacity of about 10 GW.4 In this
117
paper we focus on Texas because its feasible capacity exceeds that of other states. Texas also has
118
substantial potential for CO2 sequestration via oil and natural gas reservoirs within an estimated
119
volume of between 135 and 140 billion metric tons.13 The key attributes of the identified EGUs
120
are summarized in Table 1. For the suitable EGUs, there are at least three options available to
121
comply with a rate-based standard: purchase the required amount of ERCs from a trading
122
market; retrofit enough partial CCS to exactly meet the emission standard; and retrofit CCS for
123
90% CO2 capture (i.e. “full-CCS”) and sell the generated ERCs to a trading market.
124 125
MATERIALS AND METHODS
126
The Integrated Environmental Control Model (IECM v9.1), a power plant modeling tool
127
developed by Carnegie Mellon University, was employed to simulate and evaluate feasible
128
existing coal-fired EGUs.14 This tool provides systematic estimates of the performance, resource
129
use, emissions, costs, and uncertainties for fossil fuel-fired power plants with or without CCS.
130
The IECM has an array of power plant configurations that can employ a variety of environmental
131
control and cooling systems as well as a fuel database including representative U.S. coals and
ACS Paragon Plus Environment
Page 6 of 30
Page 7 of 30
Environmental Science & Technology
132
typical natural gas compositions. The IECM applies basic mass and energy balances along with
133
empirical data to develop process performance models and further link them to
134
engineering−economic models that estimate the capital cost, annual operating and maintenance
135
(O&M) costs, and total annual levelized cost of electricity (LCOE) of an overall power plant and
136
environmental control systems. 14 Details on the IECM are in Section S-1 of the Supporting
137
Information (SI).
138
These EGUs selected for retrofit evaluation are characterized and modeled in the IECM
139
are based on the unit-specific attributes information from an integrated emissions and power
140
generation database that combines the U.S. EPA's National Electric Energy Data System and
141
Emissions and Generation Resource Integrated Database.4 The key unit-specific attributes
142
adopted for characterizing individual EGUs include the unit location, unit age, boiler type, coal
143
type, heat rate, summer capacity, annual electricity generation, operating hours, and
144
environmental control systems. The Econamine CCS in the IECM, current commercially
145
available technology, is employed for the retrofit assessment. Other technologies still under
146
development are to be ill-suited for this purpose.4 Details on the IECM simulations are in Zhai et
147
al.4 The key performance metrics considered include the CO2 removal efficiency, CO2 emission
148
rate, total annual CO2 emissions, net power output, annual electricity generation, water use, and
149
net unit efficiency. Key cost metrics are the total LCOE of an EGU with or without CCS and the
150
cost of CO2 avoided by CCS, a most commonly reported measure that quantifies the average cost
151
of avoiding a ton of CO2 emissions while still generates a unit of electricity.15
152
For a given CO2 emission performance standard, the IECM was used to assess each EGU
153
under the rate-based emission standard regulation via three compliance options: purchasing
154
ERCs from a trading market; implementation of CCS for partial CO2 capture; and
ACS Paragon Plus Environment
Environmental Science & Technology
155
implementation of CCS for 90% capture with an income stream from an ERC trading market.
156
The cost-effective bypass design is adopted for partial CO2 capture.16 In each CCS retrofit case,
157
the IECM is applied to first determine the CO2 removal efficiency required for an EGU in
158
meeting the given emission rate limit. The amount of saleable ERCs from full-CCS deployment
159
is then determined to estimate the unit performance and the unit LCOE as a function of the ERC
160
price. Details on the ERC, LCOE, and CO2 avoidance cost calculations are in Section S-3 of the
161
SI.
162
To make cost comparisons between CCS and renewable generation systems under the ERC
163
trading market, the plant LCOE was calculated for new wind and solar power plants using capital
164
and operating cost data from the Integrated Planning Model, which was applied by the U.S. EPA
165
to assess the CPP.17 The detailed LCOE calculations for new renewable power plants are in
166
Section S-4 of the SI.
167 168
BASE CASE RESULTS
169
IECM v9.1 was applied to evaluate the performance and cost of each feasible EGU with and
170
without Econamine CCS under a variety of design and marketing conditions. The evaluation was
171
done using sub-bituminous Wyoming Powder River Basin coal, which in the IECM's fuel
172
database has a price of $8.75/ton. The average gross power output and annual operating hours
173
were fixed for each CCS retrofit case. All costs are reported in 2009 constant dollars.
