MEETINGS
Joint ACS 45th Northwest/ 10th Rocky Mountain Regional Meeting The Joint ACS 45th Northwest/10th Rocky Mountain Regional Meeting, hosted by the Salt Lake Section, will be held on the University of Utah campus, Salt Lake City, on June 13-15. The program will include some 250 papers in eight symposia and six general technical sessions. The symposia will feature nearly 100 invited speakers. Program highlights include symposia on academic-industry transitions, field-flow fractionation, kinetics of inhomogeneous systems, postmodern organic synthesis—methods for the 1990s, practical applications of computational chemistry, targeted drug delivery, terpene biosynthesis, and transition-metal organic thermochemistry. Additionally, the Utah Supercomputer Institute (USI) and IBM will be demonstrating the capabilities of the new RISC System 6000 Power Workstation and USI's supercomputer. Demonstrations will include such applications as molecular modeling, data collection and analysis, and a system for managing material safety data sheets. The meeting will be highlighted by a conference banquet on Thursday evening, June 14, in the Rustler Lodge of the Alta Ski Resort. Free bus transportation to the lodge will be available from the university campus (schedule at registration desk). Banquet attendance is limited to 140 persons, and advance reservations are strongly recommended (see registration form on page 58). ACS president Paul Gassman will be the featured speaker at this event. In addition, the James Bryant Conant Award for Outstanding Teaching in High School Chemistry will be presented. All registrants are also invited to a social mixer with free draft beer and appetizers to be held on Wednesday evening, June 13, at the social hall in the Old Deseret Village located in Pioneer Trail State Park southeast of the campus. A chemical exposition will be held in conjunction with the meeting. Exhibits by major suppliers of laboratory equipment, analytical instruments, computers, and chemical education tools will be on display adjacent to the session rooms. Coffee and refreshments will be available in the exhibit area. The meeting and registration will be held in the Social and Behavioral Science Building (BEH S), directly south of the Marriott Library, on the campus of the University of Utah located at 400 South and 1500 East St., Salt Lake City. Ample parking for $1.50 a day is available on campus. Parking permits are required and may be obtained from university parking services in the parking lot west of the meeting site. Advance registration, at a savings of $25, is encouraged using the form on page 58. A block of 125 deluxe rooms has been reserved for the meeting at the University Park Hotel, 500 South Wakara Way, Salt Lake City, Utah 84108, phone (800) 637-4390, adjacent to campus. Please state that you are attending the regional meeting when making your reservations (single, $60; double, $70). Dormitory housing in Austin Hall on campus must be reserved and paid in advance on the registration form. A wide variety of motels are located in downtown Salt Lake City, approximately three miles west of the university, and along Foothill Drive south of campus. Addtional travel information may be obtained from the Salt Lake Convention and Visitors 56
April 23, 1990 C&EN
Bureau, 180 South West Temple, Salt Lake City, Utah 84101, phone (800) 831-4332. Salt Lake City has excellent airline service and is located at the junction of 1-15 and 1-80. Twenty national parks are within a day's drive of the city, including Arches, Bryce Canyon, Canyonlands, Capitol Reef, and Zion within the borders of the state (contact visitors bureau above for additional information). The airport is located approximately 10 miles west of the university on North Temple Street. Free shuttle service is available for guests of the University Park Hotel using the direct phone line in the baggage claim area of the airport. For additional information, contact the following planning committee members: program chairman, Joseph G. Morse, (801) 750-1633; exhibits chairman, Martin J. Rodi, (801) 5818582; registration chairman, Sean O'Connor, (801) 251-4127; and general chairman, Robert A. Earl, (801) 251-2939.
