Meetings
ACS 6th Central Regional Meeting The 6th Central Regional Meeting of the American Chemical Society will be held on April 21-24, 1974, at the Sher aton-Cadillac Hotel in Detroit, Mich. An award banquet will be held Tues day evening at the meeting at which the 9th Midgely Award will be present ed to Dr. William M. LeSuer of Lubrizol Corp. for his outstanding contribu tions in chemistry related to the auto industry. Dr. LeSuer's award address is entitled "Growth of the Chemical Ad ditive Industry." The meeting program features seven symposiums covering a wide range of
H. K. LIVINGSTON MEMORIAL SYMPOSIUM ON CONTINUING EDUCATION IN CHEMISTRY S. Fleming and M. Glick, Cochairpersons Presiding
MONDAY
MORNING
Crystal Room, 4th Floor 9:00—1. The Carnegie Commission. Continuing Education and Chemistry. R. West. 9:25—2. Sample Segments Selected from, or Paraphrases of Published Projects in Continuing Education. J. Young. 9:50—3. Continuing Education via Com puter. W. Torop. 10:15—4. Using an Audio-Tutorial Pro gram for Continuing Education in Allied Health Chemistry Programs. E. Laughlin. 10:40—5. Continuing Education at a Large State University. N. M. Bikales. 11:05—Intermission. 11:15—Panel discussion by all speakers. R. West, J . Young, Cochairmen.
SYMPOSIUM ON METAL OXIDE CATALYSTS J. Kummer, Chairman
MONDAY
MORNING
Woodward Room, 5th Floor
M. Shelef, Presiding 9:00—6. Application of EPR to Metal Oxide Catalysts. J. H. Lunsford. 10:00—7. Application of IR Methods to Catalysis. D. Yates. 11:00—8. Conventional Magnetic Meth ods in Catalysis. L. J. Hofer. MONDAY
AFTERNOON
R. L. K l i m i s c h ,
Presiding
2:00—9. Physical Chemistry of Transition Metal Ion Complexes. K. Klier. 3:00—10. The Use of Base Metal Oxide Catalyst for Automobile Exhaust Purifi cation. R. J. Farranto. 4:00—11. Some Applications of Atten uated Reflectance Spectroscopy.
30
C&EN March 1 1 , 1974
topics—effect of government policy on Wayne State University is general chemical research, continuing educa chairman for the meeting. Dr. John A. tion in chemistry, metal oxide cata McLean, Jr., University of Detroit, and lysts, water and waste treatment, bio Dr. Harold Machamer, Parke, Davis & logical aspects of chemistry, advances Co., are program chairmen. in silicon chemistry, and global atmo Advance registration and housing ac spheric chemistry. There will be 120 commodation forms are available from contributed papers in the areas of or Dr. Richard Schwing, General Motors ganic, physical, inorganic, and analyti Research Laboratories, GM Technical cal and environmental chemistry, bio Center, Warren, Mich. 48090. Ab chemistry, and chemical education. stracts of papers will be distributed at The meeting also will include a mixer the meeting. Final meeting announce on Monday evening, an exposition, and ments, available from Dr. Schwing tours of local industry for anyone inter after April 1, will provide for obtaining ested. Dr. Richard L. Lintvedt of abstracts before the meeting.
5:30-8:30—Mixer, Level
Book Casino, Lobby
J. RUSSELL BRIGHT MEMORIAL SYMPOSIUM: EFFECT OF GOVERNMENT POLICY ON CHEMICAL RESEARCH J. C. Philips, Chairman S. Kirschner, Cochairman
11:20—19. Government Policy, Regula tion and Meaningful Data. Ε. Η. Blair. 11:50—Discussion. G. A. Greiss.