174 175 176 177
Effects of CCS Retrofits on Existing EGUs We assume that Econamine CCS, a commercially available technology will be installed for CO2 capture. The major technical and economic assumptions and parameters of CCS are
ACS Paragon Plus Environment
Page 8 of 30
Page 9 of 30
Environmental Science & Technology
178
summarized in Table S-5 in the SI. Low-quality steam extracted from the unit's steam cycle
179
provides the required thermal energy for solvent regeneration. We find that a CO2 removal
180
efficiency of 50−56% would be required for CCS to meet the final national standard and
181
62−67% for the final state standard. Table 1 summarizes the performance and costs of existing
182
EGUs without and with CCS retrofits. Average gross power output for all units is 529 MW. Net
183
power output decreases from an average absolute value for existing EGUs of 505 MW.
184
Compared to existing units prior to retrofits, the implementation of partial CCS to meet the final
185
national standard would decrease the net power output and unit efficiency on average by 56 MW
186
and 6.7% (on an absolute basis) and increase the annual levelized cost of electricity generation
187
(LCOE) by $28/MWh. To comply with the final state standard, it would decrease the net power
188
output and net unit efficiency on average by 65 MW and 8.0%, respectively, and increase the
189
unit LCOE on average by $34/MWh. However, the average unit LCOE of the existing EGUs
190
retrofitted with partial CCS is similar to or less than that of new supercritical pulverized coal-
191
fired or NGCC plants without CCS.18 Table 1 also shows that the deployment of full CCS (90%
192
CO2 capture) would lead to more significant effects on the unit performance and cost. Figure 1
193
depicts the LCOE of EGUs retrofitted with CCS in meeting both the interim and final standards
194
over the compliance period.
195 196 197
Economics of CCS Retrofits under an ERC Trading Scheme We first estimated the quantity of required or saleable ERCs for each of the three mitigation
198
options available for each suitable EGU to comply with the rate-based emission standards.
199
Figure 2(a) shows this quantity for an example EGU with 670 MW of summer capacity under the
200
final national and state standards, while Figure 2(b) shows the unit LCOE of the example as a
ACS Paragon Plus Environment
Environmental Science & Technology
201
function of the ERC price for each option adopted to meet both the final state and national
202
standards. Without CCS, the example unit has to buy 4.3×106 MWh of ERCs annually from the
203
market to comply with the final state standard. However, retrofitting full CCS generates 2.0×106
204
MWh of ERCs annually for sale. There are no ERCs generated or available using partial CCS.
205
Figure 2(b) illustrates how the ERC price would affect the unit LCOE for each option. For the
206
credit purchase option, the unit LCOE increases linearly with the ERC price. It decreases linearly
207
for the full-CCS option due to the revenue from the ERC market. However, the unit LCOE stays
208
constant for the partial-CCS option. Using the credit purchase option as the benchmark across
209
this study unless otherwise noted, the breakeven ERC price is $29 per MWh for the partial-CCS
210
option and $28 per MWh for the full-CCS option under the final state rate. Under the final
211
national rate, the breakeven ERC values are higher, occurring at $39 and $35 per MWh,
212
respectively. As shown in Figure 2(b), for ERC prices less than these values, purchasing credits
213
from the ERC market is the cheapest compliance strategy for the example EGU. When ERC
214
prices are more than the breakeven prices, retrofitting CCS, in particular for 90% CO2 capture,
215
becomes economically viable. Although the addition of CCS would significantly increase the
216
cost of electricity generation even under the emission trading scheme with a breakeven ERC
217
price, the unit LCOE of the retrofitted EGU is similar or less than that of a new fossil fuel-fired
218
plant without CCS.18
219
We conducted the same analysis for all 18 suitable EGUs retrofitted with partial and full
220
CCS. The box plots in Figure 2(c) show the distributions of the resulting breakeven ERC prices
221
under the final state and national rate-based standards. Under either the state or the national
222
standard, there is considerable overlap in the breakeven ERC prices between the full and partial
223
CCS retrofit options. However, for a given retrofit option, the breakeven ERC prices in meeting
ACS Paragon Plus Environment
Page 10 of 30
Page 11 of 30
Environmental Science & Technology
224
the state standard are lower than those in meeting the national standard, indicating that under
225
more stringent standards, the CCS retrofit options become viable at lower ERC prices. When
226
complying with the state standard, the breakeven ERC prices fall within the range of $22 to $35
227
per MWh for the partial-CCS option and $23 to $31 per MWh for the full-CCS option. As a
228
result, the unit costs of electricity generation at the breakeven point fall within the range of $45
229
MWh to $54/MWh for the partial-CCS option and $44/MWh to $53/MWh for the full-CCS
230
option. These results imply that under the emission trading scheme, retrofit of full CCS is
231
economically viable at a relatively lower ERC price, compared to retrofit of partial CCS. To
232
understand which of the key unit attributes most influences the breakeven ERC price, a
233
Spearman rank correlation analysis for multiple parameters finds that unit LCOE of existing
234
units as well as added LCOE for CCS retrofits have the highest correlation. For more details of
235
this analysis, see SI section S-5.