SPECIAL EVENTS
GENERAL SYMPOSIA
TUESDAY
WEDNESDAY MORNING
4:00-8:00 PM—Meeting Registration, Room 111, BEH S
WEDNESDAY 8:00 AM-5:00 PM—Meeting Registration, Room 111, BEH S 8:00 AM-5:00 PM—Chemical Exposition, BEH S 10:00-11:30 AM—Rocky Mountain Steering Committee Meeting, Alumni House, Burbkjge Boardroom 1:00-2:30 PM—NORM Steering Committee Meeting, Alumni House, Burbidge Boardroom 2:30-4:00 PM—Joint NORM/Rocky Mountain Region Local Section Officers and Councilors Meeting, Alumni House, Burbidge Boardroom 8:00-8:00 PM—Reception/Mixer, Social Hall in the Old Deseret Village, Pioneer Trail State Park
THURSDAY 8:00 AM-5:00 PM—Meeting Registration, Room 111.BEHS 8:00 AM-5:00 PM—Chemical Exposition, BEHS 7:30 PM—Conference Banquet, Rustler Lodge, Little Cottonwood Canyon, Alta.
FRIDAY 8:00-10:00 AM—Meeting Registration, Room 111.BEHS 8:00 AM-noon—Chemical Exposition, BEH S
Room 114 Symposium on Computers in Chemistry Session A: Large-Scale Molecular Calculations and Simulations D. J. Caldwell, Organizer, Presiding 9:00—Introductory Remarks. D. J. CakhveM 0:05—1. Large-Scale Numerical Simulations in Molecular and Materials Design. E. 10:00—2. Simulation of Amorphous Polymers: Liquids and Glasses. R. H. Boyd, K. Pant 10:30—3. Theory, Modeling, and Simulation Program at the Pacific Northwest Laboratory. T. H. Dunning Jr. 11:00—4. Mechanisms of Chemical Reactions Based on the Stationary Action Principle. A. Banerjee, N. P. Adams 11:30—5. Density Functional Approach and Its Application To Study Electrostatic Properties of Molecular Complexes. J. W. Andzefcn, J. E. Mertz WEDNESDAY AFTERNOON Room 114 Session B: General Quantum Mechanical R. B. Shirts, Presiding 2:00—8. Local Density Functional Calculations on Metathesis Reaction Precursors. D. J. Caldwell. P. K. Redington, J. W. Andzelm 2:30—7. Game-Theoretic Search for Stationary Points on Surfaces. N. P. Adam·, A. Baneriee 3:00—8. Calculation of Chemical Shielding Tensors: a Tool To Understand Molecular Structure. J. C. Face»
3:30—β. Molecular Orbital Treatment of Nitro Compounds. P. K. Redington 4:00—10. Semiclassical Spectra of Poly atomic Molecules: Application to Water and Acetylene. R. B. Shirts, T. J. Pickett 4:30—11. Recent Advances in the Theory of Surface Diffusion. A. F. Voter 5:00—12. Effective Core Potential Method for Use in Correlated Calculations. K. W. Rlchman, A. Banerjee
THURSDAY MORNING Room 107 Sêmion C: Molecular Simulation* and Biological AppUcaOom
R. L. Ornsteln, Presiding 9:00—Introductory Remarks. R. L. Omsteki 0:05—13. Constrained Polymer Dynamics: Application to Separation Systems. M. R. Schure, M. Blanco 0:30—14. Molecular Dynamics Simulations of Biomaterials: Chain Dynamics and Interactions with Peptides. J. N. Herron, K. Lim, R. J. Athay J0:00—15. Molecular Dynamics Simulations of Cytochrome P-450cam. R. L. Ornsteln, M. D. Paulsen, M. B. Bass 10:30—16. Design Strategies To Identify and Target Important Sites on the Surface of a Protein. S. SrMvasan, P. Sudarsanam 11:00—17. Sequence Attributes Method for Determining Relationships between Amino Acid Sequence and Protein Secondary Structure. G. E. Arnold, A. K. Dunker. S. J. Johns, R. J. Douthart 11:30—18. Prediction of Protein Interaction Sites. T. P. Hopp THURSDAY MORNING & AFTERNOON
