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Pick-Congress, Florentine Room (3rd Floor North). Symposium on Chemistry for Health Science Students. W. A. Nevill, Presiding. 2:00—Introductory Rem...
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COUNCIL COMMITTEE ON CHEMICAL EDUCATION J. J. Hazdra, Chairman W. A. Nevill, Secretary MONDAY MORNING Symposium on Chemical Industry Career Opportunities for B.S. Chemists Joint with Council Committee on Economic Status and Division of Professional Relations (see page 63) MONDAY AFTERNOON Pick-Congress, Florentine Room (3rd Floor North) Symposium on Chemistry for Health Science Students W. A. Nevill, Presiding 2:00—Introductory Remarks. 2:05—1. School Guidance and the HealthRelated Fields. J. C. Oberhart. 2:20—2. Appropriate Chemistry Courses for Allied Health Students. R. C. Kuhli. 2:40—3. Chemistry for Baccalaureate Nursing Students. J. S. Moore. 3:00—4. The Molecular Basis of Life—A Course for Nurses. J. R. Holum. 3:20—5. The Dilemma of Academic PreProfessional Programs. H. B. Williams. 3:40—6. Organic Chemistry for Health Science Students. A. L. Ternay, Jr. 4:00—Panel Discussion. 4:30—Open Forum. 5:00—Concluding Remarks.

COUNCIL COMMITTEE ON CHEMICAL SAFETY H. H. Fawcett, Chairman TUESDAY MORNING Symposium on Resources for Chemical Health and Safety—Part I Joint with Divisions of Chemical Education, Inc. and Chemical Health and Safety (Probationary) (see page 36)

COUNCIL COMMITTEE ON ECONOMIC STATUS M. M. Joullie, Chairman

TUESDAY MORNING

MONDAY

P. C. Barlow, Presiding

Pick-Congress, Plaza Room (2nd Floor) MORNING

Symposium on Chemical Industry Career Opportunities for B.S. Chemists Joint with Council Committee on Chemical Education and Division of Professional Relations (see page 63)

H. M. Free,

Chairperson

TUESDAY AFTERNOON

COUNCIL COMMITTEE ON TECHNICIAN ACTIVITIES J. F. Wilkes, Chairman P. C. Barlow, Symposium Chairman MONDAY MORNING AND AFTERNOON Pick-Congress, Plaza Room (2nd Floor)

P. C. Barlow, Presiding 9:00—Introductory Remarks. J. F. Wilkes. 9:10—Keynote Address. 9:30—1. Electrophoretic Mass Transport Analyzer: Operation Characteristics with Aqueous Solutions and Applicability to Organic Liquid-Solid Systems. J. D. Hewitt. 10:00—2. Fire, Explosion, Detonation—The Big 3 in Refinery Hazards. H. G. Meyers. 10:30—3. Moisture in Foods via Beckman Aquameter K-4B. V. G. Hicks. 11:00—Intermission. 11:15—4. Suppression and Enhancement Effects in Emission Spectroscopy. W. C. Thompson, Jr. 11:45—Concluding Remarks. P. C. Barlow. 2:00—Introductory Remarks. 2:05—5. Composition Gradient During Electrolysis in Mixtures Analogous to Molten Salt Battery Electrolytes. D. E. Heatherly, C. E. Vallet. 2:35—6. Thermography—The Photography of Heat. R. Zeigler. 3:35—7. Plants as Solar Bioconverters. M. Price.

C & E N J u l y 2 5 , 1977

DIVISION OF AGRICULTURAL AND FOOD CHEMISTRY M. E. Mason, Chairman A. Pour-El, Secretary-Treasurer MONDAY MORNING

Symposium on Resources for Chemical Health and Safety—Part II Joint with Divisions of Chemical Education, Inc. and Chemical Health and Safety (Probationary) (see page 36)

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R. L. Moore, Presiding 2:00—1. Science, Technology, and the Public: An Overview. I. S. Bengelsdorf. 2:30—2. Science Writing for a Daily Newspaper. R. M. Kotulak. 2:55—3. Science Reporting in a Monthly Magazine. S. H. Day, Jr. 3:20—4. Science Reporting for Radio and TV. Speakers to be announced. 3:45—Panel Discussion.

E. L. Murphy, R. A. Flath, T. R. Mon, R. Teranishi, R. M. Timm, W. E. Howard. 10:15—9. Methodology of Behavioral Testing Associated with Development in Animal Foods. J. C. Smith, M. E. Rashotte. 10:50—10. Review of Food Preference Behavior in Birds and Mammals. S. A. Shumake. 11:25—11. Biochemical and Pharmacological Aspects of Preference Behavior. G. V. Odell.

Section C Conrad Hilton, Waldorf Room (3rd Floor) Symposium on Role of Universities in Agricultural and Food Progress. Part IV

H. Prebluda, Presiding

Palmer House, Parlor H (6th Floor) Symposium on Science, Technology, The Mass Media, and The Public

General

Smoking and nonsmoking sections in technical session meeting rooms have been designated as follows: Smoking: left side of room Nonsmoking: right side of room

9:00—9. Introductory Remarks—Short Term Testing for Potential Carcinogens. B. Butterworth. 10:15—Open Meeting, Council Committee on Technician Activities. 10:45—Open Meeting, National Council of Chemical Technician Affiliates.

COUNCIL COMMITTEE ON PUBLIC RELATIONS

TUESDAY AFTERNOON

Smoking/nonsmoking

4:05—8. The Technician's Role in Reducing Costs of Company Operation Or The Job You Save May Be Your Own. R. E. Imars.

Section A

Conrad Hilton, Boulevard Room (2nd Floor) Symposium on Analysis of Food and Beverages—Headspace Techniques

G. Charalambous, Presiding 9:00—Introductory Remarks. 9:05—1. Headspace Sampling: Use and Abuse. W. G. Jennings, S. G. Wyllie, M. Filsoof. 9:25—2. Quantitative Head Space Analysis: Total and Specific Group Analysis. H. Maarse, J. Schaefer. 9:45—3. A Technique for the Determination of Volatile Organic Compounds Under Equilibrium and Non-Equilibrium Conditions. F. Z. Saleeb, T. W. Schenz. 10:05—Discussion. 10:20—Intermission. 10:30—4. Porous Polymer Trapping for GC/MS Analysis of Vegetable Flavors. A. L. Boyko, M. E. Morgan, L. M. Libbey. 10:50—5. Isolation of Trace Volatile Constituents of Hydrolyzed Vegetable Protein via Porous Polymer Headspace Entrainment. D. A. Withy combe, B. D. Mookherjee, A. Hruza. 11:10—6. Headspace Techniques Used in the Analysis of Volatile Components from Lipoxygenase Catalyzed Reactions. J. A. Singleton, H. E. Pattee. 11:30—Discussion.

Section B Conrad Hilton, Beverly Room (3rd Floor) Symposium on Flavor Chemistry of Animal Foods

R. Bullard, Presiding 9:00—Introductory Remarks. 9:05—7. Progress in Animal Flavor Research. M. R. Kare, G. K. Beauchamp, W. W. Jacobs. 9:40—8. Isolation, Identification and Biological Activity Assay of Chemicals from Materials Attractive or Repellant to the Coyote.

9:00—Introductory Remarks. 9:05—12. Agricultural and Food Research at the" West Virginia University Agricultural Experiment Station. J. L. Brooks, D. A. Stelzig. 9:40—13. Contributions of the North Dakota Agricultural Experiment Station to Progress in Food and Agriculture. K. A. Gilles, D. G. McCullough. 10:15—14. Relevant Research in Meat and Meat Products—The Wyoming Agricultural Heritage. J. E. Kunsman. 10:50—15. The Role of the Virginia Agricultural Experiment Station in Agricultural and Food Research Progress. C. T. Wilson, P. H. Massay, Jr., S. J. Ritchey. 11:25—16. Chemurgy in Retrospect at Tuskegee Institute. B. D. Mayberry. MONDAY AFTERNOON

Section A

Conrad Hilton, Boulevard Room (2nd Floor) Symposium on Analysis of Food and Beverages—Headspace Techniques

G. Charalambous, Presiding 2:00—Introductory Remarks. 2:05—17. Headspace Techniques Utilized for the Detection of Volatile Flavor Compounds of the Vanilla Bean. I. Klimes, D. Lamparsky. 2:25—18. Aroma Analysis of Coffee, Tea and Cocoa by Head Space Techniques. O. G. Vitzthum, P. Werkhoff. 2:45—Discussion. 3:00—Intermission. 3:15—19. Determination of Citrus Volatiles by Headspace Analysis. E. D. Lund, H. L. Dinsmore. 3:35—20. Headspace Techniques in Mouth Odor Analysis. D. A. M. Mackay, M. M. Hussein. 4:05—Discussion.

Section B Conrad Hilton, Beverly Room (3rd Floor) Symposium on Flavor Chemistry of Animal Foods

R. Bullard, Presiding 2:00—21. The Flavor Chemistry of Carnivore Taste Systems. J. C. Boudreau, T. D. White. 2:35—22. Bacterial Action and Chemical Signalling in the Red Fox and Other Mammals. E. S. Albone, P. E. Gosden, G. C. Ware, D. W. Macdonald, N. Hough. 3:10—23. The Process of Developing Palatable Foods for Domestic Pets. T. L. Fazzina. 3:45—24. Development of Diets for FoodProducing Animals. W. Chalupa, C. A. Baile. 4:20—25. Repellents to Protect Crops from Vertebrate Pests: Some Considerations for Their Development. J. G. Rogers, Jr. 4:55—Concluding Remarks.

Section C Conrad Hilton, Waldorf Room (3rd Floor) Symposium on Role of Universities in Agricultural and Food Progress. Part IV H. Prebluda, Presiding 2:00—Introductory Remarks. 2:05—26. Advances in Mechanization and Handling of Horticultural Crops at the University of Arkansas. J. R. Morris, R. W. Buescher. 2:40—27. The Role of the New Mexico Agricultural Experiment Station in Food Research. N. L. Newcomer, V. Johansen, J. H. Wilson. 3:15—28. Food Chemistry Research at North Carolina State University. H. E. Swaisgood. 3:50—29. Successful Cooperative Research—Bringing People Together. S. H. Wittwer. 4:25—30. The Role of Biochemistry in Food Research at the Delaware Agricultural Experimental Station. J. P. Zikakis. TUESDAY MORNING

Section A

Conrad Hilton, Boulevard Room (2nd Floor) Symposium on Analysis of Food and Beverages—Headspace Techniques G. Charalambous, Presiding 9:00—Introductory Remarks. 9:05—31. Flavor Profiling of Beer Using Statistical Treatments of G LC Headspace Data. J. T. Hoff, E. Chicoye, J. R. Helbert, W. C. Herwig. 9:35—32. Sensory and Instrumental Evaluation of Wine Aroma. A. C. Noble. 10:05—Discussion. 10:25—Intermission. 10:45—33. Sake Flavor and its Improvement Using Metabolic Mutants of Yeast. H. Akiyama, K. Yoshizawa, K. Ouchi. 11:05—34. Concentration and Identification of Trace Constituents in Alcoholic Beverages. R. ter Heide, P. J. de Valois, J. Visser, P. P. Jagers, R. Timmer. 11:25—Discussion. Section B Conrad Hilton, Beverly Room (3rd Floor) Symposium on Defining Fiber in Human Nutrition G. A. Spiller, Presiding 9:00—35. Defining Some Current Problems in Plant Fiber (Plantix) Research. G. A. Spiller, E. A. Shipley. 9:30—36. The Definition and Analysis of Fiber in Human Foods and Nutrition. D. A. T. Southgate. 10:00—37. Defining "Dietary Fiber" from an Applied Point of View. D. R. Schaller. 10:20—38. The Role of Fiber in Gut Fermentation. P. J. Van Soest, J. B. Robertson. 10:50—39. Effect of Selected Fiber Sources on Mineral Balance. H. H. Sandstead, J. Munoz, L. Klevay, R. Jacob, S. Reck, F. Dintzis, G. Inglett, W. Shuey. 11:00—Let Us Define Fiber. Round Table Discussion (All Speakers).

Section C Conrad Hilton, Waldorf Room (3rd Floor) General

D. S. Ryan, Presiding 9:00—Introductory Remarks. 9:05—40. Some Chemical and Nutritional Properties of Acylated Fish Proteins. H. S. Groninger, Jr., R. Miller. 9:20—41. Effects of Peroxides, Organic Solvents, Heat and Polyphenols on Antigenicity and Conformation of Oilseed Globulin. T. J. Jacks, N. J. Neucere. 9:40—42. Effect of Ammoniated Casein in the Diet of Weanling Rats. V. H. Molsinger, Y. Hafez, P. M. T. Hansen. 10:00—43. The Origin of High Methionine Content in Sugary-1 Corn Endosperm. J. W. Paulis, J. S. Wall, J. Sanderson. 10:20—44. Carbohydrate Comparisons of Agricultural Residues by GLC. L. H. Krull, G. E. Inglett. 10:40—45. Fractionation and Characterization of Alcohol-Soluble Reduced Corn Endosperm Glutelin Proteins. J. W. Paulis, J. S. Wall. 11:00—46. Preparation of Sweet Potato Leaf Protein Concentrate. W. M. Walter, Jr., A. E. Pureed.

11:20—47. Chromatographic, Electrophoretic, and Ultracentrifugational Purification and Analysis of Green Complex from Zucchini Squash. F. J. Bonner, A. Marchesini. 11:40—48. Retention of Methyl Ketones During Spray Drying of Model Systems Containing Different Fats. H. C. Anderson, G. A. Reineccius. TUESDAY AFTERNOON Section A Conrad Hilton, Beverly Room (3rd Floor) Symposium on Lipids as a Source of Flavor M. K. Supran, Presiding 2:00—Introductory Remarks. 2:10—49. The Role Lipids Play in the Positive and Negative Flavors of Food. I. Litman. 2:50—50. Flavor Generated by Lipids at the High Temperatures of Food Processing. S. S. Chang, R. J. Peterson, C.-T. Ho, M. S. Smagula. 3:30—51. Volatiles from Frying Fats. A Comparative Study. W. W. Nawar. 4:10—52. Instrumental Analysis of Volatiles in Food Products. H. P. Dupuy, M. L. Brown, S. P. Fore, M. G. Legendre, J. I. Wadsworth, E. T. Rayner. 4:50—Concluding Remarks. 5:00—Flavor Subdivision Business Meeting. 5:00—Protein Subdivision Business Meeting (see Section B for location). Section B Conrad Hilton, Boulevard Room (2nd Floor) Symposium on Improvement of Protein Nutritive Quality of Foods and Feeds M. Friedman, Presiding 2:00—Introductory Remarks. 2:05—53. Improvement of Wheat Protein Quality and Quantity by Breeding. V. A. Johnson, P. J. Mattern. 2:30—54. The Current Status of Breeding for Protein Quality in Corn. D. Deutscher, M. S. Zuber. 2:55—55. Potential for Improving Cottonseed Quality by Genetic and Agronomic Practices. J. P. Cherry, J. G. Simmons. 3:15—56. Fortification of Foods and Feeds with Essential Amino Acids—Lysine, Methionine, Threonine, Tryptophan. N. J. Benevenga. 3:40—57. The Utilization of Acetylated Amino Acids. R. W. Boggs. 4:10—58. N-Substituted Lysines as Sources of Lysine in Nutrition. P. A. Flnot, F. Mottu, E. Bujard, J. Mauron. 4:35—59. Nutritional Improvement of Food Proteins by Means of the Plastein Reactions and its Novel Modification. S. Aral, M. Yamashita, M. Fujimaki. 5:00—Protein Subdivision Business Meeting. 5:00—Flavor Subdivision Business Meeting (see Section A for location). WEDNESDAY MORNING

Section A

Conrad Hilton, Boulevard Room (2nd Floor) Symposium on Lipids as a Source of Flavor M. K. Supran, Presiding 9:00—Introductory Remarks. 9:10—60. Generation of Aroma Compounds from Photo-Oxidation of Unsaturated Fatty Acids. B. D. Mookherjee, R. W. Trenkle. 9:50—61. Chemical Changes Involved in the Oxidation of Lipids Found in Foods. D. A. Lillard. 10:30—62. Flavor Problems in the Usage of Soybean Oil and Meal. H. J. Dutton. 11:10—63. Flavors from Lipids by Microbiological Action. L. W. Haymon. 11:50—Concluding Remarks. Section B Conrad Hilton, Beverly Room (3rd Floor) Symposium on Chemical and Nutritional Aspects of Dairy Wastes V. H. Holsinger, W. J. Harper, Cochairmen V. H. Holsinger, Presiding 9:00—Announcements. 9:05—Introductory Remarks. W. Clark.

9:20—64. Effect of Whey Applications on Chemical Properties of Soils and Crops. A. E. Peterson, W. G. Walker, K. Watson. 9:50—65. Physico-Chemical Problems of Some Older Whey Processing Technologies. P. Jelen. 10:20—66. Effects of Pretreatment of Whey on Membrane Processing. L. L. Muller, W. J. Harper. 10:50—67. Large-Scale Gel Filtration of Whey and Whey Proteins. J. K. Donnelly, R. A. M. Delaney. 11:20—68. Physical-Chemical Behavior of Whey Protein Foams. S. H. Richert. 11:50—69. Nutritional Properties of Whey Proteins and Some Foods Supplemented with Them. V. Racotta, H. Bourges, A. Navarrete, J. Zuckermann.

Section C Conrad Hilton, Waldorf Room (3rd Floor) General J. R. Whitaker,

Presiding

9:00—Introductory Remarks. 9:05—70. Elimination of Lactose Interference in the 19F NMR Determination of Available Lysine in Whey Proteins. J. R. Cavanaugh, J. P. Malpin. 9:25—71. High Performance Liquid Chromatographic Method for the Determination of 25-Hydroxycholecalciferol in Chicken Egg Yolks. K. T. Koshy, A. L. VanDerSlik. 9:45—72. High Performance Liquid Chromatographic Method for the Determination of 25-Hydroxycholecalciferol in the Bovine Liver, Kidney, and Muscle. K. T. Koshy, A. L. VanDerSlik. 10:05—73. A Rapid and Sensitive Analysis for Lysionalanine in Proteins and its Application to Food Products. M. L. Raymond, D. A. Viviano. 10:25—74. Thin Layer Chromatography—A Screening Procedure for Histamine in Foods. E. R. Leiber, S. L. Taylor. 10:45—75. Determination of Geosmin in Beet Juice by Gas Chromatography. L. D. Tyler, T. E. Acree, R. R. Nelson, R. M. Butts. 11:05—76. Extraction of Important Molecular Features of Musk Compounds Using Pattern Recognition Techniques. W. E. Brugger, P. C. Jurs. 11:25—77. Membrane Dialysis as a Means of Separating Flavor Compounds from Fatty Foods. K. A. Franklin, G. A. Reineccius. 11:45—78. The Microbial Conversion of Methionine to Methionine Hydroxy Analog and its Natural Occurrence in Various Foods and Feed Products. I. J. Belasco, H. L. Pease, R. W. Reiser. WEDNESDAY AFTERNOON

2:00—Introductory Remarks. 2:05—85. Enforced Catalysis of Additions to the Carbonyl Group. W. P. Jencks. 2:45—86. Transition State Structures for Simple Carbonyl Addition Reactions and for Hydrolysis of Nucleosides. E. H. Cordes. 3:25—87. The Carbonyl-Amine Reaction as a Tool in Protein Chemistry. R. E. Feeney. 4:05—88. Formaldehyde as a Probe of Nucleic Acids. J. D. McGhee. 5:00—Divisional Business Meeting. 6:00—Divisional Social Hour (see Section A for location). 7:00—Divisional Award Dinner (see Section A for location). THURSDAY MORNING

Section A

Conrad Hilton, Boulevard Room (2nd Floor) Symposium on The Carbonyl-Amine Reaction in Biological Systems Joint with Division of Biological Chemistry

R. E. Feeney, W. P. Jencks, Cochairmen W. P. Jencks, Presiding 9:00—Introductory Remarks. 9:05—89. Comparative Aspects of Some Carbonyl Group Dependent Enzymatic Reactions. E. E. Snell, M. N. Kazarinoff. 9:40—90. Suicide Substrates for Pyridoxalp-Dependent Enzymes. C. Walsh. 10:15—91. The Structure and Metabolism of Crosslinks in Elastin and Collagen. R. B. Rucker. 10:50—92. The Reaction of Carbon Dioxide with Amino Groups in Model Systems, Peptide Hormones, and Hemoglobin. J. B. Matthew, R. J. Wittebort, D. F. Hayes, T. M. Rothgeb, R. S. Gurd, F. R. N. Gurd. 11:25—93. The Maillard Reaction—Good, Bad, but Seldom Indifferent. J. E. Hodge. Section B Conrad Hilton, Parlor C (3rd Floor) Symposium on Nutrition and Chemical Carcinogens C. Morr, Presiding 9:00—Introductory Remarks. 9:05—94. Pathology of Human and Experimental Animal Tumors Related to.Dietary Contaminants, Deficiencies and Excesses. A. E. Rogers. 9:45—95. Metabolic Activation of Chemical Carcinogens to Reactive Mutagenic Electrophiles. J. A. Miller. 10:25—96. The Activation and Detoxification of Benzo(a)pyrene. H. V. Gelboin. 11:05—97. The Chemical Nature of Mutagens in Human Feces. W. R. Bruce. 11:45—Concluding Remarks.

Section A Conrad Hilton, Beverly Room (3rd Floor) Symposium on Chemical and Nutritional Aspects of Dairy Wastes V. H. Holsinger, W. J. Harper, Cochairmen V. H. Holsinger, Presiding 2:00—Announcements. 2:05—79. Lactose Chemistry. T. A. Nickerson. 2:35—80. Medical Aspects of Lactose Intolerance. D. M. Paige. 3:05—81. Food Additives Derived from Lactose: Lactitol and Lactitolpalmitate. J. A. van Vetthuijsen. 3:35—82. Utilization of Whey/Lactose as an Industrial Binder. A. Ferretti, J. V. Chambers. 4:05—83. Nutritional Aspects of Refeeding Cattle Manure to Ruminants. W. L. Johnson. 4:35—84. USDA Research on Whey and Whey Products as Feed for Cattle. G. P. Lynch, F. E. McDonough. 5:00—Divisional Business Meeting (see Section B for location). 6:00—Divisional Social Hour. Sages East Restaurant, 181 E. Lake Shore Dr. 7:00—Divisional Award Dinner. Sages East Restaurant, 181 E. Lake Shore Dr. Section B Conrad Hilton, Waldorf Room (3rd Floor) Symposium on The Carbonyl-Amine Reaction In Biological Systems Joint with Division of Biological Chemistry R. E. Feeney, W. P. Jencks, Cochairmen R. E. Feeney, Presiding

THURSDAY AFTERNOON

Section A

Conrad Hilton, Boulevard Room (2nd Floor) Symposium on Nutrition and Chemical Carcinogens C. Moor, Presiding 2:00—Introductory Remarks. 2:05—98. Development of New Bacterial Testers for Chemical Carcinogens. I. C. Felkner. 2:45—99. Effect of Dietary Lipids on the Carcinogenicity of 2-Acetylaminofluorene. S. P. Yang, C. E. Castro, I. C. Felkner, H. F. Sproat. 3:25—100. Dietary Factors in Cancer of the Breast and Intestine. J. H. Weisburger, E. L. Wynder. 4:05—101. Potential Role of Diet and Nutrition in the Prevention of Cancer. L. O. Crosby. 4:45—Concluding Remarks.

Smoking/nonsmoking Smoking and nonsmoking sections in technical session meeting rooms have been designated as follows: Smoking: left side of room Nonsmoking: right side of room

July 25, 1977 C&EN

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Section B Conrad Hilton, Parlor C (3rd Floor) Symposium on Improvement of Protein Nutritive Quality of Foods and Feeds M. Friedman, Presiding 2:00—102. Production of Essential Amino Acids by Microbial Process. K. Nakayama, K. Araki, H. Kase. 2:25—103. Nutritive Quality of Peanut Protein. A Critical Appraisal of the Influence and Significance of Processing on the Availability and Order of Limiting Amino ACIDS/ K. Anantharaman, J. Decombaz, F. Mottu, J. Mauron. 2:50—104. Amino Acid Supplementation of Isolated Soya Bean Protein in Milk Replac e s for Preruminant Lambs. R. Pelaez, D. D. Phillips, D. M. Walker. 3:15—105. Nutritional Evaluation of Oilseeds and Legumes as Protein Supplements to Cereals. G. Sarwar, F. W. Sosulski, J. M. Bell, J. P. Bowland. 3:40—106. Soy Protein Utilization in Food Systems. G. N. Bookwalter. 4:05—107. Cottonseed Protein Derivatives as Nutritional and Functional Supplements in Food Formulations. J. P. Cherry, L. C. Berardi, C. H. Vinnett. 4:30—108. Use of High-Quality Protein Cereals in Yeast-Leavened Breads. E. T. Mertz, A. C. Brinegar, M. J. Sammarco, P. J. Stover. FRIDAY MORNING

Section A

Conrad Hilton, Boulevard Room (2nd Floor) Symposium on Improvement of Protein Nutritive Quality of Foods and Feeds M. Friedman, Presiding 9:00—109. Fortification of Soft Drinks with Protein from Cottage Cheese Whey. V. H. Holsinger. 9:20—110. Production of Animal Protein from Nonprotein Nitrogen Chemicals. W. Chalupa. 9:50—111. The Problem of Curvature in Slope Assays for Protein Quality. J. M. McLaughlan. 10:10—112. Comparative Results of Human and Small Animal Bioassays of Protein Quality. C. Kies, H. M. Fox. 10:40—113. Position Paper on RDA for Protein for Children. R. P. Abernathy, S. J. Ritchey. 11:05—114. Effect on Nitrogen Retention by Young Adults of Different Proportions of Indispensable Amino Acids in Isonitrogenous Cereal-Based Diets. H. E. Clark, M. F. Brewer, L. B. Bailey. 11:30—115. Amino Acid Composition of Hair from Malnourished Children. M. Friedman, R. Orraca-Tetteh. 11:45—116. An Inexpensive Micro-Bore Amino Acid Analyzer from Commercially Available Components. G. R. Beecher. Section B Conrad Hilton, Beverly Room (3rd Floor) General R. E. Feeney,

Presiding

9:00—117. Non-Enzymic Browning. Effect of pH, Temperature, and Molecular Structure of Amino Acids on Development of Color, Odor, and Aroma in Ribose-Amino Acids Systems. A. ?. Mabrouk. 9:15—118. Siudies on the Effect of Processing on Beef Flavor. Changes in Aqueous Flavor Precursors. A. F. Mabrouk. 9:30—119. Volatile Constituents of Prickly Pear (Opuntia ficus indica Mill., var. de Castilla). R. A. Flath, J. M. Takahashi. 9:50—120. Effect of BHA and TBHQ on Lipid Synthesis in Tetrahymena pyriformis. J. G. Surak. 10:10—121. Identification of the Volatile Flavor Constituents of Fresh, Frozen Beef Stew. R. J. Peterson, S. S. Chang. 10:30—122. The Absorption, Tissue Distribution and Metabolic Excretion of Mono(2-Ethylhexyl)phthalate in the Rat. I. Chu, D. C. Villeneuve, V. Secours, A. Viau, G. Rock. 10:50—123. Musty Components of Table Beet Odor. T. E. Acree, L. D. Tyler, C. Y. Lee, R. R. Nelson, R. M. Butts. 11:10—124. The Aroma Composition of Catawba (V. Labruscana Bailey) Wine. R. R. Nelson, T. E. Acree, R. M. Butts, R. M. Pool, W. B. Robinson. 11:30—125. Myristicin Content in the Volatile Oil from Various Carrot Cultivars. M. B. Bohannon, R. Kleiman, L. R. Baker.

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11:50—126. Lipase-Catalyzed Acyl Exchange in Triglycerides: Effect of pH, Temperature and Acid Concentration. R. W. Stevenson, F. E. Luddy, H. L. Rothbart.

ANAL DIVISION OF ANALYTICAL CHEMISTRY J. W. Miller, Chairman F. A. Guthrie, Secretary MONDAY MORNING

Sievers, R. H. Shapiro, H. F. Walton, G. A. Eiceman, R. M. Barkley. 2:20—14. Analyses of Textile Effluent and Tobacco Smoke Condensate Samples by Glass Capillary GC/MS/COM. M. Gordon. 2:40—15. High Performance GC-Aspects of Columns Design and Selection. J. R. Jeffs. 3:00—16. Glass Capillary GC-MS Analysis of Organics in Drinking Water Concentrates and Advanced Waste Treatment Concentrates. D. C. K. Lin, B. A. Petersen, R. G. Melton, W. E. Coleman. 3:20—17. Applications of Dexsil and Other PLOT GC Columns to Metal Compound Separations and Pyrolysis. P. C. Uden, F. P. DiSanzo, D. E. Henderson, R. J. Lloyd, T. Tetu. 3:40—18. Indirect Evidence of Imprinting of Hepatic Enzyme Systems in the Human Using High Resolution Glass Capillary Gas Chromatography. C. D. Pfaffenberger. 4:00—19. Simultaneous Determination of Multiple Testicular Steroids Utilizing High Resolution Glass Capillary Gas Chromatography. R. H. Wohleb, L. L. Hilton, M. J. Free.

Section A

Palmer House, Wabash Parlor (3rd Floor) Symposium on High Resolution Gas Chromatography: Columns and Analyses

S. P. Cram, Presiding 9:00—Introductory Remarks. 9:10—1. Capillary Gas Chromatography: A Story of Success in Modern Analytical Chemistry. M. Novotny. 10:00—2. High Resolution Separations with Metal & Glass Large Bore Open Tubular Columns. R. Teranishi, R. A. Flath, T. R. Mon. 10:20—3. Characteristics and Performance of High Resolution Glass Capillary GC Systems. S. P. Cram, F. J. Yang. 10:40—4. Twenty Years Open Tubular (Capillary) Columns—An Overview. L. S. Ettre. 11:00—5. Developments in PLOT Column Technology. J. G. Nikelly, P. C. Uden, D. E. Henderson. 11:20—6. High Resolution Columns in Gas Chromatography. W. Bertsch, E. L. Anderson, M. Moskot. 11:40—7. High Efficiency GC Columns. J. Clemons, H. McNair. Section B Palmer House, Parlor B (6th Floor) Symposium on Ultratrace Metal Analysis in Biological Sciences and Environment T. H. Risby, Presiding 9:00—Introductory Remarks 9:15—8. Trace Element Analysis in Nutrition Research. W. Mertz. 9:55—9. Simultaneous Multi-element Analysis of Biologically Related Samples with a RF—ICP. Advantages and Limitations. F. N. Abercrombie, M. D. Silverster, R. B. Cruz. 10:15—Intermission. 10:30—10. Health Implications of Trace Metals in the Environment. K. Bridbord. 11:10—11. The Analysis of Molybdenum in Biological Materials. G. E. Bentley, L. Markowitz, R. R. Meglen. 11:30—12. Analysis for Size-Fractionated Airborne Particulate Matter for Metals by Atomic Absorption Spectroscopy and Neutron Activation Analysis. G. J. Rosenberger, W. D. Smith, W. W. Miller, T. H. Risby. Section C Symposium on Novel Instrumental Methods for Probing Polymer Structures Joint with Division of Polymer Chemistry Inc. (see page 60) MONDAY AFTERNOON Section A Palmer House, Wabash Parlor (3rd Floor) Symposium on High Resolution Gas Chromatography: Columns and Analyses L. Ettre, Presiding 2:00—13. High Resolution Gas Chromatographic Determination of Organic Compounds in Ozonized Wastewater. R. E.

Section B Palmer House, Parlor B (6th Floor) Symposium on Ultratrace Metal Analysis in Biological Sciences and Environment T. H. Risby, Presiding 2:00—Introductory Remarks. 2:05—20. Collection and Analysis of Airborne Metallic Elements. R. Thompson. 2:45—21. Ultratrace Quantities of Heteropolycyclic Aromatic Compounds in the Environment. G. R. Dubay, R. A. Hites. 3:05—22. Multi-element Characterization of Airborne Particulate Dispersal Patterns the New Instrumental Technique. F. N. Abercrombie, M. D. Silvester, A. Murray. 3:25—23. Ultra-trace Analysis of Metals in Biological Systems. A. V. Colucci, W. S. Simmons. 4:20—24. Application of Stable-lsotropically Labelled Organics in Analysis of Environmental Samples Water and Air. Part I. H. G. Nowicki, R. F. Devine, C. A. Kieda.

11:20—35. Simultaneous Determination of Trace Elements in Urine by Inductively Coupled Plasma-Atomic Emission Spectrometry. W. J. Haas, Jr., V. A. Fassel, R. N. Kniseley, W. L. Sutherland. 11:40—36. Isotope Dilution GCMS for Quantitative Organic Trace Analysis. B. N. Colby.

Section C Palmer House, Parlor F (6th Floor) General J. D. Carr, Presiding 9:00—37. Opto-Acoustic Spectroscopy With a Pulsed Dye Laser. R. W. Shaw. 9:20—38. Results of Multi Component Fluorescence Studies Using the Video Fluorometer. D. W. Johnson, C.-N. Ho, J. B. Callis, G. D. Christian. 9:40—39. Determination of Submicrogram Quantities of Arsenic and Methylarsenicals in Water by Arsine Generation Followed by Graphite Furnace Atomic Absorption Spectrometry. A. U. Shaikh, D. E. Tallman. 10:00—40. Determination of Some Trace Metals in Biological Excreta By Atomic Absorption Spectroscopy. G. W. C. Hung. 10:20—Intermission. 10:40—41. Lightly Sulfonated Porous Polymers for Gas-Solid Chromatography. R. F. Hirsch, R. J. Gaydosh. 11:00—42. Critical Study of Temperature Effects in Stopped-Flow Mixing Systems. F. J. Holler, C. G. Enke, S. R. Crouch. 11:20—43. Acidity and Complexation Behavior of Phosphonoacetic Acid. P.-H. C. Heubel, A. I. Popov. 11:40—44. Reaction Kinetics of Ferrate(VI) Ion With One-Carbon Compounds. J. D. Carr, A. R. Tabatabai, C. C. Greenwalt.

Section D Symposium on Novel Instrumental Methods for Probing Polymer Structures Joint with Division of Polymer Chemistry, Inc. (seepage 60) TUESDAY AFTERNOON

Section C Symposium on Novel Instrumental Methods for Probing Polymer Structures Joint Division of Polymer Chemistry, Inc. (see page 60) TUESDAY MORNING

Section A

Palmer House, WabaslvParlor (3rd Floor) Symposium on High Resolution Gas Chromatography: Techniques S. P. Cram, Presiding 9:00—Introductory Remarks. 9:10—25. Analysis of Complex Natural Samples by High Resolution Gas Chromatography. W. E. Reed, D. H. Stuermer. 10:00—26. Fractionation and Characterization of Petroleum Cycloalkanes. J. S. Warner, D. C. K. Lin. 10:20—27. A Method for Isolation, Identification and Comparison of Tobacco Essential Oil Components. R. A. Lloyd, Jr. 10:40—28. Closed-Loop Headspace Sampling. C. R. Green, F. A. Thome. 11:00—29. Photoionization Detection in a High Resolution Glass Capillary System. W. G. Jennings. 11:20—30. Application of High Resolution Capillary Columns to Complex Mixtures. M. J. Hartigan, B. Welton. 11:40—31. Moment Theory of Gas-Solid Chromatography. B. J. McCoy, R. G. Carbonell. Section B Palmer House, Parlor1 B (6th Floor) Symposium on Ultratrace Metal Analysis in Biological Sciences and Environment T. H. Risby, Presiding 9:00—Introductory Remarks. 9:05—32. Trace Metal Measurements in Assessing Human Disease Processes. M. A. Evenson. 9:45—33. Metal Carcinogenesis in Tissue Culture. M. Costa. 10:25—Intermission. 10:40—34. Future Analytical Requirements for the Determination of Trace and Ultratrace Levels of Metals in Bioenvironmental Systems. G. B. Morgan, E. W. Bretthauer.

Section A

Palmer House, Wabash Parlor (3rd Floor) Symposium on High Resolution Gas Chromatography: Techniques R. A. Lloyd, Presiding 2:00—45. Two-Dimensional Gas Chromatography. Selected Applications. E. L. Anderson, M. M. Thomason, W. Bertsch. 2:20—46. Analysis of Organic Contaminants in Surface Water Using High Resolution Gas Chromatography and Selective Detectors. T. A. Rooney, R. R. Freeman. 2:40—47. Comparison of the GC Detectors in Their Usefulness, Suitability, Sensitivity, and Selectivity in Glass Capillary Gas Chromatography. F. J. Yang, S. P. Cram, E. Freitas. 3:00—48. Detailed Analysis of Shale Oil Using Specific Detectors. C. E. Kennard, S. M. Sonchik, M. P. T. Bradley. 3:20—49. Investigation of Trace Organic Components in Chlorinated Natural Waters Using Glass WCOT Columns. R. M. Bean, P. W. Ryan, R. G. Riley. 3:40—50. Glass Capillary Gas Chromatography and Computerized Mass Spectrometry in Complex Mixture Analyses. J. Meili, F. C. Walls, R. McPherron, A. L. Burlingame. 4:00—51. A Dual GC-MS Interface for Packed and Capillary Columns. J. C. Cook jr., R. M. Milberg, L. Brayton. 4:20—52. High Resolution Gas Chromatography/Mass Spectrometry. W. A. Wolstenholme, U. Rapp, H. Kaufmann. 6:00—Divisional Social Hour. Water Tower Place, Pearson Room, 175 East Chestnut St. 6:45—Divisional Dinner/Theatre. Water Tower Place, Pearson Room, 175 East Chestnut St. 7:45—Divisional Business Meeting. Water Tower Place, 175 East Chestnut St. Section B Palmer House, Parlor B (6th Floor) Symposium on Ultratrace Metal Analysis in Biological Sciences and Environment T. H. Risby, Presiding

2:00—Introductory Remarks. 2:05—53. Zinc Biochemistry of Normal and Abnormal Growth Processes. D. S. Auld. 2:45—54. A Modified Standard Addition Method for Determining Cadmium, Lead, Copper and Iron in Sea Water Samples by Atomic Absorption Spectroscopy. C. P. Welsel, S. R. Piotrowicz, R. A. Duce, J. L. Fasching. 3:05—55. Ultratrace Determination of Sulfur Hexafluoride and Perfluorocarbons for Atmospheric Tracing. R. N. Dietz, E. A. Cote, R. W. Goodrich. 3:25—Intermission. 3:40—56. Sources of Environmentally Important Metals in the Atmosphere. R. E. Lee, Jr., F. V. Duffield. 4:20—57. Saturated Non-Resonant Emission Spectroscopy for Atomic Detection. J. A. Gelbwachs, C. F. Klein, J. E. Wessel. 4:40—58. Trace Metal Uptake in Bacillus Subtilis 168. J. J. Dulka, P. E. Kolenbrander, T. H. Risby. 6:00—Divisional Social Hour (see Section A for location). 6:45—Divisional Dinner/Theatre (see Section A for location). 7:45—Divisional Business Meeting (see Section A for location).