236
In addition to the unit cost of electricity generation, the cost of CO2 avoided is an important
237
economic metric for CCS. Figure 3 shows the costs of CO2 avoided by retrofitting CCS to
238
comply with the rate-based emission standard under different ERC market prices. Figure 3(a)
239
shows the cost of CO2 avoided by retrofitting partial or full CCS to the example EGU as a
240
function of the ERC price in complying with the final state standard. For the partial-CCS option,
241
the avoidance cost remains constant at $55/ton, as no ERCs are generated or required. However,
242
for the full-CCS option, it decreases from $53/ton to zero as the ERC price increases from zero
243
to $75 per MWh, beyond which the avoidance cost becomes negative. In Figure 3(b) box plots
244
display the distributions of the cost of CO2 avoided by full CCS for all suitable EGUs at four
245
ERC prices. All the avoidance costs decrease when the ERC price increases. Emission trading
246
does improve the economic viability of retrofitting CCS for 90% CO2 capture. However, at a low
ACS Paragon Plus Environment
Environmental Science & Technology
247
ERC price of $10 per MWh or less, the avoidance cost has an average value of $46/ton or more,
248
which is still high. This result indicates that there will be a need for additional economic
249
incentives for CCS retrofits if the trading price is low.
250
Coal price has a large effect on the unit LCOE of both existing and retrofitted EGUs. While
251
we performed our analysis with the IECM’s coal price of $8.75/ton, in the EPA's Integrated
252
Planning Model (IPM) for the CPP, the cost of coal production in Texas was projected to fall
253
within the range from $8.1/ton to $27/ton in 2016 and $9.4/ton to $31/ton in 2030 (in 2009
254
dollars).17 Hence it is necessary to examine the impacts of higher coal prices. As the coal price
255
increases from the base case value to $18/ton, $26/ton and $35/ton (two to four times IECM’s
256
base price), the levelized costs of electricity generation increase by 1.4 to 2.1 times on average
257
for existing EGUs and 1.1 to 1.4 for EGUs retrofitted with full CCS, illustrated in Figure 4. As a
258
result, the average breakeven ERC prices increase by $1.5 per MWh, $3.1 per MWh, and $4.7
259
per MWh, respectively. The fuel cost thus has a moderate effect on the breakeven ERC price.
260
Coal prices might decrease with a lower demand from coal-fired EGUs under the CPP
261
regulation. Cheaper coal prices would lead to lower breakeven ERC prices.
262
Enhanced oil recovery (EOR) can lower the retrofit cost by providing income in lieu of a
263
CO2 sequestration cost, though the CO2 transportation cost must still be covered.4 In
264
conventional EOR much of the injected CO2 is retrieved and reused. If we assume that EOR can
265
be operated in a way that provides permanent sequestration, we can then examine the effects of
266
CO2-EOR operations on the EGUs that deploy full CCS to meet the final state standard. We
267
adopt a sale price of $10/ton CO2, though current sale prices for CO2 are estimated to be
268
approximately $35−40/ton based on oil prices of $85/bbl.4,19 We used the lower value because of
269
uncertainty about reservoir capacity and oil market fluctuation and the fact that if sequestration is
ACS Paragon Plus Environment
Page 12 of 30
Page 13 of 30
Environmental Science & Technology
270
to be successful EOR operations will need to forgo strategies that now focus on maximizing CO2
271
recovery for reuse. With the $10/ton sale price, using all the captured CO2 for EOR operations
272
would substantially lower the average LCOE of EGUs retrofitted with full CCS from $65/MWh
273
to $40/MWh. As a result, the breakeven ERC prices drop dramatically from an average of $28
274
per MWh (shown in Figure 2c) to $14 per MWh (See Figure S-1 in the SI). This result indicates
275
that a low sale price of the captured CO2 can have a big impact on the ERC trading market, thus
276
enhancing the viability of deployment of full CCS as a compliance measure for suitable coal-
277
fired EGUs. Higher priced oil and subsequent higher CO2 sale prices for EOR operations would
278
thus have an even larger impact on the CCS deployment.