SYMPOSIUM ON WATER AND WASTE TREATMENT W. Katzenstein, Chairman
MONDAY
AFTERNOON
Washington Room, 5th Floor
D. Shannon, Presiding MONDAY
AFTERNOON
Crystal Room, 4th Floor N. A. L e B e l , Presiding 2:00—Introduction. M. Stiles. 2:05—12. Decision Making Processes Involved in Proposal Funding. M. K. Wilson. 2:35—Discussion. J. B. Kinsinger. 2:45—Introduction. P. Trix. 2:50—13. Trends and Directions in Grants and Contracts in Chemistry Sponsored by the National Institutes of Health. H. B. Wood. 3:20—Discussion. J. P. Horwitz. 3:30—Introduction. H. H. Szmant. 3:35—14. Trends in Federal Funding for Research at Large Research-Oriented Universities. C. G. Overberger. 4:05—Discussion. T. Dunn. 4:15—Introduction. N. A. LeBel. 4:20—15. Is Funding Policy an Effective Tool in Changing Research Styles? G. S. Hammond. 4:50—Discussion. C. L. Stevens. 5:30-8:30—Mixer, Book Casino, Lobby Level TUESDAY
MORNING
Crystal Room, 4th Floor
L. Netherton, Presiding 9:00—Introduction. B. Weinstock. 9:05—16. Scientists and Public Policy. R. C. Drew. 9:35—Discussion. S. Gratch. 9:45—Introduction. P. O. Warner. 9:50—17. The U.S. Environmental Pro tection Agency's Research and Devel opment Program. H. Durham. 10:20—Discussion. G. TerHaar. 10:30—Introduction. J. M. Campbell. 10:35—18. Conflicting Demands of Ener gy, Safety, and Vehicle Emissions. F. W. Bowditch. 11:05—Discussion. H. A. Toulmin. 11:15—Introduction. S. B. Twiss.
2:00—20. Synthetic Macromolecular Ad sorbents and Their Application to Waste Treatment. D. C. Kennedy, N. L. Avery. 3:00—21. Latest Advances in Biological Oxidation of Liquid Organic Wastes. F. A. Sanders. 4:00—22. What Price Water Pollution Control? J. G. Weidman. 5:30-8:30—Mixer, Book 'Casino, Lobby Level TUESDAY
MORNING
Washington Room, 5th Floor
11:00—29. Cytochrome P-450. Coon, T. van der Hoven.
M. J.
TUESDAY AFTERNOON I.J. Holcomb, Presiding 2:00—30. Biological Conversion of Ste roids. J. Rolls. 3:00—31. Messengers and Mediators in Cellular Immunity. D. Tubergen. 4:00—32. Diagnostic Enzymology. A. Forlano.
SYMPOSIUM ON RECENT ADVANCES IN SILICON CHEMISTRY J. Drake, Chairman
TUESDAY
MORNING
Michigan Room, 5th Floor A. G. M a c D i a r m i d , Presiding 10:00—33. Even-Electron Paramagnetic Silicon Compounds. A. G. MacDiar mid. 11:00—34. Polysilicon Derivatives of Polylithium Compounds. R. West, T. L. Chwang, W. Priester.
A. Balden, Presiding 9:00—23. The Chemical Implication of Water Re-Use. J. S. Defloss. 10:00—24. Bioassay Determination of Toxicity Levels. D. Swanson. 11:00—25. Oily Waste Treatment. W. Cook. 12:00—26. Polyelectrolytes: a Practical Approach to Oil/Water Separation. J. Rodgers.
SYMPOSIUM ON THE BIOLOGICAL ASPECTS OF CHEMISTRY S. A. Fusari, Chairman
TUESDAY
AFTERNOON
2:00—35. Silyldiazoalkanes and Their 1,3-Cyclo Addition Reactions. P. F. Jones, A. R. Bassindale. 3:00—36. Rearrangements of Silyl Enol Ethers: An Addition-Elimination Mech anism for Displacement with Retention of Configuration at Organosilicon. T. L. Pinnavaia, J. A. McClavin. 3:30—37. Some Recent Attempts at the Preparation of a Silicon-Carbon Double Bond Species. K. G. Rutherford, R. J. Seidewand. 4:00—38. Applications of Mass Spectrometric Techniques to Organosilicon Chemistry. J. M. Miller, T. R. B. Jones. 4:30—39. Structure-Properties Relation ships of Silicon Polymers. C-L. Lee. WEDNESDAY
TUESDAY
MORNING
Woodward Room, 5th Floor
I. Salmeen, Presiding 9:00—27. Chemical Mutagens and Car cinogens. V. Maher. 10:00—28. Biochemistry of Trace Metal Toxicity. H. Petering, D. Petering.
MORNING
Michigan Room, 5th Floor D. R. Bennett, Presiding 9:00—40. The Physiological Role of Sili con in Animals. K. Schwarz. 10:00—41. The Biological Activity of Or ganosilicon Compounds. R. R. LeVier, D. R. Bennett.