Section C Palmer House, Parlor F (6th Floor) General: Electrochemistry

A. I. Popov, Presiding 2:00—59. Electrogenerated Chemiluminescence of t-Stilbene Derivatives. J. R. Wilson, S-M. Park. 2:20—60. Electrochemical Studies of Dimethyl Benz(a)pyrenes. S-M. Park, J. J. Michnovicz. 2:40—61. Complexation of Monovalent Cations by the Antibiotic lonophore Monensin. J. G. Hoogerheide, A. I. Popov. 3:00—62. The Effect of Slow Two-Electron Transfers and Disproportionation on Cyclic Voltammograms. M. D. Ryan. 3:20—Intermission. 3:40—63. Potential Dependence of the Transfer Coefficient in the Electrochemical Reduction of tert-Nitrobutane and Interpretation According to Marcus Theory of Electron Transfer Reactions. D. A. Corrigan, D. H. Evans. 4:00—64. A Comparison of Differential Pulse Polarographic and Gas Chromatographic Methods for the Analysis of N-nitro-sodiethanolamine in Synthetic Cutting Fluids. M. R. Smyth, P. G. Rowley, J. G. Osteryoung. 4:20—65. Amperometric Determination of Polyhydroxy Compounds by Means of Metal Oxide Electrodes. K. G. Schick, C. O. Huber. 4:40—66. The Application of Twin-Electrode Thin-Layer Voltammetry for the Elimination of Intermetallic Compound Interferences in Stripping Voltammetry. E. E. Brooks, W. R. Heineman, D. A. Roston. 6:00—Divisional Social Hour (see Section A for location). 6:45—Divisional Dinner/Theatre (see Section A for location). 7:45—Divisional Business Metting (see Section A for location).

10:05—69. An Analysis of the Industrial Analytical Chemist. J. E. Burroughs. 10:40—70. Chemical Detectives, The FDA. C. Meloan. 11:15—71. Practical Solutions to Circuit Board Production Problems Via Chemical Analysis. J. W. Mitchell, J. E. Riley.

Section B Palmer House, Parlor B (6th Floor) General: Chromatography

Section C

P. C. Uden, Presiding 9:00—72. A General Metal Ion LC Detector Using a Copper(ll)-Selective Electrode. R. C. Oorey, P. W. Carr. 9:20—73. Metal Specific Detection in GC and HPLC with Interfaced DC Plasma Emission Spectrometry. P. C. Uden, R. M. Barnes, I. E. Bigley, W. G. Elliott, R. J. Lloyd, B. D. Quimby. 9:40—74. A Novel Two-proton Detector for Liquid Chromatography. E. S. Yeung, M. J. Sepaniak. 10:00—75. Silver Nitrate-High Performance Liquid Chromatography of Fatty Methyl Esters. C. R. Scholfield. 10:20—Intermission. 10:30—76. Quantitative Stripping of Low Molecular Weight Compounds from a Flowing Air Stream of Porous Polymers and Related Absorbents. R. J. Sydor, C-H. Chu, D. J. Pietrzyk. 10:50—77. Chemically Modified Surfaces for Normal Phase Chromatography. R. K. Gilpin, W. R. Sisco. 11:10—78. The Effect of Crown Ethers on the Ion Exchange Behavior of Selected Mono and Divalent Cations II. W. H. Delphin, E. P. Horwitz. 11:30—79. Rapid Liquid Chromatographic Assay of Chloroaniline Isomers. L. Kesner, S. M. Vratsanos. 11:40—80. Differential Temperature Programmed Gas Chromatography. R. Rowan, Jr.

Section C Symposium on Chromatography of Polymers Joint with Division of Polymer Chemistry, Inc. (see page 63)

Symposium on Novel Instrumental Methods for Probing Polymer Structures Joint with Division of Polymer Chemistry, Inc. (seepage 63) 6:00—Divisional Social Hour (see Section A for location). 6T45—Divisional Dinner/Theatre (see Section A for location). 7:45—Divisional Business Meeting (see Section A for location). WEDNESDAY MORNING Section A Palmer House, Wabash Parlor (3rd Floor) Symposium on Problem Solving: The Analytical Approach

J. T. Vanderberg, Presiding 9:00—67. The Analytical Approach. C. A. Lucchesi. 9:15—68. Analytical Problem Solving: Academia's Challenge, Industries Opportunity. J. G. Grasselli. 9:50—Intermission.

THURSDAY MORNING

Section A

2:00—81. Problem Solving with Surface Analysis. W. M. Riggs. 2:34—82. Water Quality Monitoring—Some Hows and Whys. J. H. Wiersma. 3:10—Intermission. 3:25—83. Analytical Chemists at the Launch Pad. H. D. Bennett. 4:00—84. The Use of H.P.L.C. to Establish the Optimun Purification Procedure for a Dye Used in Electrophoretic Imaging Devices. T. I. Martin, P. Macbeth.

Palmer House, Parlor B (6th Floor) General C. L. Wilkins,

Presiding

2:00—85. Clinical Profiling with an Ammonia Gas Electrode Based on an Internal Monovalent Cation Glass Electrode. R. G. Wawro, J. G. Montalvo, Jr. 2:20—86. Demonstration of Cocaine Metabolite in Human Urine by Thin Layer Chromatography. A. E. Finkler. 2:40—87. A Stopped-Flow Clinical Analyzer which Uses Immobilized Enzyme Reaction Loops. M. D. Joseph, D. J. Kasprzak, S. R. Crouch. 3:00—88. A New Enzymatic Method for Measuring Blood Alcohol. F. S. Cheng, G. D. Christian. 3:20—Intermission. 3:40—89. Structural Changes of the Chemical Constituents of Petroleum During Biodegradation. D. M. Jewell, L. Petrakis, J. D. Walker.

Smoking and nonsmoking sections in technical session meeting rooms have been designated as follows: Smoking: left side of room Nonsmoking: right side of room

Section A

Palmer House, Wabash Parlor (3rd Floor) Symposium on Forensic Chemistry M. J. Camp, Presiding 9:00—Introductory Remarks. 9:05—93. The Mbssbauer Spectrometry in the Forensic Characterization of Paint. F. E. Klink, J. D. Nicol, J. H. Liu, G. V. Smith, M. Saporoschenko. 9:25—94. X-ray Microanalysis of Physical Evidence. R. C. Briner, C. R. Longwell, D. E. Smith, T. C. Holt. 9:45—95. Identification and Differentiation of Raw Micro Marihuana Sample by Standard and Isotope Ratio Mass Spectrometric Techniques. M. P. Fitzgerald, J. H. Liu, J. D. Nicol, G. V. Smith, R. D. Cole. 10:05—96. Forensic Characterization of Commercial Bond Papers. L. A. Wolfe, C. L. Baskin. 10:25—97. Development of Methods for the Analysis of Some Food Products in Customs Laboratories. M. J. Prager, M. A. Miskiewicz. 10:45—98. The Effect of Environmental Factors on Genetic Markets in Human Bloodstains. H. C. Lee, R. E. Gaensslen, P. R. DeForest, D. Crim. 11:05—99. Identification of Some Positional and Chemical Analogues of Methaqualone. S. A. Angelos, T. A. Dal Cason, O. Washington.

Section B

Palmer House, Wabash Parlor (3rd Floor) Symposium on Problem Solving: The Analytical Approach D. G. Anderson, Presiding

Smoking/nonsmoking

Symposium on Chromatography of Polymers Joint with Division of Polymer Chemistry, Inc. (see page 63)

WEDNESDAY AFTERNOON

Section B

Section D

4:00—90. Simultaneous Quantitative Analysis of Prostaglandin F 1a and F 2a by Mass Fragmentography. A. Ferretti, V. P. Flanagan. 4:20—91. The Use of Histograms for Feature Selection in Carbon NMR Pattern Recognition. T. R. Brunner, C. L. Wilkins. 4:40—92. A General Instrumental Method for the Measurement of Mercury Vapour in Workroom, Stack and Adjacent Atmospheres. G. F. Dowd, J. C. Hilborn.

Symposium on Chromatography of Polymers Joint with Division of Polymer Chemistry, Inc. (see page 63)

BIOL DIVISION OF BIOLOGICAL CHEMISTRY B. L. Horecher, Chairman H. Z. Sable, Secretary

MONDAY MORNING

Section A

Conrad Hilton, P.D.R. #2 (3rd Floor) Symposium on Enzyme Mechanisms General

T. C. Bruice, Presiding 9:00—Introductory Remarks. 9:10—1. Kinetic and Stereochemical Probes of Enzyme Mechanisms. S. J. Benkovic. 9:50—2. The Mechanism of Oxygen Activation 1 Electron Transfer, and Dehydrogenation Reactions Mediated by Flavins. T. C. Bruice. 10:30—3. Use of Chromium and Colbalt Nucleotides to Determine Enzyme Mechanisms. W. W. Cleland. 11:10—4. Suicide Enzyme Inactivators and Related Studies. R. Abeles.

Section C

Section B

Symposium on The Present Status of the Teaching of Analytical Chemistry Joint with Division of Chemical Education, Inc. (seepage 36)

Symposium on Biosynthesis of Complex Carbohydrates Joint with Division of Carbohydrate Chemistry (see page 34)

THURSDAY AFTERNOON

MONDAY AFTERNOON

Section A

Palmer House, Wabash Parlor (3rd Floor) Symposium on Forensic Chemistry H. C. Lee, Presiding 2:00—100. The Crystal and Molecular Structure of Two Forensically Important Substances. D. Canfield, J. C. Barrick, M. J. Camp, B. C. Giessen. 2:20—101. Genetic Markers in Semen: Quantitative Analysis of Polymorphic Proteins. G. F. Sensabaugh, E. T. Blake. 2:40—102. Review of LEA A—AEROSPACE Gunshot Residue Detection Program. G. M. Wolten. General 3:40—103. Computer Controlled Spectropolarimetry. V. C. Zadnik, J. L. Scott, R. M. Megargle, K. H. Pearson. 4:00—104. Computer Controlled Spectropolarimetric Titrimetry. J. L. Scott, V. C. Zadnik, R. M. Megargle, K. H. Pearson. 4:20—105. Determination of Ionic Species in Engine Coolants by Ion Chromatograph. E. Chladek, L. C. Westwood.

Section B Symposium on The Present Status of the Teaching of Analytical Chemistry Joint with Division of Chemical Education, Inc. (seepage 36)

Enzymes 1 Conrad Hilton, Parlor B (3rd Floor) Poster Session 2:00-3:00—5. Phosphoribosyl-pyrophosphate Synthetase from Salmonella Typhimurium: Kinetic and Magnetic Resonance Studies. T. M. Li, A. S. Mildvan, R. L. Switzer. 3:00-4:00—6. The Evaluation of Phosphotransferase Mechanisms Using PulseChase Methods. H. J. Fromm, L. P. Solheim. 4:00-5:00—7. pH Studies of the Forward and Reverse Reactions Catalyzed by Yeast Hexokinase. R. E. Viola, W. W. Cleland. 2:00-3:00—8. 6-Thiofructose: Anomeric Composition, Rates of Interconversion of Anomers, and Substrate Activity with Fructokinase. C. E. Grimshaw, W. W. Cleland. 3:00-4:00—9. Ribonuclease Action on UpA. J. A. Deiters, R. R. Holmes, J. C. Gallucci. 4:00-5:00—10. 31P NMR Relaxation Studies on the Interaction on Mn(ll) and Pj at the Active Site of Yeast Inorganic Pyrophosphatase. D. J. Hamm, B. S. Cooperman. 2:00-3:00—11. An Investigation of the Phylogenetic Tree for Cytochrome-c. M. A. Sharaf, B. Weinstein, B. R. Kowalski. 3:00-4:00—12. Inactivation of Phosphofructokinase by an Adenosine Triphosphate Analogue. M. R. Gregory, E. T. Kaiser. 4:00-5:00—13. Separation of Isomers of ATP-Chromium(lll) and ATP-Tetraamminecobalt(lll) by Column Chromatography on Cross-linked Cycloheptaamylose. R. D. Cornelius, W. W. Cleland.

July 25, 1977 C&EN

31

2:00-3:00—14. The Mode of Binding of Potential Transition State Analogs to Acetylcholinesterase. A. Dafforn, G. Rych, M. Anderson, D. Ash, J. Campagna, E. Daniel, R. Horwood, P. Kerr, F. Zappitelli. 3:00-4:00—15. Subsite Specificity of Chymotrypsin. M. J. Moffitt, G. E. Means. 4:00-5:00—16. Deuterium Isotope Effects for the TPN Specific Isocitrate Dehydrogenase Using lsocitrate-2-d. P. F. Cook, W. W. Cleland. 2:00-3:00—17. Mechanistic Implications of the pH Profiles for Glutamate Dehydrogenase. J. E. Rife, W. W. Cleland. 3:00-4:00—18. Proteolysis of Immobilized Lactate Dehydrogenase in the Presence of Pyruvate and NADH. S. Ikeda, T. Lee, G. P. Royer. 4:00-5:00—19. Isotope Effects on the Fumarase Reaction. J. S. Blanchard, W. W. Cleland. 2:00-3:00—20. Specific Modification of Histidine in Bovine Erythrocyte Superoxide Dismutase by Hydrogen Peroxide. D. P. Malinowski, I. Fridovich. 3:00-4:00—21. Evidence for Essential Histidine Residues in Putrescine Oxidase by Modification with Photooxidation and Ethoxyformylation. N. Matheson, R. J. DeSa, J. M. Brewer. 4:00-5:00—22. Examination of the Catalytic Mechanism of Sulfhydryl Oxidase. H. E. Swaisgood, A. Philip. 2:00-3:00—23. Spectral Studies on Crystalline Enzyme-Substrate Complexes of Aspartate Aminotransferase. D. E. Metzler, C. M. Harris, A. E. Cahill, D. S. Martin, R. Newman. 3:00-4:00—24. Increased Rate of Hydrolysis of a Nitrophenyl Ester by a Bifunctional Nucleophile in Presence of a Binding Polymer. R. Johnson, J. Walder, I. M. Klotz. 4:00-5:00—25. Initiator-Substrate Distances on RN-Polymerase from E. coli. P. J. Stein, A. S. Mildvan. 2:00-3:00—26. Effects of Divalent Ions on the Structure and Sugar Fidelity of E. coli RNA Polymerase. K. G. Rao, F. Y. Wu, S. Seithi, G. L. Eichhorn. 3:00-4:00—27. Role of Metal Ions in the Inhibition of Nucleotide Polymerases by Rifamycins. R. J. Kostelnik, A. K. Raina.

Physical Methods Poster Session 2:00-3:00—28. Spinach Plastocyanin:Natural Abundance 13C NMR Studies. J. L. Markley, E. L. Ulrich, D. W. Krogmann. 3:00-4:00—29. Conformations of Cyclic Hexapeptides with Adjacent Basic Residues of Opposite Configuration. K. D. Kopple, A. Go, T. J. Schamper. 4:00-5:00—30. Carbon-13 NMR Studies of Glycoproteins at High Magnetic Field Strengths. K. Dill, A. Allerhand. 2:00-3:00—31. Mdssbauer and EPR Studies of Cytochrome c'. M. Emptage, E. Munck, W. Orme-Johnson, L. Que, Jr., J. M. Wood. 3:00-4:00—32. Conformational Analysis of the Phosphate Side-chain of 3' and 5'-AMP. Phosphorus-Proton Nuclear Overhauser Effects. P. A. Hart. 4:00-5:00—33. 31 p NMR Analysis of the Phosphorus Components in Human Muscles with Neuromuscular Disorders Including Duchenne Dystrophy. M. Barany, M. Vuolo, C. T. Burt, M. J. Danon, B. H. Huncke, T. Glonek. 2:00-3:00—34. Identification of a 31 p nmr Resonance from Dystrophic Chicken Muscle as L-Serine Ethanolamine Phosphodiester. J. M. Chalovich, C. T. Burt, S. M. Cohen, T. Glonek, M. Barany, L. H. Schlisefeld. 3:00-4:00—35. Comparison by 31 p NMR of the Phosphate Metabolism in Perfused Mammalian and Amphibian Hearts During Ischaemia and Perfusion. C. T. Burt, C. Holland, M. Barany, H. Levitsky, H. Feinberg. 4:00-5:00—36. A New Acid-Labile Constituent of Mammalian Heart. T. Glonek, M. Barany, P. L. Hawley, C. T. Burt, J. Molnar. 2:00-3:00—37. Spectrophotometric Determination of Dimerization Constants of Deuteroporphyrin Derivatives in Aqueous Alkali/Alcohol Solutions. G. A. Karns, W. A. Gallagher, W. B. Elliott. 3:00-4:00—38. Pentaamineurthenium— Histidine Complex Formation in Ribonuclease A: Synthesis of a Stable ChargeTransfer Complex under Physiological Conditions. C. R. Matthews, P. M. Erickson, D. V. Vliet, M. Petersheim.

32

C & E N J u l y 2 5 , 1977

4:00-5:00—39. The Reaction of Mercuric Acetate with Amino Acids. A. P. Korn, F. P. Ottensmeyer. 2:00-3:00—40. Calorimetric Studies on the Cholesterol Oxidase Reaction. E. T. McGuinness, S. K. Chattopadhyay, H. D. Brown.

Metabolism Poster Session 2:00-3:00—41. The Latter Steps of Carnitine Synthesis in Neurospora crassa. R. A. Kaufman, H. P. Broquist. 3:00-4:00—42. On the Fate of Labeled Ecdysterone and its Triacetate after Intramuscular Injection into the Lobster (Homarus americanus). B. G. Burns, M. W. Gilgan. 4:00-5:00—43. Bacterial Metabolism of Anthracycline Antibiotics: NADPH-Linked C-10 Keto Reduction of Steffimycinone. V. P. Marshall, E. A. Reisender, J. M. Koert, D. W. Elrod, P. F. Wiley. 2:00-3:00—44. N-Acetyl-L-Tryptophan in Claviceps purpurea PRL 1980. J. A. Anderson, H-J. Liang. 3:00-4:00—45. Metabolic Fate of 1-Methyladenosine in Rat:lts Relationship to the Metabolites of 1-Methylinosine. S. P. Dutta, N. C. De, A. Mittelman, G. B. Chheda. 4:00-5:00—46. The Catabolism of t-N-Methyllysine in Chickens. B. ElAmin, G. E. Means. 2:00-3:00—47. Are 20(22)-Dehydrocholesterols and 20(22)-Epoxycholesterols Intermediates in the Enzymatic Degradation of Cholesterol? B. A. Teicher, M. Koreeda, M. Shikita, P. Talalay. 3:00-4:00—48. A Preliminary Report on the use of H.P.L.C. in the Analysis of Bacterial Fatty Acid Composition. N. E. Bussell, R. A. Miller, J. Setterstrom, A. Gross. 4:00-5:00—49. Determination of 3-Keto-Bile Acids. W. T. Beher, G. J. Lin, S. Stradnieks, J. Sanfieid. 2:00-3:00—50. Quantitation of Long Chain Fatty Acids as the Methoxyphenacyl Esters using H.P.L.C. R. A. Miller, N. E. Bussell, J. Setterstrom, A. Gross.

Proteins Poster Session 2:00-3:00—51. Protein Cross-Linking Utilizing Hetero-bifunctional Reagents Containing Aryl Azides. R. V. Lewis, W. S. Allison. 3:00-4:00—52. Synthesis of LH-RH Analogs. R. W. Roeske, P. D. Gesellchen, F. C. Lee, K. U. Prasad, C. Y. Bowers. 4:00-5:00—53. The 2-Pyridinecarboxyladehyde Peptide Cleavage. K. Jayasimhulu, R. A. Day. 2:00-3:00—54. Fluorine-Proton Overhauser Effect Studies of />Tri-fluormethylbenzenesulfonylchymotrypsin. J. T. Gerig, D. T. Loehr, K. F. S. Luk. 3:00-4:00—55. Resonance Raman Spectroscopy on Furylacyl Enzymes. M. Kafina, J. Schmidt, B. Feinberg, L. Watters, J. T. McFarland. 4:00-5:00—56. Bovine Homologue of (52Microglobulin Isolated from Milk. M. L. Groves, R. Greenberg. 2:00-3:00—57. Factors Affecting Combination of Red Kidney Bean (Phaseolus vulgaris) a-Amylase Inhibitor with Porcine Pancreatic a-Amylase. J. R. Powers, J. R. Whitaker. 3:00-4:00—58. Chemical Modification of Human Plasma Alpharantitrypsin. J. C. Fretz, J. C. Gan. 4:00-5:00—59. Presence of Fatty Acids in Human-Alpha-Fetoprotein. D. C. Parmellee, M. A. Evenson, H. F. Deutsch. 2:00-3:00—60. Effects of Organic Solutes on the Conformations of Plasma Proteins. C. R. Harmison. 3:00-4:00—61. Protein Solubilization and Transfer through Aprotic Solvents. F. J. Bonner, P. L. Luisi. 4:00-5:00—62. Substitution of Mn in Soybean Agglutinin by other Transition Metals. C. Jaffe, S. Ehrlich-Rogozinski, H. Lis, N. Sharon. 2:00-3:00—63. Chemical Modification of Arginines in Transferrin. T. B. Rogers, R. E. Feeney. 3:00-4:00—64. Interaction of Anions with Iron-Transferrin-Chelate Complexes. T. B. Rogers, R. E. Feeney, C. F. Meares. 4:00-5:00—65. Vanadium Containing Proteins in Rat Tissues. R. A. Peabody, R. L. Verch, S. Wallach.

2:00-3:00—66. Structure-Volume Relationships: Influence of pH on Volume Changes Produced by Metal Cation:Protein Interactions. S. Katz, R. G. Shinaberry. 3:00-4:00—67. The Small Apolar Anion Binding Site of Human Serum Albumin. S-W. M. Koh, G. E. Means. 4:00-5:00—68. Refolding of Bovine Plasma Albumin and its Fragments. K. O. Johanson, D. B. Wetlaufer, R. G. Reed, T. Peters, Jr. 2:00-3:00—69. A Model for the Structure of Glucagon. A. P. Korn, F. P. Ottensmeyer. 3:00-4:00—70. Conformational Features of (Pro-Pro-/3Ala)n:A Polypeptide Model of Collagen. R. S. Bhatnagar, R. S. Rapaka, K. R. Sorensen, A. K. Saund. 4:00-5:00—71. The Solution Conformation of Malformin A. A. E. Tonelli. 2:00-3:00—72. Polymerization Decay upon Storage of Tubulin in Sucrose. J. S. Barton. 3:00-4:00—73. Partial Characterization of the Peptide Portion of the Exocellular Peptidophosphogalactomannan from P. Chariseli. S. J. Tonn, J. E. Gander. 4:00-5:00—74. Fractionation of the Carbohydrate of Ovalbumin. V. Shepherd, R. Montgomery. 2:00-3:00—75. Effects of Progressive Desialylation on the Survival of Human Plasma a r antitrypsin in Rat Circulation. S-D. Yu, T. F. Busby, J. C. Gan. TUESDAY MORNING

Section A

Conrad Hilton, P.D.R. #2 (3rd Floor) Symposium on Gene Action General

W. J. Rutter, Presiding 9:00—76. Nucleoprotein Structure and Gene Activity. G. Felsenfeld, P. Williamson, R. D. Camerini-Otero. 9:45—77. Chromatin Structure and Replication. H. Weintraub. 10:30—78. Activation of Transcription in Drosophilia Chromosomes. B. McCarthy. 11:15—79. Structure and Function of Eukaryotic RNA Polymerases and Faithful Gene Transcription in Reconstructed Systems. R. G. Roeder.

Section B Symposium on Biosynthesis of Complex Carbohydrates Joint with Division of Carbohydrate Chemistry (see page 34) TUESDAY

AFTERNOON

Symposium on Biosynthesis of Complex Carbohydrates Joint with Division of Carbohydrate Chemistry (see page 34)

Discussion on Enzymes Conrad Hilton, P.D.R. #1 (3rd Floor)

W. W. Cleland, Chairman 2:00-5:00— 5:00—Divisional Business Meeting and Social Hour. Conrad Hilton, P.D.R. #3 and #4 (3rd Floor).

Discussion on Physical Methods Conrad Hilton, P.D.R. #3 (3rd Floor)

J. L. Markley, Chairman 2:00-5:00— 5:00—Divisional Business Meeting and Social Hour. Conrad Hilton, P.D.R. #3 and #4 (3rd Floor).

Discussion on Proteins Conrad Hilton, P.D.R. #4 (3rd Floor) J. T. McFarland, Chairman 2:00-5:00— 5:00—Divisional Business Meeting and Social Hour. Conrad Hilton, P.D.R. #3 and #4 (3rd Floor). WEDNESDAY MORNING

Section A

Conrad Hilton, Parlor B (3rd Floor) Heme Proteins Poster Session 9:00-10:00—80. Kinetics of the Redox Reactions of a Trif luoroacetylated Derivative of Cytochrome c. T. R. LeBon, J. C. Cassatt.

10:00-11:00—81. Localization of Conformational Changes in Chemically Modified Cytochromes c by Antibody Binding. R. Jemmerson, D. L. Brautigan, E. Margoliash. 11:00-12N—82. Interaction of Feriimyoglobin with Cetyltrimethyl-ammonium Bromide. L. G. lonescu, G. E. Avaria. 9:00-10:00—83. Inhibition of the Cytochrome c.—Cytochrome c Oxidase Reaction by Anions of Physiological Importance. N. Osheroff, E. Margoliash. 10:00-11:00—84. Azide Binding Equilibria of Cytochrome c Ferric Heme Octapeptide. D. C. Blumenthal, R. J. Kassner. 11:00-12N—85. The Electric Potential Field Around Tuna Ferricytochrome c. W. H. Koppenol, Ch. Vroonland, R. Braams, S. M. Ferguson-Miller, D. L. Brautigan. 9:00-10:00—86. Interaction of RadiationGenerated Free Radicals with Myoglobin and Nitrosylmyoglobin in Aqueous Solution. J. J. Shieh, M. Z. Hoffman, M. G. Simic, I. A. Taub. 10:00-11:00—87. Metal Centered Effects on Hemoprotein Conformation Stability. G. McLendon, K. Sandberg. 11:00-12N—88. Resonance Raman and EPR Spectroscopy of Carp Hemoglobin: Implications for Hemoglobin Cooperativity. D. M. Scholler, B. M. Hoffman, D. F. Shriver. 9:00-10:00—89. Stopped-Flow ESR Studies on the Interaction of Copper with Hemoglobin. J. M. Rifkind. 10:00-11:00—90. Spectral Transitions of Cytochrome c Peroxidase at Alkaline pH. J. E. Erman, B. Dhaliwal. 11:00-12N—91. Catalysis of Autoxidation of Ascorbate by IHP-Oxyhemoglobin (A or S) Complexes. J. Steinhardt, H. Pannella, M. McD. Jones, J. Scott. 9:00-10:00—92. Affinity Difference Among Hemoglobin /?A, /3s and y Chains toward or Chain. Probable Involvement in the Switching Mechanism of Hemoglobin F to A in the Newborn. T. C. K. Lee. Enzymes 2 Poster Session 9:00-10:00—93. Detection of a Metal Ion Catalytic Group in Carboxypeptidase A. S. Jaffer, H. Zemel, M. W. Makinen. 10:00-11:00—94. Structure of Bovine Carboxypeptidase A Labeled with the 2-Hydroxy-5-Nitrobenzyl Reporter Group. L. N. Y. Wu, G. J. Young, H. R. Horton. 11:00-12N—95. The Hydrolytic Reactivity of Bovine Carboxypeptidase B. H. C. Margolis, Y. Nakagawa, E. T. Kaiser. 9:00-10:00—96. On the Structure of the Complex Formed between Papain and Hippuraldehyde. C. A. Lewis, Jr., R. V. Wolfenden. 10:00-11:00—97. Serine Hydroxymethylase (SHMase) Catalyzed Cleavage of 0-Phenylserine(S): pH Dependence of Elementary Steps. W. M. Ching, R. G. Kallen. 11:00-12N—98. The Affinity Chromatographic Purification of Papain: A Reevaluation. M. O. Funk, Y. Nakagawa, E. T. Kaiser. 9:00-10:00—99. The Secondary Structure Requirements for Thrombin Susceptible Bonds. R. A. Marlar, D. A. Walz, J. W. Fenton, II, W. H. Seegers. 10:00-11:00—100. Observations on the Stability and Possible Multiplicity of Bovine Brain Glycylglycine Dipeptidase. A. S. Brecher, R. H. Frisch. 11:00-12N—101. Angiotensin Converting Enzyme: Evidence for Proteolytic Processing and Non-Identity of Kidney with other Forms. J. Friedland, E. Silverstein. 9:00-10:00—102. Inhibition of HMG-CoA Reductase by Derivatives of Glycyrrhetic Acid. J. E. Miller, C. Jett. 10:00-11:00—103. Inhibition of HMG CoA Reductase by Derivatives of 0-Hydroxy/?-Methylglutaric Acid. J. E. Miller, C. Jett. 11:00-12N—104. Cisand 7rans-2,3-Epoxybutane-1,4-Diol, 1,4-Bisphosphate, Two New Potential Affinity Labeling Reagents for Enzymes that Bind Sugar Bisphosphates. J. V. Schloss, F. C. Hartman. 9:00-10:00—105. Kinetic Properties of Pyruvate Kinase of Neurospora Crassa at Physiological pH. M. U. Tsao, T. I. Madley. 10:00-11:00—106. Preparation and Properties of a Fluorescent Competitive Inhibitor of Yeast Hexokinase. P. A. Lartey, M. Derechin. 11:00-12N—107. Substrate Specificity of Purine-Nucleoside Phosphorylase from Bovine Thyroid. J. D. Carlson, T. P. Moyer, A. G. Fischer.

9:00-10:00—108. Evidence for the Presence I 9:00-10:00—136. Covalent Attachment of 11:00-12N—161. Embryonic Chick Lens: of Two Non-Identical Subunits in the 4-Homosulfanilamide to Synthetic PolyPresence of Enzymatic Activity Which DPN-Dependent Isocitrate Dehydrogenase peptides and Human Salivary Material. W. Hydrolyzes Messenger RNA 5'Terminal of Pig Heart. N. Ramachandran, R. F. R. Grigsby, T. H. Nalley, C. B. Sabiston, Cap Structures. G. C. Lavers. Colman. Jr. 9:00-10:00—162. Chemical Aminocylation 10:00-11:00—109. Amine Requirements for 10:00-11:00—137. The Effect of Low Temof Transfer Ribonucleic Acid (tRNA): The Activation of 2-Oxoaldehyde Dehydrogeperature and Osmolarity on Preservation of Reaction of E Co//tRNA with Ethyl N-bennase. D. L. Vander Jagt, L. M. Davison. Gluconeogenic Capacity in the Rat Kidney. zyloxycarbonylorthoglycinate. J. S. Hwang, 11:00-12N—110. A Model System for L. Kesner, K. Roistacher, S. B. Kountz. P. Bhuta, J. Zemlicka. Phosphoryl Transfer Induced by Metal Ion 11:00-12N-138. Preparation of the Yeast 10:00-11:00—163. Utilization of Microbial Catalyzed Redox Reaction. G. P. Haight, R. Component of the B-Protein Assay. S. J. Cell Mutants for the In Vivo Production of Scott, G. Woltermann, R. Gumport. Tarnowski, J. L. Rhoades, R. M. Macleod, Transfer RNA for NMR Studies. F. G. Fuji9:00-10:00—111. Polyethyieneimine E. T. Bucovaz. wara, J. Thompson, P. F. Agris, R. N. "Ghosts": Preparation, Derivatization and 9:00-10:00—139. Theoretical Aspects of the Loeppky. Application as a Catalyst for Hydrolysis of B-Protein Assay as an Aid in the Diagnosis 11:00-12N—164. The Dimerization and p-Nitrotrifluoroacetanilide. G. P. Royer, W. of Cancer. E. T. Bucovaz, W. C. Morrison, Structure of 5.85 rRNA. T. O. Sitz, S. C. E. Meyers. J. C. Morrison, J. E. Fryer, W. D. WhyKuo, R. N. Nazar. 10:00-11:00—112. Cobalt Substituted brew. •9:00-10:00—165. Yeast 5.8 S rRNA: Thermal Horseradish Peroxidase. M-y R. Wang, B. 10:00-11:00—140. Characteristics of BAnalysis of a Complex Hairpin Helix. D. M. Hoffman, P. F. Hollenberg. Protein of Human Serum. R. M. Macleod, Lightfoot. 11:00-12N—113. Purification and CharacJ. C, Morrison, W. D. Whybrew, J. E. Fryer, 10:00-11:00—166. Non-Enzymic Coupling terization of Inositol Oxygenase from Pig E. T. Bucovaz. of Oligouridylates on a Polyadenylic Acit Kidney. C. C. Reddy, G. A. Hamilton. 11:00-12N—141. Animal Studies Used as a Template. D. A. Usher, D. Young, G. I. 9:00-10:00—114. 2'(3')-0-Aminoacyl Means of Understanding B-Protein ProFishman. "Bridged" Adenosine Derivatives as Subduction. L. T. Mashbum, M. K. Dabbous, J. 11:00-12N—167. Fractionation of Human strates for Ribosomal Peptidyltransferase. C. Morrison, W. D. Whybrew, E. T. BucoDNA According to Base Composition. C. W. P. Bhuta, J. Zemlicka, C. Li. vaz. Schmid, F. P. Rinehart, P. L. Deininger. 10:00-11:00—115. Partial Purification and 9:00-10:00—142. Practical Considerations 9:00-10:00—168. DNA-Polycation InteracCharacterization of Renal a- and 0-Galacof the B-Protein Assay as a Means of Detions Sensitive to Perturbation at Low Salt tosidases in Diabetic Chinese Hamsters. A. tecting Cancer. J. C. Morrison, W. C. Concentrations. V. Mulimani, G. Bhat, R. Y. Chang. Morrison, W. D. Whybrew, J. E. Fryer, E. A. Day. 11:00-12N—116. Steroid Metabolizing CyT. Bucovaz. 10:00-11:00—169. A Potential Probe for tochromes P-450scc and P-45011/39 and 10:00-11:00—143. Differences in Nuclear Telestability in DNA. L. C. Lin, G. Bhat, R. their BrCN-derived Hemepeptides. J. Glucocorticoid Binding Between CortiA. Day. Bumpus, R. A. Swanson, K. M. Dus, V. coid-Sensitive (S) and -Resistance (R) 11:00-12N—170. Altered Physico-Chemical Spitsberg, C. Jefcoate. Mouse Lymphoma P1798 and Human Properties of DNA-mitomycin Complexes. 9:00-10:00—117. Metabolism of N-MethylChronic Lymphocytic Leukemia (CLL) Cells. D. Kaplan, M. Tomasz. carbazole by Cytochrome P-450. D. R. J. Stevens, Y-W. Stevens, V. P. Hollander, 9:00-10:00—171. Interaction -of Mitomycin Koop, P. F. Hollenberg. R. L. Rosenthal, E. Sloan. C (MC) with RNA and Synthetic Polyri10:00-11:00—118. Reversible Inactivation 11:00-12N—144. A Change in the Osmotic bonucleotides. J. Weaver, M. Tomasz. of Cytochrome c Oxidase by SH-Specific Hemolysis of the Erythrocyte as a Function I 10:00-11:00—172. Nucleotide Binding and Hydrophobic Reagents. A. J. Mann, H. E. of Age. K. Araki, J. M. Rifkind. the Electronic Absorption Spectrum of Auer. 9:00-10:00—145. DNA Synthesis in Isolated Actinomycin D. H. E. Auer, T. R. Krugh, B. 11:00-12N—119. Sphingomyelinase D from Hepatocytes:Hormonal Control. C. G. D. E. Pawlowski-Konopnicki, Y. C. C. the Venom of Loxosceles Reclusa. L. J. Morley. Chiao. Forrester, J. T. Barrett, B. J. Campbell. 10:00-11:00—146. Arginine:Thymotropic 9:00-10:00—120. Alkaline Ribonuclease Effects. E. Seifter, G. Rettura, A. Barbul, Membranes from Porcine Thyroid. R. E. Goldman, F. J. S. M. Levenson. Kull. 11.-00-12N—147. Aspirin and Murine SarPoster Session 10:00-11:00—121. In Vitro Fibrinolytic Accoma Virus: Mode of Action. G. Rettura, J. tivity of a Purified Plasminogen Activator 9:00-10:00—173. Permeability of SterolSeifter, S. M. Levenson, E. Seifter. Derived from a Continuous Porcine Cell Containing Liposomes from Diacyl, Dial9:00-10:00—148. /3-Hydroxybutyrate IncorLine. S. A. Clavin, J. L. Bobbitt. koxy, Dialkyl and Acyl-Alkoxy Phosphoporation into Brain and Liver of Under11:00-12N—122. Isolation and Purification lipids. S. Clejan, R. Bittman, P. W. Deroo, nourished Rat Pups. K. Swiatek, G. Domof Xanthine Oxidase from Human ColosA. F. Rosenthal. browski, H. L. Chao, K. L. Chao. trum. R. E. Doran, J. P. Zikakis. 10:00-11:00—174. Temperature Depen10:00-11:00—149. Dimethylbenzanthracene 9:00-10:00—123. Isolation and Purification dence of Positron Lifetimes in Liposomes. Induced Adrenal Lesions: Prevention by of Xanthine Oxidase from Goat's Milk. M. P. L. McMahon, G. Graf, J. C. Glass. Vitamin A. A. N. Critselis, G. Rettura, E. L. Brown, J. P. Zikakis. 11:00-12N—175. Transport and Partitioning Seifter. 10:00-11:00—124. Partial Purification and of Methylmercury Chloride in Phospholipid 11:00-12N—150. Isolation and CharacterProperties of a Bromoperoxidase from the Vesicles as Studied by Fluorescence ization of Cell Associating Proteins from Marine Alga Bonnemaisonia hamifera. L. Quenching. S. J. Rakow, J. R. Lakowicz, Chick Embroyo by Trypsinization. M. J. P. Hager, R. F. Theiler, J. F. Siuda. J.M.Wood. Pitts, D. C. Yang. 11:00-12N—125. A Study of the Effect of 9:00-10:00—151. Effects of Carbonyl 9:00-10:00—176. Nucleic Acid Interaction Partial Hepatectomy on Adenosine DeamCompounds on Normal and Sickle Erythwith Vero Cells: A Temperature Barrier in inase in Rat Tissues. P. F. Ma, K. J. Collier, rocytes. R. H. Zaugg, J. A. Walder, I. M. the Interaction Pattern. S. Kouidou, T. K. Jr. Klotz. I Sinha, A. M. Bobst, B. Janik. 9:00-10:00—126. Subcellular Localization 10:00-11:00—177. The Sequence of a 10:00-11:00—152. Studies on Catechol- I of Enzymes of Anthocyanin Biosynthesis in Membrane. P. H. Von Dreele. amine Metabolism by Gas ChromatoProtoplasts. G. Hrazdina, G. J. Wagner, H. 11:00-12N—178. Influence of Membrane graphic-Mass Spectrometry. N. NarasimW. Siegelman. Lipids on the Photochemical Cycle of hachari. Bacteriorhodopsin. W. V. Sherman, S. R. 61:00-12N—153. Ascorbic Acid-Oral Versus Caplan. Intravenous Administration: Effect on UriPhysiological and Clinical 9:00-10:00—179. A Study of Lipid-Lipid and nary Excretion Profiles. E. S. Wagner, B. Lipid-Protein Interaction in Biological Poster Session Lindley, W. Shergy, S. Pasternak. Membranes Using Phospholipids Contain9:00-10:00—154. Interactions Among Bovine 9:00-10:00—127. Assay of Thymidylate ing Photoreactive Groups. H. G. Khorana, Factor VIII, Ristocetin, and Polylysine in the Synthetase Activity and its Inhibition by C. M. Gupta, G. E. Gerber, R. RadhakInduction of Guinea Pig Platelet AggregaAntimetabolites in Intact Mammalian Cells. rishnan, Y. Takagaki. tion. M. Malik, S. S. Kuwahara. T. I. Kalman, J. C. Yalowich. 10:00-11:00—180. Stepwise Crosslinking 10:00-11:00—155. Light Modulation of Pea 10:00-11:00—128. Segmental Analysis of Reagents for Photocoupling of Enzymes Leaf Chloroplast Fructose- 1,6-DiphosIrregular Dose/Response Curves, Utilizing and Lectins to Mammalian Cells. P. Guire, phatase. H-M. Chin, L. E. Anderson. a Programmable Calculator, for Automated M. Swanson, A. Shan. 11:00-12N—156. Chlorophyll Array Models Radioassays. S. S. Yanari. 11:00-12N—181. Calorimetric Studies of for the In Vivo Chlorophyll Forms. L. L. 11:00-12N—129. Isotopic Lithium InvestiModel Membrane Systems. G. C. KreshShipman. gations. K. W. Lieberman, P. E. Stokes, J. eck, K. M. Kale, M. D. Vallone, G. Van9:00-10:00—157. Theoretica Kocsis. derkooi. and Experimental Aspects of Linear Di9:00-10:00—130. Manganese: Its NeuroSymposium on Carbohydrate-Protein Interchroism in the Chlorophyll Bands of Phological and Teratological Significance in actions Joint with Division of Carbohydrate tosynthetic Membranes. L. L. Shipman. Man. Y. Tanaka, C. Dupont, E. R. HarChemistry (see page 34) 10:00-11:00—158. Purification and Charpur. acterization of Chlorophyll Protein 668 from 10:00-11:00—131. Analysis of Pulmonary Atriplex hortensis. D. R. Crawford, D. M. WEDNESDAY AFTERNOON Tissue for Aerosolized Consumer Product Crawford, W. G. Hagar. Residues. T. R. Henderson, B. V. Mokler, Section A E. G. Damon, R. K. Jones. 11:00-12N—132. Induction of Human ChoNucleic Acids Symposium on the Carbonyl-Amine Reaction rionic Gonadotropin (HCG) in HeLa Cell in Biological Systems Joint with Division of Poster Session Cultures by Hyperosmolarity. R. J. Fallon, Agricultural and Food Chemistry (see page R. P. Cox, N. K. Ghosh. 9:00-10:00—159. 360 MHz 1H-NMR Deter29) 9:00-10:00—133. Characterization of Human mination of the Structure of the Monomeric Chorionic Gonadotropin and its Subunits in Unit in Poly(Adenosinediphosphoribose). A. Section B Malignant Trophoblast Cultures. R. O. M. Ferro, N. J. Oppenheimer. Hussa. 10:00—11:00—160. Structural and Confor- I 10:00-11:00—134. Effects of Antimalarials Symposium on Carbohydrate-Protein Intermational Aspects of Polyadenylic Acid. W. and Related Substances on Lysosomal actions Joint with Division of Carbohydrate J. Scovell. Proteases. C. Ha Chung, J. L. Mego. Chemistry (see page 34) 11:00-12N—135. Visual Detection of a Possible Source of Antigen(s) in Peridontal Disease. R. J. Bravman, D. L. Everhart, S. S. Stahl.