9:40—30. Laser-Initiated Polymerization of Solid Formaldehyde. E. S. Mansueto, C. A. Wight 10:20—31. Photochlorination of Simple Alkanes in Cryogenic Solids. C.A. Wight, P. R. Kligmann, T. R. Botcher, A. J. Sedlacek 10:40—32. Adsorption-Desorption Kinetics at Heterogeneous Solid-Liquid Interfaces. J. W. Bums. D. B. Marshall
Session A
Room 108 Symposium on Transition-Metal Organic Thermochemistry Session A
9:00—Introductory Remarks. J. R. Norton 9:05—33. Electron Transfer Reactions of Transition-Metal Carbonyl Anions. J.D. Atwood, Y.-Q. Zhen, S. Corraine. C. K. Lai, P. Wang 9:45—34. Structure, Bonding, and Equilibria in Chiral Aromatic Aldehyde Complexes [»?5-C6H5)Re(NOXPPh3XO = CHAr)]+BF4~. N. Q. Mondez. J. A. Gladysz 10:25—35. Ligand Lability and Asymmetric Synthesis: an Unlikely Pair. M. E. Wright, S. A. Svejda 10:55—36. Thermochemical Considerations as a Guide toward Development of New Metal Carbone Chemistry. J. M. O'Connor, LPu 11:25—37. Unusual Metal Carbonyl Fluo rides Prepared by C-f Bond Cleavage. T.G. Richmond, C E . Osterberg, M.J. Poss, M. A. King THURSDAY AFTERNOON Room 106 Session Β
Session Β 2:00—23. Percolation Theory of Solid-State Chain Reactions. C. A. Wight 2:30—24. Solid-Solid Kinetics via Dynamic X-Ray Diffraction. W. J. Thomson 3:20—25. Metal Cluster Reactivity, Spec troscopy, and Thermochemistry. M. D. Morse 3:50—26. Experimental Probes of Disorder at Solid-Liquid Interfaces. D. B. Marshall, J. W. Burns, E. W. Ellison, B. J. Stanley 4:20—27. Comparative Study of SolidMatrix Luminescence Interactions pAminobenzoate on Two Different Matri ces. R. J. HurtuMse, S. M. Ramasamy FRIDAY MORNING toom 107 tesslonC A. L. Wong, Presiding 9:00—28. Measurements of Energy Disper sion at Liquid-Solid Interfaces: Fluores cence Quenching of Pyrene Bound to Fumed Silica. A. L Wong, D. B. Marshall. J M Harris 9:20—29. Clustering of Water Molecules in Vapor Deposition with Excess Nitrogen. T. R. Botcher. C. A. Wight
R. von Wandruszka, Chairman
Symposium on Advances in Field-Flow Fractionation
K. Ratanathanawongs, J. C. Giddings, Organizers K. Caldwell, Presiding 9:00—49. Field-Flow Fractionation: Princi ples and Perspectives. J. C. Giddings 9:30—50. Influence of Hydrodynamic Lift Forces on Retention in Field-Flow Frac tionation. P. S. Williams, J. C. Giddings 10:00—51. Particle Separation and Charac terization Using Flow Field-Flow Fraction ation. S. K. Ratanathanawongs, J. C. Gid dings
M. E. Hansen, Presiding 10:45—52. Continuous Fractionation of Se lectively Mass-Labeled Cells in a SPLITT Channel. G. Nyquist, Y.-S. Gao. J. F. Ash, K. D. Caldwell 11:15—53. Study of Morphology and Size Distribution of Red Blood Cells by Flow/ Hyperlayer Field-Flow Fractionation. Β. Ν. Barman, J. C. Giddings 11:45—54. Steric Field-Flow Fractionation Using Electrical Field. Y.-S. Gao. K.D. Caldwell