GLOBAL ATMOSPHERIC CHEMISTRY SYMPOSIUM (Cosponsored by ACS and American Meteorological Society) R. A. Reck, Chairperson TUESDAY AFTERNOON Crystal Room, 4th Floor W. Heller, Presiding 2:00—42. Recent Advances in Multiple Scattering Theory with Applications to Atmospheric Aerosols. G. N. Plass. 2:45—43. Infrared Optical Properties of Minor Atmospheric Constituents. S. R. Drayson. 3:30—44. Influence of Aerosols Height and Surface Albedo on Atmospheric Thermal Balance. R. A. Reck. 4:15—45. The Effect of a Change of C 0 2 Concentration upon the Temperature Distribution of a General Circulation Model. R. T. Weatherald, S. Manbe.
WEDNESDAY MORNING Crystal Room, 4th Floor C. S. Tuesday, Presiding 9:00—46. The Major Global Gaseous Trace Constituents, Their Dynamic Balance, and the Effect upon the At mosphere. R. E. Newell. 9:50—47. Important Photochemical Reactions in the Global Atmosphere. N. Niki. 10:35—48. Troposphere Ozone. D. Stedman. 11:00—49. Inventions of Atmospheric Methane Sources. A. Baker-Blocher, D. H. Stedman.
BIOCHEMISTRY I. Salmeen, Chairman MONDAY MORNING Michigan Room, 5th Floor Session A. B i o c h e m i c a l and G e n e r a l B i o c h e m i s t r y W. A. W o o d ,
10:00—112. Synthesis of Nitronucleosides. T. Lin, R. E. Harmon. 10:20—113. The Effect of Additives on the Formation of Nitrosamines in Meat Curing Mixtures Containing Spices and Nitrite. N. P. Sen, B. Donaldson, C. Charboneau, W. F. Miles. 10:40—114. Microdetermination of Mer cury Toxicity in Tissues. H. M. Vickrey, D. S. McDann. 11:00—115. Clinical Determination of Methemealbumin. S. F. Andres, T. J. Kregoski, C. F. Frey, R. R. Joseph, D. S. McCann. 11:20—116. Compounds Leachable from Plastic Medical Devices. G. L. Ball, E. L. Johnson, J. T. Groves, E. A. Napier. 11:40—117. A Scaleup Phenomenon in a Simple Saponification Reaction. L. J. Sacco, Jr.
3:20—220. Transformations of Poly-i.Aspartic Acid and Polyβ-Benzyl-i. -Aspartate to PolyL-Succinimide. M. L. Tiffany, S. Krimm. 3:40—221. Conformational Study of For mic Anhydride. E. A. Noe, M. Raban. 4:00—222. The Synthesis of Copolymers Containing Hydrophobic Side Chains. C. G. Overberger, E. Sincich. 4:20—223. Polymerization of Cyclohexene by an Abstraction-Coupling Reac tion. C. G. Gebelein, R. B. Scarfo. 4:40—224. Cracking Cumene by the NaY-HCI System. Its Implication on the Nature of Active Sites on Cracking Catalysts. J. J. Rim, J. B. Oblad, A. G. Oblad.
WEDNESDAY MORNING East & West Rooms, 5th Floor
ORGANIC CHEMISTRY H. H. Szmant, Chairman MONDAY MORNING Washington Room, 5th Floor Session A. Synthesis H. Hart, Presiding 9:00—201. A General Synthesis of Cyclobutenephosphonates. S. D. Darling, N. Subramanian, M. Jendrisak. 9:20—202. Cyclopropanated and Homoallyl Sugars in Nucleoside Synthe ses. S. Y-K. Tarn, B. Fraser-Reid. 9:40—203. 2,5-Dihydrothiophenes. Syn thesis and Reactions. J. M. Mcintosh, H. B. Goodbrand, G. Masse, R. S. Steevensz. 10:00—204. Synthesis of the 11-Methyltricyclo[5.3.1.0 4 n ] Undecane System. M. F. Haslanger, R. G. Lawton. 10:20—205. The Selective Ortho-Formylation of Aromatic Amines. P. G. Gassman, H. R. Drewes. 10:40—206. The Ortho-Alkylation of Phe nols. P. G. Gassman, D. R. Amick. 11:00—207. New Synthetic Approaches to Pseudoguaianolides. J. P. Marino, T. Kaneko. 11:20—208. Total Syntheses in the Piperidine Field. G. Fodor, V. Sankaran, R. Sprecher. 11:40—209. Synthetic Routes to Polymethylanthracenes. H. Hart, J. B. Jiang.