THURSDAY MORNING

Section A

Symposium on the Carbonyl-Amine Reaction In Biological Systems Joint with Division of Agricultural and Food Chemistry (see page 29)

Section B Symposium on Carbohydrate-Protein Interactions Joint with Division of Carbohydrate Chemistry (see page 34)

Discussion on Enzymes Conrad Hilton, P.D.R. #1 (3rd Floor)

L. P. Hager, chairman 9:00-12N— Discussion on Heme Proteins Conrad Hilton, P.D.R. #3 (3rd Floor)

E. Margoliash, Chairman 9:00-12N—

Discussion on Membranes Conrad Hilton, P.D.R. #4 (3rd Floor)

J. M. Wood, Chairman 9:00-12N—

CARB DIVISION OF CARBOHYDRATE CHEMISTRY '

(

[D. Horton, Chairman ( D. McGinnis, Secretary G. /no- and L-/yxo-hexopyranoses and Their 1,3,4-triacetates. A. Hadfield, L. Cunningham, A. C. Sartorelli. 1 10:15—6. The Synthesis of 4-amino-3,4,6trideoxy-D-r/bo- and D-xy/o-hexose Derivatives. C. L. Stevens, D. J. Smith. 110:30—7. Reductive Amination of Lactose. P. D. Hoagland. 110:45—8. Regiospecific, Partial Syntheses of Ribostamycin and Butirosin B. V. Kumar, W. A. Remers. -\ 11:00—9. Conformation of the Hydroxymethyl Group in Aldohexopyranoses. S. Perez, R. H. Marchessault. 11:15—10. Synthesis and Properties of 21 amino-2-deoxy-5-thio-D-glucose. R. L. Whistler, C. B. Madumelu. 11:30—11. A Facile Synthesis of 3,6-dideoxy-1,2-0-isopropylidene- a-D- erythrohexos-4-ulose. C. L. Stevens, D. J. Smith. 11:45—12. Reactions of Diazo Derivatives of Sugars. M. S. Alexander, D. Horton.

July 25, 1977 C&EN

33

Section B Conrad Hilton, Parlor A (3rd Floor) Symposium on Biosynthesis of Complex Carbohydrates Joint with Division of Biological Chemistry R. W. Jeanloz, Presiding 9:00—Introductory Remarks. 9:15—13. Chemical Synthesis in the Study of "Lipid Intermediates". C. D. Warren, R. W. Jeanloz. 10:00—14. The Total Synthesis of Betulaprenol-6, and the Isolation of Natural Polyisoprenols from New Sources. J. S. Baran, D. H. Steinman, D. D. Langford, L. Hansen, T. Kosobud, J. Mueller, B. S. Pitzele. 10:45—Intermission. 11:00—15. Host-cell Processing of Envelope Glycoprotein of Vesicular Stomatitis Virus. L. H. Hunt, J. Etchison, J. Robertson, M. Robertson, D. F. Summers. 11:45—16. Chemistry and Biosynthesis of Unique Surface Polymers Containing Poly Sialic Acid in Escherichia coli K-235. F. A. Troy, T. E. Rohr. MONDAY AFTERNOON

Section A

Conrad Hilton, Astoria Room (3rd Floor) General W. W. Binkley, Presiding 2:00—17. Award Address (C. S. Hudson Award). Adventures with Nucleosides: Chemistry and Chemotherapy. J. J. Fox, 1977 Recipient. 2:55—18. Synthesis of 3,6-anhydro-D-a//oheptulosonic Acid Derivatives and Their Conversion into C-Nucleosides. F. W. Clough, L. B. Townsend. 3:10—19. Synthesis of Thieno [2,3-d] Pyrimidine Nucleosides Related to the Nucleosides Cytidine and Uridine. V. D. Patil, D. S. Wise, L. B. Townsend. 3:25—20. Synthesis and Biological Activity of Some (2-deoxy-/3-D-eryf/?ro-pentofuranosyl-uronic acid)-, -uronamide)-, and urononitrile)-pyrimidines. R. F. Schinazi, W. H. Prusoff. 3:40—21. A Mild Process for the Oxidation of Nucleosides. R. W. Binkley, D. G. Hehemann. 3:55—22. Control of Acyl Migration During Removal of the tert-Butyldi-methylsilyl Group: Synthesis of Some Esters of 9-BD-arabinofuranosyladenine (Vira-A®). D. C. Baker. 4:10—23. Some Reactions of Nucleoside 4',5'-enol Acetates and 4',5'-enamines. J. A. Secrist, III, S. L. Cook, W. J. Winter, Jr. 4:25—24. Acetylenic Precursors for Synthesis of C-Nucleoside Analogs. D. Horton, W. R. Turner. 4:40—25. Synthesis of p-nitrophenyl 2deoxy-2-(thioacetamido)- J8-D- hexopyranosides as Inhibitors of 2-acetamido-2deoxy-/3-D-hexosidase. G. S. Bedi, R. H. Shah, O. P. Bahl. 4:55—26. Synthesis of 2,3-dideoxy-D-g/ycero-pentopyranosyland 2-deoxy-Df/ireo-pentopyranosyl-anthracyclines. H. S. El Khadem, D. Matsuura. Section B Conrad Hilton, Parlor A (3rd Floor) General G. D. McGinnis, Presiding 3:00—27. Cationic, Galactosamine Exopolysaccharide from Various Aspergillus Species. P. A. Sandford, P. R. Watson, K. A. Burton, M. C. Cadmus. 3:15—28. Rheological Properties of Polysaccharide Mixtures. II. Synergistic Interaction of Xanthan Gum with Various Acidic and Neutral Polysaccharides. P. A. Sandford, J. E. Pittsley, C. A. Knutson. 3:30—29. Separation of Xanthan Gums of Differing Pyruvate Content by Fractional Precipitation with Alcohol. P. A. Sandford, P. R. Watson, C. A. Knutson. 3:45—30. Light-scattering Molecular Weights and Specific Increment Behavior of Amylose and Dextran in Methyl Sulfoxide— Water. F. R. Dintzis, R. Tobin. 4:00—31. Enzymic Studies on kappa- and /ote-Carrageenans. S. S. Bhattacharjee, C. Bellion, W. Yaphe. 4:15—32. Polysaccharides as Texture-stabilizing Additives for Dehydrated Vegetables. M. G. Driver, A. R. Rahman, D. E. Westcott. 4:30—33. Use of Polymers as Protecting Groups in Carbohydrate Chemistry. Polystyrylboronic Acid: Selectivity and Applications. J. M. J. Frechet, E. Seymour.

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4:45—34. Pyrolytic Synthesis and Decomposition of 1,4:3,6-dianhydro-a-D-glucopyranose. F. Shafizadeh, R. H. Furneaux, T. T. Stevenson, T. G. Cochran. TUESDAY MORNING

Section A

Conrad Hilton, Astoria Room (3rd Floor) Symposium on Biosynthesis of Complex Carbohydrates Joint with Division of Biological Chemistry C D . Warren, Presiding 9:00—35. Biosynthesis of Dolichol Derivatives in Yeast and Their Role in Protein Glycosylation. A. J. Parodi. 9:45—36. Tunicamycin: An Inhibitor of Dolichol-mediated Protein Glycosylation. J. S. Tkacz. 10:30—Intermission. 11:00—37. Participation of Dolichol in Glycosylation Systems in Smooth Muscle Cells in culture. A. M. Adamany, J. T. Mills. 11:45—38. Biosynthesis of Dolichol-linked Saccharides in Calf-pancreas Microsomes. A. Herscovics. Section B Conrad Hilton, Parlor A (3rd Floor) Symposium on Carbohydrate Sulfates Joint with Cellulose, Paper and Textile Division R. G. Schweiger, Presiding 9:00—Introductory Remarks. 9:10—39. Sulfate Esters of L-Ascorbic Acid. P. A. Seib, D. Lillard, C. H. Lee, R. C. Hoseney, Y. T. Liang. 9:40—40. Glucosinolates and Other Natural Sulphates. A. Kjaer. 10:10—41. Biological Effects of Sulphated Glycoproteins on Cell Metabolism and Growth Characteristics. P. W. Kent, C. J. Coles, J. R. Cooper, N. Mian. 10:40—42. Sulphur-containing Glycolipids. R. Gigg. 11:10—43. Spectrofluorimetric Methods for Estimating and Studying the Interactions of Sulphated Polysaccharides in Biological Systems. R. B. Cundall, D. Murray, G. O. Phillips. 11:40-44. Sulfated Glycosaminoglycans Obtained by Chemical Modification of Polysaccharides. D. Horton, T. Usui. TUESDAY AFTERNOON

Section A

Conrad Hilton, Astoria Room (3rd Floor) Symposium on Biosynthesis of Complex Carbohydrates Joint with Division of Biological Chemistry R. W. Jeanloz,

Presiding

2:00—45. The Elongation of Asparagine-A/Acetylglucosamine Type Oligosaccharides. H. Schachter, S. Narasimhan, J. R. Wilson. 2:45—46. Regulation of Synthesis of Chondroitin Sulfate Proteoglycan. N. B. Schwartz. 3:30—Intermission. 4:00—47. Biosynthesis of Glycosaminoglycans. J. E. Silbert. 4:45—48. Glycoprotein as Acceptor in Glycogen Biosynthesis. N. Patil, E. E. Smith, W. J. Whelan. 5:15—Divisional Business Meeting. Section B Conrad Hilton, Parlor A (3rd Floor) Symposium on Carbohydrate Sulfates Joint with Cellulose, Paper and Textile Division R. G. Schweiger, Presiding 2:00—49. Heparin Derivatives of High Molecular Weight. L. Mester, M. Mester. 2:30—50. Enzymic Formation and Hydrolysis of Polysaccharide Sulfates. K. Yamamoto, K. K. De, R. L. Whistler. 3:00—51. Some Novel Methods and Results in the Sulfation of Polysaccharides. K. B. Guiseley. 3:30—52. Sodium Cellulose Sulfate via Cellulose Nitrite. R. G. Schweiger. 4:00—53. Reaction of Starch with the Chlorosulfonic Acid—Formamide Reagent. F. Schierbaum, D. Kordel. 4:30—54. Sulfonic Acid-containing, Graft Polymers of Xanthan Gum. I. W. Cottrell, G. H. Best, R. A. Empey. 5:15—Divisional Business Meeting (see Section A for location).

Section C Symposium on Fuels and Energy from Renewable Resources I Joint with Cellulose, Paper, and Textile Division and Division of Fuel Chemistry (see page 35) 5:15—Divisional Business Meeting (see Section A for location). WEDNESDAY MORNING

3:50—71. Carbohydrate-derived Polyols for Rigid Urethane Foam Production. F. H. Otey. 6:00—Divisional Social Hour (see Section A for location). 7:00—Divisional Dinner. (Hudson Award). (See Section A for location).

Section C

Section A

Conrad Hilton, Astoria Room (3rd Floor) Symposium on Carbohydrate Sulfates Joint with Cellulose, Paper and Textile Division R. G. Schweiger, Presiding 9:00—55. Sulfated Polysaccharides Metabolised by the Marine Chlorophyceae. E. Percival. 9:30—56. Sulfated Polysaccharides of the Rhodophyceae. E. Percival. 10:00—57. Sulfated Fucose-containing Polysaccharides from Brown Algae: Structural Features and Biochemical Implications. D. G. Medcalf. 10:30—58. The interaction of Small Ions with Polysaccharide Sulfates. P. Ander, N. Swanson, A. Kowblansky, M. Tomasula, R. Sasso. 11:00—59. Interaction of Sulphated Polysaccharides with Counterions. G. Pass, G. O. Phillips, D. J. Wedlock, R. B. Morley. Section B Conrad Hilton, Parlor A (3rd Floor) Symposium on Carbohydrate-Protein Interactions Joint with Division of Biological Chemistry I. J. Goldstein, Presiding 9:00—Introductory Remarks. 9:05—60. Studies on the Interaction of Lectins with Saccharides on Lymphocyte Cell-surfaces. N. Sharon, Y. Reisner, A. Ravid, A. Prujansky. 9:50—61. Study of Cell Surface Carbohydrates with Lectins. R. D. Poretz. 10:15—62. The Carbohydrate-binding Site of Concanavalin A. K. D. Hardman. 11:00—63. The Mechanism of Binding of Mono- and Oligo-saccharides to Concanavalin A. C. F. Brewer, R. D. Brown, III. 11:40—64. Binding of p-Nitrophenyl 2-0a-D-mannopyranosyl- a-D- mannopyranoside to Concanavalin A. T. J. Williams, J. A. Shafer, I. J. Goldstein.

Section C

Symposium on Fuels and Energy from Renewable Resources III Joint with Cellulose, Paper and Textile Division and Division of Fuel Chemistry (see page 35) 6:00—Divisional Social Hour (see Section A for location). 7:00—Divisional Dinner. (Hudson Award). (See Section A for location).

THURSDAY MORNING AND AFTERNOON Conrad Hilton, Astoria Room (3rd Floor) Symposium on Carbohydrate-Protein Interactions Joint with Division of Biological Chemistry

I. J. Goldstein, Presiding 9:00—72. An Induced Association Model for Carbohydrate Receptors in the Bacterial Sensing System. D. E. Koshland, Jr., P. Strange, R. Zukin, P. Hartig. 9:45—73. New Insights on Carbohydrase Action by Use of Glycosyl (Nonglycosidic) Substrates. E. J. Hehre. 10:30—74. The Coordinated Action of the Two Glycogen-debranching Enzyme Activities on Phosphorylase Limit-dextrin. T. E. Nelson, B. K. Gillard, R. C. White. 11:25—Discussion. D. French. 2:00—75. The Role of Glycosidically Bound Mannose in the Cellular Assimilation of /3-D-Galactosidase. G. W. Jourdian, J. Distler, V. Hieber, R. Schmickel. 2:45—76. Complementarity Between the Ganglioside GM2 and the Enzyme GMT Synthetase is a Possible Recognitionmechanism in the Chick Retino-tectal Projection. J. M. Pierce, E. A. Slavinski, S. Roth. 3:30—77. Structure and Function of Proteoglycans. L. Rosenberg, L.-H. Tang, D. Zucker-Franklin. 4:25—78. Circular Dichroism and Saccharide-induced Conformational Transitions of Soybean Agglutinin. M. W. Thomas, E. F. Walborg, Jr., B. Jirgensons, J. E. Rudzki. 4:45—79. Dependence of Agglutination on Concanavalin A Molecular Transition. D. W. Evans, P. Y. Wang.

Symposium on Fuels and Energy from Renewable Resources II Joint with Cellulose, Paper and Textile Division and Division of Fuel Chemistry (see page 35) WEDNESDAY AFTERNOON Section A Conrad Hilton, Astoria Room (3rd Floor) Symposium on Carbohydrate-Protein Interactions Joint with Division of Biological Chemistry I. J. Goldstein, Presiding 2:00—65. Antibodies Against Oligosaccharides. D. A. Zopf, C.-M. Tsai, V. Ginsburg. 2:45—66. Interaction of Glycosyl Irnmunogens with Immunocyte Receptor-sites in the Synthesis of Anti-glycosyl Isoantibodies. J. H. Pazur, K. L. Dreher. 3:30—67. The Specificity of Sugar Tasteresponses in the Gerbil. W. Jakinovich, Jr. 4:25—Panel Discussion: Nature of the Carbohydrate Combining Site. 6:00—Divisional Social Hour. Chicago Athletic Club, 12 S, Michigan Ave. 7:00—Divisional Dinner (Hudson Award). Chicago Athletic Club, 12 S. Michigan Ave. Section B Conrad Hilton, Parlor A (3rd Floor) Symposium on Industrial Uses of Non-food Carbohydrates D. H. Ball, Presiding 2:00—Introductory Remarks. 2:10—68. Non-food Use of Sugars. A. G. Holstein. 2:40—69. Carbohydrate-based Chelating Agents. A. G. Holstein. 3:20—70. Hydrogenolysis of Formose Sugars to Polyols. A. H. Weiss.

CELL CELLULOSE, PAPER AND TEXTILE DIVISION C. Schuerch, Jr., Chairman E. J. Soltes, Secretary-Treasurer MONDAY MORNING

Section A

Conrad Hilton, P.D.R. #4 (3rd Floor) Symposium on New Solvents for Cellulose and Related Polysaccharides I R. H. Marchessault, Presiding 9:00—Introductory Remarks. 9:15—1. Newer Cellulose Solvents. M. Lift. 9:45—2. Dilute Solution Properties of Methylol Cellulose in Dimethylsulfoxide. D. A. Tiede, R. A. Stratton. 10:15—3. N.M.R. Studies of Cellulose Solutions in Organic Solvents. D. Gagnaire, D. Mancier, M. Vincendon. — 4 . Aspects of Cellulose Solvency. N. Franks, (by title only)

Section B Conrad Hilton, P.D.R. #3 (3rd Floor) Symposium on Modified Cellulosics I R. M. Rowell, R. Young,

Co-Chairmen

9:00—Introductory Remarks. 9:15—5. Chemical Modification of Cellulose—A Historical Review. D. F. Durso. 10:15—6. Modified Cellulosics—An Overview of the Future. T. E. Muller, H. L. Hergert. 11:15—7. Cotton—A World Cellulose Fiber. R. S. Corkern, B. M. Kopacz, M. E. Carter. 11:45—8. Wood Cellulose Inventory. N. Sanyer. MONDAY AFTERNOON

10:50—27. Oxidation and Degradation of Cellulose. M. Lewin. 11:30—Discussion. —28. Hydroxy I Reactivity and Availability in Cellulose. S. P. Rowland, (by title only) —29. Recent Studies on the Preparation, Structure, and Properties of Some Cellulose Derivatives. S. S. Bhattacharjee, A. S. Perlin. (by title only) —30. Cellulose Solvents. M. Litt. (by title only)

stituent Groups. G. F. Touzinsky, S. H. Gordon. 4:50—49. Award Address (Anselme Payen Award sponsored by Cellulose, Paper, and Textile Division). Versatility of Cellulose. K. Ward, Jr. 5:30—Divisional Business Meeting (see Section A for location). 6:00—Divisional Social Hour {see Section A for location). 7:00—Divisional Dinner (Anselme Payen Award). (See Section A for location).

Section C

Section D

Symposium on Carbohydrate Sulfates Joint with Division of Carbohydrate Chemistry (see page 34)

Symposium on Carbohydrate Sulfates Joint with Division of Carbohydrate Chemistry (see page 34) 5:30—Divisional Business Meeting (see Section A for location). 6:00—Divisional Social Hour (see Section A for location). 7:00—Divisional Dinner (Anselme Payen Award). (See Section A for location).

Section A

Conrad Hilton, P.D.R. #4 (3rd Floor) Symposium on New Solvents for Cellulose and Related Polysaccharides II R. H. Marchessault, Presiding

TUESDAY AFTERNOON

2:00—9. Single Crystals of Cellulose IV. A. Buleon, H. Chanzy. 2:30—10. Studies of Polymer-Cellulose Blends Prepared from Solution. A. H. Jolan, R. E. Prud'homme. 3:00—11. Process and Fiber Spinning Studies for the Cellulose/Paraformaldehyde/ Dimethylsulfoxide System. R. B. Hammer, M. E. O'Shaughnessy, E. R. Strauch, A. F. Turbak. 3:30—12. The Use of Cellulose Solvents in Fiber Bonding. C. J. Su. —13. Action of Nitrosylic Compounds on Cellulose. B. Phillip, H. Schleicher, W. Wagenknecht. (by title only)

H. L. Needles,

Section B Conrad Hilton, P.D.R. #3 (3rd Floor) Symposium on Modified Cellulosics II 2:00—14. Recent Developments in Hemicellulose and Potential Industrial Applications. R. L. Whistler, R. N. Shah. 3:00—15. Graft Copolymers of Cellulose and Starch—Initiation by Peracetic Acid and Mn + 3 Ions. B. Ranby. 3:30—16. Modifications to Cellulose Using UV Grafting Procedures. N. P. Davis, J. L. Garnett. 4:00—17. Wood Pulp Grafting with Different Monomers by the Xanthate Method. V. Hornof, C. Daneault, B. V. Kokta, J. J. Valade. 4:30—18. A Novel Process for the Treatment of Pulp Mill Effluent Using Grafted Pulp Fibers. P. Lepoutre, S. H. Hui, A. A. Robertson. TUESDAY MORNING

Section A

Conrad Hilton, P.D.R. #4 (3rd Floor) Symposium on Fiber Modifications and Finishing I H. L. Needles, Presiding 9:00—Introductory Remarks. 9:05—19. Photoinitiated Grafting of NMethylolacrylamide With Cotton in a Process for Producing Wrinkle Resistant Fabrics. R. M. Reinhardt, J. C. Arthur, Jr. 9:35—20. Interaction of Carbamates and Their N-Methylol Derivatives with Cotton and Sephadex Measured by Gel Filtration. D. J. Stanonis, S. P. Rowland. 10:05—21. Cellulose Modifications via RF Cold Plasmas. H. Z. Jung, T. L. Ward, O. Hinojosa, R. R. Benerito. 10:35—Intermission. 10:50—22. Characterization of Reactive Sites Resulting from RF Cold Plasma Treatments of Cellulose. O. Hinojosa, T. L. Ward, H. Z. Jung, R. R. Benerito. 11:20—23. Changes in the Properties of Flame Retardant Cotton Fabrics Caused by Washing Treatments. S. H. Zeronian, I. Hardin, K. Alger. Section B Conrad Hilton, P.D.R. #3 (3rd Floor) Symposium on Modified Cellulosics III

R. Young, Presiding 9:00—Introductory Remarks. 9:05—24. Antibacterial Fibers. T. L. Vigo. 9:50—25. The Effect of Anhydrous Ammonia on Cellulose II. L. G. Roldan. 10:20—26. Effect of Changes in Supramolecular Structure on the Thermal Properties and Pyrolysis of Cellulose. K. E. Carbrdilla, S. H. Zeronian.

Section A

Conrad Hilton, Bel Air Room (3rd Floor) Symposium on Fiber Modifications and Finishing II Presiding

2:00—Introductory Remarks. 2:05—31. Radiation Curing of Flame Retardants: A Comparison of Application and Curing Techniques. J. Ennis, E. Bhttencourt, W. K. Walsh. 2:35—32. Studies of Flame Retardant Finished Textiles via Electron Microscopy. L. G. Roldan, S. B. Sello, C. V. Stevens. 3:05—Intermission. 3:20—33. Flammability of Combinations of FR Cotton and Untreated Fabrics. S. R. Hobart, S. P. Rowland. 3:50—34. The Effect of pH of the THPC Formulation on the Flame-Resistance and Dimensional Stability of Cotton/Wool Blend Fabrics. R. D. Mehta. 4:20—35. Multipurpose Finishes for Wool. M. Friedman, J. F. Ash, R. E. Bry, R. A. Simonaitis. 5:30—Divisional Business Meeting. 6:00—Divisional Social Hour. Conrad Hilton, Parlor B (3rd Floor). 7:00—Divisional Dinner (Anselme Payen Award). Conrad Hilton, Parlor B (3rd Floor). Section B Conrad Hilton, Parlor B (3rd Floor) Symposium on Fuels and Energy from Renewable Resources I Joint with Divisions of Carbohydrate Chemistry and Fuel Chemistry L. Anderson,

Presiding

2:00—Introductory Remarks. 2:10—36. How Much Energy Do We Really Need? C. M. Mottley. 2:40—37. Uncounted Energy: Renewable Organic Resources. D. A. Tillman. 3:10—38. Energy from Waste Materials, 1977 Overview. M. D. Schlesinger. 3:40—39. Energy Recovery from Municipal Waste. J. R. Greco. 4:10—40. Thermal Analysis of Forest Fuels. F. Shafizadeh, W. F. DeGroot. 5:30—Divisional Business Meeting (see Section A for location). 6:00—Divisional Social Hour (see Section A for location). 7:00—Divisional Dinner (Anselme Payen Award). (See Section A for location).

Section C Conrad Hilton, P.D.R. #2 (3rd Floor) Anselme Payen Award Symposium Honoring K. Ward, Jr. Chemical Modifications of Cellulose for Paper and Textile Applications

W. J. Weaver, Presiding 2:00—41. Practical Textile Finishes Based on Chemical Modification of the Cotton Fiber. J. D. Reid, R. M. Reinhardt. 2:20—42. Rayon Fibers of Today. G. C. Daul, F. P. Barch. 2:40—43. The Modification of Cellulosic Textile and Paper-Making Fibers by Grafting. V. Stannett. 3:00—44. Cellulose Modification via Methylol Cellulose Solutions. D. C. Johnson. 3:20—45. Mercerization of Cotton by Sodium Hydroxide, Ethylamine and Liquid Ammonia: In Retrospect and Prospect. M. L. Nelson. 3:40—Intermission. 3:50—46. The Structure of Cellulose. R. H. Atalla. 4:10—47. Second Order Transitions in Cellulosic Materials. S. H. Zeronian. 4:30—48. Degree of Substitution of Cellulose Derivatives Containing N Different Sub-

WEDNESDAY MORNING

Section A

Conrad Hilton, P.D.R. #4 (3rd Floor) Symposium on Fiber Modifications and Finishing III

H. L. Needles, Presiding 9:00—Introductory Remarks. 9:05—50. Fabric Modification Using the Plasmoid. K. S. Gregorski, A. E. Pavlath. 9:35—51. Electron Beam-Induced Grafting of Acrylic Acid on Nylon 6. H. L. Needles, K. W. Alger, A. Tai. 10:05—52. Wetting Properties of Radiation Polymerized Hydrophilic Finishes on Polyester. M. M. Hurlocker, W. K. Walsh. 10:35—Intermission. 10:50—53. Detergency Kinetics of Particulate Soil. E. Kissa. 11:20—54. The Effect of Plasticizing Compounds on Acrylic Fibers. Z. Gur-Arieh, W. Ingamells, R. H. Peters.

Section B Conrad Hilton, Parlor C (3rd Floor) Symposium on Fuels and Energy from Renewable Resources II Joint with Divisions of Carbohydrate Chemistry and Fuel Chemistry

D. Tillman, Presiding 9:00—Introductory Remarks. 9:10—55. Anticipated Competition for Available Wood Fuels in the U.S. J. B. Grantham. 9:40—56. Conversion of Stagnated Timber Stands to Productive Sites Using Noncommercial Material for Fuel. J. I. Zerbe. 10:10—57. The Pyrolysis-GasificationCombustion Process. D. L. Brink, G. W. Faltico, J. F. Thomas. 10:40—58. A Vertical Bed Pyrolysis System. M. D. Bowen, J. Knight, K. Purdy. 11:10—59. Industrial Wood Energy Conversion. G. D. Voss. 11:40—60. Prospects for Co-generation of Steam and Power in the Forest Products Industry. L. N. Johanson, K. V. Sarkanan.

Section C Symposium on Carbohydrate Sulfates Joint with Division of Carbohydrate Chemistry (see page 34)

WEDNESDAY AFTERNOON Conrad Hilton, Parlor C (3rd Floor) Symposium on Fuels and Energy from Renewable Resources III Joint with Divisions of Carbohydrate Chemistry and Fuel Chemistry K. V. Sarkanen, Presiding 2:00—Introductory Remarks. 2:10—61. An Evaluation of the Use of Agricultural Residues as an Energy Feedstock. F. A. Schooley, J. A. Alich, K. R. Ernest, R. Hamilton, K. A. Miller, T. C. Veblen, J. G. Witwer, B. M. Louks. 2:40—62. Logistics of Resources and Residues. T. Miles. 3:10—63. Bagasse as a Renewable Energy Source. W. Arlington. 3:40—64. Using Gin Waste to Provide Heat for Seed Cotton Dryers. W. F. Lalor, J. K. Jones, G. A. Slater. 4:10—65. The Design of a Large Scale Manure/Methane Facility. F. T. Varani, J. L. Burford, R. P. Arber.

4:40—Discussion. 5:30—Divisional Social Hour (Joint with Divisions of Organic Coatings and Plastics Chemistry and Polymer Chemistry, Inc.). Palmer House, State Ballroom. (4th Floor).

THURSDAY MORNING Conrad Hilton, Beverly Room (3rd Floor) General Symposium on Cellulose, Wood and Textile Topics

C. Schuerch, Presiding 9:00—Introductory Remarks. 9:05—66. Use of Benzotriazole Derivatives to Retard the Photoyellowing of Wool. N. A. Evans, I. H. Leaver, P. J. Waters. 9:25—67. Chemical Modification of Wood for Toxicity to Decay Fungi. M. A. Kalnins. 9:45—68. High Performance Liquid Chromatography of Wood Polysaccharides. G. D. McGinnis. 10:05—69. Kinetics of the Celluloytic Degradation of Cellulose by Trichoderma Viride Cellulase. H. L. Griffin, J. H. Sloneker, G. E. Inglett. 10:25—Intermission. 10:35—70. Cellulose Activity in Mixed Solvents. W. T. Smith, Jr., C. Cheng. 10:55—71. Photooxidative Degradation of Cellulose: Reactions of the Cellulose Free Radicals with Oxygen. D. N.-S. Hon.

CHED DIVISION OF CHEMICAL EDUCATION INC. R. W. Ramette, Chairman J. A. Young, Secretary MONDAY MORNING AND AFTERNOON Pick-Congress, Gold Room (2nd Floor South) Symposium on Incorporation of Photochemistry in the Undergraduate Curriculum

F. D. Lewis, Presiding 9:00—Introductory Remarks. 9:10—1. Molecular Organic Photochemistry. A Clock and a Map for Exploring the Microscopic World. N. J. Turro. 10:00—2. Teaching Molecular Orbital Methods and Photochemistry in Organic Chemistry. H. E. Zimmerman. 10:50—3. Using Simple HMO Calculations to Construct Orbital Correlation Diagrams. A Perspicuous Pedagogical Demonstration of the Non-Crossing Rule. J. C. Dalton, L. E. Friedrich, J. J. Snyder. 11:20—4. Photochemistry of Alkyl Halides. P. J. Kropp, N. J. Pienta. 2:00—5. Photophysics. F. S. Wettack. 2:45—6. Experiments in Inorganic Photochemistry. J. N. Demas. 3:30—7. Inorganic Photochemistry: Concepts and Experiments. H. D. Gafney. 4:15—8. Photochromism of Inorganic Compounds: Principles and Practice. C. Kutal, P. Schwendiman. 4:55—Concluding Remarks. TUESDAY MORNING

Section A

Pick-Congress, Gold Room (2nd Floor South) Symposium on Public and Private Funding of Undergraduate Research

W. C. Harris, Presiding 9:00—Introductory Remarks. 9:15—9. National Science Foundation Support of Undergraduate Research. L. A. Gist. 9:45—10. The ACS-PRF Program of GrantsIn-Aid for Fundamental Research in Undergraduate Departments. C. A. Walker, J. W. Collat.

July 25, 1977 C&EN

35

10:15—Intermission. 10:45—11. Industrial Support of Undergraduate Research. C. W. Theobald. 11:15—12. The Case For Support of Research in The Undergraduate College. J. W. Powers. 11:45—Panel Discussion.

Section B Symposium on Resources for Chemical Health and Safety—Part I Joint with Council Committee on Chemical Safety and Division of Chemical Health and Safety (Probationary) (see page 36) TUESDAY AFTERNOON

Section A

Pick-Congress, Gold Room (2nd Floor South) Poster Session-General

D. W. Chandler, Presiding 2:00-3:00—13. Preparing Students for Employment. M. M. Renfrew. 2:00-3:00—14. The Use of Video Cassettes As An Integral Part of Chemical Education. D. C. Blumenthal, L. L. Jones, C. F. Liu. 2:00-3:00—15. An Integrated First Semester Organic Laboratory Program. T. D. Walsh. 2:00-3:00—16. Reliability and Validity Of An Inventory To Assess Piaget's Stages. L. Milakofsky, H. O. Patterson. 2:00-3:00—17. New Molecular Models of Biopolymers. E. J. Barrett. 2:00-3:00—18. A Laboratory Based General Chemistry Course Using The Piaget Model. D. M. Whisnant. 3:00-4:00—19. Industrial Chemistry Revisited. W. L. Smith. 3:00-4:00—20. The Symmetry of Atomic States and Atomic Orbitals in Crystalline and Molecular Environments. R. L. DeKock, A. J. Kromminga, T. S. Zwier. 3:00-4:00—21. An Equilibrium Experiment for General Chemistry: The Hydrolysis of Ethyl Acetate. F. P. Gasparro, W. M. Stigliani. 3:00-4:00—22. Physical Chemistry Laboratory Can Be Fun with Computer Graphics. G. F. Pollnow. 3:00-4:00—23. What Teachers Need To Know About the Toxic Substance Control Act. L. T. Pryde. 3:00-4:00—24. An Automatic Recording Gas Volumeter. K. L. Stevenson, D. D. Davis. 4:00-5:00—25. The North Carolina Section's Short Course Program: A Successful Model For A Local Section Solution to Local Needs. M. Nees. 4:00-5:00—26. The Preparation of Amines By The Use of Grignard Reagents in the Undergraduate Organic Chemistry Laboratory. I. E. Pollak. 4:00-5:00—27. The Role of Science Museums in Chemical Education. G. L. Gilbert. 4:00-5:00—28. Chemistry for Potters. A. A. Denio. 4:00-5:00—29. An On-Line System For Helping Faculty Members Write Computer Programs For The Generation of Individualized Problem Assignments. R. W. Collins, S. J. Duff. 4:00-5:00—30. Structure and Conformational Aspects of Nucleic Acids. W. M. Scovell. 5:00—Divisional Business Meeting. PickCongress, Seminar Room (3rd Floor North). 6:30—Divisional Social Hour. Marina City Restaurant, 300 N. State St. 7:30—Divisional Dinner. (Speaker: G. R. Crosby, "Faculty Responsibilities in the Pursuit of Excellence."). Marina City Restaurant, 300 N. State St.

