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Dinuclear Cu(II) complexes, CuII2Nn (n = 4 or 5), were recently found to specifically cleave DNA in the presence of a reducing thiol and O2 or in the presence of H2O2 alone. However, CuII2N3 and a closely related mononuclear Cu(II) complex exhibited
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4846
J. Am. Chem. SOC.1983, 105, 4846-4848
C(6)
CO-Co = 2.494(1)
Figure 1. View of (Me3Si),CP=PC(SiMep)3
(1) showing the atom numbering scheme. Pertinent metric Parameters for mokcule A: p(l)-P(l)’ 2.014 (61, P(I)-c(1) 1.85 (1) A; fl(l)’-p(l)