J. D. Atwood, Presiding 1:30—38. Hydrogen Atom and H"*" Transfer from Transition-Metal Hydride Complexes. D. C. Eisenberg, S. S. Kristjansdottir, C. J. C. Lawrie, A. E. Moody. J. R. Norton 2:05—39. Oxidatively Induced Reaction of Group 6-8 Cyclopentadienylmetal Hydride and Methyl Complexes. M. Tibet 2:40—40. Thermodynamic and Kinetic Stud ies of the Reactions of H2Gas and Transi tion-Metal Hydrides with the Chromium Centered Radicals Cr(COyC5R6). G. Kiss, K. Zhang, S. Mukerjee, G. Roper, C. Hott 3:05—41. Periodic Trends in Transition-Met al Hydrogen, Carbon, Nitrogen, and Oxy gen Bonds. P. B. Armentrout FRIDAY MORNING Room 102 Symposium on Academic-Industry Transi tions
R. Carpenter, Chairman L. F. Cannizzo, Presiding 9:00—Introductory Remarks 9:10—42. From DNA Recognition to Peptide Recognition: a Transition from Academia to Industry. R. S. Youngquist 9:40—43. University to Industry Transition: from the Fundamental to the Practical. R. R. Bennett 10:10—-44. Cooperative Research Pro grams: a Key to the Future of Academic Research. M. E. Wright 10:40—45. Academic Study of Ammonium Nitrate Blasting Agents. J. C. Oxley 11:10—48. University-Federal Laboratory Transitions: Ivory Tower to Ivory Tower? R. T. Paine 11:40—47. Science in a New Setting: the Transition to a National Laboratory. L. R. Gllllon-Sylvester 12:10—48. Undervaluing the Generalist: Fu ture Trends in Scientific Research. J.J. Eberhard, P. M. Morton, J. K. Young
9:55—83. Advances in Fiber-Optic Spec troscopy. A. E. Grey, J. K. Partin, M. L. Stone, D. A. Femec, R. von Wandruszka 10:20—84. Analysis of Phenolic Pesticides by Peroxyoxalate Chemiluminescence. M A. Abubaker, R. von Wandruska 10:45—85. Fundamental Interactions in BCyclodextrin/Sodium Chloride Solid-Matrix Luminescence Analysis. M. D. Richmond, R. J. Hurtubise 11:10—88. Photoinitiation of Peroxyoxalate Chemiluminescence: Applications to Flow Injection Analysis of Chemilumophores. R. E. Mllofsky, J. W. Birks THURSDAY AFTERNOON
WEDNESDAY MORNING & AFTERNOON Room 109
V. D. Parker, Organizer J. R. Norton, Presiding
D. B. Marshall, Organizer, Presiding 9:00—Introductory Remarks. Ο. Β. Marshall 9:10—19. Low-Dimensional Reaction Kinet ics. R. R. Kopeknan 10:00—20. Theory of Reaction Dynamics in Solution. J. T. Hynes 10:50—21. Fluorescence Energy Transfer on Membrane Aggregates: Theoretical and Biophysical Aspects. T. G. Dewey 11:20—22. Deterministic Chaos Arising from Spatial Inhomogeneities Associated with Mixing in CSTR Experiments. L. Gyorgyi. R.J. Field
ANALYTICAL CHEMISTRY
THURSDAY MORNING
Room 116 Symposium on Kinetics of Inhomogonoous Systems
TECHNICAL SESSIONS
Room 114 General Session Β A. E. Grey, Presiding 1:30—87. Observation and Evaluation of Transient Faradaic Current. R. von Wan druszka. X. Yuan 1:55—88. Application of Polyphosphazene Pervaporation Membranes for Separation of Chlorinated Hydrocarbons from Water. A.K. Gianotto. W.F. Bauer. D.G. Cummings 2:20—89. Laboratory Study of Submerged Metal Mine Tailings 2: Effects of Exposed Tailings on Pond Water Quality. P.L Drake, R. D. Doepker 2:45—70. Chemistry of Rime and Snow Collected at a Site in the Central Washing ton Cascades. L. C. Duncan 3:10—71. Seasonal Changes (Summer) of the Chemistry of an Alpine Lake. D. Stauffer, S. Wagner, C. Duncan 3:35—72. Analysis of Municipal Wastewater Sludge Incinerator Emission Samples Us ing XANES for the Determination of Chro mium and Nickel Species. J. E. S I * , N. F. Mangelson. L B . Rees. M.W. Hill. R.B. Gregor. F. W. Lytle 4:00—73. PIXE Elemental Analysis of Prod ucts from Incineration of Red Phosphorous Munitions. B. Sun, S.S.W. Kwak, N.F. Mangelson, M. W. Hill. L. B. Rees FRIDAY MORNING