279 280 281
POTENTIAL HIGHER COSTS OF CCS RETROFITS While Econamine CCS is an available technology, it has yet to be deployed at large scale for
282
capture at power plants. When estimating the capital cost of a technology, the process
283
contingency accounts for additional capital costs that may arise as a system matures into a
284
commercial-scale technology, whereas the project contingency accounts for additional
285
equipment or other costs that may be identified in a more detailed project design.20 The Electric
286
Power Research Institute's Technical Assessment Guide estimates process contingency to vary
287
from 5% to 20% for a technology whose full-scale modules have been operated, and the project
288
contingency to vary from 15% to 30% for a preliminary project.21 To account for potential
289
difficulty of access to different areas of the plant and integration of a new system with existing
290
facilities, a recent study suggests an average retrofit factor of 1.25 for post-combustion CCS,
291
representing the cost ratio of new equipment for a retrofitted plant versus a new plant.22-23 When
292
estimating the total annual levelized cost, the fixed charge factor (FCF) converts the total capital
ACS Paragon Plus Environment
Environmental Science & Technology
293
requirement to the constant annualized amount, depending on the interest or discount rate and the
294
economic lifetime of a project. In the base case, the FCF values range from 0.113 to 0.127. To
295
examine the economic impact of potential high cost financing, a high fixed charge factor of 0.15
296
is often adopted for CCS assessments.18,24-25 Considering all these factors in implementing full
297
CCS retrofits to comply with the final state standard, Figure 5 shows the cumulative economic
298
effects of elevating the total contingency from 30% to 50%, retrofit factor from 1.00 to 1.25, and
299
FCF from the base values to 0.15.
300
Without ERC trading, Figure 5a shows the cumulative effects of the elevated contingency,
301
retrofit factor, and FCF values on the unit LCOE of EGUs retrofitted with full CCS. With the
302
elevated values for the three cost parameters, the unit LCOE would cumulatively increase by
303
29% on average for the 18 EGUs, compared to the base case. Figure 5b shows that under the
304
ERC trading market, the breakeven ERC prices associated with CCS retrofits would
305
cumulatively increase by 38% on average, due to the combined effect of the three elevated
306
parametric values, compared to the base case. Figure 5c shows the unit LCOE of retrofitted
307
EGUs with income measured at the corresponding breakeven prices shown in Figure 5b. In
308
comparison between Figure 5a and Figure 5c, we can see that trading ERCs from full-CCS
309
deployment would decrease the unit LCOE by 29−31% on average for the three high retrofit cost
310
scenarios.
311
Figure 5 also shows the economic effects of CO2-EOR operations with different CO2 sale
312
prices for the cases with the highest retrofit costs. As shown in Figure 5, the viability of full-CCS
313
deployment improves with an increase in CO2 sale price. Figure 5c shows that with a CO2 sale
314
price of $30/ton, the LCOE values of retrofitted EGUs are similar to those given in Table 1 for
315
existing EGUs without CCS. This result implies that even under the highest retrofit cost scenario,
ACS Paragon Plus Environment
Page 14 of 30
Page 15 of 30
Environmental Science & Technology
316
the combination of ERC trading and CO2 product utilization would substantially facilitate
317
deployment of full CCS at existing coal-fired EGUs. More rigorous cost analysis, however,
318
needs more detailed data on various site-specific factors such as space availability and
319
integration readiness level for CCS deployment, and CO2 transport and sequestration network
320
designs.