Session D. Mechanisms and Stereo chemistry C. R. Johnson, Presiding 9:00—225. A Study of the Oxidation of 1-Phenylcyclohexanol by Chromium Trioxide. J. L Pyle, R. W. Fuller, W. E. Barnhart. 9:20—226. Triethylamine-lnduced Dehydrobrominations of 1,2-Dibromosulfones. J. C. Philips, M. Oku, M. Aregullin, A. Sierra, J. Germano. 9:40—227. Abnormal Reactions of Chlorophosphazenes. J. C. Graham. 10:00—228. The Phosgenation of Methyl Anthranilate. N. P. Peet, S. Sunder. 10:20—229. Stereochemical Aspects of the Cycloaddition Reactions of Alkenylidene-Cyclopropanes with Chlorosulfonylisocyanate. D. J. Pasto, J. K. Borchardt. 10:40—230. Formation of Optically Ac tive 1,3-Diethylallene from Two Differ ent Cyclopropylidene Precursors. W. R. Moore, S. D. Clark. 11:00—231. 1 -Alkoxycyclopropanoxides as Intermediates to Favorskii Rear rangement Side Reaction Products. W. W. Bannister, S. A. Madison, D. W. Smith, A. Tajuddin. 11:20—232. A "New" Mechanism for the Favorskii Rearrangement. W. W. Ban nister, S. A. Madison.
9:00—101. Field lonization/Field Desorption Mass Spectrometry of Some Important Biological Molecules. G. W. Wood, P.-Y. Lau, N. Mak. 9:20—102. Field Desorption Mass Spec tra of Peptides. S. Asante-Poku, D. E. Schmidt, Jr. 9:40—103. The Intrinsic Viscosity Pa rameter and Molecular Weight of DNA Molecules. A. C. Plaush. 10:00—104. An Arsenate-lnduced Eleva tion of Inorganic Pyrophosphate Me diated by Liver Mitochondrial Fatty Acyl CoA Synthetase. E. Florin, R. A. Mitchell. 10:20—105. Osmotic Water Permeability of Liposomal Model Membranes. S. E. Schullery, J. P. Garzaniti, C. Y. Chen. 10:40—106. Production of Singlet Molec ular Oxygen by the Adrenodoxin Reductase-Adrenodoxin Enzyme System. A. P. Schaap, K. Goda, T. Kimura. 11:00—107. The Separation of a Tran scriptionally Active Fraction of Rat Ventral Prostate (EU) Chromatin from Less Active (Hetero) Chromatin. H. Chance, N. Kadohama, Κ. Μ. Ander son. 11:20—108. Terpenoid Ethers as Juve nile Hormone Analogs. G. Brieger, R. F. Ellis.
H. H. Jaffe, Chairman
WEDNESDAY MORNING Woodward Room, 5th Floor
Session B. Biopharmaceutical Chemistry H. Dion, Presiding 9:00—109. Interactions of "Platinum Blues" with Polynucleotides. H. C. Pant, R. G. Fischer, Jr., H. J. Peresie, B. Rosenberg, R. Wagner. 9:20—110. Antitumor Activity of "Plati num Blues" and Related Complexes. R. G. Fischer, Jr., H. J. Peresie. 9:40—111. Preparation of Anticancer Colchicine Derivatives. K. K. De, R. E. Harmon.
TUESDAY MORNING East & West Rooms, 5th Floor
Session B. General L. Rand, Presiding 10:00—210. ^-Substituted Phosphorus(lll) Derivatives of 1,2,3-Triazoles. R. Harris, R. Haushalter, D. Tatman, M. Yamauchi, B. West. 10:20—211. The Darzens Synthesis of Glycidic Thiolesters. D. Dagli, J. Wemple. 10:40—212. The Effect of Side-Chain Branching on Reactivity of 12a-Hydroxy Steroids. K. Atkinson, R. T. Blickenstaff. 11:00—213. Formation of Remote Dou ble Bonds by Ferrous Sulfate Cupric Acetate Promoted Decomposition of Primary and Secondary Alkyl Hydro peroxides. Z. Cekovic, M. M. Green. 11:20—214. Reactions of Pyridine Anhydrobases. V. J. Traynelis, J. A. Benvenuto. 11:40—215. Cycloaddition Reactions of a Stable lodonium Ylide. G. F. Koser, S.-M. Yu. TUESDAY
AFTERNOON
East & West Rooms, 5th Floor
Session C. General R. Boeckman, Presiding 2:00—216. Why Are Reverse Electroneg ative Semipolar Bonds Unstable? J. R. Grunwell, A. G. Miller. 2:20—217. 1-Phospha-2,8,9-Trioxaadamantane Ozonide: a Convenient Source of Singlet Molecular Oxygen. A. P. Schaap. A. L. Thayer, K. Kees. 2:40—218. Synthetic Aspects of 6-Azauracil Photoadditions. A Versatile Syn thesis of 5-Substituted-6-Azauracils. J. S. Swenton, R. J. Balchunis. 3:00—219. Photochemically Induced Ad dition of Oxo-Carbinyl Systems to Con jugated Enones. E. R. Hicks, B. Fra ser-Reid.