K. Ratanathanawongs, Presiding
Room 114
2:00—55. Use of Field-Flow Fractionation To Study Pollutant-Colloid Interactions. R. Beckett, D. M. Hotchin, Β. Τ. Hart 2:30—58. Utilization of Inductively Coupled Plasma-Mass Spectrometry as an Ele ment-Specific Detector for Sedimentation Field-Flow/Fractionation. H.E. Taylor, J. Garbarino, R. Beckett, D. M. Hotchin 3:00—57. Analysis of Octane-in-Water Macroemulsions. M. E. Hansen
General Session C
J. C. Giddings, Presiding 4:00—58. Thermal Field-Flow Fractionation of Polymers. M. N. Myers. J. C. Giddings 4:30—59. Separation and Molecular Weight Distribution of Water-Soluble Polymers by Flow Field-flow Fractionation. M. A. Benincasa, J. C. Giddings 5:00—80. Coriolis-lnduced Secondary Flow Effects in Sedimentation FFF. M R . Schure, S. K. Weeratunga
THURSDAY MORNING Room 114 General Session A R. von Wandruszka, Presiding 9:00—Introductory Remarks. R. von Wan druszka 9:05—61. Raman Spectroscopy as a Probe of Interactions between Acetonitrile and Chromatographic Silica. K. L. Rowlen, E. H. Ellison, J. M. Harris 9:30—62. Characterization of a SheathFlow Nozzle for Supercritical Fluid/Super sonic Jet Spectroscopy. M. R. Llnford, C. H. Sin, R. B. Hales. S. R. Goates
R. von Wandruszka, Presiding 9:00—Introductory Remarks. R. von Wan druszka 9:05—74. Effect of Organic Solvent and An ion Type on Cation Binding Constants and Their Use in Designing Selective Concen trator Columns. M. L. Bruening, D. M. Mitchell, R. L. Bruening, R. M. Izatt 9:30—75. Novel Ion Exchange and Cokximetric Iodide Indicator Column Prepared by Binding Pd^to an Immobilized Ligand. D. M Mitchell, M. L. Bruening, R. L. Bru ening, R. M. Izatt 9 : 5 5 - 7 8 . GC and SFC Determination of Metal Species by Complexation with Dithiocarbamates. J.J. Yu. K.E. Laintz, C M Wal 10:20—77. Spatially Resolved Electrochem ical Detection for High-Performance Liquid Chromatography at Semiconducting Titani um Dioxide Wires. G.N. Brown, J. W. Birks, C. A. Koval 10:45—78. Microsecond Fluorescence Thermometry of Porous Silica Heated by a Joule Discharge. S. W. Walte, J. M. Harris. E. H. Ellison, D. B. Marshall 11:10—79. NMR Longitudinal Relaxation Study of the Fluidity at Octadecyl Silica Surface. E. H. EIHson, D. B. Marshall 11:35—80. Laser Pyrolysis-Transfer Line Chromatography/Mass Spectrometry of Single Levitated Coal Particles. W. Maswadeh, N. S. Arnold, H. L. C. Meuzelaar
April 23, 1990 C&EN
57
Meetings
Advance Registration Form
Joint 45th Northwest/10th Rocky Mountain Regional Meeting University of Utah
June 13-15
(Please print of type) Name.
First
Last Organization.
Ml
Please check below for dormitory accommodations in Austin Hall and enclose full payD Tuesday, June 12
Address.
D Wednesday, June 13 City Phone: Work (
. State. Home (
)-
.ZIP.