Section B Symposium on Resources for Chemical Health and Safety—Part II Joint with Council Committee on Chemical Safety and Division

Smoking/nonsmoking Smoking and nonsmoking sections in technical session meeting rooms have been designated as follows: Smoking: left side of room Nonsmoking: right side of room

36

C & E N J u l y 2 5 , 1977

of Chemical Health and Safety (Probationary) (see page 36) 5:00—Divisional Business Meeting (see Section A for location). 6:30—Divisional Social Hour (see Section A for location). 7:30—Divisional Dinner. Speaker: G. R. Crosby. "Faculty Responsibilities in the Pursuit of Excellence". (See Section A for location).

WEDNESDAY MORNING AND AFTERNOON Pick-Congress, Gold Room (2nd Floor South) Symposium on New Directions in the Teaching of Physical Chemistry Joint with Division of Physical Chemistry A. W. Adamson, Presiding 9:00—Introductory Remarks. 9:10—31. Physical Chemistry— Quo Vadis? G. W. Castellan. 9:40—32. New Demands in the Teaching of Physical Chemistry. D. A. McQuarrie. 10:10—33. "Mainstream" Physical Chemistry for the Chemistry Major. R. N. Porter. 10:40—34. Physical Chemistry for Life Scientists: Physicochemical Cytology. G. Gorin. 11:00—35. How Much Physical Chemistry Should be Included in General Chemistry? H. B. Gray. 11:20—36. The Undergraduate ACS Examination in Physical Chemistry. Division into Three Parts. H. P. Hopkins, Jr. 11:40—Discussion.

G. W. Castellan, Presiding 2:00—Introductory Remarks. 2:05—37. S.I. Units Their Introduction and Use in Europe. U. H. Hofacker. 2:25—38. S. I. Units? A Camel is a Camel! A. W. Adamson. 2:50—Discussion. 3:00—39. Can Colligative Properties be Easily Explained? K. J. Mysels. 3:20—40. Can P-Chem be Learned in the Laboratory? R. E. Watras, M. L. James. 3:40—41. Thermodynamics a la Piaget, Weinhold, and Gibbs. W. F. Arendale. 4:00—42. A Modular Problem Oriented Tutorial Course in Physical Chemistry. G. F. Pollnow. 4:20—43. NMR Spectroscopy, A Practical Introduction to Molecular Orbital Theory. J. B. Grutzner. 4:40—44. New Directions in Teaching Physical Chemistry at a British University of Technology—an American View. G. F. Sheats. THURSDAY MORNING AND AFTERNOON Pick-Congress, Gold Room (2nd Floor South) Symposium on The Present Status of the Teaching of Analytical Chemistry Joint with Division of Analytical Chemistry T. R. Williams, Presiding 9:00—Introductory Remarks. 9:10—45. Analytical Chemistry In An Integrated Laboratory Sequence. K. E. Dolbow. 9:40—46. Analytical Chemistry At A Community College: A Balance Of Wet Chemical Methods And Instrumental Analysis. J. M. Hayes. 10:10—47. The Sophomore Level Analytical Laboratory For Non-Majors. R. A. Pacer. 10:40—Intermission. 10:50—48. The Analytical Textbook Situation: Can A Textbook Present Analytical Chemistry As It Really Is? R. H. Bromund, T. R. Williams. 11:20—49. Industrial Expectations Of The Recent Graduate In Analytical Chemistry. J. C. Abbott. 11:50—Concluding Remarks. 2:00—50. The Graduate Level Analytical Chemistry Teaching Program At The University of Massachusetts. R. M. Barnes, D. J. Curran, J. E. Roberts, S. Slggia, P. C. Uden. 2:30—51. The Making Of The Analytical Chemist—1977. Conflicts In Graduate Education. L. R. Faulkner. 3:00—Panel Discussion on the Teaching of Analytical Chemistry. R. Large, Chairman, L. R. Faulkner, P. C. Uden, J. G. Grasselll, J. C. Abbott. 4:30—Concluding Remarks.

CHSA DIVISION OF CHEMICAL HEALTH AND SAFETY (Probationary) H. H. Fawcett, Chairman E. I. Becker, Secretary-Treasurer TUESDAY MORNING Pick-Congress, Florentine Room (3rd Floor North) Symposium on Resources for Chemical Health and Safety—Part I Joint with Council Committee on Chemical Safety and Division of Chemical Education, Inc. H. H. Fawcett, Presiding 9:00—1. Introductory Remarks and Purpose of Symposium. H. H. Fawcett. 9:05—2. Manufacturing Chemists Association Resource Material for Health and Safety. V. H. Peterson. 9:35—3. The National Institute for Occupational Safety and Health Current Intelligence System. R. M. Moore, Jr., H. P. Stein. 10:05—4. Department of Defense Chemical Ammunition Safety Program. R. A. Scott, Jr. 10:35—5. Health and Safety Resources at the State Level. C. Wiant. 11:05—Discussion. TUESDAY

AFTERNOON

Pick-Congress, Florentine Room (3rd Floor North) Symposium on Resources for Chemical Health and Safety—Part II Joint with Council Committee on Chemical Safety and Division of Chemical Education, Inc. E. I. Becker, Presiding 2:00—6. The National Fire Protection Association's Role in Chemical Fire Safety. R. P. Benedetti. 2:30—7. Industrial Hygiene Training at Quinnipiac College. F. A. Van Atta. 3:00—8. Studies of Hazardous Materials at NT Research Institute. H. Napadensky, J. Keith, R. Remaly, P. Holmes. 3:30—9. Operation of a Carcinogen Repository. R. F. Remaly, J. N. Keith. 4:00—Discussion. 5:00—Divisional Business Meeting.

CHIF DIVISION OF CHEMICAL INFORMATION P. F. Sorter, Chairman C. H. O'Donohue, Secretary

MONDAY MORNING AND AFTERNOON Conrad Hilton, Lower Summit (27th Floor) Symposium on Trends in Handling Patent Information

C. C. Conrad, Presiding 9:00—Introductory Remarks. 9:10—1. Patent Searching in a Pharmaceutical Company. T. M. Johns, D. I. Ryno. 9:40—2. Pitfalls to Avoid in Procuring Patents. T. M. Schmitz.

10:10—3. Patent Information Activity of the Technical Information Retrieval Committee of the Manufacturing Chemists Association. P. T. O'Leary. 10:40—4. Patent Intelligence & Technology—Revealing Pseudo Proprietary Information in a New Format. H. M. Allcock, J. W. Lotz. 11:10—5. INPADOC and Its Fully Computerized Patent Documentation System. W. Pilch. 2:00—6. Panel Discussion on the Industrial Importance of Patent Information Services. R. H. Blaker, Moderator. 2:15—The Importance of Patents and Information Services to Research Workers. W. M. Bowman. 2:35—Patent Information Needs from a Marketing Manager's Point of View. N. H. Giragosian. 2:55—What the Patent Attorney Needs from a Patent Information Point of View. P. Newman. 3:15—The Information Chemist's View of the Patent Information Needs of Research Workers and Patent Attorneys. A. K. Valicenti. 3:35—Discussion. 3:55—7. Patents and Information. M. J. Marcus. 4:15—8. Hints on Reading and Understanding Patents. G. L. Rushton.

TUESDAY MORNING Conrad Hilton, Lower Summit (27th Floor) Symposium on Environmental Information Systems A. Gel berg, Presiding 9:00—Introductory Remarks. 9:10—9. The Pesticide Chemical Information System. R. J. Heuwinkel. 9:35—10. Bridging Among Environmental Information Systems. R. G. Dunn, D. C. Myers, H. V. Vo, D. W. Weisgerber, G. A. Wilson. 10:00—11. On-Line Environmental Information Goes to Court. D. B. Seba. 10:30—12. An Improved Method for the Calculation, Validation, and Retrieval of Air Quality Data. M. J. Kopecky, J. R. Fodor. 11:00—13. Structure and Substructure Search in EPA. S. R. Heller, J. A. Miller, A. E. Fein, G. W. A. Milne, R. J. Feldmann. 12:00—Divisional Luncheon (partially subsidized). Conrad Hilton, Parlor C (3rd Floor).

TUESDAY AFTERNOON Conrad Hilton, Lower Summit (27th Floor) General P. F. Sorter, Presiding 2:00—Introductory Remarks. 2:10—14. The Meanings, Ambiguities, Misuses and Paradoxes of Chemical Prefixes. A. Addleston. 2:30—15. Shortcomings of the Traditional Chemical Nomenclature. J. M. Knego. 2:50—16. User Education for Effective Use of Chemical Information. A. K. Kent. 3:15—17. CASCC—Current Awareness System in Coordination Chemistry. M. A. Czechowski, S. Kirschner. 3:35—18. Compact Representation of Chemical Reactions for Automated Retrieval and Generation. G. E. Vladutz. 4:00—19. General Subject Hierarchies in Chemical Abstracts (CA) Indexes. A. J. Beach. 5:00—Divisional Business Meeting. WEDNESDAY

MORNING

Conrad Hilton, Lower Summit (27th Floor) Symposium on Fossil Fuels Information Systems and Services

R. R. Graham, Presiding 9:00—Introductory Remarks. 9:05—20. Information Retrieval for the Petroleum Production Industry. S. J. Martinez, J. A. Bailey. 9:30—21. Information Services from the American Petroleum Institute—Central Abstracting and Indexing Service. E. H. Brenner, I. Zarember. 10:00—22. Fossil Fuels in Chemical Abstracts. C. W. Moulton. 10:30—23. U. S. Bureau of Mines Coal Data. W. G. Park, R. E. Harris. 11:00—24. Steps Toward a Coal Information Management System. D. J. Hlllman, R. R. Graham. 11:30—25. The Penn State Coal Data Base. W. E. Spackman.

WEDNESDAY

AFTERNOON

Conrad Hilton, Lower Summit (27th Floor) Workshop H. M. Allcock,

Presiding

2:00—26. Workshop of IFI/Plenum Data Company Patent Services. H. M. Allcock.

CMEC DIVISION OF CHEMICAL MARKETING AND ECONOMICS

WEDNESDAY MORNING AND AFTERNOON Palmer House, P.D.R. #17 (Club Floor) Symposium on Agricultural Chemicals Update

N. H. Giragosian, Presiding 9:00—Introductory Remarks. 9:10—21. Wheat Fallow Weed Control Market Opportunities. K. L. Moller. 9:40—22. Insecticides for Field Crops. J. Salter. 10:20—23. Use of Insecticides and Herbicides on Fruits and Vegetables. R. L. Carlsen. 11:00—24. Insecticides for Corn. D. Clark. 2:00—Introductory Remarks. 2:10—25. The Dynamic Miticide Market. D. W. Young. 2:40—26. Fungicides. C. Troph. 3:2C—27. Growth Regulators—Their Present and Future Role in Agriculture. M. A. Eggleton. 4:00—28. The Challenges and Opportunities of the Home and Garden Market. D. P. Hogan. 4:30—Summary and Panel Discussion.

E. Balgley, Chairman R. D. Shepherd, Jr., Secretary MONDAY MORNING AND AFTERNOON

COLL

Palmer House, Crystal Room (3rd Floor) Symposium on Impact of the Automobile on the U.S. Polymer Industry W. Burlant, Presiding 9:00—Introductory Remarks. 9:10—1. Feedstock Projections for Key Automotive Materials. D. F. Frldley. 9:45—2. The Automotive Market—Impetus to the Growth of Polyolefins. E. Carson, J. Houston. 10:15—3. Styrenic Thermoplastics: Past, Present and Future. L. A. Paradis, L. A. Conn. 10:45—4. Urethane Molding Materials in the Automotive Industry. D. G. Leis. 11:15—5. Polyurethane Automotive Coatings. G. A. Hudson, J. J. McGuinness, L. J. St. George, R. L. White. 2:00—6. PVC—Past, Present and Future. R. S. Brookman, R. A. Park. 2:30—7. Epoxy Resins—The Automotive Industries' Versatile Polymer. W. R. McConnell, G. G. Velten. 3:00—8. The Role of Acrylics in Automotive Coatings. R. B. Graver. 3:30—9. Engineering Thermoplastics in the Automotive Industry. J. D. Young. 4:00—10. Polyester Resins—The Growth Structural Resin. J. J. Young. 4:30—11. Plastics for Automotive Applications—A Perspective. D. T. Wark. TUESDAY

MORNING

Palmer House, Crystal Room (3rd Floor) Symposium on Corporate Planning R. Weiss, Presiding 9:00—Introductory Remarks. 9:10—12. The Good Planner—Characteristics and Qualities. J. D. McConnell. 9:40—13. Planning for the Future in a Large Company. F. S. Addy. 10:10—14. How to Make Corporate Planning Succeed. V. S. Nigrelli. 10:40—15. Service Companies Must Plan. W. C. Martschinke. 11:10—16. Strategic Planning at Air Products and Chemicals, Inc. J. F. Dempsey. TUESDAY

AFTERNOON

Palmer House, Crystal Room (3rd Floor) Symposium on Agricultural Chemicals Update N. H. Giragosian, Presiding 2:00—Introductory Remarks. 2:10—17. Pesticide Industry Overview. T. A. Blue, O. H. Johnson. 2:40—18. Weed Control in Field Corn. T. F. Armstrong. 3:20—19. Untapped Potential of Herbigation. J. DiVall. 4:00—20. Industrial Use of Herbicides. J. P. Doyle. 4:30—Divisional Business Meeting. 5:30—Divisional Social Hour. Palmer House, Crystal Room (3rd Floor).

DIVISION OF COLLOID AND SURFACE CHEMISTRY T. Fort, Jr., Chairman F. J. Micale, Secretary M. E. Schrader, Meeting Secretary MONDAY MORNING

Section A

Palmer House, Grand Ballroom (4th Floor) Symposium on Surface Science of Catalysis: Spectroscopic Characterization of Catalyst and Crystal Surfaces Joint with Divisions of Petroleum Chemistry Inc. and Physical Chemistry

R. P. Eischens, Presiding 9:00—Introductory Remarks. 9:05—1. Surface Information from Spectroscopies: An Overview. G. L. Haller. 10:00—2. Infrared Studies of Carbon Surfaces. J. R. Keifer, D. M. Smith. 10:40—3. Characterization of Oxide Surfaces via High Resolution, Solid State NMR Techniques. R. W. Vaughan, M. T. Duncan, D. G. Carson, J. R. Schlup. 11:30—4. Molecular Characterization of Electrode Surfaces by Raman and Resonance Raman Spectroscopy. R. P. Van Duyne, D. L. Jeanmaire, C. S. Allen. Section B Palmer House, State Ballroom (4th Floor) Symposium on Surface Chemistry in Biology and Medicine: Intermolecular Forces in Biological Systems

V. A. Parsegian, Presiding 9:00—5. The Sequence of a Membrane. P. H. Von Dreele. 9:25—6. Bilayer Charge Asymmetry as a Source of Membrane Potential. M. N. Sarbolouki. 9:50—7. Membrane Fusion in a Model System. R. E. Hauser, R. U. Muller. 10:15—8. Dynamic Structures and Reaction-Perturbed Double Layers. J. A. DeSimone. 10:40—9. Interactions in Mixed Monolayers of Myelin Structural Protein and a Natural Phospholipid. C. Thomas, L. Ter-Minassian-Saraga. 11:05—10. Phase Behavior of Lecithin-Cholesterol Surface Films: Analysis of the "Condensing" Effect of Cholesterol. N. L. Gershfeld, K. Tajima.

11:30—11. Spectroscopic Investigations of i 9:55—31. Surface Chemistry of Activated Hydrodesulfurization Catalysts by X-Ray Hydrogen and Polar Bonds in Association Photoelectron Spectroscopy. J. S. Brinen, Structures. S. Friberg. W. D. Armstrong. 10:30—32. Valence Level Photoelectron Section C Spectroscopy of Adsorption and Oxidation Processes at Metal Surfaces, and of Bulk Palmer House, Red Lacquer Room (4th Metal Oxides. C. R. Brundle. Floor) 11:05—33. Characterization of Metal SurGeneral | faces by SIMS and XPS. N. Winograd, R. Hewitt, A. Shepard, W. E. Baitinger, G. L. W. K. Hall, Presiding Ott, W. N. Delgass. 9:00—Introductory Remarks. 11:40—34. Characterization of Alloy Sur9:05—12. Covalently Attached Organic Mofaces by SIMS and XPS. G. L. Ott, W. N. nolayers on Semiconductor Surfaces. I. Delgass, R. W. Hewitt, A. Shepard, W. E. Haller. Baitinger, N. Winograd. 9:35—13. Variations of Chemical and Phys12:30—Divisional Luncheon. The Greek ical Properties of a Magnesium Silicate Island, 766 W. Jackson Blvd. Corresponding to Progressive Leaching by HCI. A. T. Armstrong, O. A, Battista, J. J. Section B Brown, D. R. Martin, S. M. Willoughby. 10:05—14. Lattice Model Calculations Used Palmer House, State Ballroom (4th Floor) in the Simulation of Adsorption of Polar Symposium on Ordered Fluids and Liquid Compounds Out of Nonpolar Solvents onto CaF2. J. J. Bladon, W. I. Higuchi. Crystals 10:35—15. Photo-Induced Formation of SuJ. F. Johnson, Presiding peroxide Ions in Non-Aqueous Pigment 9:00—Introductory Remarks. Dispersions. J. R. Harbour, M. L. Hair. 9:05—35. Molecular Structure and its Rela11:05—16. The Thickness of a Surfactant tionship to Nonlinear Thermal Behavior of Film, as Measured by the Pressure CoeffiSome Binary Liquid Crystalline Systems. A. cient of Interfacial Tension. R. J. Good, C. C. Griffin, T. R. Britt, N. W. Buckley, R. F. J. Sun, J. D. Wieser. Fisher, S. J. Havens. 11:35—17. X-Ray Photoelectron Spectros9:30—36. Theoretical Model for the Phoscopy of Fluorine-Containing Polymers. N. pholipid Bilayer System: Single Component H. Turner, J. R. Griffith. Phase Transition and Binary Mixture Phase Diagram. R. G. Priest, J. P. Sheridan. MONDAY AFTERNOON Section A 9:55—37. Domains Due to Electric and Palmer House, Grand Ballroom (4th Floor) Magnetic Fields in Bulk Samples of Symposium on Surface Science of Catalysis: Nematic Liquid Crystals. E. F. Carr. 10:20—38. Thermal and Chemical PerturSpectroscopic Characterization of Catalyst bations of Molecular Order at the Interface and Crystal Surfaces Joint with Divisions of and in the Alkyl Chain Region of a Lyotropic Petroleum Chemistry Inc. and Physical Liquid Crystalline System. R. C. Long, Jr., Chemistry J. H. Goldstein. R. P. Eischens, Presiding 10:45—39. Orientational Dependence of Pure-Dipolar Relaxation (T1D) in Nematic 2:00—18. Infrared Spectra and Structure of Liquid Crystals. C. E. Tarr, F. Vosman, T. Adsorbed Layers on Metal Single Crystals. B. Tripp, L. R. Whalley. J. Pritchard. 11:10—40. The Ordering of Cholesteric Me2:55—19. The Chemistry of Weil-Defined, sophases by Linear Cellulosic Polymers. T. Small Metal Clusters. M. Moskovits. Sarada, P. F. Waters. 3:30—20. Infrared Reflectance Spectroscopy 12:30—Divisional Luncheon (see Section A of Single Crystal Metal Surfaces. W. G. for location). Golden, J. Overend, L. D. Schmidt. 3:55—21. Application of Inelastic Electron Tunneling Spectroscopy to the Study of Section C Adsorption on Metals and Oxides. P. K. Palmer House, Red Lacquer Room (4th Hansma. Floor) 4:30—22. Investigation of the Catalytic Activation of N 2 0 on a Chromia Surface. E. Symposium on Surface Chemistry in MateKugiler. rials Science: Interactions of Polymers with Other Solids

Section B Palmer House, State Ballroom (4th Floor) Symposium on Surface Chemistry in Biology and Medicine: Intermolecular Forces in Biological Systems

S. L. Brenner, Presiding 2:00—23. Interaction of Two Spherical Double Layers. D. A. McQuarrie, M. MedinaNoyola. 2:25—24. The Measurement of Repulsive Forces Between Lecithin Bilayers Induced to Swell with CaCI2. L. J. Lis, R. P. Rand, A. C. Cowley, V. A. Parsegian. 2:50—25. Measurement of Forces Between and Within Spontaneously Forming Bilayers of Dipalmitoyl Lecithin Above and Below its Melting Temperature. M. McAlister, R. P. Rand, V. A. Parsegian. 3:15—26. Structural Forces in Solution. S. Marcelja, D. J. Mitchell, B. W. Nimham, N. Radic, M. J. Sculley. 3:40—27. Force Balance in the Myosin Filament Lattice of Striated Muscle. E. W. April. 4:05—28. Electrostatic Repulsion Between Cylindrical Rods in Biological Systems. B. M. Millman, T. J. Racey, M. Loosley. 4:30—29. Polyelectrolyte Model for DNA. D. Stigter. TUESDAY MORNING

Section A

Palmer House, Grand Ballroom (4th Floor) Symposium on Surface Science of Catalysis: Spectroscopic Characterization of Catalyst and Crystal Surfaces Joint with Divisions of Petroleum Chemistry Inc. and Physical Chemistry

W. N. Delgass, Presiding 9:00—30. Core Level Photoelectron Spectroscopy of Adsorbates on Metal Single Crystal Surfaces. D. Menzel.

F. M. Fowkes, Presiding 9:00—41. lonically Bonded Filler-Elastomer Composites. T. P. Abbott, C. James, F. H. Otey. 9:30—42. Rate of Dissolution of Sparingly Soluble Particles in Gels. H. T. Hsia, H. P. Gregor. 10:00—43. Studies of Solid-Solid Adhesion with Polymers of Various Surface Polarities. L. Ter-Minassian-Saraga, A. Baszkin. 10:30—44. Metal Oxide Deposits on Polymer Surfaces. J. A. Emerson, W. J. Baron, C. P. Wong, L. G. Frank. 11:00—45. Effect of Fillers on the Relaxation Behavior of Polymers. J. A. Manson, J. Williams, M. J. Marmo. 11:30—46. The Role of Electrostatic Forces in the Deposition of Metal Oxides on Polymer Surfaces. W. P. Townsend, J. D. Evans, F. M. Fowkes, F. H. Hielscher. 12:30—Divisional Luncheon (see Section A for location). TUESDAY AFTERNOON Section A Palmer House, Grand Ballroom (4th Floor) Symposium on Surface Science of Catalysis: Spectroscopic Characterization of Catalyst and Crystal Surfaces Joint with Divisions of Petroleum Chemistry Inc. and Physical Chemistry

W. N. Delgass, Presiding 2:00—47. The Adsorption of 0 2 on the Tungsten (110) Plane. J. Chen, R. Gomer, C. Leung, C. Steinbruchel, C. Wang. 2:40—48. A Mossbauer Investigation of a Platinum-Tin Paraffin Oxidative Dehydrogenation Catalyst. P. R. Gray, F. E. Farha. 3:15—49. Mossbauer Spectroscopy as a Tool for Characterizing Ruthenium Moieties Supported on a Variety of Common Catalytic Supports. C. A. Clausen, III, M. L. Good.

July 25, 1977 C&EN

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3:50—50. Surface Composition of Promoted Iron Catalysts for Ammonia Synthesis. D. C. Silverman, M. Boudart. 4:25—51. Role of the Polymer-Oxide Interface in the Oxidative Degradation of Polypropylene on Cu0 6718 Films from ISS Depth Profiles. A. W. Czanderna, A. C. Miller, H. H. G. Jellinek, H. Kachi. 5:00—Divisional Business Meeting. Section B Palmer House, State Ballroom (4th Floor) Symposium on Ordered Fluids and Liquid Crystals A. C. Griffin, Presiding 2:00—Introductory Remarks. 2:05—52. A New Method for Inducing Homeotropic and Tilted Alignments of Nematic Liquid Crystals on Silica Surfaces. L. J. Miller, J. Grinberg. 2:30—53. A New Method for Inducing Homogeneous Alignment of Nematic Liquid Crystals. M. J. Little, H. L. Garvin, L. J. Miller. 2:55—54. Donor-Acceptor Interactions in Liquid Crystal Systems. J. W. Park, M. M. Labes. 3:20—55. Transitions within the Cholesteric Mesophase of Cholesteryl Stearate. L. R. Farmer, P. F. Waters. 3:45—56. Alignment of Liquid Crystals on Plasma Polymerized Films and Effect of Interfacial Surface Energy on Induced Liquid Crystal Orientation. P. Datta, G. Kaganowicz, A. W. Levine. 4:10—57. Magnetic Relaxation of Small Molecules in Ordered Fluids and Liquid Crystals. B. M. Fung, J. H. Johnson, E. A. Grula. 4:35—58. Modification with an Electric Field of the Acousto-Optic Effect in a Nematic Liquid Crystal. C. F. Hayes. 5:00—Divisional Business Meeting (see Section A for location).

Section C Palmer House, Red Lacquer Room (4th Floor) Symposium on Molecular Processes at Solid Surfaces: Physical Adsorption, Experiment and Theory

W. A. Steele, Presiding 2:00—Introductory Remarks. 2:05—59. Light Atom Scattering as a Probe of Surface Properties. J. H. Weare. 2:30—60. Molecular Beam Adatom Spectroscopy. E. D. Thompson, H. Chow. 2:55—61. Selective Adsorption of 3He and 4 He on Clean Alkali Halide Surfaces. G. Derry, D. Wesner, S. V. Krishnaswamy, D. R. Frankl. 3:20—62. Potential Energy of One or Two Atoms on a Surface. M. W. Cole, J. Pliva, C. Schwartz, T. T. Tsong. 3:50—63. A Simple Model for the Internal Mode Dependence of Gas/Solid-Surface Sticking Probabilities. J. D. Doll. 4:15—64. Atomic Recombination Dynamics on Solid Surfaces. J. H. McCreery, G. Wolken, Jr. 4:40—65. Diffraction and Selective Adsorption of Molecular Beams from Solid Surfaces. G. Boato, P. Cantini, G. P. Felcher, R. Tatarek. 5:00—Divisional Business Meeting (see Section A for location). WEDNESDAY MORNING

Section A

Palmer House, Crystal Room (3rd Floor) General-Catalysis and Related Surface Chemistry G. L. Haller, Presiding 9:00—66. The Kinetics of the Water Gas Shift Reaction over Group VIII Noble Metals. D. C. Grenoble. 9:35—67. Isomerization of the n-Butenes over Zinc Oxide and Alumina Catalysts. E. a. Lombardo, V. V. Kharlamov, W. C. Conner, Jr., R. Madon, W. K. Hall. 10:10—68. Hydrogen Electrosorption on Single Crystal Platinum Surfaces. W. E. O'Grady, M. Y. C. Woo, P. L. Hagans, E. Yeager. 10:45—69. The Kinetics of Oxidation of Hydrocarbons and CO Over Pt and Pd Catalysts. Y.-F. Y. Yao. 11:20—70. Strong Metal-Support Interactions. S. J. Tauster, S. C. Fung, R. L. Garten.

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C & E N J u l y 2 5 , 1977

Section B Palmer House, Parlor F (6th FLoor) Symposium on Ordered Fluids and Liquid Crystals R. G. Priest, Presiding 9:00—Introductory Remarks. 9:05—71. EPR Investigation of a Nematogen-Like Nitroxide Spin Probe in the Solid Modifications of a Liquid Crystal. A. E. Stillman, L L. Jones, R. N. Schwartz. 9:30—72. Some Modifications of the Flory Lattice Model for Rigid Chain Polymers and Their Effect on Isotropic-Anisotropic Phase Equilibria. E. Wee, L. Kou, W. G. Miller. 9:55—73. Raman Band Shapes as a Probe of Liquid Crystal Rotational Motion, B. J. Bulkin, K. Brezinsky. 10:20—74. Absorbance and Pitch Relationships in Dichroic Guest-Host Liquid Crystal Systems. H. S. Cole, S. Aftergut. 10:45—75. Photochemical and Thermal Stability Studies on a Liquid Crystal Mixture of Cyanobiphenyls. F. G. Yamagishi, D. S. Smythe, L. J. Miller, J. D. Margerum. 11:10—76. The Preparation and Thermodynamic Properties of Some Chiral 4-Alkyl4'-Cyanostilbenes and Tolans. R. J. Cox, N. J. Clecak, J. F. Johnson.

Section C Palmer House, Red Lacquer Room (4th Floor) Symposium on Molecular Processes at Solid Surfaces: Physical Adsorption, Experiment and Theory T. Fort, Jr., Presiding 9:00—77. Brownian Motion and Chemical Dynamics on Solid Surfaces. S. A. Adelman. 9:20—78. Brownian Motion and Chemical Dynamics on Solid Surfaces: Applications and Models. S. A. Adelman. 9:45—79. Perturbation Theory and the Equation of State of Two Dimensional Fluids with Application to Adsorption. D. Henderson. 10:10—80. A Generalized Frenkel-Halsey-Hill Theory for Multilayer Films. W. A. Steele. 10:35—81. Monte Carlo Studies of the Adsorption of Argon on Graphite-Like and Related Surfaces at 80 K at Coverages up to ~1.5 Monolayers. D. Nicholson, L. A. Rowley, N. G. Parsonage. 11:00—82. Classification of Order-Disorder Transitions in Adsorbed Systems. E. Domany, M. Schick, J. Walker. 11:20—83. The Application of Two-Dimensional Precus-Yevick Theory to the Physical Adsorption of Rare-Gas Atoms on Graphite. E. D. Glandt, A. L. Myers, D. D. Fitts. 11:40—84. The Adsorption of Multipolar Molecules on Graphite. T. H. Spurling, J. E. Lane. WEDNESDAY AFTERNOON Section A Palmer House, Crystal Room (3rd Floor) General-Catalysis and Related Surface Chemistry R. L. Garten, Presiding 2:00—85. Adsorption of Gases on Chromia at Lower Temperatures. R. L. Burwell, Jr., S. R. Ely. 2:30—8§. Hydrogen on Solids: Infrared and Deuterium Exchange Studies of Molybdena Supported on 7-Alumina. W. S. Millman, M. Crespin, W. K. Hall. 3:00—87. Studies of Supported Nickel-Containing Catalysts be ESCA. M. Wu, D. M. Hercules. 3:30—88. An Infrared Study of the Adsorption of CO and NO on Silica-Supported Ru-Pt Bimetallic Clusters. R. D. Gonzalez, M. F. Brown. 4:00—89. Hydrogenation of Ethylene over Molybdena-Alumina Catalysts. W. K. Hall, E. A. Lombardo, M. Houalla. 4:30—90. Model Experiments on the Poisoning of Pt Catalysts by Sulfur. T. E. Fischer. 5:30—Divisional Social Hour (This event is partially subsidized by Kendall Co.). Palmer House, P.P.R. #16 (Club Floor). Section B Palmer House, Parlor F (6th Floor)

Symposium on Ordered Fluids and Liquid Crystals

R. S. Porter, Presiding 2:00—Introductory Remarks. 2:05—91. Liquid Crystals and Cholesterol Nucleation During Equilibration in Supersaturated Bile and Bile Analogs. R. T. Holzbach, C. Corbusier. 2:30—92. Lateral Species Separation in the Gel and Liquid Crystal Phases of the Membrane Bilayer. P. H. Von Dreele. 2:55—93. Formation of the Liquid Crystals of Polynucleotide Complexes. E. lizuka, J. T. Yang. 3:20—94. The Self Control of Lipid Bilayers. D. L. Melchior, J. M. Steim. 3:45—95. Orientational Effects in HeatConducting Smectic Liquid Crystals. M. N. L. NarasimhanLT. E. Kelley. 4:30—96. Microcoritinuum Theory of HeatConducting Smectic Liquid Crystals. M. N. L. Narasimhan, T. E. Kelley. 5:30—Divisional Social Hour (This event is partially subsidized by Kendall Co.) (See Section A for location).

Section C Palmer House, Red Lacquer Room (4th Floor) Symposium on Molecular Processes at Solid Surfaces: Physical Adsorption, Experiment and Theory E. D. Thompson, Presiding 2:00—97. Neutron Scattering Studies of Physisorbed Films. W. D. Ellenson, L. Passell, J. Eckert, J. P. McTague 2:25—98. Prediction of Adsorbed Monolayer Dielectric Constants as a Function of Surface Coverage. W. C. Jones, T. Fort, Jr. 2:50—99. Phase Transitions in Krypton Monolayers on Graphitized Carbon Black. V. P. Toan, T. Fort, Jr. 3:15—100. Structure and Properties of Physically Adsorbed Helium and Molecular Hydrogen Monolayers. M. A. Lee, C.-W. Woo. 3:40—101. Effect of Surface Hydration on the Physical Adsorption of Gases on a CobaltMolybdate Catalyst. E. L. Fuller, Jr. 4:05—102. The Surface Composition and Energetics of Type HM Graphite Fibers. J. A. Mescher. 4:30—103. A Model of GaAs Growth by Molecular Beam Epitaxy. S. Holloway. 5:30—Divisional Social Hour (This event is partially subsidized by Kendall Co.) (See Section A for location). THURSDAY MORNING

Section A

Palmer House, Grand Ballroom (4th Floor) Symposium on Physical Chemical Properties of Colloidal Particles: Fractionation and Size Distribution Determination of Colloidal Particles T. P. Wallace, Presiding 9:00—104. Hydrodynamic Chromatography—A Method for the Size Analysis of Sub-Micron Colloidal Particles. H. Small. 9:30—105. Chromatography of Latex Particles. A. J. McHugh, C. A. Silebi, D. Nagy. 10:00—106. Liquid Exclusion Chromatography of Colloidal Dispersions. H. Coll, G. R. Fague. 10:30—107. Chromatography of Suspensions—Axial Dispersion Corrections. A. Hamielec, S. Singh. 11:00—108. High Speed Liquid Chromatography of Particles. F. E. Regnier, R. Noel, K. Gooding. 11:30—109. Liquid Exclusion Chromatography (GPC) of Reversed Micellar Systems. P. L. Dubin. Section B Palmer House, State Ballroom (4th Floor) Symposium on Ordered Fluids and Liquid Crystals E. M. Barrall II, Presiding 9:00—Introductory Remarks. 9:05—110. A Rigid Rod Lattice With Long Ranged Anisotropic Attractions. M. S. Rapport, A. G. De Rocco. 9:30—111. Liquid Crystal and the Non Aqueous Foam Stability. S. I. Ahmad.

9:55—112. Fluctuations and Ordering in Nematic Liquid Crystals. R. Chang. 10:20—113. The Determination of Moments of the Orientational Distribution Function in Liquid Crystals. L. L. Chapoy, D. B. DuPre, E. T. Samulski. 10:45—114. Conduction Currents Associated with the Variable Grating Mode in Nematic Liquid Crystals. J. M. Pollack, P. K. Watson, J. B. Flannery. 11:10—15. Light Scattering Studies of Lotropic Free Films. C. Y. Young, N. A. Clark.

Section C Palmer House, Red Lacquer Room (4th Floor) Symposium in Commemoration of the 50th Anniversary of the Discovery of Raney Nickel

S. R. Montgomery, Presiding 9:00—Introductory Remarks. 9:10—116. Nature of Hydrogen in a Commercial Raney Nickel. I. Nicolau, R. B. Anderson. 9:40—117. Effect of Phase Distribution on the Raney Nickel Catalyst. M. J. Kelley. 10:10—118. Fibrous Eutectic Alloy Catalysts. C. S. Brooks, F. D. Lemkey, G. Golden. 10:35—119. Activation Processes in Raney Iron and Related Iron Catalysts. L. J. Swartzendruber, L. H. Bennett, B. J. Evans. 11:05—120. Petrochemical Feedstocks and Fuels from Synthesis Gas. R. A. Diffenbach, R. Gormley. 11:30—121. Methanation Activity of Raney Nickel Catalysts: Effect of Proportion of NiAI3 and Ni 2 AI 3 in Precursor. L. L. Oden, J. H. Russell. THURSDAY AFTERNOON Section A Palmer House, Grand Ballroom (4th Floor) Symposium on Physical Chemical Properties of Colloidal Particles: Fractionation and Size Distribution Determination of Colloidal Particles

T. Provder, Presiding 2:00—122. Hydrodynamic Volume Evidence for Swellability of Styrene-Butadiene Carboxylated Latexes. R. D. Athey, Jr., T. Provder, G. W. Poehlein, J. Scolere. 2:30—123. Capillary Particle Chromatography. D. M. Ball, C. Orr. 3:00—124. Size Distribution Analysis of Polymer Latex by Preparative Centrifugation. T. P. Wallace. 3:30—125. Field-Flow Fractionation: A Tool for the Separation, Characterization, and Size Distribution Measurement of Colloidal Particles. J. C. Giddings, M. N. Myers. 4:00—126. The Application of Analytical Centrifugation to the Characterization of Carbon Black. F. A. Heckman, A. I. Medalia, J. E. Connolly.

Section B Palmer House, State Ballroom (4th Floor) Symposium on Ordered Fluids and Liquid Crystals

E. F. Carr, Presiding 2:00—Introductory Remarks. 2:05—127. Molecular Orientation in Mesophases of Some P-n-alkoxy Benzoic Acids. A. Blumstein, L. Patel, A. Skoulios. 2:30—128. An Investigation of Molecular Order in Synthetic and Naturally Occurring Mixed Lipid Bilayers. J. P. Sheridan, J. M. Schnur, P. E. Schoen. 2:55—129. A Simple and Inexpensive Synthetic Method for Alkylcyanobiphenyls. C. S.Oh. 3:20—130. Polymers of ^-Lactam Antibiotics: Structural, Chemical and Biological Properties. M. K. Stanfield, B. L. Warren, F. H. Wilson. 3:45—131. Spectroscopic Studies of Dyes in Liquid Crystal Impregnated Microporous Polypropylene Films. E. J. Poziomek, T. J. Novak, R. A. Mackay. 4:10—132. Symetric and Asymetric Thin Films of Smectic and Nematic Liquid Crystal. E. Perez, J. E. Proust, L. TerMinassian-Saraqa.