Washington Room, 5th Floor Session B. General R. A. B o n h a m ,
Presiding
2:00—311. Optical Rotatory Strengths and Magnetic Moments. C. A. Masmanidis, H. H. Jaffe. 2:20—312. The Structures of Ion Pairs Containing /V-Alkylpyridinium Cations. I. M. Walker. 2:40—313. A Modified CNDO Method for Saturated Organic Molecules. J. W. H. Kao, A. Chung-Philips. 3:00—314. Decomposition of Hot Atom Substitution Products. c-C4H7T and cC4D7T. W. L. Hase, C. C. Chou. 3:20—315. Factors Influencing Reverse Osmosis Rejection of Inorganic So lutes from Aqueous Solution. M. E. Heyde, C. R. Peters, J. E. Anderson. 3:40—316. The Enthalpies of Formation of Tc 2 0 7 (c) and Tc0 4 (aq) by Solu tion Calorimetry. A. Y. Herrell, R. H. Busey, Κ. Η. Gayer. 4:00—317. Electrochemistry of Vicinal Dibromides. C.-Y. Li, A. Bazzi, R. J. Darnowski, R. R. Schroeder. 4:20—318. Conductance Behavior of Some Uni-univalent Electrolytes in 2Methyl-pyridine-/V-Oxide at 55° C. J. F. Casteel, P. G. Sears. 4:40—319. Dielectric Constants, Viscosi ties, and Other Physical Properties of Some Liquid Pyridine-/V-Oxides and Cyanopyridines. P. G. Sears, J. F. Casteel. 5:00—320. The Angular Dependence of the Generalized Oscillator Strength for the Lyman-Birge-Hopfield Band in N 2 as Determined by High-Energy Elec tron Impact Spectroscopy. T. Wong, J.-S. Lee, R. A. Bonham.
ANALYTICAL AND ENVIRONMENTAL CHEMISTRY P. O. Warner,
Chairman
MONDAY MORNING
PHYSICAL CHEMISTRY
Methods
Presiding
TUESDAY AFTERNOON
MONDAY
MORNING
Sheraton Room. 5th Floor
Session A. Spectroscopy M. Rogers, Presiding 9:00—301. Infrared Absorption Bands of Coordinated Water in LiOH-H 2 0. I. Gennick, Κ. Μ. Harmon. 9:20—302. Proton NMR Relaxation Study of Dynamic Local Structure in Chloro form-Toluene Mixture. K. W. Woo, T. Tokuhiro. 9:40—303. Proton Arrangement Around Trapped Electrons in Alkaline Ice and Trapped Hydrogen Atoms in Acid Glass Deduced from a Study of Satel lite Lines in ESR Spectra. M. K. Bow man, L. Kevan, R. N. Schwartz. 10:00—304. Effect of Photoionization En ergy on the Distance Distribution Be tween Trapped Electrons and Phenolate Radicals in 10M Sodium Hydroxide Glass and Alcohol Glasses at 77° K. K. Ho, L. Kevan. 10:20—305. Polarization Dependence of Scattered Light Intensity in Dilute Poly mer Solutions. R. A. Harris, W. M. McClain. 10:40—306. Radiationless Transitions in Isolated Large Molecules. J. C. Hsieh, C. S. Huang, E. C. Lim. 11:00—307. On the Nature of the Radi cal Formed by Radiolysis of Adamantane. G. J. Hyfantis, A. C. Ling. 11:20—308. Electron Conduction Band Levels in Liquid Alkanes. S. Noda, L. Kevan. 11:40—309. Selected Properties and Electronic Spectra for a Series of Copper(ll) Alkali, Alkaline Earth, and Lanthanide Metal Chloride Oxyhydrochlorination Catalysts on Alumina. R. L. Dotson. 12:00—310. Negative Ion Charge Exchange Mass Spectrometry. G. P. Reck, S. Y. Tang, E. W. Rothe.