D Thursday, June 14
)-
D Single occupancy ($17/night) D Double occupancy ($11/night)
Admission to sessions and social events will be by badge only. Registration Fee
Advance On-Site
D ACS member
Desire free bus transport to banquet: DYes DNo
Roommate name: Please assign me a roommate: D Yes D No
$40
$65
D Nonmember
50
75
I plan to attend the June 13 Mixer:
G Student
10
15
DYes DNo
Total enclosed: $_
10
15 15
Make hotel reservations directly with the University Park Hotel, 500 South Wakara Way, Salt Lake City, Utah, 84108, phone (800) 6374390, at the special meeting rate of $60 (single) and $70 (double). Please state that you are attending the ACS Regional Meeting when making your reservation.
I plan to park on campus.
10
D Teacher (high school) G Retired member
D Rustler Lodge banquet, 20 June 14
25 a
a If available; banquet limited to 140 persons. Total registration and banquet: $
FRIDAY AFTERNOON Room 114 General Session D
BIOCHEMISTRY & MEDICINAL CHEMISTRY
Total housing: $
.days.
Return this form no later than May 15 with a check for the total amount payable to ACS Northwest Regional Meeting to: Sean O'Connor, M/S C-1, Hercules Inc., P.O. Box 98, Magna, Utah 84044
THURSDAY MORNING & AFTERNOON Room 115
FRIDAY MORNING Room 101 General Session
Symposium on Targeted Drug Delivery R. J. Hurtubise, Presiding 1:30—81. Optically Controlled Ligand Delivery 1. Copolymers Containing 2-Nitrobenzyl Bonds. H.-R. Yen. J. D. Andrade. J. Kopecek 1:55—82. Optically Controlled Ligand Delivery 2. Copolymers Containing a-Methylphenacyl Bonds. H.-R. Yen, J. D. Andrade, J. Kopecek 2:20—83. Direct Transfer Line GC/MS Anal· ysis of Incomplete Combustion Products from the Incineration of Medical Wastes and the Thermal Treatment of Contaminated Soils. W. H. McOennan, N. S. Arnold, S. N. Sheya, J. S. Lighty, H. L. C. Meuzelaar 2:45—84. Quantitative Determination of Three Mineral Concentrations in 8 ANL Coals. I. Bae, F. Khayat, J. Cleverly. H. Huai, J. DuRow 3:10—85. Whole Column Detection: Appll· cation to Preparative-Scale Liquid Chromatography. K. L. Kelly. J. W. Birks 3:35—88. Interactions in Normal-Phase High-Performance Liquid Chromatography via Ultraviolet Spectroscopy. L. D. Olson, R. J. Hurtubise 4:00—87. HPLC-FTIR by Concentration Flow Nebulization. A. J. Lang. P. R. Griffiths 4:25—88. Variable Capacity Columns for Gradient Elution Anion Chromatography Based on Macrocyclic Complexes. P. A. Drake. K. Woolley. J. D. Lamb
58 April 23, 1990 C&EN
W. S. Caughey, Presiding
N. D. Heindel, Organizer, Presiding W. S. Caughey, Chairman WEDNESDAY MORNING & AFTERNOON Room 116 Terpene Biosynthesis Symposium
C. D. Poulter, Presiding 9:00—Introductory Remarks. C. D. Poulter 0:05—89. Gernarylgeranylcysteine Is a Component of Prenylated Proteins. H.C. Rilling, D. C. Lever, W. W. Epstein 10:00—90. Stereochemistry of Proton Elimination in Terpene Biosynthesis. R. Coates, H. Pyun, P. Chakraborty 11:00—91. Metabolism of Monoterpenes. R. Croteau