Symposium on Computer-Aided Instruction

COMP DIVISION OF COMPUTERS IN CHEMISTRY E. C. Olson, Chairman R. J. Marcus, Secretary MONDAY AFTERNOON Conrad Hilton, Upper Summit (27th Floor) General—Software Applications L. N. Davis, Presiding 2:00—Introductory Remarks. 2:05—1. On-Line Searching of Large Libraries of Mass Spectra. C. Cone. 2:35—2. A Versatile Document Search and Retrieval System. J. Eskinazi, D. J. Macero. 3:05—3. Evaluation of the Super-Modified Simplex Algorithm for Use in Chemical Pattern Recognition. S. L. Kaberline, C. L. Wilkins. 3:35—4. Comparative Computer Simulation of Several Signal to Noise Enhancement Techniques. M. F. Delaney, D. E. Henderson, P. C. Uden. 4:05—5. Development of a New Method for the Determination of Protein Homology. M. A. Sharaf, B. R. Kowalski, B. Weinstein. TUESDAY

R. Collins, Presiding 9:00—Introductory Remarks. 9:15—17. Instructional Use of Data Reduction and Simulation Programs. K. J. Johnson. 9:45—18. Computer-Generated Repeatable Tests in Chemistry. J. W. Moore. 10:15—19. Tutorial Computer-Assisted Instruction. S. G. Smith. 10:45—20. Computer-Managed Instruction (CMI). W. Torop. 11:15—21. The Minicomputer in Chemical Education. M. L. Lyndrup. 11:45—22. Use of Computer-Based Instructional Techniques on a Small College Chemistry Curriculum. C. T. Furse.

WEDNESDAY AFTERNOON Conrad Hilton, Upper Summit (27th Floor) General—Computer Applications

P. Mitacek, Jr., Presiding

TUESDAY MORNING

2:00—Introductory Remarks. 2:05—23. Application of Computer Image Processing for Transmittance Electron Microscopy Picture Enhancement of Shaleand Coal-Derived Asphaltenes. J. T. Kwan, J. Worral, H. Saade, I. Schwager, T. F. Yen. 2:35—24. Computer-Assisted Reaction Path Synthesis. R. Govind, P. Blower, G. J. Powers. 3:05—25. SALAP—An Aid for Teaching Assembly-Language Programming. M. S. Spritzer. 3:35—26. SLIDE: A Microfilm Lettering and Line-Drawing Program. E. A. Mottel.

Hyatt Regency, Water Tower (Concourse) Symposium on Biological Effects of Environmental Pollutants: Detection

MORNING

Conrad Hilton, Upper Summit (27th Floor) General—Interfacing and Hardware Applications

ENVT

J. Leone, Presiding 9:00—Introductory Remarks. 9:05—6. A Desk-top Calculator Based Laboratory Data System. M. L. Lyndrup, F. W. Telewski, W. E. Huyck, M. L. Tahan. 9:35—7. The Use of a Commercial Microcomputer to Upgrade the Existing Instrumentation of an Undergraduate Teaching Laboratory. T. L. Nunes. 10:05—8. A Bidirectional Analog Interface for Microcomputers. M. P. Brindle, R. S. Rodgers. 10:35—9. A Microcomputer-Controlled Voltammetry System. D. J. Macero, F. C. McElroy. 11:05—10. Application of a Minicomputer to the Determination of Favorable Instrument Parameters for Square-Wave Polarography. P. E. Sturrock, A. C. Hayman.

TUESDAY AFTERNOON Conrad Hilton, Upper Summit (27th Floor) Symposium on Laboratory Automation— Some Specific Applications on a Time Shared System

E. C. Olson, Presiding 2:00—11. Automation of Organic Elemental Analysis—CHN. E. C. Olson, N. H. Knight, B. J. Cronk, M. D. Kenny, D. Marks. 2:15—12. The UPACS Single Crystal X-ray Diffractometer System. D. J. Duchamp, C. G. WickremaSinha, J. B. Aldrich, D. Marks, M. D. Kenny. 2:45—13. An Automated Cary 60-IBM 1800 System. W. Krueger, M. Kenny, D. Marks, L. Pschigoda, J. Zieserl. 3:15—14. UPACS Computerized Gas-Liquid Chromatography System. D. G. Kaiser, H. Ko, G. J. Van Giessen, J. F. Zieserl, D. Marks, M. D. Kenny. 3:45—15. The UPACS Mass Spectrometry System. L. Baczynskyj, J. B. Aldrich, D. J. Duchamp, J. E. Herman, M. D. Kenny, D. Marks, J. F. Zieserl. 4:15—16. Laboratory Automation on a Time-Share System—The Economics. E. C. Olson.

WEDNESDAY MORNING Conrad Hilton, Upper Summit (27th Floor)

2:30—7. Alteration in Host-Bacteria Interaction by Environmental Chemicals. D. E. Gardner. 3:00—Intermission. 3:10—8. Biological Effects of Environmental Pollutants: Methods for Assessing Biochemical Changes. M. G. Mustafa, S. D. Lee. 3:40—9. Lung Organ Cultures: A Useful Model for Investigating the Biochemical and Toxicological Effects of Environmental Contaminants. R. S. Bhatnagar, M. Z. Hussain, J. C Belton. 4:10—10. Biochemical Measurements of Early Events in Ozone Damage. J. B. Mudd, B. A. Freeman, R. E. Peters, K. Knight. 5:00—Divisional Business Meeting. 6:30—Divisional Social Hour. Armando's Restaurant, La Stanza del'Arte, 735 Rush St. 7:30—Divisional Dinner. Armando's Restaurant, La Stanza del'Arte, 735 Rush St.

D. B. Menzel, Presiding 9:00—11. Mutagenic Activity of Airborne Particulate Organic Pollutants. J. N. Pitts, Jr., D. Grosjean, T. M. Mischke, V. F. Simmon, D. Poole. 9:30—12. Biophysical Studies of the Effects of Environmental Agents on the Plasma Membrane of Intact Cells. J. R. Rowlands, G. Strong, C Allen-Rowlands, J. Padilla. 10:00—Intermission. 10:10—13. Biomathematical Modelling Applications in the Evaluation of Ozone Toxicity. F. J. Miller. 10:40—14. Influence of Atmospheric Particulates on Pulmonary Absorption Phenomenon. J. M. Charles, D. B. Menzel.

TUESDAY AFTERNOON Hyatt Regency, Water Tower (Concourse) Symposium on Industry (Patron)

N. I. McClelland, Presiding

DIVISION OF ENVIRONMENTAL CHEMISTRY N. I. McClelland, Chairman L H. Keith, Secretary MONDAY MORNING AND AFTERNOON Hyatt Regency, Water Tower (Concourse) Symposium on Biological Effects of Environmental Pollutants: Detection

S. D. Lee, Presiding 9:00—Introductory Remarks. 9:10—1. From Animals to Man, The Grand Extrapolation of Environmental Toxicology. D. B. Menzel. 9:40—2. The Role of Nonhuman Primates in Environmental Pollution Research. W. Tyler, W. Castleman, J. Gillespie, P. Kosch, L. Schwartz. 10:10—Intermission. 10:20—3. Health Effects of Air Pollution: Controlled Studies in Humans. J. D. Mackney, W. S. Linn, K. A. Bell, R. D. Buckley. 10:50—4. The Contribution of Long-Term/ Low-Level Investigations to the Assessment of Environmental Pollutants. J. F. Stara. 11:20—5. Function Analysis: Linear Relationships for the Physical Properties of Elements and Compounds as a Function of Temperature, and Changes with Age in Biological Systems. G. Rouser. J. B. Mudd,

Presiding

2:00—6. Aqueous Extract of Cigarette Smoke—Effects on Metabolism and Phagocytosis by Rabbit Alveolar Macrophages. J. B. L. Gee, B. R. Boynton, A. S. Khandwala.

2:00—Introductory Remarks. 2:10—15. Corporate Environmental Control in a Company with Diverse Manufacturing Interests. M. A. Paliobagis, L. B. Weisfeld. 2:40—16. Satisfying Anticipated Regulatory Requirements for the Use of PVC Packaging Materials: The Technical Story Behind What Appeared to be an Impossible Task. A. J. Haefner, G. A. Hughmark. 3:10—17. The Chemistry of the Beavon Sulfur Removal Process. D. M. Fenton, H. W. Gowdy. 3:40—Intermission. 3:55—18. Application of Bipolar Membrane Technology, A Novel Process for Control of Sulfur Dioxide from Flue Gases. K. J. Liu, F. P. Chlanda, K. Nagasubramanian. 4:25—19. An Approach to Environmental Characterization of Coal Gasification Activities. R. A. Magee, D. D. Rosebrook.

WEDNESDAY AFTERNOON Hyatt Regency, Water Tower (Concourse) General

B. Willey, Presiding 2:00—Introductory Remarks. 2:10—26. Air Quality in a Conference Room. T. C. Wang, J. P. Krivan, Jr. 2:35—27. Characterization of Dust Within a Large Research Laboratory. C. J. Weschler. 3:05—28. Physico-Chemical Characterization of Lead in Urban Dusts—A Microanalytical Approach to Lead Tracing. R. W. Linton, D. F. S. Natusch, R. L. Solomon, C. A. Evans, Jr. 3:35—Intermission. 3:50—29. Ozone Formation in Power Plant Plumes. W. Keifer, G. M. Klauber, D. D. Davis. 4:20—30. Chemical Element Balance of Trace Elements in Washington, D. C. and Rural Maryland Aerosols. G. E. Gordon, G. Kowalczyk, C. E. Choquette, E. S. Gladney.

THURSDAY MORNING Hyatt Regency, Water Tower (Concourse) General

L. Deans, Presiding 9:00—Introductory Remarks. 9:10—31. Determination of the Surface Composition of Airborne Pollutant Particles Using Ion Microprobe Mass Spectrometry in Conjunction with Solvent Leaching. R. W. Linton, P. Williams, C. A. Evans, Jr., D. F. S. Natusch. 9:40—32. Kinetics and Mechanism of the Oxidation of Sulfide by Oxygen: Catalysis by Homogeneous Metal-Phthalocyanine Complexes. M. R. Hoffmann, B. C. H. Lim. 10:10—Intermission. 10:25—33. Toxicity of Palladium. R. S. Bhatnagar, T. Z. Liu, S. D. Lee. 10:55—34. The Dissolution Rate of Iron Sulfide in Anoxic Aqueous Systems. J. F. Pankow, J. J. Morgan.

FERT DIVISION OF FERTILIZER AND SOIL CHEMISTRY F. A. Retzke, Chairman K. L. Parks, Secretary

WEDNESDAY MORNING

TUESDAY MORNING

Hyatt Regency, Water Tower (Concourse) Symposium on Monitoring and Photochemistry of Halogenated Air Pollutants

Symposium on Biological N Fixation Joint with Division of Microbial and Biochemical Technology {see page 50) 12:00—Divisional Luncheon. Pick-Congress, Alcove (Main Floor).

R. K. Stevens, R. Rasmussen, Presiding 9:00—20. Halogenated Trace Constituents in the Urban and Nonurban Atmospheres. H. B. Singh, L. Salas, H. Shigeishi. 9:25—21. Infrared Spectra and Characterization of the Products of the Reactions of Chlorine Atoms with Matrix Isolated NO2 Molecules. D. E. Tevault, R. E. Smardzewski. 9:55—Intermission. 10:10—22. The Homogeneous Gas Phase Hydrolysis of Some Acid Chlorides. A. Snelson, R. Butler, I. J. Solomon. 10:35—23. Hydroxyl Radical Distribution in the Troposphere and its Implication to Catalytic Destruction of Stratospheric Ozone by Free Chlorine Atoms. J. Fishman. 10:55—24. Stratospheric Photochemistry of CBrF3, CBrF2CBrF2 and Bromine Nitrate, BrON02. F. S. Rowland, J. E. Spencer, C. C. Chou. 11:20—25. Halocarbon Photochemistry. J. P. Jesson, C. Miller, L. C. Glasgow, P. Meakin.

TUESDAY AFTERNOON Pick-Congress, Lincoln Room (3rd Floor) Symposium on Trace Elements in Today's Agriculture M. Forbes, Presiding 2:00—Introductory Remarks. 2:15—1. Iron Chlorosis of Crops in the U.S. and Current Methods of Correction. J. J. Mortvedt. 2:50—2. Effect of Soil Properties and Fertilizer Placement on Crop Response to Different Zinc Sources. G. W. Hergert, G. W. Rehm, R. W. Wiese. 3:25—Intermission. 3:35—3. A New Soil Test for Simultaneous Extraction of Macro and Micro Nutrients in Alkaline Soils. P. N. Soltanpour. 4:10—4. Potential Toxic Effects of Trace Elements. L. M. Walsh. 4:45—Concluding Remarks. 5:00—Divisional Business Meeting.

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WEDNESDAY MORNING Pick-Congress, Lincoln Room (3rd Floor) Symposium on Quality Assurance of Fertilizer Products W. E. Perry, Presiding 9:00—Introductory Remarks. 9:10—5. Quality Control in Granular Fertilizer Production. W. D. Whatley. 9:40—6. Quality Control in Ureaforms and Other Slowly Available Fertilizers. J. T. Hays. 10:10—7. Nutrient Deficiency in Blended Fertilizers. T. C. Woodis, Jr. 10:40—Intermission. 10:50—8. Summary of "A Study of Official Sampling Techniques for Bulk Fertilizer in the State of Florida," a Report to Florida Agricultural Research Institute, by Arthur D. Little Inc. J. R. Perrin. 11:20—9. Product Safety—A Positive Approach to Product Liability. W. J. Dietz. 11:50—Concluding Remarks.

WEDNESDAY AFTERNOON Pick-Congress, Lincoln Room (3rd Floor) General Chemistry and Technology of Fertilizer Z. T. Wakefield,

Presiding

2:00—Introductory Remarks. 2:15—10. Recent Bureau of Mines Progress on Direct Sulfuric Acid Digestion of Phosphate Matrix. C. B. Daellenback, P. C. Good, J. C. White. 2:50—11. Purified Liquid Fertilizer from Wet-Process Acid via Solid Urea Phosphate. J. M. Stinson, H. C. Mann, J. R. Burnell. 3:25—Intermission. 3:35—12. Demonstration—Scale Production of Suspension Fertilizer from Wet-Process Orthophosphoric Acid. J. A. Wilbanks, M. R. Burns, J. R. Watson. 4:10—13. Experience with the Pipe Cross Reactor in Making N-P-K Fertilizers. F. T. Nielsson, J. L. Medberry. 4:45—Concluding Remarks.

FLUO DIVISION OF FLUORINE CHEMISTRY H. F. Koch, Chairman D. D. DesMarteau, Secretary TUESDAY AFTERNOON

4:20—8. The Reaction Of Alkylidenetriphenylphosphoranes With Difluorocarbene. I. Chang, D. J. Burton.

WEDNESDAY MORNING AND AFTERNOON Conrad Hilton, P.D.R. #1 (3rd Floor) General D. G. Naae, Presiding 9:00—9. Nucleophilic Reactions Of Fluorohaloalkenes. L. J. Wagner, H. F. Koch. 9:20—10. An Alkoxyfluoroaryliodinane: A Stable Tricordinate Iodine (III) Species. J. C. Martin, R. L. Amey. 9:40—11. Reversible Friedel-Crafts Acylation Of Fluoroaromatics. Rearrangements of Fluoro-fluorenes. I. Agranat, Y. Bentor, Y. S. Shih. 10:00—12. Application of HSAB Theory To Substitution In Perfluorocycloalkenes. R. L. Soulen, S. Natarajan. 10:20—13. Stereochemistry Of Dehydrohalogenation Reactions. N. A. Touchette, K. S. Root, J. G. Koch, H. F. Koch. 10:40—14. Syntheses and Rearrangements of Hexafluoroisopropyl Allyl Sulfides. Y. Inouye, D. J. Burton. 11:00—15. Synthetic Routes To F-tertiary Amines. R. J. DePasquale. 11:20—16. Synthesis of Dihalomethylene Olefins. B. Mundell, D. J. Burton. R. J. DePasquale,

Presiding

2:00—17. The Thermal Decomposition Of Poly(carbon monofluoride). P. Kamarchik, J. Margrave. 2:20—18. Carbon-13 NMR Spectra Of Some Fluorocarbons. N. Walker, R. A. DeMarco, W. B. Fox. 2:40—19. Some Fluorinated Compounds Of Pentacoordinate Sulfur (VI). T. Kitazume, J. M. Shreeve. 3:00—20. Perfluoroacyl Hypochlorites. D. D. DesMarteau. 3:20—21. The Reaction Of Sulfur Trioxide With Perfluoro Tertiary Amines and the Synthesis Of Mono and Dicarboxylic Perfluoro Acids Therefrom. F. J. Pavlik. 3:40—22. The Oxyfunctionalization—Fluorination Of Hydrocarbons. A 'one-shot' Synthesis Of Functional Fluorocarbons. J. L. Adcock, N. M. Irving. 4:00—23. Hybrid Fluorosilicones. The Preparation Of Homo- and Copolymers. O. R. Pierce, M. O. Riley, Y. K. Kim. 4:20—24. Solubility Of Oxygen In Aqueous Fluorocarbon Emulsions. C. M. Snarls, H. R. Reese, K. A. Ginsburg, F. K. Multer. M. D. Nielson, A. G. Greenburg, G. W. Peskin, D. M. Long. 4:40—Divisional Business Meeting 5:30—Divisional Social Hour. Conrad Hilton, P.D.R. #1 (3rd Floor).

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C&EN July 25, 1977

WEDNESDAY AFTERNOON

TUESDAY MORNING

DIVISION OF FUEL CHEMISTRY B. D. Blaustein, Chairman H. R. Appell, Secretary-Treasurer MONDAY MORNING AND AFTERNOON Blackstone Quality Inn, Embassy Room (1st Floor) Symposium on New Techniques in Coal Analysis J. K. Kuhn, Presiding 9:00—Introductory Remarks. 9:05—1. The Direct Determination of Organic Sulfur in Raw Coals. B. Paris. 9:30—2. Oxygen Determination and Stoichiometry of Some Coals. A. Volborth, G. E. Miller, P. A. Jerabek, C. K. Garner.

Section A

Blackstone Quality Inn, Embassy Room (1st Floor) Symposium on the Organic Chemistry of Coal

Blackstone Quality Inn, Embassy Room (1st Floor) Symposium on Liquid Fuels from Coal

J. W. Larsen, Presiding

J. O. Golden, Presiding

9:00—Introductory Remarks. 9:05—14. Electron Spin Resonance Studies of Coals and Coal-Derived Asphaltenes. H. L. Retcofsky, G. P. Thompson, M. Hough, R. A. Friedel. 9:30—15. Isotopic Studies of Thermally Induced Reactions of Coal and Coal-like Structures. C. Collins, V. F. Raaen, B. M. Benjamin. 10:00—16. The Chemistry of Coal Liquefaction. F. Mayo, J. G. Huntington, N. A. Kirshen. 10:30—17. Initial Stages of Coal Pyrolysis: Evidence for Isomerization Reactions. S. Chakrabartty, N. Berkowitz. 11:00—18. The Dissolution of Coal and Lignite in Supercritical Media. D. S. Ross, J. E. Blessing. 11:30—19. Heteroatom Species in Coal Liquefaction Products. F. K. Schweighardt, C. M. White, S. Friedman, J. L. Shultz.

2:00—Introductory Remarks. 2:05—30. Cryogrinding of Coal and Its Effect on the Surface Structure. J. Solomon, G. J. Mains. 2:30—31. Determination of Tetralin and Naphthalene in a Coal-Derived Solvent. R. J. Hurtubise, J. F. Schabron, H. F. Silver. 2:55—32. Viscosity of Coal Liquids—The Effect of Character and Content of the Non-Distillable Portion. J. E. Schiller, B. W. Farnum, E. A. Sondreal. 3:20—33. Temperature Effects on Coal Liquefaction: Rates of Depolymerization and Product Quality as Determined by Gel Permeation Chromatography. C. L. Knudson, J. E. Schiller, A. L. Ruud. 3:45—34. X-Ray Analysis of Ash Sedimentation in Coal Derived Liquids. J. G. Ondeyka, F. H. Verhoff, J. D. Henry. 4:10—35. Laboratory Studies for Separation of Solids from SYNTHOIL Gross Product. H. Huang, J. Fischer. 4:35—36. Photochemical H Atoms as a Structural Probe of the Surface of Coal. G. J. Mains, M. Sundaram, J. Solomon. 5:00—37. Enthalpy Measurements on a Syncrude from a Western Kentucky Coal. A. J. Kidnay, R. R. Fleckenstein, H. Omid, V. F. Yesavage.

TUESDAY AFTERNOON

Conrad Hilton, Waldorf Room (3rd Floor) General A. F. Clifford, Presiding 2:00—1. Synthesis Of 2-(Perfluoroalkylether)and (Perfluoroaryl) Benzothiazoles. E. C. Kalathil, C. Tamborski. 2:20—2. Addition Reactions Of Pentafluorosulfanyl Isocyanate. A. F. Clifford, J. L. Howell. 2:40—3. Mechanisms For Hydrogen-Deuterium Exchange In Ring-Fluorinated Imidazoles. Y. Takeuchi, P. A. Cohen, K. L. Kirk, L. A. Cohen. 3:00—4. Some New Perfluoroethers From 'Dewar' Hexafluorobenzene. M. S. Toy, R. S. Stringham. 3:20—5. Perfluoroalkyiene Oxide Iodides. Hydrolysis and Coupling Products. T. Psarras. 3:40—6. Synthesis and Reactions Of HaloF-methylphosphonate Esters. R. M. Flynn, D. J. Burton. 4:00—7. The Gas-solid Reaction Between Simple Amines and A Polyfluorophosphine Oxide. D. G. Naae, T.-W. Lin.

Section B 10:00—3. Neutron-Gamma Techniques for I On-Stream Analysis of Coal. J. R. Symposium on Fuels and Energy from ReRhodes. newable Resources I Joint with Division of 10:25—Intermission. Carbohydrate Chemistry and Cellulose, Paper 10:40—4. An ASTM Approach to Standardand Textile Division (see page 35) ization of New Techniques Applied to Coal 5:00—Divisional Business Meeting (see Analysis. W. J. Montgomery. Section A for location). 11:10—5. Characterization of Liquids and Gases Obtained by Hydrogenating Lumps of Texas Lignite. C. V. Philip, R. G. AnthoWEDNESDAY MORNING Section A nyBlackstone Quality Inn, Embassy Room (1st 11:35—6. Carbon-13 Nuclear Magnetic Floor) Resonance Spectra of Model Hydroaromatic Hydrocarbons and Solvents. K. S. Henry H. Storch Award Symposium Seshadri, R. G. Ruberto, D. M. Jewell, H. R. T. Eddinger, Presiding P. Malone. 9:00—Presentation of Storch Award to F. C. R. R. Ruch, Presiding Schora. R. T. Eddinger. 9:15—26. Award Address (Henry H. Storch 2:00—Introductory Remarks. Award sponsored by Division of Fuel 2:05—7. Multielement^! Analysis Using ProChemistry). Search for a New Coal Techton Induced Photon Emission. P. C. Simms, nology. F. C. Schora. F. A. Rickey, K. A. Mueller. 9:45—27. Frequency of Cross-Links and 2:30—8. Simultaneous Determination of Molecular Weight Distributions in Coal. J. Major, Minor, and Trace Constituents in D. Kovac, J. W. Larsen. Coal Ash by Inductively Coupled Plasma10:15—28. Gasification at Very High Heating Atomic Emission Spectroscopy. V. A. Rates. R. E. Gannon, D. B. Northam, C. W. Fassel, E. M. Layton, E. L. DeKalb. von Rosenberg, Jr. 2:55—9. Comparison of Atomic Absorption 10:45—29. Riser Cracking of Coal to Oil and and D. C. Plasma-Arc Spectrometry in Gas. D. A. Duncan. Multi-Element Analysis of Coal. N. H. Suhr, 12:15—Divisional Luncheon. Blackstone H. Gong. Quality Inn, English Room (Ballroom 3:20—10. Trace Metal Analyses in Coal by Floor). Multielement Isotope Dilution Spark Source Mass Spectrometry. J. A. Carter, D. L. Donohue, J. C. Franklin. Section B 3:45—11. Recent Application of Neutron Symposium on Fuels and Energy from ReActivation Analysis to Coals. H. T. Millard, newable Resources II Joint with Division of Jr. Carbohydrate Chemistry and Cellulose, Paper 4:10—12. An Overview of X-Ray Fluorescence Analysis of Coal. J. K. Kuhn, L. R. and Textile Division {see page 35) Henderson. 12:15—Divisional Luncheon (see Section A 4:35—13. X-Ray Fluorescence Analysis of for location). Trace Metals in Solvent Refined Coal. J. W. Prather, A. R. Tarrer, J. A. Guin.

Section A

Blackstone Quality Inn, Embassy Room (1st Floor) Symposium on the Organic Chemistry of Coal J. W. Larsen, Presiding 2:00—20. Chemical Constituents in Different Solvent Refined Coals as a Function of the Feed Coal. L. T. Taylor, H. C. Dorn, W. M. Coleman, D. L. Wooton. 2:30—21. Comparison of Solvent Refined Lignites with Solvent Refined Bituminous Coals. N. F. Woolsey, V. I. Stenberg, K. J. Klabunde, R. J. Baltisberger. 3:00—22. Characterization of Coal Products by Mass Spectroscopy. H. E. Lumpkin, T. Aczel. 3:30—23. Field Ionization and Field Desorption Mass Spectrometry Applied to Coal Research. M. Anbar, S. E. Buttrill, Jr., G. A. St. John. 4:00—24. Oxidative Degradation Studies of Coal and Its Solvent Refined Coal. R. Hayatsu, R. E. Winans, R. G. Scott, L. P. Moore, M. H. Studier. 4:30—25. Oxidative Study of the Structure of Vitrinites. P. H. Given, J. Bimer, S. Raj. 5:00—Divisional Business Meeting.

Section B Symposium on Fuels and Energy from Renewable Resources III Joint with Division of Carbohydrate Chemistry and Cellulose, Paper and Textile Division (see page 35) THURSDAY MORNING

Section A

Blackstone Quality Inn, Embassy Room (1st Floor) Symposium on Liquid Fuels from Coal

R. M. Baldwin, Presiding 9:00—Introductory Remarks. 9:05—38. Homogeneous Catalytic Hydrogenation of Complex Carbonaceous Substrates. J. L. Cox, W. A. Wilcox, G. L. Roberts.

9:30—39. The Selectivity of Coal Minerals as Catalysts in Coal Liquefaction and Hydrodesulfurization. J. M. Lee, A. R. Tarrer, J. A. Guin, J. W. Prather. 9:55—40. Flash Pyrolysis Coal Tar. W. G. Willson, S. A. Qader, E. W. Knell. 10:20—41. The SRC II Process. R. P. Anderson. 10:45—42. A Dispersion Model for the Solvent Refined Coal Reactor. M. H. Lee, J. A. Guin, A. R. Tarrer. 11:10—43. Continuous Liquefaction of Lignite in a Process Development Unit. D. E. Severson, A. M. Souby, G. G. Baker. 11:35—44. Mineral Matter Effects in Coal Liquefaction. B. Granoff, M. G. Thomas.

10:45-58. Liquid Hydrocarbons From Low Btu Gas: Dilute Phase Fischer—Tropsch Synthesis. J. L. Cox, E. G. Baker. 11:05-59. Economic Comparison of Coal Feeding Systems in Coal Gasification— Lock Hopper vs. Coal Slurry. W. C. Morel. 11:35-60. Coal Desulfurization During Gaseous Treatment. E. T. K. Huang, A. H. Pulsifier.

WEDNESDAY MORNING AND AFTERNOON

HIST

Section B Blackstone Quality Inn, Gold Room (1st Floor) Symposium on Comparative Economics of Coal Conversion Processes W. W. Bodle, W. C. Chambers, Presiding 9:00—Introductory Remarks. 9:10—45. Synthetic Fuels: A Perspective on Commercialization. R. L. Dickenson. 9:40—46. Coal Conversion Plant Cost Escalation. S. L. Cohen, F. P. Hayoz. 10:10—Intermission. 10:20—47. Economics of Coal Gasification Processes for Electric Power Generation. G. E. Pack. 10:50—48. Conversion of Coal to Liquids by Fischer-Tropsch and Oil/Gas Technologies. J. B. O'Hara, N. E. Jentz, R. V. Teeple. THURSDAY AFTERNOON Blackstone Quality Inn, Embassy Room (1st Floor) Symposium on Comparative Economics of Coal Conversion Processes W. W. Bodle, W. C. Chambers, Presiding 2:00—Introductory Remarks. 2:05—49. Costs of Solids-Liquids Separation Methods in Coal Liquefaction. K. Migut, S. Kasper. 2:35-50. Regional and Feedstock Effects on Economics of Integrated Coal Gasification/Power Plant Systems. Y. K. Ahn, C. A. Bolez. 3:05—51. High- and Low-Btu Gas From Montana Subbituminous Coal. J. L. Arora, K. B. Burnham, C. L. Tsaros. 3:35—52. Comparative Economics of the Cities Service CS-SRT Process With the Lurgi Process. C. J. LaDelfa, M. I. Greene. 4:05—53. Economics of Producing Methanol From Coal by Entrained and Fluidized-Bed Gasifiers. W. C. Morel, Y. J. Ylm. FRIDAY MORNING Blackstone Quality Inn, Embassy Room (1st Floor) General A. H. Pulsifer, Presiding 9:00—Introductory Remarks. 9:05—54. Asphaltenes and Preasphaltenes—Components of an Original High Volatile Bituminous Coal. A. Marzec, T. Krzyzanowska, D. Bodzek. 9:30—55. The Hydrotreatment of Coal with AICI3/HCI and Other Strong Acid Media. J. Y. Low, D. S. Ross. 9:55-56. Particle Size Analysis in the SRC Process by Coulter Counter. C. W. Curtis, A. R. Tarrer, J. A. Guin. 10:20—57. Engineering Development of the Cities Service, Short Residence Time (CS-SRT) Process. M. I. Greene.

Smoking/nonsmoking Smoking and nonsmoking sections in technical session meeting rooms have been designated as follows: Smoking: left side of room Nonsmoking: right side of room

2:25—16. Vitamins and Nobel Prizes. A. J. Ihde. 2:50—17. Lavosier's "Reflections on Phlogiston". A. S. Kirsch. 3:15—18. Wheat, Blood and Spirit: Chemistry and Life in the 17th Century. A. G. Debus. 4:00—Dexter Award. Divisional Business Meeting.

DIVISION OF THE HISTORY OF CHEMISTRY J. A. Miller, Chairperson R. M. Hawthorne, Jr., SecretaryTreasurer MONDAY MORNING Conrad Hilton, P.D.R. #1 (3rd Floor) Symposium on Chemotherapy Joint with Division of Medicinal Chemistry T. A. Koeppel, Presiding 9:00—Introductory Remarks. 9:05—1. The Dawn of Chemotherapy. J. K. Crellin. 9:35—2. The Theoretical Basis of Ehrlich's Chemotherapy. J. Parascandola. 10:05—3. Sulfa Drugs and the Age of Chemotherapy. R. G. Shepherd. 10:35—4. The American Reception of Salvarsan. P. S. Ward. 11:00—5. Molecular Modification in Drug Discovery. J. H. Biel. 11:30—6. Antineoplastic Agents from Plants, A Progress Report. A. T. Sneden.

MONDAY AFTERNOON Symposium on Contemporary Developments in Chemotherapy Joint with Division of Medicinal Chemistry (see page 49)

TUESDAY MORNING AND AFTERNOON Pick-Congress, Washington Room (3rd Floor North) General O. B. Ramsay, Presiding 9:00—7. Monroe Jackson Rathbone: Chemical Engineer, Petroleum, Education, and Business Leader (1900-1976). R. D. Billinger. 9:20—8. Contributions of Women to Chemistry. V. F. McConnell. 9:40—9. V. N. Ipatieff 's Relationship with the Soviet Government. G. Siemiencow. 10:00—10. The Discovery of the Raney Nickel Catalyst and its Importance to Chemistry. S. R. Montgomery. 10:25—11. Chemical Competency in Early Homeopathic Medical Publications. N. D. Heindel, N. I. Foster. 10:45—12. Wohler and the Urea Synthesis: the Background in the 1820's. R. N. Hawthorne, Jr. 11:05—13. The Energism of the German Physical Chemist and Nobel Laureate, Wilhelm Ostwald. N. Holt. 11:35—14. The Spectacular Story of Spectroscopy. W. J. Wiswesser. 12:15—Divisional Luncheon. Pick-Congress, Grant Park Room (3rd Floor North). J. Miller,

Presiding

2:00—15. The Contributions of Howard J. Lucas to Physical Organic Chemistry. D. S. Tarbell, A. T. Tarbell.

Pick-Congress, Florentine Room (3rd Floor North) Symposium on Archaeological Chemistry G. F. Carter, Presiding 9:00—Introductory RemarKs. General 9:05—19. Chemistry and Archaeology: A Creative Bond. S. V. Meschel. 9:30—20. Some Applications of X-Ray Radiography in the Study of Archaeological Objects. P. Meyers. 10:00—21. Use of Spark Source Mass Spectrometry in Archaeological Chemistry. A. M. Friedman, J. L. Lerner. 10:30—22. Chemical Aspects of the Conservation of Archaeological Materials. N. S. Baer. Organic Materials 11:00—23. Radiocarbon Dating in Retrospect and Prospect: An Archaeological Perspective. R. E. Taylor. 11:30—24. Trace Element Analysis in the Characterization of Archaeological Bone. G. Wessen, F. H. Ruddy, C. Gustafson, H. Irwin. 12:30—Archaeological Chemistry Luncheon. Pick-Congress, Board Room (3rd Floor North). 1:30—25. Asphalts from Middle Eastern Archaeological Sites. R. F. Marschner, H. T. Wright. 2:00—26. The Analysis of Dyes in Early American Textiles. M. Saitzman. 2:30—27. Amino Acid Analysis as a Tool in Radiocarbon Dating of Bone Collagen. A. A. Hassan, P. E. Hare. 3:00—Intermission. 3:20—28. Geochemical Analysis of Archaeological Deposits. F. A. Hassan, A. A. Hassan. 3:50—29. Chemical Investigations on Ancient Near Eastern Archaeological Ivory Artifacts. III. Fluorine and Nitrogen Composition. N. S. Baer, T. Jochsberger, N. Indictor. 4:20—30. Advances in Amino Acid Racemization Dating of Bone and Shell. J. L. Bada, P. M. Masters.

THURSDAY MORNING AND AFTERNOON Pick-Congress, Florentine Room (3rd Floor North) Symposium on Archaeological Chemistry G. F. Carter, Presiding Ceramics 9:00—31. New Dimensions in Archaeometric Data Interpretation Achieved Through Large Data Bases. G. Harbottle, E. V. Sayre. 9:30—32. Application of X-Ray Photoelectron Spectroscopy to Mycenaean Pottery and Egyptian Glass. J. B. Lambert, C. D. McLaughlin, A. Leonard. 10:00—33. Elemental Compositions of Spanish and Spanish-Colonial Majolica Ceramics and Their Use in the Identification of Provenience. J. S. Olin, E. V. Sayre. 10:30—34. The Use of Rare Earth Element Distribution Patterns to Characterize Steatite Artifacts. R. O. Allen, S. E. Pennell. 11:00—35. The Use of Trace Elements in Fingerprinting Prehistoric Chert Quarries. D. J. Ives. 11:30—36. Atomic Absorption Spectrophotometry Analysis of Artifacts and Clay in Archaeological Context. N. M. Magalousis. Metals 1:30—37. Lead Isotope Ratios From Some Chinese Bronzes. I. L. Barnes, W. T. Chase, J. W. Gramlich, L. J. Moore, L. P. Dunstan, M. G. Diaz, E. F. Heald. 2:00—38. The Possible Change of Lead Isotope Ratios in the Manufacture of Pigments—A Fractionation Experiment. I. L. Barnes, J. W. Gramlich, M. G. Diaz, R. H. Brill.

2:15—39. Isotopic Studies of Nigerian Bronzes". C. G. Goucher, J. H. Teilhet, K. R. Wilson, T. J. Chow. 2:45—40. Ternary Representations of Ancient Chinese Bronze Compositions. W. T. Chase, T. Ziebold. 3:15—Intermission. 3:30—41. Prehistoric Copper Artifacts in the Eastern United States. S. I. Goad, J. E. Noakes. 4:00—42. Gold Analysis by Differential Absorption of a Gamma Ray Pair at the X-Ray Edge. P. Gaspar, E. S. Macias, C. D. Radcliffe. 4:30—43. Fingerprinting New Jersey Copper Coins by Energy Dispersive X-Ray Fluorescence Spectrometry. S. A. Katz. 5:00—44. Chemical Compositions of Copper-Based Roman Coins IV. Augustan Quadrantes, ca. 9 to 4 B.C. G. F. Carter.

INDE DIVISION OF INDUSTRIAL AND ENGINEERING CHEMISTRY J. R. Ehrenfeld, Chairman R. G. Squires, Secretary MONDAY MORNING Blackstone Quality Inn, Gold Room (1st Floor) Symposium on Dynamic Membranes and Related Topics A. E. Marcinkowsky, Presiding 9:00—Introductory Remarks. 9:10—1. Evolution of Dynamic Membranes. A. E. Marcinkowsky. 9:30—2. Dynamic Membrane Formation in Ultrafiltration and Reverse Osmosis. G. B. Tanny. 10:30—Intermission. 10:40—3. Closed-Cycle Operation of HighTemperature Textile Unit Processes with Hyperfiltration. C. A. Brandon, J. L. Gaddis, J. J. Porter. 11:10—4. Practical Application for Membrane Processing of Oily Waste Water and Coolant. I. K. Bansal, A. A. Bibeau. 11:30—5. pH and Temperature Effects on Zr(IV) Dynamic Membrane Formation. D. Freilich, G. B. Tanny. 6. Dynamic Enzymatic Membranes in Ultrafiltration and Reverse Osmosis. E. Drioli. (by title only) MONDAY AFTERNOON

Section A

Blackstone Quality Inn, Gold Room (1st Floor) Symposium on Dynamic Membranes and Related Topics C. A. Brandon,

Presiding

2:00—Introductory Remarks. 2:10—7. Dynamically Formed Membranes in Processing of Kraft Pulping Effluents. L. J. Breithaupt, Jr., J. T. McKinnon, P. H. Hayes, J. S. Johnson, Jr., A. J. Shor, C. G. Westmoreland. 2:40—8. Anion Removal from Water by Donnan Dialysis. C. J. Wallace, A. Rembaum. 3:05—Intermission. 3:15—9. The Effect of Stability on the Ultrafiltration Processing of Oil/Water Emulsions. A. A. Bibeau, N. R. Ramakrishnan. 3:40—10. Investigations Aimed at Preventing Membrane Fouling. W. Krieger, W. Kissing, R. Reiner. 4:10—11. Flux Decline of Dynamic Zirconium-Polyacrylate Membranes Exposed to Suspensions of Particulates. D. K. Todd, C. A. Brandon.