321 322 323
DISCUSSION Although retrofits of CCS are not a viable option for meeting emission standards across the
324
entire existing coal-fired fleet, it is feasible for the coal-fired EGUs in Texas that have been
325
evaluated in this study.4 At the state level, the losses in net electricity generation from retrofitting
326
CCS can be offset by the increased use of existing NGCC plants in meeting the CPP standards,
327
which would also lower the costs of electricity generation for those gas-fired plants. ERC trading
328
programs are able to improve the economic viability of CCS retrofits, especially for the
329
implementation of CCS for 90% CO2 capture. However, if actual ERC market prices were less
330
than the breakeven values, additional economic incentives, such as direct financial support,
331
subsides or revenue from CO2 sales, would be needed in order to promote investments in CCS
332
deployment. If the ERC trading price were to remain as low as $10 per MWh, the income stream
333
from selling the captured CO2 for CO2-EOR, even at a price of $10/ton would substantially lower
334
the average avoidance cost from $46 to $19/ton. As an alternative solution, an investment tax
335
credit, similar to the 30% tax credit on capital investment currently in place for renewables,26
336
could be adopted to incentivize CCS deployment if ERC prices were to remain low. With respect
337
to the total mass-based emission reduction, just retrofitting partial CCS at those suitable coal-
338
fired EGUs with removal efficiencies slightly higher than to meet the state rate-based standard
ACS Paragon Plus Environment
Environmental Science & Technology
339
would result in a total amount of emission reductions similar to that necessary for achieving the
340
state mass-based emission goal for the entire existing fleet (see Section S-7 of the SI). It is
341
important to note the increased use of existing NGCC plants in compliance with the CPP,
342
especially at low natural gas prices. However, this paper is focused on assessing the viability of
343
retrofitting CCS to coal-fired EGUs under the emission trading scheme.
344
Because the life cycle CO2 emissions associated with sequestration via CO2-EOR will be net
345
positive when the produced oil is combusted,27 EOR sequestration should be regarded as an
346
interim bridging solution that can improve the viability of CCS as technological learning
347
continues. In the future it is possible that other forms of CO2 utilization may be developed, but
348
given the enormous volumes that are involved, to date viable alterative uses have yet to be
349
found.28
350
Another important consideration for CCS is the water required to perform the large amount
351
of cooling needed by the capture process.29 Retrofitting CCS for 90% CO2 capture at existing
352
coal-fired EGUs with wet cooling towers would approximately double water use intensity,
353
though the total water use highly depends on the actual amount of electricity generation. (See
354
Figure S-2 in the SI). Hence water availability must be considered in evaluating CCS retrofits,
355
especially in regions such as Texas, that have experienced increased frequencies of drought and
356
high temperatures.30 See Section S-6 of the SI for additional water information and analysis.
357
The decision to add CCS to existing units to meet the rate-based standards will be in
358
competition with new wind and solar power plants outlined in the CPP as the best system of
359
emission reductions. For the same amount of electricity generation, new zero-emission
360
renewable plants would generate more ERC credits than full CCS. Thus, the ERC market could
361
greatly affect the choice of mitigation options between CCS and new renewable plants. The
ACS Paragon Plus Environment
Page 16 of 30
Page 17 of 30
Environmental Science & Technology
362
LCOE values of new wind and solar plants were estimated to be $65/MWh and $111/MWh
363
based on the Integrated Planning Model's capital and fixed O&M cost estimates for 2016,
364
respectively.17 As shown in Figure 6a for the example unit, LCOE decreases linearly as the ERC
365
price increases. The resulting breakeven ERC price for wind is less than that of full CCS at about
366
$21 per MWh, and for PV is more than that for retrofitting full CCS to the 670 MW example
367
coal-fired unit at $42 per MWh. Figure 6b shows that for the 18 suitable EGUs, the average
368
breakeven ERC prices for wind and solar are $23 and $45 per MWh as compared to $28 per
369
MWh for EGUs retrofitted with full CCS. However, because of intermittency, renewable plants
370
may not generate the same level of stable ERCs as CCS retrofits for a given period.
371
At any ERC prices less than $141 per MWh coal-fired EGUs retrofitted with full CCS have
372
a lower levelized cost of electricity generation than that of new solar, but is never lower than that
373
of new wind for the base case. Figure 6b compares the distributions of the breakeven ERC price
374
for the 18 EGUs between partial and full CCS retrofits and new renewable plants employed for
375
meeting the final state standard. The lowest breakeven ERC prices occurs under the mitigation
376
option of new wind. However, the Integrated Planning Model projects that by 2030, new PV
377
plant costs would drop dramatically by 38.5%.17 With such low costs, the lowest breakeven ERC
378
prices are similar between new solar and wind plants. See Section S-6 of the SI for additional
379
analyses.