W. W. Epstein, Organizer, Presiding 2:00—92. IPP Isomerase, Mechanism and Stereochemistry for the Yeast Enzyme. C. D. Poulter, I. P. Street, D. J. Christensen 3:00—93. D NMR-NA Studies of Irregular Monoterpenes: Chrysanthemol and Lyratol. M. F. Leopold, A. Edison, M. Klobus, D. M. Grant, W. W. Epstein
9:00—Introductory Remarks. N. D. Heindel 9:10—94. Potential of Water-Soluble Polymers in Targeted Drug Delivery. J. Ko9:55—95. Nuclear Imaging of Hypoxia. J. R. Grierson, J. E. Biskupiak, K. A. Krohn, J. S. Rasey 10:40—98. Application of Nuclear Imaging to Drug Discovery and Development. H. D. Bums, R. E. Gibson, H. F. Solomon 11:25—97. Therapeutic Targeting with Drug-Polymer-Antibody Conjugates. N. D. Heindel. H. Zhao. R. A. Bender. J. H. Abel H. D. Burns, Presiding 1:30—98. Radiohalogen Labeling of Monoclonal Antibodies for Application to Cancer Therapy. D. S. Wilbur. S. W. Hadley 2:15—99. Attaching Macrocyclic Chelates to Monoclonal Antibodies. C F . Meares, T. Rana, M. Studer, H. Diril. D. Kukis. M. McCall 3:00—100. Porphyrins and Metal loporphyrins as Site-Selective Agents. J. A. Mercer-Smith, D. A. Cole. J. K. Norman. S. A. Schreyer. J. C. Roberts. R. Fawwaz. D. K. Laval lee 3:45—101. Antibody-Mediated Drug Delivery: Comparison of Random versus SiteSpecific Antibody Modification Techniques. J.C. Roberts, Y.A. Adam, J. A. Mercer-Smith, D. K. Lavallee 4:15—102. Liposome Medicated Drug Delivery. S. M. Sullivan
8:55—Introductory Remarks. W. S. Caughey 9:00—103. In-Situ Scanning Tunneling Ml· croscopy Studies of Deoxyribonucleic Acid. C. E. Rabke. T. P. Beebe Jr. 9:20—104. Molecular Packing Studies of the Purine Bases of Deoxyribonucleic Acid by Scanning Tunneling Microscopy. C. E. Rabke. T. P. Beebe Jr. 9:40—105. Stable and Nonmetabolizable CGlycosylphosphonyl Analogs of 5Phosphorylribose 1-a-Diphosphate (PRPP) that Act as Inhibitors of Orotate Phosphoribosyltransferase (OPRTase). R.W. McClard, J. F. Witte 10:00—108. Building Blocks of Protein Structure. S. Wherland, R. Unger. D. Harel, J. L. Sussman 10:20—107. Carbon Monoxide and Oxidation State Induced Modifications of the Secondary Structure of Cytochrome c by Infrared Spectra. A. Dong. P. Huang. W. S. Caughey 10:40—108. Enzymatic Activity of Polyethylene oxide) Modified towards Low- and High-Molecular-Weight Substrates. P. Kopsckova. H.-C. Chiu, S. Zalipski. J. Ko11:00—109. Susceptibility of Zymogens Adsorbed at Solid-Liquid Interfaces to Enzymatically Catalyzed Hydrolysis. S. Oscarsson, J. Kopecek 11:20—110. Increased Oxyradical and Peroxide Production from Autoxidations of Myoglobin and Hemoglobin under Conditions of pH and p0 2 Found in the Ischemic Heart. M. R. Gunther, V. Sampath, W. S. Caughey
11:40—111. Effect of Chelators on the Re activity of Crocktolite Asbestos. L.G. Lund, A. E. Aust 12:00—112. Dye-Ligand Chromatography and Immobilized Metal Ion Affinity Chro matography (IMAC): Tools for Purification of Enzymes of Prenyl Pyrophosphate Me tabolism. N. Lanznaster, R. Croteau
CHEMICAL EDUCATION