July 25, 1977 C&EN

41

Section B Blackstone Quality Inn, English Room (Ballroom Floor) Symposium on Recent Advances in Separation Technology N. N. Li, D. T. Wasan, Presiding

I

Section B Blackstone Quality Inn, Gold Room (1st Floor) General S. A. Weiner, Presiding 2:00—Introductory Remarks. 2:05—30. Butanediol and Tetrahydrofuran from Propylene via Allyl Acetate. W. E. Smith, J. L. Webb, J. E. Corn, N. Kirk, D. F. Aycock, R. J. Gerhart. 2:45—31. Some Aspects of Dry Chemical Fire Control Agents: Laboratory Testing and Evaluation of Potential New Systems. R. L. Altman, L. A. Mayer, A. C. Ling. 4:15—Divisional Business Meeting (see Section A for location).

2:00—Introductory Remarks. 2:05—12. An Overview of Ultrafiltration Applications. N. C. Beaton, H. Steadly. 2:30—13. Membrane Electrodialysis Process for Recovery of Sulfur Dioxide from Power Plant Stack Gases. K.-J. Liu, K. Nagasubramanian, F. P. Chlanda. 3:00—14. Measurement of Local Mass Transfer Rates in Membranes. J. L. Duda, J. S. Vrentas. 3:30—15. Recovery of p-Xylene by Slurried Clathrate. E. J. Fuller. 4:00—16. Molecular Sieve Applications— Adsorption and Ion Exchange. C. W. Chi. 4:30—17. Hydrogen Separation Using Metal Hydrides. D. Gidaspow, V. Cholera.

ACS Short Course on Chemical Engineering for Chemists sponsored by Division of Industrial and Engineering Chemistry and ACS Dept. of Educational Activities (see page 85)

TUESDAY MORNING

WEDNESDAY

Section A

Blackstone Quality Inn, English Room (Ballroom Floor) Symposium on Materials Challenges in Turbine Applications K. R. Kinsman, Presiding 9:00—Introductory Remarks. 9:10—18. Turbines and Materials Engineering. R. L. Duncan. 9:55—19. The Nature of Steam Turbine Materials. R. C. Bates. 10:40—20. Chemical Factors Influencing Steam Turbine Life. B. W. Bussert. 12:00—Divisional Social Hour. Blackstone Quality Inn, French Room (Ballroom Floor). 12:30—Divisional Luncheon. Blackstone Quality Inn French Room (Ballroom Floor). Section B Blackstone Quality Inn, Gold Room (1st Floor) Symposium on Non-Solid Fuels From Coal—Leo Friend Chemical Technology Award B. J. Luberoff, Presiding 9:00—21. Leo Friend Chemical Technology Award Symposium, Non-Solid Fuels from Coal. B. J. Luberoff. 9:10—22. A Primer on the Constitution of Coal. D. D. Whitehurst. 9:40—23. Processes to Convert Coals to Non-Solid Fuels—And Why Bother. R. Shinnar. 10:10—24. Economic Prognostications for Coal Based Fuels. G. A. Mills. 10:40—25. Designing Huge Plants via "COLD MODELS"—The Case of COGAS. R. T. Eddinger. 11:10—Intermission. 11:20—26. Award Address. (Leo Friend Chemical Technology Award). Recent Advances in the Production of Fuels and Petrochemicals over Zeolite Catalysts. S. L. Meisel, J. P. McCullough, C. H. Lechthaler, P. B. Weisz. 11:50—Panel Discussion. 12:00—Divisional Social Hour (see Section A for location). 12:30—Divisional Luncheon (see Section A for location). ACS Short Course on Chemical Engineering for Chemists sponsored by Division of Industrial and Engineering Chemistry and ACS Dept. of Educational Activities (see page 85) TUESDAY AFTERNOON

Section A

Blackstone Quality Inn, English Room (Ballroom Floor) Symposium on Materials Challenges in Turbine Applications R. H. Richman, Presiding 2:00—27. Nature of Gas Turbine Alloys. J. M. Davidson, J. T. Tien. 2:45—28. Chemical Factors Influencing Gas Turbine Life. M. A. Decresente. 3:30—29. Advanced Turbine Materials. R. H. Richman, K. R. Kinsman. 4:15—Divisional Business Meeting.

42

C&EN July 25, 1977

MORNING

Blackstone Quality Inn, Gold Room (1st Floor) Symposium on Monitoring Techniques for Toxic Substances From Industrial Operations D. Schuetzle, Presiding 9:00—Introductory Remarks. 9:10—32. Plenary Speaker. Detection and Hazards of Environmental Carcinogens/ Mutagens. B. N. Ames. 10:10—33. Gene Locus Mutagens: Human Health Hazards Which Could be Monitored in the Workplace. W. G. Thilly. 10:40—Intermission. 10:50—34. GC/MS Analysis of Wastewater and Receiving Water. R. A. Hites. 11:20—35. Determination of Trace Inorganic Toxic Substances in Industrial Environments by Inductively Coupled PlasmaAtomic Emission Spectroscopy. V. A. Fassel.

9:30—43. Innovation in the Large Chemical Company. M. C. Throdahl. 9:55—44. The EPA Charter to Protect Health and the Environment. D. Costle. 10:20—Intermission. 10:30—45. Innovation is Vital to the Life of the Small Company. N. Phaneuf. 10:55—46. Innovation Can Exist With Regulation. F. D. Hoerger. 11:15—Written questions from the floor for discussion by the speakers. THURSDAY

2:00—47. Opto-Acoustic Spectroscopy Applied to the Detection of Gaseous Pollutants. C. K. N. Patel. 2:30—48. Use of the NIH-EPA Chemical Information System in Support of the Toxic Substances Control Act. S. R. Heller, G. W. Milne. 3:00—49. Ion Chromatography: A New Technique for the Analysis of Trace Ions in Solution. W. E. Rich. 3:30—Intermission. 3:40—50. Analysis of Air Pollutants Using X-Ray Photoelectron Spectroscopy (ESCA). A. S. Werner, B. M. Myatt. 4:10—51. Analysis of Air Pollutants by FT/IR. P. D. Maker, H. Niki, C. M. Savage, L. P. Breitenbach. 4:40—52. The Organic Analysis of the Wastewaters and Receiving Waters of a Specialty Chemicals Manufacturing Plant. G. Jungclaus, V. Lopez, R. A. Hites.

INOR

ACS Short Course on Chemical Engineering for Chemists sponsored by Division of Industrial and Engineering Chemistry and ACS Dept. of Educational Activities (see page 85) WEDNESDAY

AFTERNOON

Blackstone Quality Inn, Gold Room (1st Floor) Symposium on Monitoring Techniques for Toxic Substances From Industrial Operations R. Hites, Presiding 2:00—36. N-Nitroso Compounds in the Workplace. D. H. Fine. 2:30—37. Standards for Industrial Effluents Analysis. P. D. LaFleur. 3:00—Intermission. 3:10—38. Applications of Liquid Chromatography to the Analysis of Industrial Pollutants. J. N. Little, R. W. Edwards. 3:40—39. Development of Methods for Sampling and Analysis of Polychlorinated Naphthalenes in Ambient Air. M. D. Erickson, L. C. Michael, R. A. Zweidinger, E. D. Pellizzari. 4:10—40. Novel Ionization and Computer Techniques for the Analysis of Air Pollutants by Mass Spectrometry. T. M. Harvey, D. Schuetzle, J. R. Koskinen, S. P. Levine. ACS Short Course on Chemical Engineering for Chemists sponsored by Division of Industrial and Engineering Chemistry and ACS Dept. of Educational Activities (see page 85) THURSDAY

MORNING

Blackstone Quality Inn, Crystal Ballroom (Art Hall Floor) Symposium on a New National Priority— Chemical Innovation with Chemical Legislation J. W. Leenhouts, Presiding 9:00—41. A New National Priority—Chemical Innovation With Chemical Legislation. J. W. Leenhouts. 9:05—42. The Responsibility of the American Chemical Society For Action. A. J. Harrison.

AFTERNOON

Blackstone Quality Inn, Crystal Ballroom (Art Hall Floor) Symposium on Monitoring Techniques for Toxic Substances From Industrial Operations D. Schuetzle, Presiding

DIVISION OF INORGANIC CHEMISTRY N. Bartlett, Chairman J. Burmeister, SecretaryTreasurer SUNDAY

Section C Hyatt Regency, Toronto Room (Ballroom Level) General—Organometallic Subdivision: Metal Carbonyls

J. R. Shapley, Presiding

EVENING

6:00—Organometallic Subdivision Social Hour. Hyatt Regency, Acapulco Room (Ballroom Level) MONDAY MORNING

Section B Hyatt Regency, Acapulco Room (Ballroom Level) General—Solid State Subdivision E. Kostiner, Presiding 9:00—6. Crystal Structure Refinement of Basic Tellurium Nitrate: A Reformulation as (Te 2 0 4 H + XN03-). J. B. Anderson, E. Kostiner. 9:15—Discussion. 9:20—7. Preparation and Properties of LixVS2(0 < x < 1). D. W. Murphy, C. Cros, F. J. Di Salvo, J. V. Waszczak. 9:35—Discussion. 9:40—8. CsScCI3, A New Linear Metal Chain Compound Containing Divalent Scandium. K. R. Poeppelmeier, J. D. Corbett. 9:55—Discussion. 10:00—9. Hysteresis in and Crystallography of AB5 Hydrides. M. Mendelsohn, D. Gruen, E. Gebert. 10:15—Discussion. 10:20—10. Photoelectron Spectral Evidence for d-p Interactions in Solids with d-Type Conduction Bands. H. Franzen, C. Myers, M. Umaha. 10:35—Discussion. 10:40—11. Polybismuth Anions. The Synthesis and Crystal Structure of a Salt of the Tetrabismuthide(2—) Ion, B i 4 2 _ . A. Cisar, J. D. Corbett. 10:55—Discussion. 11:00—12. One-Dimensional Partially Oxidized Tetracyanoplatinate Complexes Containing the Bifluoride Anion (FHF)~. Two Crystal Modifications of the Rb + and Cs + Salts with "Short" and "Long" Pt-Pt Spacings. A. J. Schultz, P. L. Johnson, J. M. Williams. 11:15—Discussion. 11:20—13. Synthesis and Properties of Complexes from Tetracyanoquinodimethane (TCNQ) and Cyclid Phosphazenes. R. W. Allen. 11:35—Discussion. 11:40—14. The Synthesis, Structure, and Physical Properties of the Bis(7,7,8,8,Tetracyano-p-quinodimethane) Salt of the Paramagnetic Tris(Di-/*-Chloro)Tris(Hexamethylbenzene)-Triniobium Cluster [Nb3(M-CI)6(C6Me6)3]2+(TCNQ)22-. J. S. Miller, m. Abkowitz, S. Z. Goldberg, R. Eisenberg, G. Stanley, B. Spivak, D. M. Braitsch. 11:55—Discussion.

Section A

Hyatt Regency, Ballroom A (Ballroom Level) Symposium on Electronic Structure and Spectra H. B. Gray, Presiding 9:00—1. Molecular Orbital Calculations and Photoelectron Spectra. R. F. Fenske. 9:30—Discussion. 9:35—2. The Study of Back-Bonding by X-Ray Photoelectron Spectroscopy. W. L. Jolly. 10:05—Discussion. 10:10—3. Photoelectron Spectra of Substituted Chromium, Molybdenum, and Tungsten Pentacarbonyls; The Relative Pi Acceptor and Sigma Donor Properties of Various Phosphines and Phosphites. M. B. Hall, L. W. Yarbrogh, II. 10:30—Discussion. 10:35—4. Ligand-Ligand Interactions in Transition Metal Complexes. G. A. Crosby. 11:05—Discussion. 11:10—5. Magnetooptical Studies on Inorganic Systems. P. N. Schatz. 11:40—Discussion.

9:00—15. The Effect of Metal-Isotope Substitution on the Vibrational Spectra of Metal Carbonyls. B. Hutchinson, R. L. Hance, R. Shipley, L. Daniels. 9:15—Discussion. 9:20—16. Synthesis and Characterization of HOs3(CO)10(CH3) and H2Os3(CO)10(CH2). Interconversion of Cluster-Bound Methyl and Methylene Ligands. R. B. Calvert, J. R. Shapley. 9:35—Discussion. 9:40—17. Stereodynamics and Reactivity of Isonitrile Derivatives of Iridium Carbonyl. G. F. Stuntz, J. R. Shaply. 9:55—Discussion. 10:00—18. Reactions of Cyclopentadienyl Metal Carbonyls with Methylaminobis(difluorophosphine). R. B. King, M. G. Newton, J. Gimeno, M. Chang, K.-N. Chen. 10:15—Discussion. 10:20—19. Reactions of Halogens with [Ru(CO)3L]3. G. Kramer, A. Poe. 10:35—Discussion. 10:40—20. Ditertiary Phosphines as Monodentate Ligands in Transition Metal Carbonyls. R. L. Keiter, R. D. Borger, J. J. Hamerski, S. J. Garbis, G. S. Leotsakis. 10:55—Discussion. 11:00—21. Some New Cyclopentadienylmolybdenum and Cyclopentadienyltungsten Derivatives Containing Organonitrogen Ligands. K.-N. Chen, R. B. King. 11:15—Discussion. 11:20—22. Preparation and Spectropic Studies of Carbinol Derivatives of 7r-Cyclopentadienyldicarbonylnitrosylchromium and the Corresponding Carbonium Ions. E. A. Mintz, M. D. Rausch, D. J. Kowalski. 11:35—Discussion.

11:40—23. Neutron Diffraction Studies on [H4Re(PEt2Ph)2]2 and M3-HFeCo3(CO)9(P(OCH3)3)3. R. G. Teller, R. Wilson, R. McMullan, T. Koetzle, E. Carrol, R. Bau. 11:55—Discussion. MONDAY AFTERNOON Section A Hyatt Regency, Ballroom A (Ballroom Level) Symposium on Electronic Structure and Spectra A. B. P. Lever, Presiding 2:00—24. Theoretical and Experimental Studies of Multiple Bonds Between Transition Metal Atoms. F. A. Cotton. 2:30—Discussion. 2:35—25. Single Crystal Optical Absorption Spectra for Dimeric Complexes with Metal-Metal Bonding. D. S. Martin, P. E. Fanwick. 3:05—Discussion. 3:10—26. Electronic Spectra of Compounds Containing Strong Metal-Metal Bonds. W. C. Trogler, H. B. Gray. 3:40—Discussion. 3:45—27. From Strong to Weak Metal-Metal Bonds. J. G. Norman, Jr., H. J. Kolari, B. J. Kalbacher. 4:15—Discussion. 4:20—28. Electronic Structures of Adducts of Rhodium(ll) Carboxylate Dimers. R. S. Drago, T. C. Kuechler, R. M. Richman, S. P. Tanner. 4:40—Discussion.

Section B Hyatt Regency, Acapulco Room (Ballroom Level) Poster Session 2:00-3:00—29. Molecular Dynamics of Mixed-Metal Clusters. Evidence for an Intrametallic Rearrangement in H2FeRu3(CO)13 and H2FeRuOs2(CO)13. G. L. Geoffroy, W. L. Gladfelter. 3:00-4:00—30. The Dynamical Stereochemistry of Unsymmetric Aminoboranes. K. K. Curry, J. W. Gilje. 4:00-5:00—31. Oxygen-17 NMR Study of Nickel Sulfate Complexes. D. B. Bechtold, G. Liu, J. P. Hunt, H. W. Dodgen. 2:00-3:00—32. d 8 Metal Complexes of Tetrathiometalate Ions: Synthesis, Spectroscopy and Electrochemistry. K. P. Callahan, P. A. Piliero. 3:00-4:00—33. Synthesis and Structural Characterization of a Cu(l)—Cu(lll) Pentanuclear Cluster with a Dithiolate Ligand. D. Coucouvanis, D. Swenson, R. Pedelty, S. Kanodia, W. Richardson, N. C. Baenziger. 4:00-5:00—34. Structural Characterization of Monomeric Tetrahedral Mercaptides of Divalent Zn, Cd, Co, and Mn. D. C. Swenson, N. C. Baenziger, D. Coucouvanis. 2:00-3:00—35. The Photoelectron Spectra of the Metal Nitrosyl Complexes XW(CO)4NO (X = CI, Br, I). D. L. Lichtenberger, A. C. Sarapu. 3:00-4:00—36. Radiation Synthesis of Ruthenium^) and Iron(ll) Alkylnitroso Complexes. R. P. Cheney, S. D. Pell, M. Z. Hoffman. 4:00-5:00—37. The Thermodynamics of Chelation. R. T. Myers. 2:00-3:00—38. Kinetic Complexities of the Permanganate-Iodide Reaction in Aqueous Alkaline Solution. L. J. Kirschenbaum, J. D. Rickley, T. F. Mathews. 3:00-4:00—39. The Reaction of Methylsil, oxanes with Mercuric Salts. J. S. Thayer. 4:00-5:00—40. Synthesis, Properties and Structural Characterization of Macrocyclic Complexes of Rh(l) and Rh(lll). G. C. Gordon, M. C. Weiss, V. L. Goedken. 2:00-3:00—41. Macrocycle Promoted Oxygenation Reactions. G. McLendon, M. Mason. 3:00-4:00—42. Rapid Preconcentration of Trace Metals for Multielement XRF Analysis. A Unique Method Using a Combination of Polymer and Organic Precipitating Agents. Rm. Panayappan, D. L. Venesky, J. V. Gilfrich, L. S. Birks. 4:00-5:00—43. Reaction of Mn(lll) EDTA and Mn(ll) EDTA with Superoxide Anion. J. P. Fackler, Jr., J. Stein, G. McClune, J. A. Fee. 2:00-3:00—44. Mechanisms of Metal Ion and Chelate Promoted Hydrolyses of Amino Acid Esters. S. A. Bedell, R. Nakon. 3:00-4:00—45. The Molecular Stereochemistry of Diaquotetraphenylporphinatoiron(lll) Perchlorate. W. R. Scheldt, M. E. Kastner.

4:00-5:00—46. The Molecular Stereochemistry of Bis(tetrahydrothiophene)a,jS,7,5-tetraphenylporphinatoiron(ll). M. E. Kastner, W. R. Scheldt, C. A. Reed, D. Musser. 2:00-3:00—47. Synthesis and Characterization of the Four Tris [(S)-asparaginato] cobalt(lll) Isomers. F. Jursik, R. D. Arpher. 3:00-4:00—48. Zirconium Bis Quadridentate Schiff Base Synthesis via Both Coordinated Ligand and Metathesis Routes. M. L. IIlingsworth, R. D. Archer. 4:00-5:00—49. Phosphoryl Transfer Reactions Catalyzed by the Oxidation of Transition Metal Ions. G. P. Haight, P. R. Robinson, E. Hochberg, C. T. Shen. 2:00-3:00—50. Spectrophotometric and EPR Studies of Tris(2-amino-ethanethiolato) Dioxo, ix,tx' Dioxodimolybdate(V). H. L. Chapman, R. L. Belford, G. P. Haight. 3:00-4:00—51. The Stereochemical Activity of S Orbitals or Why Extended Huckel Theory Works. M. B. Hall.

Symposium on Preparation, Properties, and Applications of Crystals and Films

G. M. Blom, Presiding 9:00—Introductory Remarks. 9:05—65. Growth and Characterization of Ribbon Silicon. K. Ravi. 9:35—Discussion. 9:40—66. Solution Growth of Large Single Crystals. G. M. Loiacono. 10:10—Discussion. 10:15—Intermission. 10:25—67. Skull-Melting and Growth of Refractory Crystals. J. F. Wenckus. 10:55—Discussion. 11:00—68. Growth of Gd 3 Ga 5 0 12 Single Crystals for Bubble Device Substrates. P. C. S. Yin. 11:30—Discussion. 11:35—69. Synthesis and Purification in a Class 100 Laboratory of Oxides and Fluorides for Crystal Growth Feed. D. R. Gabbe, V. Belruss. 11:50—Discussion.

Section C

Section C

Hyatt Regency, Toronto Room (Ballroom Level) General—Organometallic Subdivision

Hyatt Regency, Gold Coast Room (Concourse) General—Organometallic Subdivision

S. D. Ittel, Presiding

G. Davies, Presiding

2:00—52. Oxidative Addition of OH Bonds by Bis(Dimethylphosphino)ethane Complexes of Iron. S. D. Ittel, C. A. Tolman, J. P. Jesson, A. D. English. 2:15—Discussion. 2:20—53. The Insertion of 3-Buten-1-ol into Metal-Alkyl Bonds Utilizing Typical Ziegler-Natta Catalyst Systems. D. W. Thompson, A. V. Youngblood, R. A. Coleman. 2:35—Discussion. 2:40—54. Fluxional Behavior of Triphosphine Ligands in Dimethylplatinum(ll) Complexes. K. D. Tau, D. W. Meek. 2:55—Discussion. 3:00—55. c/'s-Dihydride Complexes of Pt(ll) and Their Dehydrogenation to form Dimeric Pt(O) Complexes. The Structure of [Pt(tBu)2P(CH2)3P(t-Bu)2]2. T. Yoshida, T. Yamagata, T. H. Tulip, J. A. Ibers, S. Otsuka. 3:15—Discussion. 3:20—56. Reactions of Coordinated Ligands. Ring-Opening Reactions of Methylenecyclopropane Derivatives by Platinum(ll) Hydrides. T. G. Attig, M. T. Collopy. 3:35—Discussion. 3:40—57. A New Series of Sulfur Dioxide Complexes. The Preparation, Characterization, and Reactivity of the Sulfur Dioxide Adducts of a Series of Rhodium(l) Complexes Containing Triphosphine Ligands. P. R. Bium, D. W. Meek. 3:55—Discussion. 4:00—58. A Kinetic Study of the Insertion of Hexafluoroacetone into Halocarbonylbis(tertiary phosphine)dioxygen Iridium(lll). W. B. Beaulieu, D. M. Roundhill. 4:15—Discussion. 4:20—59. The Preparation and Structure of Bis(cycloocta-1,5-diene)rhodium(l) Tri-^ichlorohexacarbonyldirhenate(l). N. C. Baenziger, J. R. Doyle, E. A. Mottel. 4:35—Discussion.

9:00—70. Catalysis by Manganese(l) Complexes. E. L. Muetterties, L. S. Stuhl. 9:15—Discussion. 9:20—71. Lewis Acid Influenced Homogeneous Hydrogenation of Ethylene by Rhodium Complexes. S. H. Strauss, D. F. Shriver. 9:35—Discussion. 9:40—72. Homogeneous Oxidative Coupling Catalysts. Properties of the Initiator Produced from the Reaction of Copper(l) Chloride with Oxygen in Pyridine. I. Bodek, G. Davies. 9:55—Discussion. 10:00—73. Alkyl Exchange Reactions Between Organometals in Aqueous and Semi-Aqueous Solutions. J. S. Thayer. 10:15—Discussion. 10:20—74. Bis-Aryldiazo and Mixed Nitrosyl-Aryldiazo Complexes of Manganese. B. L. Haymore. 10:35—Discussion. 10:40—75. Low Temperature Structure of a Four-Coordinate Iridium-Aryldiazo Complex. G. L. Hillhouse, V. A. Culver, B. L. Haymore. 10:55—Discussion. 11:00—76. The Homogeneous Dehydrogenation of Ureas and Organic Amines by a Titanocene Complex. J. N. Armor. 11:15—Discussion. 11:20—77. /^-Elimination From Transition Metal Amides. S. E. Diamond, F. Mares. 11:35—Discussion.

TUESDAY MORNING

Section A

Hyatt Regency, Ballroom A (Ballroom Level) Symposium on Electronic Structure and Spectra W. C. Trogler, Presiding 9:00—60. Dioxygen Bonding to Fe, Cu, Co, and Ni Sites. W. A. Goddard III. 9:30—Discussion. 9:35—61. The Electronic Spectra of Metal Complexes Containing Coordinated DiOxygen. A. B. P. Lever. 10:05—Discussion. 10:10—62. Electronic Spectroscopy of Iron-Sulfur Proteins. P. J. Stephens. 10:40—Discussion. 10:45—63. Spectroscopic and Magnetic Studies of Binuclear Metalloproteins. N. Eickman, R. R. Gay, R. S. Himmelwright, E. I. Solomon. 11:10—Discussion. 11:15—64. Electronic Absorption and Resonance Raman Spectra of Some CopperSulfur Atom Clusters. O. Siiman, C. P. Huber, M. L. Post. 11:40—Discussion. Section B Hyatt Regency, Acapulco Room (Ballroom Level)

TUESDAY AFTERNOON

Section A

Hyatt Regency, Ballroom A (Ballroom Level) Symposium on Electronic Structure and Spectra W. A. Goddard, Presiding 2:00—78. Natural Solid State Optical Activity and Circular Dichroism of 5-Coordinate Complexes of Divalent Transition Metal Ions. R. A. Palmer, P. B. Marshburn. 2:25—Discussion. 2:30—79. Application of a Non-Parameterized SCCC-MO Method to Some Inorganic Fluorides and Chlorides. E. A. Boudreaux, A. Dutta Ahmed, L. E. Harris, E. Elder. 2:45—Discussion. 2:50—80. Characterization of the Electronic Structure of Ferraboranes by UV Photoelectron Spectroscopy. J. A. Ulman, E. L. Andersen, T. P. Fehlner. 3:05—Discussion. 3:10—81. Metal Ligand Bockbonding via SCF-Xa-SW Molecular Orbital Calculations. B. E. Bursten, R. F. Fenske. 3:25—Discussion. 3:30—82. The Electronic Structure of Fool's Gold, FES2. J. A. Tossell. 3:45—Discussion. 3:50—83. A Study of Porphyrin Ion-Pairs by Fluorescence Spectrometry. D. K. Lavallee. 4:05—Discussion. 4:10—84. Ionization Studies of Mixed Ligand Cu(ll) Complexes. H. A. Kuska, D. H. Beebe. 4:25—Discussion. 4:30—85. A Spectroscopic Investigation of Mixed-Valence Dinuclear Copper Complexes of a Macrocyclic Ligand. R. R. Gagne, C. A. Koval, T. J. Smith. 4:45—Discussion.

5:00—Divisional Business Meeting. 6:00—Divisional Social Hour. Hyatt Regency Acapulco-Hong Kong Rooms (Ballroom Level).

Section B Hyatt Regency, Acapulco Room (Ballroom Level) Symposium on Preparation, Properties, and Applications of Crystals and Films

J. M. Woodall, Presiding 2:00—86. Theory and Animated Computer Simulation of Thin Film Single Crystal Growth. G. H. Gilmer. 2:30—Discussion. 2:35—87. Inelastic Light Scattering Studies of Chemical Vapor Deposition (CVD) Systems. T. O. Sedgwick. 3:05—Discussion. 3:10—88. Growth Morphologies of the Ga^xAlxAs System Growth by Liquid Phase Epitaxy. M. B. Small. 3:4,0—Discussion. 3:45—89. Peltier-Induced Liquid Phase Epitaxy. J. J. Daniele. 4:15—Discussion. 4:20—90. Molecular Beam Epitaxy of Compound Semiconductors. B. I. Miller. 4:50—Discussion. 5:00—Divisional Business Meeting (see Section A for location). 6:00—Divisional Social Hour (see Section A for location).

Section C Hyatt Regency, Gold Coast Room (Concourse) General—Magnetic Studies D. R. McMillin, Presiding 2:00—91. EPR and Magnetic Studies of Mixed Valence Ruthenium Compounds. B. C. Bunker, R. S. Drago, D. N. Hendrickson, S. L. Kessel. 2:15—Discussion. 2:20—92. Preparation, Magnetism, and EPR of a Trinuclear Titanium(lll) Compound. B. F. Fieselmann, D. N. Hendrickson, G. D. Stucky. 2:35—Discussion. 2:40—93. Crystallographic, EPR, and Magnetic Studies on Binuclear Titanium(lll) Compounds with Bridging Organic Ligands. B. F. Fieselmann, D. N. Hendrickson, G. D. Stucky. 2:55—Discussion. 3:00—94. Interactions Across Pyrazine in Dimetallomers. J. P. Cannady. 3:15—Discussion. 3:20—95. Physical Studies of a Bimetallomer Copper(ll) Complex. K. A. Leslie, J. Breese. 3:35—Discussion. 3:40—96. Low-Temperature Electron Paramagnetic Resonance, Mossbauer, and Magnetochemical Studies of Spin-Equilibrium Tris(monothiocarbamato)iron(lll) Complexes. D. L. Perry, K. R. Kunze, L. J. Wilson. 3:55—Discussion. 4:00—97. Polymer Bound Schiff Base Complexes. J. H. Gaul, Jr., R. S. Drago. 4:15—Discussion. 4:20—98. Nitric Oxide Reactivity with Manganese Complexes Containing Linear Pentadentate Ligands. W. M. Coleman, L. T. Taylor. 4:35—Discussion. 5:00—Divisional Business Meeting (see Section A for location). 6:00—Divisional Social Hour (see Section A for location). WEDNESDAY MORNING

Section A

Hyatt Regency, Ballroom A (Ballroom Level)

Smoking/nonsmoking Smoking and nonsmoking sections in technical session meeting rooms have been designated as follows: Smoking: left side of room Nonsmoking: right side of room

July 25, 1977 C&EN

43

Symposium on Inorganic and Organometallic Photochemistry M. S. Wrighton, Presiding

WEDNESDAY AFTERNOON Section A

THURSDAY MORNING

Section A

9:00—99. Photoinduced Redox Reactions of Hydrophobic Ruthenium(ll) Complexes. P. J. Delaive, J. T. Lee, T. J. Meyer, D. G. Whitten. 9:40—Discussion. 9:45—100. Stereochemistry of the Photosubstitution Reactions of Rhodium(lll) Amine Complexes. J. D. Petersen, F. P. Jakse. 10:00—Discussion. 10:05—101. Photochemical and Photophysical Processes in 2,2'-Bipyridine and 1,10-Phenanthroline Complexes of Ir(lll) and Ru(ll). R. J. Watts, J. S. Harrington, J. Van Houten. 10:45—Discussion. 10:50—102. Thermal and Light-Induced Electron Transfer Between Iron(ll) and Cobalt(lll) Mediated by Bridging Pyrazines. J. M. Malin, D. A. Ryan, T. V. O'Halloran. 11:05—Discussion. 11:10—103. Photo-Induced Electron Transfer Reactions. N. Sutin. 11:50—Discussion.

D. G. Whitten, Presiding

Hyatt Regency, Toronto Room (Ballroom Level) Symposium on Inorganic and Organometallic Photochemistry N. Sutin, Presiding

2:00—118. Catalysis of Olefin Photoreactions by Transition Metal Salts. R. G. Salomon. 2:35—Discussion. 2:40—119. A Photochemically Induced Ligand Migration. D. G. Marsh, J. S. Miller, R. J. Weagley. 2:55—Discussion. 3:00—120. Use of Transition Metal Compounds to Sensitize an Energy Storage Reaction. C. Kutal. 3:35—Discussion. 3:40—121. The Mechanism of Photooxidation of Trichlorocuprate(l) Ion in Aqueous Solution. K. L. Stevenson, D. D. Davis. 3:55—Discussion. 4:00—122. Photochemistry of Metal-lsocyanide Complexes: Applications to Solar Energy Conversion. H. B. Gray, K. R. Mann, N. S. Lewis. 4:40—Discussion.

9:00—137. The Roles of Charge Transfer States in the Photochemistry of Ruthenium(ll) Ammine Complexes. P. C. Ford. 9:40—Discussion. 9:45—138. Charge Transfer Photochemistry of Cr(lll)(NH3)5X Species. D. J. McFay, W. F. Coleman. 10:00—Discussion. 10:05—139. Photochemical Processes in Cyclopendadienylmetal Carbonyl Complexes. D. G. Alway, K. W. Barnett. 10:45—Discussion. 10:50—140. Charge Transfer Photochemistry of W(CO) 5 N 3 -. R. M. Dahlgren, J. I. Zink. 11:05—Discussion. 11:10—141. Solution Medium Effects on the Photochemistry and Photophysics of Polypyridyl Complexes of Chromium(lll). M. S. Henry, M. Z. Hoffman. 11:50—Discussion.

Section B

Section B

Section B

Hyatt Regency, Acapulco Room (Ballroom Level) Symposium on Preparation, Properties, and Applications of Crystals and Films

Hyatt Regency, Acapulco Room (Ballroom Level) Symposium on Preparation, Properties, and Applications of Crystals and Films

Hyatt Regency, Acapulco Room (Ballroom Level) General—Bioinorganic C. F. Shaw, Presiding 9:00—142. The Distribution of Gold(l) Among Cytoplasmic Proteins and Subcellular Organelles in the Rat Kidney. C. J. Knudtson, H. O. Thompson, J. Blaszak, C. Murphy, C. F. Shaw. 9:15—Discussion. 9:20—143. Enzymatic Hydrolysis Products of Synthetic DNA's Treated with an Antitumor Platinum Complex. A. D. Kelman, H. J. Peresie. 9:35—Discussion. 9:40—144. Structure and Differential Reactivity of Diastereoisomers of the Bis(pyridoxy+ideneaminoacido)cobalt(lll) Complexes. K. S. Bose, E. H. Abbott. 9:55—Discussion. 10:00—145. Equilibrium Studies of Ternary Metal Chelates of L-3,4-dihydroxyphenylalanine (L-DOPA) with a Number of Secondary Ligands. K. S. Rajan, S. Mainer, J. M. Davis. 10:15—Discussion. 10:20—146. Lanthanide Induced NMR Shift Studies Elucidating the Role of Pyrimidine Bases in Enzymatic RNA Hydrolysis. D. K. Lavallee, R. B. Myers. 10:35—Discussion. 10:40—147. Cu"N3(SR), Cu'N3(SR), and Co"N3(SR) Complexes: Synthetic Approximations for the Active Site of the Blue (Type 1) and the Cobalt(ll)-Substituted Electron Transfer Proteins. J. S. Thompson, T. J. Marks, J. A. Ibers. 10:55—Discussion. 11:00—148. Binuclear Metal Complexes of Cofacial Diporphyrins. C. K. Chang, C. B. Wang. 11:15—Discussion. 11:20—149. Thermodynamic and ESR Studies of Dioxygen Binding to Cobalt(ll) Protoporphyrin IX Dimethylester. J. A. Breese, R. S. Drago, T. Beugelsdijk. 11:35—Discussion.

G. M. Blom, Presiding

Hyatt Regency, Ballroom A (Ballroom Level) Symposium on Inorganic and Organometallic Photochemistry

J. M. Woodall, Presiding

9:00—104. Techniques and Applications of Sputtered Thin Films. J. J. Cuomo. 9:30—Discussion. 9:35—105. Preparation and Properties of Amorphous Silicon. D. E. Carlson. 10:05—Discussion. 10:10—106. Polycrystalline Semiconductor Films for Solar Cells. T. L. Chu, S. S. Chu. 10:40—Discussion. 10:45—107. Electroluminescence in Large Band-Gap Semiconductors. J. I. Pankove. 11:15—Discussion. 11:20—108. Polymeric Sulfur Nitride and Its Halogen Modifications. G. B. Street. 11:50—Discussion.

Section C Hyatt Regency, Toronto Room (Ballroom Level) General—Main Group

2:00—123. SEM Characterization of the Electrical Properties of Defects in Semiconductors. L. C. Kimerling. 2:25—Discussion. 2:30—124. Characterization of Deep Energy Levels in Semiconductors. R. N. Bhargava. 2:55—Discussion. 3:00—125. Defect and Characterization of Multilayered Semiconductors. P. M. Petroff. 3:25—Discussion. 3:30—126. New Developments in Auger Microprobe Analysis. W. Bottoms. 3:55—Discussion. 4:00—127. Ultraviolet Photoelectron Spectroscopy Studies of Semiconductor Surfaces. J. L. Freeouf. 4:25—Discussion. 4:30—128. The Oxidation of Silver Thin Films by Atomic Oxygen. W. M. Moore, P. J. Codella. 4:50—Discussion.

J. Y. Corey, Presiding 9:00—109. Structure Basicity Relationships in OP(CH2CH2)3CH and OP(CH2CH2)2CHCH2. D. S. Milbrath, J. G, Verkade, G. L. Kenyon. 9:15—Discussion. 9:20—110. Lone Pair Orientational Effects in Amino Phosphines—A New Tricyclic System. D. W. White, J. G. Verkade. 9:35—Discussion. 9:40—111. The Visible Spectrum of Gas Phase Thiazyl Chloride. R. L. DeKock, M. S. Haddad. 9:55—Discussion. 10:00—112. Molecular Motion in Tricycles Containing Silicon and Sulfur Heteroatoms. J. Y. Corey, D. W. Larsen, B. A. Soltz. 10:15—Discussion. 10:20—113. 1-Silaadamantanes. A New Class of Bridgehead Organo-silicon Compounds. C. A. Kapfer, P. Boudjouk. 10:35—Discussion. 10:40—114. Preparation of (Trifluoromethyi) Group IVA Compounds, (CF3)nMX4_n, by Reaction of (CF3)2Hg with MX4. J. A. Morrison, R. J. Lagow, R. Eujen, L. L. Gerchmarv 10:55—Discussion. 11:00—115. Plasma Synthesis of Novel Trifluoromethyi Compounds. L. J. Turbini, T. J. Juhlke, R. J. Lagow. 11:15—Discussion. 11:20—116. Fluorination of Dimethylmercury, Tetramethylsilane and Tetramethylgermanium. E. K. S. Liu, R. J. Lagow. 11:35—Discussion. 11:40—117. Solvent Effects on the Dissociation of Monocomplexes of Nickel(ll): A Kinetic Method for Determining the Relative Lewis Basicity of Solvents. P. K. Chattopadhyay, B. Kratochvii. 11:55—Discussion.