East & West Rooms, 5th Floor Session A. Environmental Chemistry N . I . M c C l e l l a n d , Presiding 9:00—401. Preliminary Evaluation of the Behavior of Zinc, Copper, and Chromi um in the Treatment of Waste Water by Coagulation. C. T. Elly, W. J. Weber, Jr. 9:20—402. The Michigan State Universi ty Water Qualtiy Management Pro gram—A Waste Water Renovation and Re-Use Facility. F. M. D'ltri. 9:40—403. Drinking Water Quality: Ap plication of Monitoring Techniques, J. R. Adams, R. R. Wood, N. I. McClel land. 10:00—404. Effects of Street Salting on Ambient Air Monitoring of Particulate Pollutants in Detroit. P. O. Warner, J. O. Jackson, S. Schaldenbrand, B. Ra phael. 10:20—405. The Photostationary State of Photochemical Smog. J. O. Jackson, D. H. Stedman. 10:40—406. Interactions of Photostation ary State and Other Smog Processes on Urban Ozone Levels. A. Levy.
TUESDAY AFTERNOON Normandy Room, 4th Floor Session B. Analytical A. I. Popov, Presiding 2:00—407. Multifunctional Nonlinear Re gression Analysis. W. H. Sachs. 2:20—408. Physicochemical Studies of Monensin and Sodium Monensin in Chloroform and Methanol Solutions. P. G. Gertenbach, A. I. Popov. 2:40—409. Spectroscopic Studies of Lithium Ion Solvation in Acetone and Âcetone-Nitromethane Mixtures. R. G. Baum, A. I. Popov. 3:00—410. Use of Luminol Reaction for Metal Ion Detection in Liquid Chromatography: pH and Semiaqueous Solvent Studies. R. Delumyea, A. Hartkopf. 3:20—411. Hydrogen Flame Detector—a Challenge of the "FID" Principle. K. F. Sporek. 3:40—412. Solvent Effects of Fluorescence of Aromatic Acids. G. H. Schenk, C. Koziatek, W. A. Reed.
March 1 1 , 1974 C&EN
31
4:00—413. Outer-Sphere Complexes as a Bioanalytical Probe. D. E. Francis. 4:20—414. Application of High-PressureLiquid Chromatography to Tire Analysis. A. Traub. 4:40—415. Use of Intrinsic Fluorescence as an Indicator of Molecular Interaction. M. J. Ruwart, F. Schroeder, J. F. Holland, A. Timnick. 5:00—416. Analytical Applications of a Time-Resolved, Miniature Spark Discharge. R. K. Lantz, E. Glass, S. R. Crouch.
CHEMICAL EDUCATION
10:40—506. Putting the Excitement Back into General Chemistry with the Excited State. G. H. Schenk. 11:00—507. The Energy Crisis: a Teaching Opportunity in the General Chemistry Course for Nonscientists. J. L. Pyle. 11:20—508. General Chemistry for Nurses à la Keller by Long Distance. C. C. Houk. 11:40—509. The Detroit Science Center, a Store-Front Museum. W. M. Shwayder.
INORGANIC CHEMISTRY
K. Henold, Chairman TUESDAY MORNING
TUESDAY MORNING Normandy Room, 4th Floor R. Collins, Presiding 9:00—501. The Effect of Building Construction Materials upon the Public's Exposure to Ionizing Radiation. H. P. Stein. 9:20—502. Balanced Chemical Equations. L. C. Grotz, J. E. Gauerke. 9:40—503. Displaying Molecular Configurations with a Minicomputer Graphics System. W. M. Butler, M. D. Glick. 10:00—504. Improving General Chemistry Lab Instruction via the Use of Computer-Simulated Individualized Prelab Exercises. R. W. Collins. 10:20—505. Optimizing Keller Plan Teaching via the Use of ComputerBased Instructional Materials. R. W. Collins.
Sheraton Room, 5th Floor Session A. General R. DeSimone, Presiding 10:00—601. A Current Awareness Literature Information Retrieval System for Coordination Chemistry. M. A. Richter, S. Kirschner. 10:20—602. The Photochemistry of Some Cyclam and Bisethylenediamine Complexes of Rh(lll). J. B. Sellan, R. C. Rumfeldt. 10:40—603. Complexes of Pd(ll) and Rh(III) with 2-Pyridone and 2-Methoxypyridine. R. L. Kellemeyer, C. C. Houk. 11:00—604. Synthesis and Characterization of Cobalt(ll) Compounds with 1, 4, 7, 10-Tetra-benzyl-1, 4, 7, 10-Tetra azacyclododecane. E. L. Blinn, C. M. Sarther. 11:20—605. Complexes of Molybdenum and Niobium with Cyclic Polythiaether Ligands. R. DeSimone.