380
While renewable plants are expected to make growing contributions to meeting future
381
energy needs, coal-fired power plants will continue to provide a large share of the electricity
382
demand in the United States and other countries like China and India.31 The deep emission
383
reductions 80−90%, that will be needed to stabilize the climate, pose a much more challenging
384
target than the 32% outlined by the CPP.32-33 To avoid serious problems in the future, short-term
ACS Paragon Plus Environment
Environmental Science & Technology
385
mitigation solutions should be able to scale up in a much more carbon-constrained future.33 CCS
386
retrofits are a defensible step in the effort to reach the ambitious abatement aim. In addition,
387
given current prices of natural gas, new fossil fuel-fired power generation systems to be installed
388
by 2030 may be NGCC plants without CCS.34 Thus, retrofitting CCS to some existing coal-fired
389
EGUs is a promising option to ensure that technological learning occurs in the medium-term so
390
that deep reduction target can be achieved in the future.
391 392
Supporting Information
393
Supporting Information includes additional text, tables, and figures on the IECM, technical and
394
economic aspects of the CCS system, cost assessment methods, rate-based compliance results,
395
water use analysis, and a mass-based compliance assessment. This material is available free of
396
charge via the Internet at http://pubs.acs.org.
397 398
ACKNOWLEDGEMENTS
399
This work was supported by the Center for Climate and Energy Decision Making through a
400
cooperative agreement between the National Science Foundation and Carnegie Mellon
401
University (SES-0949710). All opinions, findings, conclusions and recommendations expressed
402
in this paper are those of the authors alone.
403 404
REFERENCES
405
(1)
United Nations Framework Convention on Climate Change Conference of the Parties.
406
Adoption of the Paris Agreement. Proposal by the President; United Nations, Geneva,
407
Switzerland, 2015.
ACS Paragon Plus Environment
Page 18 of 30
Page 19 of 30
408
Environmental Science & Technology
(2)
409 410
Intergovernmental Panel on Climate Change. Fifth Assessment Report; IPCC, Bern, Switzerland, 2014.
(3)
U.S. Environmental Protection Agency. Carbon pollution emission guidelines for existing
411
stationary sources: electricity generating units; final rule. Fed. Regist.2015, 80(205),
412
64661–65120.
413
(4)
Zhai, H.; Ou. Y.; Rubin, E. Opportunities for decarbonizing existing U.S. coal-fired
414
power plants via CO2 capture, utilization and storage. Environ. Sci. Technol. 2015,
415
49(13), 7571–7579.
416
(5)
417 418
United Nations Environment Programme. An Emerging Market for the Environment: A Guide to Emissions Trading; United Nations Publication, 2002.
(6)
U.S. Environmental Protection Agency. The U.S. Experience with Economic Incentives
419
for Protecting the Environment; U.S. Environmental Protection Agency, Washington,
420
DC., 2001.
421
(7)
Chan, G.; Stavins, R.; Stowe, R.; Sweeney, R. The SO2 Allowance Trading System and
422
the Clean Air Act Amendments of 1990: Reflections on Twenty Years of Policy
423
Innovation; Harvard Environmental Economics Program, Cambridge, MA, 2012.
424
(8)
425 426
Provisions of H.R. 2454; Congressional Research Service, Washington, DC, 2009. (9)
427 428 429
Parker, L.; Yacobucci, B. Climate Change: Costs and Benefits of the Cap-and-Trade
Center for Climate and Energy Solutions. Market Mechanisms: Understanding the Options; C2ES, Arlington, VA, 2015.
(10)
Regional Greenhouse Gas Initiative. Overview of RGGI CO2 Budget Trading Program; RGGI, Inc., New York, NY, 2007.
ACS Paragon Plus Environment
Environmental Science & Technology
430
(11)
431 432
California Air Resources Board. Overview of ARB Emissions Trading Program; California Environmental Protection Agency, Sacramento, CA, 2015.
(12)
Liang, T.; Sato, M.; Grubb, M.; Comberti, C. Assessing the effectiveness of the EU
433
Emissions Trading System; Grantham Research Institute on Climate Change and the
434
Environment, London, UK, 2013.