44

C&ENJuly25, 1977

Section C Hyatt Regency, Toronto Room (Ballroom Level) General—Lanthanides and Actinides

E. T. Maas, Jr., Presiding 2:00—129. Synthesis and Characterization of a New Mixed-Metal Oxyfluoride of Uranium. E. T. Maas, Jr. 2:15—Discussion. 2:20—130. Stereochemical Nonrigidity in Solid Zirconium and Hafnium Tetrakistetrahydroborates. Evidence for Two Dynamic Intramoleculer Rearrangement Processes in Covalent Tetrahydroborates. I.-S. Chuang, T. J. Marks. 2:35—Discussion. 2:40—131. Adducts of Lanthanide Iodides and Thioxane-Oxide (TSO). G. Vicentini, L. B. Zinner, K. Zinner. 2:55—Discussion. 3:00—132. Mossbauer Spectra of Np(V)Cr(lll) and Np(V)-Rh(lll) Complexes. D. G. Karraker, J. A. Stone. 3:15—Discussion. 3:20—133. Hydrogen Evolving Reactions. The Preparation and Thermal Decomposition of Cerous Hydroxycarbonate. E. J. Peterson, E. I. Onstott, M. G. Bowman. 3:35—Discussion. 3:40—134. Synthesis and Properties of Cerous Chlorocarbonate Trihydrate. E. J. Peterson, E. I. Onstott, M. G. Bowman. 3:55—Discussion. 4:00—135. Volatility Enhancement of Lanthanide Halides: Gaseous Complexes of Samarium(lli) and (II) Chlorides with Aluminum Chloride. G. N. Papatheodorou, G. H. Kucera. 4:15—Discussion. 4:20—136. The Activation of ZnS Towards Flotation by Cu 2 + . D. A. Baldwin, J. M. Pratt, M. J. Storey. 4:35—Discussion.

Section C Hyatt Regency, Atlanta Room (Ballroom Level) General—Macrocyclic Complexes J. C. Dabrowiak, Presiding 9:00—150. Macrocyclic Polythiaether Complexes of Palladium(ll). T. E. Jones. 9:15—Discussion. 9:20—151. Multiply Bonded and Other Dimeric Molybdenum Complexes with Cyclic Polythiaethers. R. E. DeSimone, J. Cragel, Jr. 9:35—Discussion. 9:40—152. The Nature of the Macrocyclic Effect as Exhibited by Copper(ll)-Polythiaether Complexes in Aqueous Solution. D. B. Rorabacher, L. L. Diaddario, L. S. W. L. Sokol, L. L. Zimmer, T. E. Jones, L. A. Ochrymowycz. 9:55—Discussion. 10:00—153. Metal Complexes of Chiral and Achiral 12-Crown-4 Macrocycles— .Structures, Conformations, Stabilities, and Kinetics. R. R. Hendrixson, R. A. Palmer, R. G. Ghirardelli. 10:15—Discussion.

10:20—154. Crystal and Molecular Structure of a Dimeric Oxo-bridged Oxomolybdenum (IV) Polythiaether Complex. R. E. DeSimone, M. D. Glick, J. Cragel, Jr. 10:35—Discussion. 10:40—155. Synthesis and Characterization of Palladium Complexes with a Synthetic Macrocyclic Ligand. S. Brawner, K. B. Mertes. 10:55—Discussion. 11:00—156. EPR Studies of 1:1 Adducts of Two Low-Spin Cobalt(ll) Macrocyclic Complexes. A. Pezeshk, F. T. Greenaway, J. C. Dabrowiak, G. Vincow. 11:15—Discussion. 11:20—157. Reactivity Patterns of a Macrocyclic Schiff Base. G. Ferrara, J. C. Dabrowiak. 11:35—Discussion. THURSDAY AFTERNOON

Section A

Hyatt Regency, Toronto Room (Ballroom Level) Symposium on Inorganic and Organometallic Photochemistry

P. C. Ford, Presiding 2:00—158. Photochemical Reactions of Selected Transition Metal Cluster Complexes. G. L. Geoffroy, R. A. Epstein. 2:40—Discussion. 2:45—159. Photoreactions of Metal-Metal Bonded Carbonyls with Potential Hydrogen Donors. J. A. Labinger, S. Madhavan. 3:00—Discussion. 3:05—160. The Photochemistry of Bis(Dinitrogen)bis [ 1,2-bis(diphenylphosphino) ethane] Molybdenum. D. C. Busby, T. A. George, S. D. A. Iske, Jr. 3:45—Discussion. 3:50—161. Photocatalyzed Reactions of Alkenes with Silanes Using Trinuclear Metal Carbonyl Catalyst Precursors. R. G. Austin, R. S. Paonessa, M. S. Wrighton. 4:30—Discussion.

Section B Hyatt Regency, Acapulco Room (Ballroom Level) General

L. Sneddon, Presiding 2:00—162. A Pulsed-Flow Instrument to Measure Very Rapid Reactions in Solution. R. W. Taylor, G. D. Owens, D. W. Margerum. 2:15—Discussion. 2:20—163. Reactions of Free Radicals with Transition Metal Complexes in Aqueous Solutions. D. Meyerstein. 2:35—Discussion. 2:40—164. Intermediates with a Copper Carbon Bond Formed by the Reaction of Copper Ions and Aliphatic Radicals. M. Freiberg, D. Meyerstein. 2:55—Discussion. 3:00—165. Direct Synthesis of Metallocarborane Clusters from Boron Hydrides and Alkynes via Metal Atom or Organometallic Reagents. G. J. Zimmerman, R. Wilczynski, L. W. Hall, L. G. Sneddon. 3:15—Discussion. 3:20—166. Platinathiaboranes. T. K. Hilty, D. A. Thompson, R. W. Rudolph. 3:35—Discussion. 3:40—167. The Synthesis and Characterization of an Intermediate-Sized Manganaborane, 2,2,2-(CO)3-2-MnB5H10. M. B. Fischer, D. F. Gaines, J. D. Kessler. 3:55—Discussion. 4:00—168. Organothiaboranes. B. J. Meneqhelli, R. W. Rudolph. 4:15—Discussion. 4:20—169. Spectral and Kinetic Properties of Co(py) 2 3+ aq. G. Davies. 4:35—Discussion.

Section C Hyatt Regency, Atlanta Room (Ballroom Level) General

M. Hillman, Presiding 2:00—170. Structural Studies of Ferrocenophanes. M. Hillman, B. M. Gordon, E. Fujita, L. D. Spaulding, G. J. Williams. 2:15—Discussion. 2:20—171. Electrochemistry of the Rhenium Dimers Re2CI6-x(PR3)2+x (x = 0, 1 or 2). D. J. Salmon, R. A. Walton. 2:35—Discussion.

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2:40—172. Bimetallic Complexes of the Ligand: 1,2,4,5-Tetra(3-lsopropylsalicylidene)aminobenzene. P. H. Merrell, L. Maheu. 2:55—Discussion. 3:00—173,, Binuclear Complexes of Fluorinated 1,3,5-Triketones. Structure and Magnetic Properties of Bis(1,1,1,7,7,7hexafluoro-2,4,6-heptanetrionato)dicopper(ll). J. W. Guthrie, R. L. Lintvedt, M. D. Glick. 3:15—Discussion. 3:20—174. Poly(ethyleneiminoacetic Acid) (PEIA): Preparation and Coordination Properties. W. G. Mitchell, M. M. Jones. 3:35—Discussion. 3:40—175. Solubility of the Dithionates of Binuclear Ions. T. Emilsson, V. S. Srinivasan. 3:55—Discussion. 4:00—176. Stoichiometric Reduction of Acetylene and Nitrogen by Complexes of Mo(V), Mo(IV), and Mo(lll). P. R. Robinson, E. L. Moorehead, B. J. Weathers, G. N. Schrauzer. 4:15—Discussion. 4:20—177. The Sodium Sulfur System. III. VSEPR (Valence Shell Electron Pair Repulsion) and the Shape of Polysulfide Ions. D.-G. Oei. 4:35—Discussion. 4:40—178. Spectroscopic and Magnetic Properties of Exchange Coupled Cu(ll)Mn(ll) Dimers. D. A. Krost, G. L. McPherson. 4:55—Discussion. FRIDAY MORNING

10:00—191. Matrix Isolation Spectroscopy of Aluminum, Copper and Nickel Hydride and Deuteride. R. B. Wright, J. K. Bates, D. M. Gruen. 10:15—Discussion. 10:20—192. A Stable Chromium(V) Compound: Synthesis, Properties and Crystal Structure of Potassium Bis(2-Hydroxy-2Methylbutyrato)oxochromate(V) Monohydrate. M. Krumpolc, B. G. DeBoer, J. Rocek. 10:35—Discussion. 10:40—193. The Structure of Fe(lll) in Low pH Perchloric Acid Solutions: An Extended X-Ray Absorption Fine Structure (EXAFS) Study. A. H. Reis, Jr., T. I. Morrison, G. S. Knapp, F. Y. Fradln, H. Chen, T. E. Klippert. 10:55—Discussion. 11:00—194. A Spectrophotometric Study of the CoBr2-AI2Br6, CoCI2-ln2CI6, PdCI2ln2CI6 Vapor Complexes. G. H. Kucera, G. N. Papatheodorou. 11:15—Discussion. 11:20—195. Ferrocenylphosphine Complexes of Ruthenium. Induction of a MetalMetal Interaction. B. P. Sullivan, T. J. Meyer, D. J. Salmon. 11:35—Discussion. 11:40—196. Synthesis of Terpyridyl-Ruthenium Complexes. B. P. Sullivan, T. J. Meyer, T. R. Weaver. 11:55—Discussion.

Section A

Hyatt Regency, Ballroom D (Ballroom Level) General—Photochemistry

P. S. Sheridan, Presiding 9:00—179. Stereochemistry of d 6 Ligand Field Photochemistry. E. Martins, P. S. Sheridan. 9:15—Discussion. 9:20—180. Photochemistry of Triscyclopentadienyl Thorium and Uranium Alkyls. D. G. Kalina, T. J. Marks, W. A. Wachter. 9:35—Discussion. 9:40—181. Spectroscopic Studies of Photochemically Important Transition Metal Excited States. R. B. Wilson, S. R. Desjardins, E. I. Solomon. 9:55—Discussion. 10:00—182. Effect of Phosphine Ligands in the Photochemical Conversion of Norbornadiene. J. C. Bommer, K. W. Morse. 10:15—Discussion. 10:20—183. Spectra of Mixed Phosphine, a.a'-Diimine Complexes of Cu(l). M. T. Buckner, D. R. McMillin. 10:35—Discussion. 10:40—184. A Review of the Photochemistry of Boron-Containing Compounds. L Turbini, R. F. Porter. 10:55—Discussion. 11:00—185. Photoreactions of Tetrafluorodiphosphine with Alkynes and Fluoroalkynes. J. J. Mielcarek, J. G. Morse, K. W. Morse. 11:15—Discussion. 11:20—186. Isotopically Specific Te Laser Induced Chemical Reactions of CI2CF2 and Br2CF2. J. J. Ritter. 11:35—Discussion. 11:40—187. Excitation Dependence of the Emission Spectrum of U0 2 CI 2 . A. G. Baca, C. M. Castillo, J. L. Moore, W. F. Coleman. 11:55—Discussion.

Section B Hyatt Regency, Acapulco Room (Ballroom Level) General

J. Rocek, Presiding 9:00—188. Donor Properties of Neutral Phosphonate Esters Toward Phenol and Selected M(CI04)2 Salts (M = Mg, Mn, Co). N. M. Karayannis, C. M. Mikulski, L. L. Pytiewski. 9:15—Discussion. 9:20—189. Some New Thermochromic Complexes of Ni(ll) of the Type [RXNH4_X]2 NiCI4. J. R. Ferraro, A. T. Sherren. 9:35—Discussion. 9:40—190. Isotopic Studies of the Thermal Decomposition of Hydroxylammonium Nitrate. I. S. Jaworiwsky, N. M. Semo, J. J. Kaufman, W. S. Koski. 9:55—Discussion.

MEDI DIVISION OF MEDICINAL CHEMISTRY B. Roth, Chairman D. Led nicer, Secretary

Section B I Poster Session Symposium on Chemotherapy Joint with Division of The History of Chemistry (see page 41)

2:00—28. Synthesis and Evaluation of Inhibitors of Estrogen Biosynthesis. R. W. Brueggemeier, R. E. Counsell. 29. Synthesis and Antiviral Activity of 5MONDAY AFTERNOON Methylamino-2'-deoxycytidine. T-S. Lin, W. H. Prusoff. Conrad Hilton, Normandy Lounge (2nd 30. Microbiological Synthesis of IsoapoFloor) codeine. R. V. Smith, P. J. Davis. Symposium on Contemporary Developments ] 3:00—31. A New Opiate-Receptor Model. V. in Chemotherapy Joint with Division of The M. Kolb. History of Chemistry 32. Synthesis and Properties of Poly(2A. Burger, Presiding fluoroadenylic Acid). V. Amarnath, A. D. Broom. 2:00—Introductory Remarks. 33. Metabolic Studies with the Hematinic 2:05—8. Molecular Pharmacology of Tumor Agent Ferrocene. R. P. Hanzlik, W. H. and Virus Inhibitors. A. P. Grollman. Soine. 2:40—9. Biochemical Background of Cancer 4:00—34. Extrahepatic Tissue Distribution, Chemotherapy. J. A. Montgomery. Covalent Binding, and Toxicity of Halothane 3:20—10. The Mechanism of Action of Penin Normal and Phenobarbital-Pretreated icillin and Related Beta-Lactams of Natural Rats. G. S. Rao, J. O. Grumley, J. J. Hefand Synthetic Origin. K. G. Holden. ferren. 4:00—11. Virus Chemotherapy—Today. C. 35. The Binding Interaction of Aquated E. Hoffmann. cis-(NH3)2PtM to Homopolynucleotides. R. 4:40—12. Evolution of Antifungal ChemoReaoch, W. M. Scovell. therapy. S. Shadomy. 36. Acid Dissociation and Metal Complex Formation Constants of Anti-Rheumatoid TUESDAY MORNING Arthritis Agents at Simulated Biological Conditions: Implications for Bioavailability. Conrad Hilton, Normandy Lounge (2nd T. Zucconi, G. Janauer, S. Donahe. Floor) 37. Inhibition of Dihydrofolate Reductase Symposium on Antidiabetic Agents by Impurities in Methotrexate. G. W. Parkhurst, P. E. Carson. A. Y. Chang, Presiding 9:00—13. Hypoglycemic Lactamimides. J. M. Grisar, N. L. Wiech, J. K. Woodward. 9:30—Discussion. 9:35—14. Insulin Structure and Function. B. H. Frank. 10:00—Discussion. 10:05—15. The Synthesis and Hypoglycemic Activity of 4-Substituted 3-Mercaptopicolinic Acids. B. Blank, N. W. DiTullio, L. Deviney, J. T. Roberts, A. Magnani, M. Billig, H. L. Saunders. 10:30—Discussion. 10:45—16. Development of Somatostatin Analogs with Dissociated Biological Activities. D. H. Coy, C. Meyers. 11:15—Discussion. 11:20—17. Aldose Reductase Inhibitors. D. Dvornik. 11:55—Discussion. TUESDAY AFTERNOON

SUNDAY EVENING 8:00—Divisional Business Meeting and Mixer. Conrad Hilton, Parlors A and B (3rd Floor). MONDAY MORNING

Section A

Conrad Hilton, Normandy Lounge (2nd Floor) Symposium on Diuretic Agents

E. J. Cragoe, Jr., Presiding 9:00—Introductory Remarks. 9:05—1. Renal Hormones and Activity of Diuretics. J. C. McGiff, P. Y-K. Wong, D. A. Terragno. 9:30—Discussion. 9:35—2. Structure-Activity Relationships of Aminobenzoic Acid Diuretics and Related Compounds. P. W. Feit, O. B. T. Nielsen. 10:00—Discussion. 10:05—3. 4-(3-Sulfamoylphenyl)thiazolidin4-oles, a Novel Class of Sulfonamide Compounds with Salidiuretic Activity. H-J. Lang, B. Knabe, R. Muschaweck. 10:30—Discussion. 10:35—4. Sulfonamide Diuretics. L. H. Werner, E. Habicht. 10:55—Discussion. 11:00—5. Saliuretic, Diuretic and Uricosuric Properties of Phenoxyacetic Heterocyclic Derivatives in Mice, Rats, and Dogs. Structure Activity Relationship. Therapeutic Interest in Man of an Heterocyclic Compound of This Series, Ticrynafen (Tienilic Acid). P. Bessin, J. Bonnet, M. F. Malin. 11:13—6. Ticrynafen: an Antihypertensive, Diuretic, Uricosuric Agent. A. R. Maass, R. M. Stote, I. B. Snow, R. Erickson. 11:25—Discussion. 11:30—7. 2-Aminomethylphenols, a New Class of Saluretic Agents. R. L. Smith, G. E. Stokker, E. J. Cragoe, Jr. 11:55—Discussion.

L. Bauer, Presiding

Section A

Conrad Hilton, Normandy Lounge (2nd Floor) General

W. L. Matier, Presiding 2:00—18. Synthesis and Structure-Activity of a New Series of Hypoglycemic Agents. C. R. Rasmussen, G. F. Tutwiler, B. E. Reynolds, A. R. Hood, M. Mackay, A. J. Molinari, B. E. Laky. 2:30—19. 1-Aralkyl-2-pyrazolin-5-ones, a New Class of Highly Potent Diuretics with High Ceiling Activity. H. Horstmann, E. Moller, E. Wehlnger, K. Meng. 2:45—20. An Approach to a Vasodilator//?Adrenergic Blocking Agent. J. J. Baldwin, E. L. Engelhardt, R. Hirschmann, P. K. Lumma, G. F. Lundell, G. S. Ponticello, A. W. Raab, C. S. Sweet, A. Scriabine. 3:00—21. Studies on the Flexibility of Some Phenethylamines and Phenylethanolamines in Solution Using Carbon-13 NMR. A. Makriyannis, J. Knittel. 3:15—22. Synthesis of 2-(1-Piperazinyl)pyrazines with Serotonin-Like Activity in the Central Nervous System. W. C. Lumma, Jr., R. D. Hartman, W. S. Saari, B. V. Clineschmidt, M. L. Torchiana. 3:30—23. Synthesis and Properties of New Dopaminergic Potential Antiparkinson Compounds: N,N-Di-Substituted-/3-(3,4dihydroxyphenyl)ethylamines. J. Z. Ginos, G. C. Cotzias. 3:45—24. 1-Phenyl-3-aminotetralin Derivatives as Narcotic Antagonists. D. S. Fries, D. J. Bertilli. 4:00—25. The Synthesis of /5-Spiropyrrolidinoindolines, Their Binding to the Glycine Receptor, and In Vivo Biological Activity. F. M. Hershenson, K. A. Prodan, R. L. Kochman, J. L. Bloss, C. R. Mackerer. 4:15—26. 2,6-, 2,7-Di-, and 2,7,9-Trisubstituted 4H-Pyrido[1,2-a]pyrimidin-4-ones. H. L. Yale, E. R. Spitzmiller. 4:30—27. Prodrug Delivery Systems for 9/?-D-Arabinofuranosyladenine (VIRA-A®). D. C. Baker, T. H. Haskell, S. R. Putt.

Section B Conrad Hilton, Grand Ballroom Foyer (2nd Floor)

WEDNESDAY MORNING Conrad Hilton, Normandy Lounge (2nd Floor) Symposium on Selected Topics in Medicinal Chemistry

P. S. Portoghese, Presiding 9:00—38. Potential of Immunopharmacology. S. Spector. 9:40—Discussion. 9:45—39. Carbocyclic Nucleosides and Inhibitors of Ribosomal Functions. R. Vince. 10:25—Discussion. 10:30—40. Does Selectivity Among Monoamine Oxidase Inhibitors Have Meaning for the Future? R. W. Fuller. 11:10—Discussion. 11:15—41. Award Address (Smissman Award sponsored by Bristol Laboratories). Drug Discovery and Development. A Realistic Appraisal. A. Burger.

WEDNESDAY AFTERNOON Conrad Hilton, Normandy Lounge (2nd Floor) General R. E. Counsell, Presiding 2:00—42. Synthesis and Biological Properties of Prostacyclins. K. C. Nicolaou, G. P. Gasic, W. E. Barnette, R. L. Magolda, W. J. Sipio, C. M. Ingerman, J. B. Smith, M. J. Silver. 2:15—43. Total Synthesis of Clavulanic Acid. P. H. Bentley, M. L. Gilpin, E. Hunt, G. Brooks, 1.1. Zomaya. 2:30—44. Pyrimido[4,5-b]quinoline-2-carboxylic Acid Esters—A New Class of Potent Orally Active Antiallergy Agents. T. H. Althuis, P. F. Moore, H.-J. Hess. 2:45—45. Nitro-lmidazoles with Antibacterial Activity Against Neisseria Gonorrhoeae. R. C. Tweit, R. D. Muir, S. Ziecina. 3:00—46. Methyl 6(Phenylsulfinyl)imidazo[1,2-a]pyridine-2-carbamate, a Potent New Anthelmintic. R. J. Bochls, R. A. Dybas, J. R. Egerton, P. Eskola, P. Kulsa, B. O. Linn, E. P. Meitzner, J. Milkowski, H. Mrozik, L. E. Olen, D. A. Ostiind, L. H. Peterson, R. L. Tolman. A. F. Wagner, F. S. Waksmunski. 3:15—47. Vinblastine-Oxazolidinediones: Novel Orally Active Catharanthus Alkaloids. G. B. Boder, J. C. Miller, G. A. Poore. 3:30—48. A Comparison of Catharanthus Alkaloids Isomeric at C 4 '. G. B. Boder, G. C. Paschal, G. A. Poore, G. L. Thompson. 3:45—49. Biological Evaluation of N-/3-Hydroxyethyl-, N-/?-Mercaptoethyl-, and Other N-Substituted Desacetyl Vinblastine Amide (Vindesine) Sulfates. R. A. Conrad, G. J. Cullinan, K. Gerzon, G. A. Poore, R. K. Johnson. 4:00—50. New Chemical Modifications of Antitumor Anthracyclines and Synthesis of the 14C Labelled Antibiotics. F. Angelucci, F. Arcamone, E. Arlandini, S. Penco, G. P. Vicario, A. Vigevani.

July 25, 1977 C&EN

49

4:15—51. Transition Metal Complexation with the Antibiotic Bleomycin. J. C. Dabrowiak, W. Longo, M. Van Husen, F. Greenaway, S. T. Crooke. 4:30—52. Synthesis of Hydroquinone Dialdehydes with Antineoplastic Activity. E. M. Newman, A. J. Lin, A. C. Sartorelli. 4:45—53. Synthesis and Antineoplastic Activities of Chloroethyl- and Methyl Nitrosourea Analogues of Thymidine. T-S. Lin, P. H. Fischer, G. T. Shiau, W. H. Prusoff. THURSDAY MORNING

Section A

Conrad Hilton, Normandy Lounge (2nd Floor) General

P. H. Jones, Presiding

MICR DIVISION OF MICROBIAL AND BIOCHEMICAL TECHNOLOGY G. T. Tsao, Chairman C. L. Cooney, Secretary

9:00—54. Novel Pyrimidine to Pyrimidine Transformation Reactions. K. Hirota, K. A. Watanabe, J. J. Fox. MONDAY MORNING 9:15—55. Synthesis and Biological Activity of Amino Analogues of Thymidine. T-S. Lin, Pick-Congress, Great Hall (2nd Floor South) W. H. Prusoff. General 9:35—56. Potential Antitumor Agents. SynG. T. Tsao, Presiding thesis, Reactivity, and Testing of a-Methylene Carbonyl Compounds. I. K. Stamos. S. Evans, A. McKenzie, S. R. Byrn, J. M. j 9:00—Introductory Remarks. 9:05—1. Dialysis Continuous Process for Cassady. Ammonium-Lactate Fermentation of Whey: 9:45—57. Some New Chelating Polymers for Mathematical Model and Computer SimuToxic Metals. G. A. Nyssen, M. M. Jones, lation. G. A. Coulman, R. W. Stieber, P. J. D. Jernigan, J. S. MacDonald, R. D. Gerhard! Harbison. 9:25—2. Dialysis Continuous Process for 10:00—58. Development of Iron Chelators as Ammonium-Lactate Fermentation of Whey: Potential Therapeutic Agents for the Experimental Tests. R. W. Stieber, G. A. Treatment of Cooley's Anemia. N. E. Coulman, P. Gerhardt. Spingarn, A. C. Sartorelli. 9:45—3. Enhanced Product Formation in 10:15—59. Cellular and Enzymatic Studies Continuous Fermentations with Microbial with /3-Ferrocenylalanine. W. H. Soine, R. Cell Recycle. D. N. Bull, M. D. Young. P. Hanzlik. 10:05—4. Kinetics of Acetic Acid Production 10:30—60. Vitamin D Analogs with Antiin Continuous Culture With and Without Cell Metabolite Activity. W. H. Okamura, M. L. Recycle. F. M. Vera, D. I. C. Wang. Hammond, A. Mourino, P. Blair, W. 10:25—Intermission. Wecksler, R. L. Johnson, A. W. Norman. 10:40—5. Dissipated Heat in Agitated Aerated 10:45—61. DNA-Associated Products of and Non-Aerated Fermentation Systems. 7,12-Dimethylbenz(a)antracene. ChromaB. Volesky, H. T. Luong. tographic Analysis and Comparison of Symposium on Directed Fermentations Products with Those Resulting from Use of the "Non-Carcinogenic" 5-Fluoro Analog. 11:00—6. Strategical Considerations in DeD. T. Witiak, F. B. Daniel, F. D. Cazer, R. signing Directed Fermentations. D. PerlW. Hart. man. 11:00—62. 7,8-7rans-Diol-9,10-epoxides from Benzo[a]pyrene: Highly StereoseMONDAY AFTERNOON lective Formation and Reactions with Protein, RNA, and DNA in Mouse Skin. P. D. Pick-Congress, Great Hall (2nd Floor South) Moore, M. Koreeda, P. G. Wislocki, W. Symposium on Directed Fermentations Levin, A. H. Conney, H. Yagi, D. M. JeriD. Perlman, Presiding na. 11:15—63. Nitrosopyrrolidine Carcinogene2:00—7. Effects of Aeration on Inosine and sis: Evidence for Metabolic a-HydroxylAICA-Riboside Production. Y. Hlrose, H. ation. C-h. B. Chen, S. S. Hecht, D. HoffShibai. mann. 2:30—8. Quantitative Physiology in Penicillin 11:30—64. Effect of 4'-Alkoxy Substituents Fermentation as a Directed Fermentation. on the Microsomal N-Hydroxylation of D. Y. Ryu, J. Hospodka. 7rans-4-Acetamidostilbenes. P. E. Hanna, 3:00—9. Control of Fermentations by the R. E. Gammans, R. D. Sehon, M. W. AnAddition of Metabolic Inhibitors. J. J. ders. Goodman. 11:45—65. The In Vitro Metabolism of Phenyl 3:30—10. Fermentations Directed by pH. D. Acetone, Phenyl-2-butanone, and PhenylD. Dobry. 3-methyl-2-butanone by Rabbit Liver 3:50—Intermission. Preparations. R. C. Kammerer, A. K. Cho, 4:00—11. Influence of Fermentor Design on J. Jonsson. Product Quality in Continuous Fermentations. F. Wagner. THURSDAY MORNING Section B Symposium on Antitumor Compounds from Fermentations Joint with Division of Microbial and Biochemical Technology (see page 50)

TUESDAY

MORNING

THURSDAY AFTERNOON

Pick-Congress, Great Hall (2nd Floor South) Symposium on Biological N Fixation Joint with Division of Fertilizer and Soil Chemistry

Conrad Hilton, Normandy Lounge (2nd Floor)

O. R. Zaborsky, J. M. Sullivan, Presiding

Symposium on Antitumor Compounds from Fermentations Joint with Division of Microbial and Biochemical Technology P. F. Wiley, Presiding

9:00—Introductory Remarks. 9:05—12. Mechanism of Biological Nitrogen Fixation. W. J. Brill. 9:45—13. Mechanisms of Chemical Nitrogen Fixation. W. E. Newton. 10:30—Intermission. 10:45—14. Agronomic and Economic Considerations of Biological Nitrogen Fixation. R. W. F. Hardy. 11:30—15. Economic Considerations of Chemical Nitrogen Fixation. D. E. Nichols, G. M. Blouin.

2:00—66. Chemical Structures of Antitumor Antibiotics. P. F. Wiley. 2:30—Discussion. 2:35—67. Structure Activity Relationships Among Daunorubicin and Adriamycin Analogs. D. W. Henry. 3:15—Discussion. 3:20—68. Pharmacokinetics and Pharmacodynamics of Anthracycline Antibiotics. R. K. Johnson. 4:00—Discussion. 4:05—69. Clinical Studies with Anthracycline Antibiotics. M. Slavik. 4:45—Discussion.

TUESDAY AFTERNOON

Section A

Pick-Congress, Great Hall (2nd Floor South) General H. J. Peppier, W. D. Maxon, Presiding 2:00—16. Degradation of the Phetyl Side Chain of Cannabinoids by Microorganisms. L. W. Robertson, S.-W. Koh, S. R. Huff, A. Ghosh, R. Malhotra.

50

C&EN July 25, 1977

2:20—17. Origin of the Pyrrolidine Ring of Slaframine. E. C. Clevenstine, H. P. Broquist, T. M. Harris. 2:40—18. 13C NMR Study of Daunorubicin and its Microbial Transformation Products. J. A. Chan, A. A. Aszalos. 3:00—19. Kudzu (Pueraria Lobata) Root Starch as a Substrate for the Lysine-Enriched Baker's Yeast and Ethanol Fermentation Process. R. D. Tanner, S. S. Hussain. 3:20—20. Rapid Liquid Chromatography of Carbohydrates Using Water as the Eluant. M. R. Ladisch, G. T. Tsao. 3:40—21. Preparation of Immobilized Soy Bean's /3-Amylase by Using Cellulose Beads and Continuous Maltose Production. H. Maeda, G. T. Tsao, L. F. Chen. 4:00—Divisional Business Meeting.

Section B

9:05—38. Discovery and Development of Antitumor Compounds from Fermentation. G. L. Neil. 9:35—39. Aspects of Screening and Prescreening in the Identification of New Antitumor Compounds from Fermentations. W. T. Bradner. 10:05—40. Directed Biosynthesis of Actinomycins with cis- and frans-4-Methylprolines. E. Katz, A. B. Mauger. 10:45—41. Production of Anthracycline Antibiotics by Fermentation. J. Lunel, J. Florent, D. Mancy, J. Renaut. 11:20—42. Biotransformations of Antitumor Compounds. J. P. Rosazza.

THURSDAY AFTERNOON Symposium on Antitumor Compounds from Fermentations Joint with Division of Medicinal Chemistry (see page 50)

Pick-Congress, Plaza Room (2nd Floor) General

C. L. Cooney, R. D. Tanner, Presiding 2:00—22. Characterization of the Enzymic Activities of Endoglucanases from the Cellulase System of Trichoderma Viride. S. P. Shoemaker, R. D. Brown, Jr. 2:20—23. Cellulose Degradation Using a Thermophilic and Anaerobic Microorganism. M. Jimenez, J. Gordon, D. I. C. Wang, C. L. Cooney. 2:40—24. Modelling Cellulose Degradation by a Species of Thermoactinomyces. A. Moreira, J. A. Phillips, W. B. Armiger, A. E. Humphrey. 3:00—25. Kinetics of Cellobiose Utilization by a Cellulolytic Thermoactinomyces sp. S. E. Lee, A. E. Humphrey. 3:20—26. A Model for the Utilization of d Compounds via the RMP Cycle, Based on the Regulatory Role of Formaldehyde. E. Papoutsakis, H. C. Lim, G. T. Tsao. 3:40—27. Fermentation Routes from Plant Biomass to Fuels. H. R. Bungay. 4:00—Divisional Business Meeting (see Section A for location).

WEDNESDAY MORNING AND AFTERNOON Pick-Congress, Great Hall (2nd Floor South) Symposium on Aeration in Fermentations K. L. Phillips, R. K. Finn, Presiding 9:00—Introductory Remarks. 9:05—28. Aerated Fermentors—State of the Art. R. K. Finn. 9:35—29. Use of Microelectrodes in Studying Gas-Liquid Oxygen Transfer. Y. H. Lee, P. C. Wankat, G. T. Tsao. 10:05—30. Utilization of Culture Fluorescence for Monitoring Oxygen Uptake and Volumetric Mass transfer Rates. W. B. Armiger, A. E. Humphrey. 10:35—31. Aeration and Mixing in an Air-Lift Contactor. M. Moo-Young, C. W. Robinson, D. Gabbanni. 11:05—32. Oxygen Transfer in the SplitCylinder Airlift. R. T. Hatch, S. Goldhahn. 11:35—33. Oxygen Transfer in a Tower Fermentor Containing Pellets of Filamentous Fungus. H. Takahashi, F. Yoshida. 2:00—34. A Low-Energy and Economical Superoxygenation Process for Biological Oxidation and Fermentations. R. H. L. Howe. 2:30—35. Fermentations with Oxygen-Enriched Air: Neomycin and Bacitracin. M. C. Flickinger, D. Perlman. 3:00—36. Influence of Cultural Dissolved Oxygen Tension on Bacterial Extracellular Protein Synthesis. D. F. Carpenter, G. J. Silverman, W. M. Spira. 3:30—37. Potential Effects of the Energy Shortage on the Fermentation Industries. (Round Table: W. H. Bartholomew, R. K. Finn, Y. Hirose, A. E. Humphrey, W. D. Maxon, D. Perlman, K. L. Phillips, D. Y. Ryu, B. T. Sheehan, P. Shu, R. W. Squires, G. T. Tsao, D. I. C. Wang). THURSDAY

MORNING

Pick-Congress, Great Hall (2nd Floor South) Symposium on Antitumor Compounds from Fermentations Joint with Division of Medicinal Chemistry

J. P. Rosazza, Presiding 9:00—Introductory Remarks.

NUCL DIVISION OF NUCLEAR CHEMISTRY AND TECHNOLOGY A. M. Poskanzer, Chairperson T. T. Sugihara, Secretary MONDAY MORNING

Section A

Pick-Congress, Buckingham Room (Main Floor) Eugene Eichler Symposium: Nuclear Spectroscopy

G. D. O'Kelley, Presiding 9:00—Introductory Remarks. N. R. Johnson. 9:05—1. Eugene Eichler. N. R. Johnson. 9:25—2. Nuclei at High Angular Momentum. F. S. Stephens. 10:10—Intermission. 10:20—3. Pre-Equilibrium and Equilibrium Evaporation Following Fusion Reactions with Heavy Ions. D. G. Sarantites, L. Westerberg, R. Goldworm, J. H. Barker, M. L. Halbert, R. A. Dayras, D. C. Hensley, E. Eichler, N. R. Johnson. 11:05—4. Charge Distribution in the Spontaneous Fission of 252Cf. H. N. Erten, N. K. Aras. 11:25—5. Systematics of Quasirotational Bands in N = 8 8 Nuclei. D. R. Zolnowski, M. B. Hughes, J. L. Hunt, T. T. Sugihara.

Section B Pick-Congress, Windsor Room (Main Floor) General

H. Diamond, Presiding 9:00—6. A Comparison of Iodine-129 Levels in Human, Beef and Deer Thyroids from Missouri. R. V. Ballad, S. H. Tan, J. E. Johnson, L. L. Oliver, E. W. Hennecke, O. K. Manuel. 9:20—7. Noble Gases in a Whole Rock, Spinel Lherzolite Xenolith and an Amphibole Mineral Separate. D. P. Thompson, O. K. Manuel, A. R. Basu. 9:40—8. Noble Gases in Josephinite. R. G. Downing, O. K. Manuel. 10:00—9. Sorption of Plutonium and Americium from Aqueous Solution by Geologic Materials. P. Rickert, M. G. Seitz, S. Fried, A. M. Friedman, M. J. Steindler. 10:20—10. Migration of Technetium and Iodine Radioactive Wastes in the Lithosphere. R. Strickert, A. M. Friedman, S. Fried. 10:40—11. Interaction of Plutonium Ions with the Lithosphere. C. S. Sabau, S. Fried, A. M. Friedman. 11:00—12. Neptunium Chemistry and Radioactive Waste Management. D. Cohen. 11:20—13. An Apparatus to Study RadonAirborne Particulate Interactions. J. Jerabek, J. J. Stukel, W. L. Ho, Z. S. Hsu, P. K. Hopke.

11:40—14. Gamma-Spectroscopic Analysis of Uranium Decay Series with Planar Germanium Detectors. H. Diamond, L. I. Katzin. MONDAY AFTERNOON

Section A

Pick-Congress, Buckingham Room (Main Floor) Eugene Eichler Symposium: Nuclear Spectroscopy A. M. Friedman, Presiding 2:00—15. Rotational Band Discontinuities. L. L. Riedinger. 2:45—16. Coulomb Excitation of High Spin States: Experimental Tests of the Rotational Model in Even-Even and Odd-A Nuclei. H. R. Andrews. 3:30—Intermission. 3:40—17. Gamma-Ray Transition Rates in Actinide Nuclei. I. Ahmad, R. R. Chasman. 4:00—18. Heavy-Ion Rotational Scattering at Barrier and Sub-Barrier Energies. M. W. Guidry. 5:00—Divisional Business Meeting. 5:30—Divisional Social Hour. Pick-Congress, Grant Park Room (3rd Floor North).

Section B Pick-Congress, Windsor Room (Main Floor) Symposium on Nuclei Far from Stability R. G. Korteling, Presiding 2:00—19. Search for Particle-Bound Polyneutron Systems. A. Turkevich, J. R. Cadieux, T. Economou, J. J. LaRosa, J. Warren, H. R. Heydegger. 2:20—20. On-Line Time-of-Flight Mass Identification. W. C. McHarris, M. D. Edmiston, R. A. Warner, W. H. Kelly. 2:40—21. Atomic Mass Measurements of New Neutron-Rich Nuclides. P. E. Haustein, S. Katcoff, E.-M. Franz, J. Gilat. 3:00—22. Q0 Studies of Neutron-Rich Species at TRIUMF. G. Bischoff, H. Dautet, B. D. Pate, W. Wiesehahn, J. d'Auria. 3:20—Intermission. 3:35—23. Neutron and Gamma Spectroscopy of Rb, In, and Cs Delayed-Neutron Precursors. P. L. Reeder, L. J. Alquist, F. H. Ruddy. 3:55—24. Studies of Light Alpha Emitters in the Rare Earth Region. H. Dautet, J. d'Auria, W. Wieshahn, G. Bischoff, B. D. Pate. 4:15—25. Decay of Mass Separated 195.197TL R. A. Braga, G. M. Gowdy, J. L. Wood, R. W. Fink. 5:00—Divisional Business Meeting (see Section A for location). 5:30—Divisional Social Hour (see Section A for location). TUESDAY MORNING

Section A

Pick-Congress, Buckingham Room (Main Floor) Symposium on Nuclei Far from Stability

G. W. Butler, Presiding 9:00—26. Mass Measurements and Nuclei Far from Stability. C. Thibault. 9:45—27. Production of the New Nuclides 27 Ne, 31 Mg, 32 Mg, 3 4 AI, and 39 P by the 800-MeV Proton Bombardment of Uranium. G. W. Butler, D. G. Perry, L. P. Remsberg, A. M. Poskanzer, J. B. Natowitz, F. Plasil. 10:20—Intermission. 10:30—28. Initial Studies with the On-Line Mass Analysis System RAMA. J. Cerny, D. M. Moltz, D. J. Vieira, R. A. Gough, M. S. Zisman. 11:15—29. Studies of 12Be and Other OffStability Nuclei. D. E. Alburger.