Calendar of Events Future ACS national meetings March 31-April 4, 1974. Los Angeles, Calif. Sept. 8-13, 1974. Atlantic City, N.J. April 6-11, 1975. Philadelphia, Pa. Aug. 24-29, 1975. Chicago, 111. Write Meetings Dept., ACS, 1155—16th St., N.W., Washington, D.C. 20036. March 13-14. NSIA Ocean Science and Technology Advisory Committee Spring Mtg. Mayflower Hotel, Washington, D.C. Write National Security Industrial Asso ciation, Dept. OS, Suite 700, 740—15th St., N.W., Washington, D.C. 20005; Tel. 202-393-3620. March 18-20. Seminar on Textile Print ing. Clemson University, Clemson, S.C. Write Office of Professional Development, College of Industrial Management and Textile Science, Clemson University, Clemson, S.C. 29631; Tel. 803-656-3178. March 25-27. 53rd Annual Conv. Gas Pro cessors Assoc. Denver Hilton and Brown Palace Hotels, Denver, Colo. Program chairman: Kenneth H. Rhoads, Shell Oil Co., Houston, Tex. March 29-30. Conf./Workshop on Women in Post Secondary Education. Tuscaloo sa, Ala. Write Mrs. Otis H. Owens, P.O. Box 6293, University, Ala. 35486. May 20-22. Practice of Electron Spectros copy for Chemical Analysis. Purdue University, West Lafayette, Ind. Write W. E. Baitinger, Department of Chemistry, Purdue University, West Lafayette, Ind. 47907. May 20-22. Sth Cellulose Conf. TAPPI and State U of New York. Syracuse, N.Y. Write T. E. Timell, Cellulose Research Inst., SUNY College, Syracuse, N.Y. 13210. May 20-23. Conf. on Biology of Cytoplas mic Microtubules. New York Academy of Sciences. Barbizon Plaza Hotel, New York, N.Y. Write Gary R. Gruber, NYAS, 2 East 63rd St., New York, N.Y. 10021. 32
C&EN March 11, 1974
11:40—606. Synthesis and Some Chemistry of Binuclear Oxomolybdenum(V) Xanthate Complexes. J. W. McDonald, J. L. Corbin, W. E. Newton. 12:00—607. Crystal Lattice Energy Calculations for Several Inorganic Tin (I I) Salts. R. P. Aston, J. D. Wilcox, R. W. Collins. TUESDAY
4:20—615. Further Evidence for FranckCondon Barrier to Electron Transfer Between Low-Spin Cobalt (I I) and Cobalt(lll). W. Schmonsees, M. D. Glick, J. F. Endicott. 4:40—616. Trans-Labilization Effects of Alkylated Cobalt(lll) Complexes. D. J. Halko, J. F. Endicott.
WEDNESDAY MORNING
AFTERNOON
Sheraton Room, 5th Floor Session B. Transition Metal Chemistry
Sheraton Room, 5th Floor Session C. Organometallic, General K. H e n o l d , Presiding
A. B. P. Lever,
9:00—617. Carbon-13 NMR of Mercury, Zinc, and Aluminum Organometallics Containing Terminal Olefin Functionality. M. Albright, J. St. Denis, J. P. Oliver. 9:20—618. Exchange Reactions of Methyl Mercury Mercaptides. R. D. Bach, A. T. Weibel. 9:40—619. 31 P NMR Study of Some Phosphine Complexes of Pd(ll) and Pt(ll). I. Lin, J. P. Fackler, Jr. 10:00—620. The UV-Visible Absorption Spectra of Silylmercury Compounds. T. F. Schaaf, A. K. Hovland, J. P. Oliver. 10:20—621. An NMR Investigation of Bridge-Terminal Exchange in Tris-Tolylaluminum Derivatives. T. P. Stanford, Jr., K. L. Henold. 10:40—622. A Spectroscopic Study of Tetrasulfur Dinitride. R. Kanczuzewski, A. G. Turner. 11:00—623. X-Ray Photoelectron Spectroscopy of Inorganic and Organometallic Compounds of Molybdenum. L. J. Matienzo, S. O. Grim. 11:20—624. Studies on Cyclopentadienyldimethylindium(lll). Β. Η. Freeland, D. G. Tuck.