435
(13)
436 437
Pittsburgh, PA, 2015. (14)
438 439
(15)
Rubin, E. S. Understanding the pitfalls of CCS cost estimates. Int. J. Greenhouse Gas Control 2012, 10, 181–190
(16)
442 443
Carnegie Mellon University. Integrated Environmental Control Model Version 9.1; Carnegie Mellon University, Pittsburgh, PA, 2015.
440 441
National Energy Technology Laboratory. Carbon Storage Atlas, Fifth Edition; USDOE,
Rao, A. B.; Rubin, E. S. Identifying cost-effective CO2 control levels for amine-based CO2 capture systems. Ind. Eng. Chem. Res. 2006, 45 (8), 2421−2429.
(17)
U.S. Environmental Protection Agency. Documentation for EPA Base Case v.5.15 Using
444
the Integrated Planning Model, Incremental Documentation; U.S. Environmental
445
Protection Agency, Washington, DC, 2015.
446
(18)
Zhai, H.; Rubin, E. S. Comparative performance and cost assessments of coal-and
447
natural-gas-fired power plants under a CO2 emission performance standard regulation.
448
Energy & Fuels 2013, 27(8), 4290–4301.
449
(19)
National Energy Technology Laboratory. Improving Domestic Energy Security and
450
Lowering CO2 Emissions with “Next Generation” CO2 Enhanced Oil Recovery (CO2-
451
EOR); USDOE, Pittsburgh, PA, 2011.
ACS Paragon Plus Environment
Page 20 of 30
Page 21 of 30
452
Environmental Science & Technology
(20)
Rubin, E.; Short, C.; Booras, G.; Davison, J.; Ekstrom, C,; Matuszewski, M.; McCoy, S.
453
A proposed methodology for CO2 capture and storage cost estimates. Int. J. Greenhouse
454
Gas Control 2013, 17, 488−503.
455
(21)
Electric Power Research Institute. Technical Assessment Guide (TAG), Volume 1:
456
Electricity Supply 1993 (Revision 7); Electric Power Research Institute, Palo Alto, CA,
457
1993.
458
(22)
459 460
Middleton, R.; Bielicki, J. A scalable infrastructure model for carbon capture and storage: SimCCS. Energy Policy 2009, 37(3): 1052−1060.
(23)
National Energy Technology Laboratory. Cost Estimation Methodology for NETL
461
Assessments of Power Plant Performance; U.S. Department of Energy, Pittsburgh, PA,
462
2011.
463
(24)
Rubin, E.; Yeh, S.; Antes, M.; Berkenpas, M.; Davison, J. Use of experience curves to
464
estimate the future cost of power plants with CO2 capture. Int. J. Greenhouse Gas
465
Control 2007, 1(2), 188−197.
466
(25)
467 468
power plants. Environ. Sci. Technol.2012, 46(6), 3076−3084. (26)
469 470
473
Database of State Incentives for Renewables and Efficiency. Business Energy Investment Tax Credit (ITC); N.C Clean Energy Technology Center, Raleigh, NC, 2015.
(27)
471 472
Rubin, E.; Zhai, H. The cost of carbon capture and storage for natural gas combined cycle
Jaramillo, P.; Griffin, M.; McCoy, S. Life cycle inventory of CO2 in an enhanced oil recovery system. Environ. Sci. Technol. 2009, 43(21), 8027−8032.
(28)
National Research Council. Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration; National Academies Press, Washington, DC, 2015.
ACS Paragon Plus Environment
Environmental Science & Technology
474
(29)
Zhai, H.; Rubin, E.; Versteeg, P. Water use at pulverized coal power plants with
475
postcombustion carbon capture and storage. Environ. Sci. Technol. 2011, 45(6),
476
2479−2485.
477
(30)
478 479
USGCRP, Washington, DC, 2014. (31)
480 481
(32)
National Research Council. America’s Climate Choices: Limiting the Magnitude of Future Climate Change; National Academies Press, Washington, DC, 2010.
(33)
484 485
International Energy Agency. Medium-Term Coal Market Report 2015; IEA, Paris, France, 2015.
482 483
The U.S. Global Change Research Program. Third National Climate Assessment;
Morgan, M. G. Opinion: Climate policy needs more than muddling. Proc. Natl. Acad. Sci. U.S.A. 2016, 113(9), 2322−2324.
(34)
U.S Environmental Protection Agency. Regulatory Impact Analysis for the Final
486
Standards of Performance for Greenhouse Gas Emissions from New, Modified, and
487
Reconstructed Stationary Sources: Electric Utility Generating Units; U.S. EPA,
488
Washington, DC, 2015.