Section B Pick-Congress, Windsor Room (Main Floor) Symposium on Radiation Effects in Honor of John E. Willard

W. T. Carnall, R. F. Firestone, Presiding 9:00—Introductory Remarks. 9:05—30. John E. Willard: Pioneer Nuclear Chemist. G. T. Seaborg. 9:25—31. Fast Spectrophotometric Studies of the Kinetics and Mechanism of Reactions of Excited Argon Atoms in Pure Argon and in the Presence of Quenching Agents. R. F. Firestone, T. Oka, S. Takao, M. F. Beno. 10:05—32. Infrared Spectroscopy of Ions by Pulse Radiolysis Techniques. H. A. Schwarz.

10:45—Intermission. 11:00—33. Chemical Effects of Fission Recoils: Radical Concentrations and Temperatures in the Recoil Track and Their Evaluation by Competition Kinetics. G. G. Meisels, J. L. LaVerne, W. C. Richardson. 11:40—34. Ultraviolet Photoabsorption Spectra of Some Molecules of Atmospheric Interest. A. P. Uthman, P. J. Demlein, M. J. McClements, G. A. Takacs. TUESDAY AFTERNOON

Section A

Pick-Congress, Buckingham Room (Main Floor) Symposium on Nuclei Far from Stability

9:50—52. Long Range Tunneling by Electrons in Rigid Matrices. J. R. Miller, J. V. Beitz, A. Barkatt, C. A. Naleway. 10:30—Intermission. 10:40—53. Adamantane as an Isolation Matrix in Radiation Chemistry: A Review. A. C. Ling. 11:20—54. Second Moment Studies of the ESR Lineshape of Trapped Electrons in Sodium-Ice Condensates: Relation to the Molecular Structure Around Trapped Electrons. D.-P. Lin, L. Kevan. 11:40—55. Crystal Structure Differences Between the Radiation Sensitive and Resistant Forms of Choline Chloride. R. M. Lemmon, V. Petrouleas, A. Christensen.

10:40—71. Characteristics of Fragments Emitted in the Interaction of 200-500 MEV Protons with Silver. R. E. L. Green, R. G. Korteling, A. G. Seamster, L. B. Church. 11:00—72. Angular Distributions of Recoil Fragments from 28-GeV Proton Irradiation of Thin Gold Targets. R. L. Klobuchar, J. B. Cumming, G. Virtes. 11:20—73. Thick Target Recoil Properties of P, Cu, and Ag Nuclides from U at 400 GeV. S. K. Chang, R. A. Johns, K. Wielgoz. 11:40—74. Differential Range Studies of Silver from Uranium at 400 GeV. R. A. Johns, S. K. Chang, K. Wielgoz, N. Sugarman.

WEDNESDAY AFTERNOON

Pick-Congress, Windsor Room (Main Floor) Symposium on Synchrotron Radiation Joint with Division of Physical Chemistry

Section B Section A

J. Cerny, Presiding 2:00—35. Proton Rich Nuclei Far from Stability. W. Benenson. 2:40—36. Mass Measurements of ProtonRich Light Nuclei. R. E. Tribble, J. D. Cossiart, R. A. Kenefick, D. P. May. 3:20—Intermission. 3:30—37. New Isotopes in the f-p Shell Produced by Heavy-Ion Reactions. C. N. Davids. 4:10—38. Decay Scheme Studies and Nuclear Systematics Far from the Line of Beta Stability. J. L. Wood. 4:35—39. Decay Studies in the Neutron-Rich Tin Region with TRISTAN II. J. C. Hill, F. Wohn. Section B Pick-Congress, Windsor Room (Main Floor) Symposium on Radiation Effects in Honor of John E. Willard J. C. W. Chien, Chairperson, Presiding 2:00—Introductory Remarks. 2:05—40. Theory of the Chemical Effects of High-Energy Electrons. J. L. Magee, A. Chatterjee. 2:45—41. ESR Studies of Radiation Produced Radicals. R. H. Schuler. 3:25—Intermission. 3:40—42. Radiation Chemistry of Fluorohydrocarbon-Hydrocarbon Mixtures. R. J. Hanrahan. 4:20—43. Transient Charge Transfer Interactions in Alkyl Halide—Halogen Systems. R. L. Strong. 4:40—44. Characterization of Products in the Photolysis of Aqueous Purine Solutions. R. Arce. WEDNESDAY MORNING

Section A

Pick-Congress, Buckingham Room (Main Floor) J. M. Miller Symposium on Nuclear Reactions

G. Friedlander, Presiding 9:00—Introductory Remarks. 9:10—45. Deep Inelastic Pion-lnduced Reactions in the Isobar Model. J. N. Ginocchio. 9:50—46. Inclusion of a and d Clusters in Intranuclear Cascade Calculations. R. A. Moyle, B. G. Glagola, G. J. Mathews, V. E. Viola, Jr. 10:10—47. JULIAN. A Monte-Carlo HauserFeshbach Evaporation Program. M. Hillman, Y. Eyal. 10:30—Intermission. 10:40—48. Reactions of Relativistic Protons with Complex Nuclei. S. B. Kaufman. 11:20—49. Production of Near-Target Spallation Products and 149Tb by 1 GeV to 400 GeV Protons on Uranium. R. A. Johns, S. K. Chang. 11:40—50. Muon Induced Reactions Involving the Emission of Charged Particles. A. Wyttenbach, P. Baertschi, S. Bajo, J. Hadermann, K. Junder, S. Katcoff, E. A. Hermes, H. S. Pruys. Section B Pick-Congress, Windsor Room (Main Floor) Symposium on Radiation Effects in Honor of John E. Willard D. R. Miller, M. C. Sauer, Jr., Presiding 9:00—Introductory Remarks. 9:10—51. Isotope Effects on the Yields of Trapped Electrons in 7-lrradiated Hydrocarbon Glasses. H.-Y. Wang, J. E. Willard.

Pick-Congress, Buckingham Room (Main Floor) J. M. Miller Symposium on Nuclear Reactions

G. T. Seaborg, Presiding 2:00—56. Charged Particles Emitted in Reactions of 720 MeV 86Kr with Au. J. Miller, D. Benson, G. Catchen, L. Kowalski, D. Logan, N. Lu, J. Alexander, T. Debiak, M. Rajagopalan, M. Kaplan, M. Zisman. 2:25—57. Coincidence Studies for 4He and Heavy Products from Reactions of 720 MeV 86 Kr with Au. J. Miller, G. Catchen, D. Logan, M. Rajagopalan, J. Alexander, M. Kaplan, M. Zisman. 2:40—58. Monte Carlo Calculations as Compared to Experiments for 4He Emmision from Reactions of 720 MeV 86 Kr with Au. J. M. Miller, D. Logan. 3:05—Intermission. 3:10—59. Formation and Decay of 194Hg at High Excitation Energy. J. Miller, D. Logan, G. Catchen, L. Kowalski, M. McMahan, M. Rajagopalan, J. Alexander, M. Kaplan, J. Ball, M. Zisman. 3:25—60. Coincidence Studies of Heavy Fragments Formed in Reactions of 720 MeV 86Kr with Au. J. Miller, D. Logan, L. Kowalski, G. Catchen, M. Rajagopalan, J. Alexander, M. Kaplan, M. Zisman. 3:50—61. What is Limiting Complete Fusion Between Complex Nuclei? M. Lefort. 4:40—62. The Reaction of 48Ca with Medium and Heavy Mass Targets. G. T. Seaborg, D. J. Morrissey, W. Loveland, R. J. Otto, D. Lee.

Section B Pick-Congress, Windsor Room (Main Floor) Symposium on Radiation Effects in Honor of John E. Willard J. R. Miller, Presiding 2:00—Introductory Remarks. 2:05—63. Electron Solvation in Mixtures of Polar and Non-Polar Liquids. J. H. Baxendale. 2:45—64. High LET Pulse Radiolysis. M. C. Sauer, Jr., K. H. Schmidt, C. D. Jonah, E. J. Hart, C. A. Naleway. 3:25—Intermission. 3:35—65. Positron and Positronium Reactions and Their' Relationship to Radiation Chemistry. H. J. Ache, R. E. Wild, B. Djermouni. 3:55—66. Pulse Radiolysis Studies of Actinides and Lanthanides. J. C. Sullivan, S. Gordon, W. A. Mulac, K. H. Schmidt, R. Sjoblom, D. Cohen. 4:35—67. Deuterium Solvent Isotope Effect on the Rate of Acid-Catalyzed Decarboxylation of Carbonatotetraminecolbalt(lll) Complex Ions—A Mechanistic Reappraisal. G. M. Harris, K. E. Hyde. THURSDAY MORNING

Section A

Pick-Congress, Buckingham Room (Main Floor) J. M. Miller Symposium on Nuclear Reactions

L. Yaffe, Presiding 9:00—68. Recoil Nuclei from the Reactions of Heavy Ions with Heavy Elements. R. L. Hahn. 9:40—69. Evaporation Calculations of 1H and 4 He Emitted from *5Br at High Excitation Energies. J. M. Miller, N. H. Lu. 10:00—70. Coincidence Study of Light Fragment Production from the 28-GeV Proton Bombardment of Uranium. L. P. Remsberg, Y. Y. Chu, D. Benson.

M. L. Perlman, Presiding 9:00—Introduction, Qualities of Synchrotron Radiation, Facilities in Being and in Prospect. M. L. Perlman. 9:15—75. Experiments Utilizing Synchrotron Radiation for the Study of Protein Crystals. A. Wlodawer, J. C. Phillips, J. M. Goodfellow, K. D. Hodgson. 10:10—Intermission. 10:20—76. Electron Excitations in Atoms and Molecules by Photoabsorption Spectroscopy. D. L. Ederer. 11:10—77. Photo-lonization Mass Spectrometry. J. W. Taylor. THURSDAY AFTERNOON

Section A

Pick-Congress, Buckingham Room (Main Floor) Symposium on Nuclear Reactions and Relativistic Heavy Ion Reactions

P. E. Haustein, Presiding 2:00—78. Recoil Properties of 24Na, 64Cu and 67 Cu Produced in 3-300 GeV Bombardment of Heavy Targets. J. A. Urbon, E. P. Steinberg, S. B. Kaufman. 2:20—79. Interaction of TC~ and ir+ Mesons with 197 Au. E. P. Steinberg, S. B. Kaufman, C. W. Butler. 2:40—80. The Dependence of Nuclear Orbiting and Charge Distributions on Bombarding Energy in the 144 Sm + 84Kr Reaction. A. Mignerey, D. Raich, K. Wolf, R. Boudrie, C. Roche, J. Birkelund, W. Schroder, J. Huizenga, V. Viola. 3:00—81. Angular Momentum Transfer in Deeply Inelastic Scattering. P. Dyer, R. J. Puigh, R. Vandenbosch, T. D. Thomas, M. S. Zisman. 3:20—Intermission. 3:30—Introductory Remarks. 3:40—82. Central Collisions Induced by Relativistic Heavy Ions. W. G. Meyer. 4:25—83. Spallation of Copper by Relativistic Heavy Ions: Cross Section Systematics and Fragment Recoil Properties. P. E. Haustein, J. B. Cumming.

Section B Pick-Congress, Windsor Room (Main Floor) Symposium on Synchrotron Radiation Joint with Division of Physical Chemistry

J. L. Dehmer, Presiding 2:00—84. Angular Resolved Photoelectron Spectroscopy of Surfaces. E. W. Plummer. 2:55—Intermission. 3:05—85. Investigation of the Geometric and Electronic Structure of Supported Metal Catalysts by x-Ray Absorption Spectroscopy. F. W. Lytle. 4:00—86. x-Ray Absorption Spectroscopy: The Study of Metals in Biochemical Systems. J. P. Smith, J. Goulon, J. A. Kirby, M. P. Klein, N. Kafka, A. S. Robertson, A. F. Thompson, T. P. Walker. FRIDAY MORNING

Section A

Pick-Congress, Buckingham Room (Main Floor) Symposium on Relativistic Heavy Ion Reactions

W. G. Meyer, Presiding 9:00—87. How Inelastic Are the Collisions of Relativistic Heavy Nuclei? J. P. Vary. 9:40—88. Large Collision Residues and Nuclear Fission in Relativistic Heavy Ion Reactions with Heavy Targets. G. T. Seaborg, W. Loveland, R. J. Otto, D. J. Morrissey. 10:15—Intermission.

July 25, 1977 C&EN

51

10:25—89. In Beam Gamma-Ray Studies Using Relativistic Alpha and Carbon Ions. T. Shibata, H. Ejiri, J. Chiba, S. Nagamiya, K. Nakai, H. Bowman, J. G. loannou, J. 0. Rasmussen. 11:00—90. Target Fragmentation of Au by 25-GeV Carbon Ions. S. B. Kaufman, E. P. Steinberg, B. D. Wilkins. 11:30—91. Nuclear Reactions of Silver with 25.2 GeV 12C Ions. N. T. Porlle, G. D. Cole, C. R. Rudy.

Section B Pick-Congress, Windsor Room (Main Floor) General

T. D. Thomas, Presiding 9:00—92. Merits of Synchrotron Radiation in x-Ray Fluorescence. M. O. Krause, C. J. Sparks, Jr., E. Rlcci, S. Raman, H. L. Yakel, R. V. Gentry. 9:20—93. Observation of Surface Excitons in NaCI by Yield Spectroscopy. V. Rehder, W. Gudat, R. Hayes, C. Kunz. 9:40—94. Adaptation of the Mbssbauer Backscatter Technique for the Determination of 119m Sn Spectra at Low Temperatures. C. P. Monaghan, E. J. O'Brien, Jr., M. L. Good. 10:00—95. Time Dependent Perturbed Angular Correlation Study of Short Range Order in Disordered Nf-Fe Alloys. E. Selvatici, W. H. Ellis. 10:20—96. Precise Half-Life Measurements of 238 Pu, 239 Pu, 240 Pu, and 242 Cm. A. H. Jaffey, H. Diamond, W. C. Bentley, K. F. Flynn, D. J. Rokop, A. M. Essling, J. Williams, D. G. Graczyk. 10:40—97. Mass Distributions in Monoenergetic Neutron Fission of 2 3 8 U. S. Nagy, K. F. Flynn, J. E. Gindler, L. E. Glendenin, J. W. Meadows. 11:00—98. The Spontaneous Fission of 254 Fm. J. E. Gindler, K. F. Flynn, L. E. Glendenin, R. K. Sjoblom. 11:20—99. Kinetics of Cesium Uranate Formation. W. A. Shinn, D. C. Fee, G. E. Staahl, I. Johnson, C. E. Johnson.

General M. A. McKinney, Presiding 9:00—4. Synthesis of a Photoproduct from UV-lrradiated Bacterial Spores: 5,6-Dihydro-5-(a-thyminyl)thymine. D. E. Bergstrom, K. F. Rash. 9:15—5. Synthesis of C-5 Substituted Pyrimidine Nucleosides via Organopalladium Intermediates. D. E. Bergstrom, M. K, Ogawa, J. L. Ruth. 9:30—Discussion. 9:35—6. Unusual Rearrangements of Some 8-Substituted Pyrido-[2,3-d]Pyrimidines. A. Srinivasan, A. D. Broom. 9:50—7. Phosphorus-Containing Nucleoside Derivatives. P. A. Bartlett, J. L. Adams, J. T. Hunt. 10:05—Discussion. 10:10—8. A Non-nitrogenous Benzene Analogue of Pyridoxal. C. A. Panetta, A. L. Miller. 10:25—9. 8-Amino-1H-pyrimido[4,5-c]1,2-diazepin-6(7H)-ones: Versatile Intermediates for Heterocyclic Transformations. R. W. Morrison, Jr., W. R. Mallory, V. L. Styles. 10:40—Discussion. 10:45—10. Ring Opening Reactions of 3,7Dideazaxanthine and Two of its Derivatives. S. W. Schneller, R. S. Hosmane. 11:00—11. Synthesis of Cyclo(-L-Prolyl-LProlyl-L-Thiazolidine Carboxyl). Conformational Analysis by 1H and 13C NMR. D. H. Rich, J. Singh. 11:15—Discussion. 11:20—12. The Biosynthesis of Lipoic Acid From Octanoic Acid. R. J. Parry. 11:35—13. Synthesis and Reactivity of Substrates for Photometric Assay of Epoxide Hydrase. J. Hilbert, R. P. Hanzlik. 11:50—Discussion.

Section C Conrad Hilton, Grand Ballroom (2nd Floor) General—Photochemistry

P. H. Mazzocchi, Presiding

9:00—14. Decay Kinetics of Light-Induced Chemiluminescence. G. D. Mendenhall. 9:15—15. Stereochemistry of Six-Membered Cyclic Diacylperoxide Fragmentation. Synthesis and Thermal Decomposition of meso- and dl- 2,3-Dimethylsuccinoyl Peroxides. P. B. Dervan, C. R. Jones. 9:30—Discussion. 9:35—16. Thermolysis of Some Tricyclic 1,2-Dioxetanes. K. R. Kopecky, P. A. Lockwood, J. E. Filby. 9:50—17. Carbonyls as Oxidants: The Photooxidation of Some Sulfides and Phosphines by n,7r# Carbonyl Compounds. M. A. Fox. 10:05—Discussion. 10:10—18. a-Diketone Sensitized Photooxidation of Pyrimidines, Formation of Pyrimidine Epoxides. H.-S. Ryang, S. Y. E. C. Taylor, Chairman Wang. E. M. Burgess, Secretary10:25—19. Heavy-Atom Effect on the Photodimerization of Acenaphthylene: A SubTreasurer stituent Analysis on the Efficiency of External Aromatic Perturbers. G. F. Koser, V.-S. Liu. 10:40—Discussion. SUNDAY EVENING 10:45—20. Substituent Effects in the Photorearrangement of Azoxybenzene. N. J. 8:00—Divisional Business Meeting and Mixer. Bunce, J.-P. Schoch, M. C. Zerner. Conrad Hilton, Parlor C (3rd Floor). 11:00—21. Photochemical Substituent Effects: The Photocleavage of DiarylniMONDAY MORNING Section A trosamines in Neutral Media. D. S. Crumrine, P. Dombrowski, T. J. Haberkamp, R. Conrad Hilton, International Ballroom South J. Kekstas, P. Nabor, G. S. Nomura, H. A. (2nd Floor) Padleckas, D. J. Suther. Symposium on Chemistry of S-N Com11:15—Discussion. pounds 11:20—22. Photolysis of 2-Pentyl PhenylaD. Swern, Presiding cetate: Solvent Effects on the Norrish Type II Reaction. W. H. Saunders, K. H. 9:00—Introductory Remarks. Brown. 9:05—1. Sulfilimines. D. Swern. 11:35—23. Photochemistry of Carbanions. A 9:55—Discussion. Novel Photoalkylation Reaction. L. M. Tol10:00—2. Stereochemistry of Cyclic Nbert. Aryl-sulfimides: Synthesis, Configuration, Conformation and Rearrangement. P. K. 11:50—Discussion. Claus, F. W. Vierhapper, J. Bailer, W. Rieder, R. L. Wilier, W. R. Kenan, Jr. MONDAY AFTERNOON Section A 10:50—Discussion. 10:55—3. [2,3]-Sigmatropic Rearrange- Conrad Hilton, International Ballroom South ments of Ylids Derived from Azasulfonium (2nd Floor) Salts. P. G. Gassman. Symposium on the Chemistry of S-N Com11:45—Discussion. pounds

ORGN

DIVISION OF ORGANIC CHEMISTRY

F. A. Davis, Presiding Section B Conrad Hilton, International Ballroom North (2nd Floor)

52

C & E N J u l y 2 5 , 1977

2:00—24. Preparation and Reactions of Sulfilimines from Organosulfur Cation Radicals. H. J. Shine, B. K. Bandlish, K. Kim, S. R. Mani, A. G. Padilla.

2:30—Discussion. 2:35—25. Nitrogen-Centered Ligands to Sulfur(IV) in Azasulfuranes, Sulfilimines, and Related Compounds. J. C. Martin, I. C. Paul, L. J. Adzima, C. C. Chiang, G. Astrologes, M. Mueth. 3:25—26. The Chemistry of Thione S-lmides. E. M. Burgess. 4:20—Discussion. 4:25—27. Sulfur Transfer Reagents in Synthesis. D. N. Harpp, K. Steliou. 5:15—Discussion.

Section B Conrad Hilton, International Ballroom North (2nd Floor) General

J. J. D'Amico, Presiding 2:00—28. Asymmetric Reductions via Balkyl-9-borabicyclo-[3.3.1]nonane(9-BBN). M. M. Midland, A. Tramontano, S. A. Zderic. 2:15—29. Aminomethylation of Thiolcarboxylic Acids. I. E. Pollak. 2:30—Discussion. 2:35—30. Synthesis of 7,12-Benz[a]anthraquinones via Diels-Alder Reaction of 1,4-Phenanthraquinones. B. I. Rosen, W. P. Weber. 2:50—31. The 2 + 4 Cycloaddition of 1,4Naphthoquinone and Methoxystyrenes for the Synthesis of 1-, 2-, 3- and 4-Substituted Benz[a]anthracene-7,12-diones, Benzfal anthracenes and 7,12-dimethylbenz[a] anthracenes. G. M. Muschik, J. E. Tomaszewski, R. I. Sato, W. B. Manning. 3:05—Discussion. 3:10—32. Quinizarin Boroacetate and Analogues as Dienophiles and Dipolarophiles. A. M. Birch, A. J. H. Mercer. 3:25—33. Synthesis of 2-Methyl-1-phenylphospholan-3-one 1-Oxide. E. Howard, Jr., R. D. Rossi. 3:40—Discussion. 3:45—34. Synthesis of Novel Energetic Aliphatic Compounds. E. F. Witucki, M. B. Frankel. 4:00—35. The Thermal Cyclization of Dinitrophenyl-N,N-Dimethyl-dithiocarbamates. A General Synthesis of 1,3-Benzodithiole2-Ones. K. Rasheed, J. D. Warkentin. 4:15—Discussion. 4:20—36. Reactions of Trithiocarbonic Acid Derivatives with Substituted Ketenes. H. Kohn, P. Charumilind, Y. Gopichand. 4:35—37. A Novel Nitration System— N 2 0 4 /0 2 /NO. D. S. Ross, W. G. Blucher. 4:50—Discussion. Section C Conrad Hilton, Grand Ballroom (2nd Floor) General—Physical Organic and Photochemistry L. Tolbert, Presiding 2:00—38. The Photodemerization of 2Cyanoquinoline. B. M. Vittimberga, T. Coronna, S. Morrocchi. 2:15—39. Photochemical Reactions of Fused Heterocyclic Compounds: Part X Indole and its Derivatives. P. D. Davis, D. C. Neckers. 2:30—Discussion. 2:35—40. Photolysis of 4-Hydroxypyrylium Cations. Regiospecificity and Furyl Cation Formation. J. W. Pavllk, D. R. Bolin, K. R. Bradford, M. V. Matera, L. T. Pauliukonis, W. G. Anderson. 2:50—41. The Photochemical Addition of Dienes to N-Alkylphthalimides. P. H. Mazzocchi, M. W. Bowen, N. K. Narain. 3:05—Discussion. 3:10—42. A "Nonbleachable" Rhodopsin Analog Formed From 11,12-Dihydroretinal. M. A. Gawinowicz, V. Balogh-Nair, J. S. Sabol, K. Nakanishi. 3:25—43. Inversion of CIDNP Signals by Selective Irradiation in the Photoreduction of Ketones by Amines. R. I. Walter, H. Fischer. 3:40—Discussion. 3:45__44. On the Structure and Photodestruction of Phaeomelanin. M.R. Chedekel, R. M. Deibel, M. Kalus, P. W. Post. 4:00—45. A Synthetic Biomimetic Model of Special Pair Bacteriochlorophyll a. M. R. Waslelewski, U. H. Smith, B. T. Cope, J. J. Katz. 4:15—Discussion. 4:20—46. Catalyzed Oxidation Reactions: Picolinic Acid Catalysis of Chromic Acid Oxidations. J. Rocek, T-Y. Peng.

4:35—47. Acid-Catalyzed Hydration of cisand trans-1-Methylcyclooctene. W. K. Chwang, Y. Chiang, A. J. Kresge, S. Szilagyi. 4:50—Discussion. TUESDAY MORNING

Section A

Conrad Hilton, International Ballroom South (2nd Floor) Symposium on the Chemistry of S-N Compounds D. Swern, Presiding 9:00—48. Asymmetric Synthesis with Sulfoximines. C. R. Johnson, D. L. Goff, T. Imamoto, L. Jenssen, C. J. Stark, Jr. 9:50—Discussion. 9:55—49. Chemistry of Sulfonamide Derivatives. F. A. Davis. 10:45—Discussion. 10:50—50. Axial and Central Chirality in Sulfonamides. M. Raban. 11:40—Discussion.

Section B Conrad Hilton, International Ballroom North (2nd Floor) Symposium on Organic Photochemistry

O. L. Chapman, Presiding 9:00—Introductory Remarks. 9:05—51. Recent Advances in Mechanistic and Exploratory Organic Photochemistry. H. E. Zimmerman. 9:35—Discussion. 9:40—52. Photocycloaddition of Conjugated Polyenes to Aromatic Hydrocarbons. N. C. Yang, R. R. Jones, J. K. McVey, D. M. Shold, K. Srinivasachar. 10:10—Discussion. 10:15—53. Photochemistry of Cyclic Polyenes. W. G. Dauben, C. P. Baskin, D. M. Michno, E. G. Olsen. 10:45—Discussion. 10:50—54. Electronic Excited States of Small Ring Compounds. Photochemistry of Some Cyclopropenes. D. R. Arnold, R. M. Morchat, P. C. Wong. 11:20—Discussion. 11:25—55. Substituent Probes on Excited State Reactivity. R. S. Givens, W. K. Chae, J. Liu, P. Wylie, R. Stitt. 11:50—Discussion.

Section C Conrad Hilton, Grand Ballroom (2nd Floor) General-Physical Organic

A. J. Arduengo, Presiding 9:00—56. 3,3-Dimethylallenyllithium. Reaction with Electrophiles Leading to Carbenoid, Electron Transfer, and Nucleophilic Processes. X. Creary. 9:15—57. Effect of f-Butylated Phenols on Reactions of N-Acetoxy-2-acetylaminofluorene with Biological Molecules. T. E. Schmidt, D. Leonov, V. Yachandra, N. C. Yang. 9:30—Discussion. 9:35—58. Radical/Anion-Radical Pair (RARP) Mechanism in Reactions of Anions with Perhalomethanes. C. Y. Meyers, T. E. Parady, V. M. Kolb, D.H. Hua. 9:50—59. Reaction of Ozone with tert-Butyl Hydroperoxide. M. E. Kurz, W. A. Pryor. 10:05—Discussion. 10:10—60. The Conversion in High Yield of Aromatic Compounds to Arene Oxides Using Hypochlorite and Phase Transfer Catalysts. G. A. Hamilton, S. Krishnan, D. G. Kuhn, H. E. Fonouni. 10:25—61. Mechanism of the Oxidation of frans-Cyclododecene by Potassium Permanganate in Non-aqueous Solvents. D. G. Lee, V. S. Chang. 10:40—Discussion. 10:45—62. Synthesis and Spectroscopic Properties of a Series of Chiral Polyether Macrocycles and Their Metal Complexes. M. P. Mack, R. R. Hendrixson, R. A. Palmer, R. G. Ghirardelli. 11:00—63. How Does A Naphthalene Derivative Respond to a Poke in the Pi Face? Crown Ether Model Systems for the Study of Photoexcited State Response to Oriented Perturbers. L. R. Sousa, J. M. Larson. 11:15—Discussion. 11:20—64. Polytertiary Phosphinomacrocyclic Ligand Systems. E. P. Kyba, C. W. Hudson, M. J. McPhaul.

11:35—65. Evidence for Minimal Stereoelectronic Control in a 1,2-H Shift to an Alkylcarbene. E. P. Kyba, A. M. John. 11:50—Discussion. TUESDAY AFTERNOON

Section A

Conrad Hilton, International Ballroom South (2nd Floor) Symposium on the Chemistry of Free Radicals

W. G. Bentrude, Presiding 2:00—Introductory Remarks. 2:05—66. 1,4 Diradicals. Effects of Pressure on Their Chemistry. R. C. Neuman, Jr., C. Berge. 2:35—Discussion. 2:40—67. Radical, Anion & Anion-Radical Reactions With Organic Halides. S. Bank. 3:10—Discussion. 3:15—68. The Synthesis and Reactions of Bicyclo 2.2.1 Endoperoxides Analogous to Prostaglandin Intermediates. N. A. Porter. 3:45—Discussion. 3:50—69. Free Radical Displacements at Bivalent Sulfur. J. A. Kampmeier, R. B. Jordan, M. S. Liu, H. Yamanaka, D. J. Bishop. 4:20—Discussion. 4:25—70. The "Cage" Effect in Reactions of Peresters and Hyponitrites. T. Koenig. 4:55—Discussion.

4:15—Discussion. 4:20—84. Hydrogen-Deuterium Exchange Reactions of Carbanions with D 2 0 in the Gas Phase. J. H. Stewart, R. H. Shapiro, C. H. DePuy, V. M. Bierbaum. 4:35—85. Gas Phase Reactions of Organic Anions with N 2 0. C. H. DePuy, V. M. Bierbaum, R. H. Shapiro. 4:50—Discussion. WEDNESDAY MORNING

Section A

Conrad Hilton, International Ballroom South (2nd Floor) Symposium on the Chemistry of Free Radicals

J. M. McBride, Presiding 9:00—Introductory Remarks. 9:05—86. Free Radical Aspects of Photooxidation. P. D. Bartlett. 9:45—Discussion. 9:50—87, Some Applications of Free Radical Isomerizations. K. U. Ingold. 10:30—Discussion. 10:35—88. Radical Production from the Interaction of Closed-Shell Molecules. Current Studies of MAH, Electron Transfer, and Pericyclic Reactions. W. A. Pryor. 11:15—Discussion. 11:20—89. The Application of Kinetic Electron Spin Resonance Spectroscopy to Some Reactions of the f-Butylperoxy Radical in Solution. J. A. Howard. 12:00—Discussion. Section B

Conrad Hilton, International Ballroom North (2nd Floor) Symposium on Organic Photochemistry

Conrad Hilton, International Ballroom North (2nd Floor) General

O. L. Chapman, Presiding

A. Ternay, Presiding

2:00—71. Aspects of the Photochemistry Cyclic Ketones. P. Yates. 2:30—Discussion. 2:35—72. Diastereomeric Biradicals in the Photochemistry of 4-lsobutyl-4-methylcyclopentenone. W. C. Agosta. 3:05—Discussion. 3:10—73. Unusual Carbonyl Photoreactions. J. C. Daiton, R. A. Bourque, M. Shen, D. K. Simpson, M. M. S. Wu. 3:40—Discussion. 3:45—74. Temperature Effects in Solution Photochemistry. D. S. Weiss. 4:15—Discussion. 4:20—75. Type I Rearrangement of 2Ethoxypyrrolin-5-Ones. Determination of the Scope and Stereochemistry. T. H. Koch, G. C. Crockett, J. M. Burns, M. E. Ashley. 4:50—Discussion.

9:00—90. Allene Episulfide. E. Block, R. E. Penn, M. D. Ennis, S-L. Yu. 9:15—91. Organic Chemistry by Infrared Lasers. 1. Isomerization of Allene and Methylacetylene in the Presence of SiF4. C. Cheng, P. Keehn. 9:30—Discussion. 9:35—92. The Role of Electron Transfer in the Reaction of Cyclopropenyl Cations with Cyclopropenyl Anions. M. R. Wasielewski. 9:50—93. Pyrolysis of A/,A/-Dichloroamines. P. Kovacic, J. T. Roberts, F. V. Scalzi, M. J. Seely, J. A. Tonnis. 10:05—Discussion. 10:10—94. Iron Carbonyl Mediation of the Michael Reaction. Addition of Stabilized Anions to 7T-(Alkene)iron-tetracarbonyl Complexes. N. H. Baine, M. R. Baar, B. W. Roberts, M. Ross. J. Wong. 10:25—95. Stereoselective Reduction of a Cyclopropyl Halide with Lithium Aluminum Hydride. M. A. McKinney, S. C. Nagarajan. 10:40—Discussion. 10:45—96. Electronic and Steric Effects on the Cleavage of Substituted Arylcyclopropanes in HCI-HOAc. M. A. McKinney, J. S. Nelson, C. Chung. 11:00—97. Metal Assisted Cycloaddition Reactions. P. Lennon, M. Rosenblum, J. Tancrede. 11:15—Discussion. 11:20—98. A Reversible Grignard Reagent Rearrangement. E. A. Hill, M. M. Myers. 11:35—99. The Stereochemistry of the Degenerate Metathesis of Terminal Alkenes —The Nature of the Chain Carrying Metal Carbene Complex. C. P. Casey, H. E. Tuinstra. 11:50—Discussion.

Conrad Hilton, Grand Ballroom (2nd Floor) General—Physical Organic C. Y. Meyers, Presiding 2:00—76. Synthesis and Properties of II-EIectron Donors Bound to Polystyrene Resins. E. M. Engler, F. B. Kaufman, D. C. Green. 2:15—77. A Synthetic Method for the Preparation of Monosubstituted and Asymmetric Multisubstituted Sulfur and Selenium Heterofulvalene Donor Molecules. D. C. Green. 2:30—Discussion. 2:35—78. Thiapen Chemistry II: 1,3-Dithiole and Diselenole Capping of Thiapendione. E. M. Engler, R. R. Schumaker. 2:50—79. Thiapen Chemistry I: Synthesis and Properties of the 1,3,4,6-Tetrathiapentalene Ring System. R. R. Schumaker, E. M. Engler. 3:05—Discussion. 3:10—80. Synthesis of the Organic 7r-Donor 1,3-Dithiole-2(A4'-Thiopyran) and Its Conducting Salts with TCNQ. D. J. Sandman, A. P. Fisher, ill, T. J. Holmes, A. J. Epstein. 3:25—81. Preparation and Reactions of Dicationic Salts that Contain the Disulfide Linkage. M. P. Doyle, D. M. Hedstrand. 3:40—Discussion. 3:45—82. Ionization of Nitromethane: Comparison of Gas Phase and Solution Results. A. J. Kresge, D. K. Bohme, G. I. Mackay. 4:00—83. Reaction of Tritium (Hydrogen) Atoms with Solids: Factors Influencing Reactivity and Site of Reaction in Amino Acids and Peptides. R. Ehrenkaufer, A. P. Wolf, W. C. Hembree.

WEDNESDAY

AFTERNOON Section A

Conrad Hilton, International Ballroom Soutlr (2nd Floor) Symposium on the Chemistry of Free Radicals

W. A. Pryor, Presiding

Section B

Section C

10:10—104. Iminium Ion Formation and Deuterium Exchange by Acetone in the Presence of Pyrazolidine. R. A. Evangelista, J. Hine. 10:25—105. Comparative Capabilities of 1-Phenylpropane-1-13C and 1-Phenylbutane-1-1^C Toward the Alkylbenzene Automerization. R. M. Roberts, T. L. Gibson, M. B. Abdel-Baset. 10:40—Discussion. 10:45—106. Consequences of 2p-3d Overlap in the Alkaline Cleavage of Benzyltriarylphosphonium Chlorides. G. L. Keldsen, W. E. McEwen. 11:00—107. Acid-Catalyzed Cleavage of ij-Diketones. L. F. Hatch, M. D. Coburn, M. El-Emary, D. B. Nelson. 11:15—Discussion. 11:20—108. Trapping of the Oxocarbonium Ion Intermediate in the Hydrolysis of Acetophenone Dimethyl Ketals. P. R. Young, W. P. Jencks. 11:35—109. Solvolysis of /3,/3-Divinyl-/5phenethyl Tosylate. J. W. Wilt, R. Niinemae. 11:50—Discussion.

Section C Conrad Hilton, Grand Ballroom (2nd Floor) General—Physical Organic W. Jorgensen, Presiding 9:00—100. Heterocyclic Aromatic Anions. F. G. Bordwell, H. E. Fried. 9:15—101. The Effect of Solvation on Bronsted (3 Values for Proton Transfer Reactions. D. J. Hupe, D. Wu. 9:30—Discussion. 9:35—102. A Carbon-14 Isotope Effect and Kinetic Study of the Base-promoted Dehydrochlorination of p-Substituted DDT-Type Compounds. S. W. Crook, A. Fry. 9:50—103. The Reaction of a-Ketotriflates with Sodium Methoxide. X. Creary, A. J. Rollin. 10:05—Discussion.

2:00—Introductory Remarks. 2:05—110. Forty Years of Free Radicals. C. Walling. 2:35—Discussion. 2:40—111. Primary Salt Effects in Electron Transfer Reactions. E. S. Huyser, R. Tang. 3:10—Discussion. 3:15—112. Nucleophilic and Chemiluminescent Reactions of Superoxide Anion Radical. W. C. Danen, R. J. Warner, R. L. Arudi. 3:45—Discussion. 3:50—113. Electrophilic Reactions of Aromatic Cation Radicals. H. J. Shine. 4:20—Discussion. 4:25—114. Phase and Solvent Effects in Reactions of Organic Peroxides. R. Hiatt. 4:55—Discussion. Section B Conrad Hilton, International Ballroom North (2nd Floor) General—Natural Products Synthesis

J. Swenton, Presiding 2:00—115. Interconversions of Nuphar Thiaspiranes. R. T. LaLonde, C. F. Wong. 2:15—116. A Transannular Route to the Indolizidine Skeleton. The Total Synthesis of (±)-