Presiding
2:00—608. Further Aspects of the d-d and Charge Transfer Spectra of Tetragonal Metal Complexes. A. B. P. Lever, G. London. 2:20—609. The Effects of Optically Active Coordination Compounds on the Mutarotation and Optical Rotation of Glucose. R. V. Moraski, S. Kirschner. 2:40—610. The Nature of Electronic Excited States of Ru(lll) Complexes as Elucidated by Magnetic Circular Dichroism at Cryogenic Temperatures. A. F. Schreiner, R. S. Evans. 3:00—611. ESR and NMR of Fe(CN) 5 NH 3 2 . B. R. McGarvey, C. Ezzeh. 3:20—612. Synthesis and Kinetics of the First-Stage Aquation of C/s-Dichlorobis(Meso- and DL-Butylenediamine) Chromium(lll) Cations. C. P. Madhusudhan, J. A. McLean, Jr. 3:40—613. Magnetic Exchange Between V(IV)-V(IV) in Some Binuclear VO(II) Chelates of 1, 3, 5-Triketonates. R. L. Lintvedt, J. Mack. 4:00—614. An Investigation of the Permanganate lon-Vanadium(IV) Reaction. K. W. Hicks, F. W. Moore.
May 21-22. ASTM Symp. on Properties of Materials for Liquid Natural Gas. Statler Hilton Hotel, Boston, Mass. Write Hank Hamilton, ASTM, 1916 Race St., Philadelphia, Pa. 19103. May 21-23. 4th Intl. Environmental Expo sition and Conf. Hyatt Regency O'Hare Hotel, Chicago, 111. Write John Slater, McGraw-Hill Publications Co., 1221 Ave. of the Americas, New York, N.Y. 10020. June -7. 8th Miles Intl. Symp.—1st Sec tion. Johns Hopkins Medical Institutions, Baltimore, Md. Write Edward G. Bassett, Miles Labs, Elkhart, Ind. 46514. June 17-21. Inter/Micro-74 Conferences on Microscopy. Hyatt Regency, Chicago, 111. Write Inter/Micro-74, McCrone Re search Institute, 2820 South Michigan Ave., Chicago, 111. 60616. June 19-20. 2nd Natl. Biomedical Plastics Conf. Chicago, 111. Write William A. Kulok, 600 Third Ave., 37NR, New York, N.Y. 10016. June 22-28. (ith Intl. Chemical Fair. Park of Recreation, Bratislava, Czechoslovakia. Write Incheba, Foreign Trade Corp., Drienova 24, 829 57 Bratislava, CzechoslovaJune 24-25. 8th Miles Intl. Symp.—2nd Section. U College London, London, En gland. Write Edward G. Bassett, Miles Labs, Elkhart, Ind. 46514.
ACS Short Courses March 17-22. Minicomputers and Inter facing. Dr. Raymond Dessy and David Larsen. Blacksburg, Va. March 30-31. Column Selection in Gas Chromatography. Dr. Harold M. McNair and Dr. Walter Supina. Los Angeles, Calif. March 30-31. Management of Technology. Dr. Philip Marvin. Los Angeles, Calif. April 6-7. Modern Liquid Chromatogra phy. Dr. Lloyd R. Snyder and Dr. J. J. Kirkland. Atlantic City, N.J.
April 19-20. Interpretation of Infrared Spectra. Norman Colthup. New York City. May 9-10. Organic Synthesis—Modern Reactions and Approaches. Dr. Barry Trost and Dr. Edwin Vedejs. Chicago, 111. May 15-17. Principles of Color Technolo gy. Dr. Fred Billmeyer, Jr. Boston, Mass. May 16-18. Emulsions and Dispersions. Dr. Sydney Ross and Dr. Frederick Fowkes. Houston, Tex. May 29-31. Laboratory Safety—Recogni tion and Management of Hazards. Nor man V. Steere, Dr. Rodney L. Olsen, and Maurice Golden. New York City. June 1-2. Modern Liquid Chromatog raphy. Dr. Lloyd R. Snydër and Dr. J. J. Kirkland. Minneapolis, Minn. June 3-7. Gas Chromatography, Theory and Practice. Dr. Harold M. McNair and Dr. James Miller. Blacksburg, Va. To register or obtain complete information on the courses, student discounts, and free enrollment for unemployed ACS members, write to Department of Educational Activities, American Chemical Society, 1155— 16th St., N.W., Washington, D.C. 200,36. During the two-week period prior to a course, registration should be by telephone: area code 202, 872-4508.
MEN AND MOLECULES March 15 MORE POWER, LESS POLLUTION Daniel Bienstock U.S. Bureau of Mines