ACS Paragon Plus Environment
Page 22 of 30
Page 23 of 30
489 490 491
492 493 494 495 496 497
Environmental Science & Technology
Table 1. Performance and Costs of Feasible Coal-Fired EGUs with and without CCS Retrofits Characteristic Statistic Existing Retrofit of Partial CCS Retrofit of State National EGUsa Full CCS Standard Standard Average Gross Power Output Min 374 374 374 374 (MW) Mean 529 529 529 529 Max 711 711 711 711 Net Power Output (MW) Min 359 317 310 295 Mean 505 448 440 418 Max 655 588 576 547 Efficiency(HHV, %) Min 29.9 24.3 23.1 20.3 Mean 32.6 25.9 24.6 21.6 Max 34.4 27.7 26.2 22.9 Annual Operation Hours Min 7276 7276 7276 7276 Mean 8186 8186 8186 8186 Max 8678 8678 8678 8678 CO2 Emission Rate (lb/MWh) Min 2103 1304 1040 316 Mean 2220 1305 1042 336 Max 2424 1305 1042 356 Annual Net Electricity Min 3.05 2.69 2.64 2.51 Generation (Billion kWh) Mean 4.13 3.67 3.60 3.41 Max 5.62 5.05 4.95 4.70 Unit Levelized Cost of Min 12.0 39.9 44.8 59.9 Electricity (2009 constant Mean 15.3 43.5 49.3 65.5 $/MWh) Max 22.0 48.3 53.9 70.9 a
The summer capacity ranges from 436 MW to 760 MW with an average of 576 MW.
ACS Paragon Plus Environment
Environmental Science & Technology
498 499 500 501 502
Figure 1. Unit LCOE under different emission rate standards (a): Unit LCOE of example unit. (b) Boxplot of unit LCOE for all units
ACS Paragon Plus Environment
Page 24 of 30
Page 25 of 30
Environmental Science & Technology
503
504 505 506 507 508 509
Figure 2. Economics of EGUs under an ERC trading scheme: (a) ERCs generated for an illustrative EGU with and without CCS retrofits under the rate-based standards. (b) Unit LCOE of the example EGU as a function of ERC price for three compliance options. (c) Boxplot of breakeven ERC prices for partial and full CCS options. The ERC purchase option is treated as the benchmark.
ACS Paragon Plus Environment
Environmental Science & Technology
510 511 512
513 514 515 516 517 518
Figure 3. Cost of CO2 avoided by CCS as a function of ERC price: (a) Cost of CO2 avoided by retrofitting CCS for an illustrative EGU under an ERC trading market. (b) Boxplot of costs of CO2 avoided by full CCS at EGUs under different ERC trading prices.
ACS Paragon Plus Environment
Page 26 of 30
Page 27 of 30
519 520 521 522 523
Environmental Science & Technology
Figure 4. Effect of coal prices on breakeven ERC prices for EGUs with full CCS under the state rate-based standard
ACS Paragon Plus Environment
Environmental Science & Technology
524 525 526 527 528 529 530 531
Figure 5. Economics of EGUs with high CCS retrofit costs: (a) Unit LCOE of EGUs retrofitted with full CCS under different retrofit cost scenarios prior to emission trading. (b) Breakeven ERC prices for the full-CCS option under high retrofit cost scenarios. (c) Unit LCOE for EGUs under high retrofit cost scenarios at the breakeven prices. Note: C = high contingencies (process = 20%; project = 30%), C+RF = high contingencies and retrofit factor, C+RF+FCF = high contingencies, retrofit factor, and fixed charge factor, EOR10/30 = all factors and EOR at different CO2 sale prices ($10/ton and $30/ton).
ACS Paragon Plus Environment
Page 28 of 30
Page 29 of 30
Environmental Science & Technology
532 533
534 535 536 537 538 539 540 541 542 543 544 545 546 547 548 549 550 551 552
Figure 6. Cost comparisons between CCS retrofits and new renewable plants under an ERC trading scheme: (a) Unit LCOE of example EGU and new renewable plants under an emission trading market. (b) Breakeven trading prices for different compliance options.
ACS Paragon Plus Environment
Environmental Science & Technology
553 554
Table of Contents Art
555
556
ACS Paragon Plus Environment
Page 30 of 30