WEDNESDAY MORNING Room 115 Computer Gestion W. D. Smith, Presiding 9:00—Introductory Remarks. W. D. Smith 9:05—113. Using Animation Software To Il lustrate Dynamic Events. E. R. Mat|eka 9:30—114. Computer-Assisted Coulometric Titration for the Quantitative Analysis Lab oratory. R. K. Behm 10:00—115. Calmodulin as the Prototypical Protein; Analysis via Desktop Computer Molecular Modeling. E. K. McGoran, A. K. Hanson 10:30—116. Interactive Organic Nomencla ture Software. K. W. Raymond 1 1 : 0 0 — 1 1 7 . Contemporary ProblemSolving Techniques. O.J. Parker, G.L. Breneman 11:30—118. Computer Program To Aid in Laboratory Hazardous Waste Manage ment. D. L. Hertlng WEDNESDAY AFTERNOON Room 115 General Session W. D. Smith, Presiding 2:00—Introductory Remarks. W. D. Smith 2:05—119. A Day at the Blackboard. M. B. Jones 2:30—120. Isomerization of Dimethyl Maleate to Dimethyl Fumarate. C.B. Fryhle, C. M. Rybak 3:00—121. Organizing and Operating a Summer Science Camp for Elementary Students. R. A. Hermens 3:30—122. Whole-School Approach to Hands-on Science in the Elementary Grades. G. D. Mercer, L. M. Mercer, G. J. Kaytor
10:00—126. Complexes of the Formula (Ph3P)aCuFeX4. D. J. Satumbio 10:20—127. Synthesis and Chemistry of Polyfluoroalkyl Tetrazenes. G. Sarwar, R. L. Kirchmeier, J. M. Shreeve 10:40—128. Synthesis and Characterization of a Series of Osmium(ll) Complexes In corporating Polypyridyl Bridging Ligands. M. M. Rlchter, K. J. Brewer 11:00—129. Carbonyl Difluoride: Reactions with Metal-Phosphine Complexes. O. D. Gupta, R. L. Kirchmeier, J. M. Shreeve 11:20—130. Models of Vitamin Be: Acid Range Catalysis of Glycyl Hydrogen Ex change in Sodium bis(Pyridoxylideneglycinato)Cobaltate(lll). J. R. Fischer, E. H. Ab bott 11:40—131. Nucleophilic Substitution Re actions of Polyfluoroalkyl Sulfonamide An ions. C.-Y. Guo. R.L. Kirchmeier, J.M. Shreeve 12:00—132. Volumes of Activation for Electron Transfer between a Series of Co balt Clathrochelates and Ferrocenes as a Function of Solvent and Added Electrolyte. S Wheriand. M. A. Murguia
THURSDAY AFTERNOON Room 110 General Session Β W. N. Setzer, Presiding 2:00—133. Metal Carbides via Molten Salt Solution Routes. J. F. Davis, G. F. Holland 2:20—134. Acidity Dependence of the Ki netic Deuterium Isotope Effect in the Chromic Acid Oxidation of 2-Propanol: Ca talysis and Cooxidation. C. R. Everett, S. N. Mahapatro 2:40—135. Electronic and Vibrational Spec troscopy of Mononuclear and Dinuclear Polypyrazoylborato and Chloro Mo(V)-Oxo Complexes. S. Lincoln, T. M. Loehr 3:00—136. Structural Characterization and Solution Studies of a Cyclic Vanadium(V) Pinacol Compound. R. A. Felty, D. C. Crans 3:20—137. Directed Synthesis of Nonstoichiometric Metallic Oxides Using a SolidState Electrochemical Cell. J. Lee, G. F. Holland 3:40—138. Synthesis and Complexation Studies of Mesocyclic Trithioethers. W. N. Setzer, G. J. Grant 4:00—139. Validity of the Size Selectivity Rule in Thiophilic Metal lon-Thiocrown Ether Interactions. G. Wu, N. K. Dalley, W. Jiang, R. M. Izatt FRIDAY MORNING
11:00—146. New Catalyst for the Epimerizatkxi of Secondary Alcohols: Unusual Reac tions of Rhenium Alkoxide Complexes (175C5Rs)Re(NOXPPh3)OCHRR'). I. Saura-Uamas, C. M. Gamer, J. A. Gladysz 11:20—147. Synthesis of BkJentate Halophosphine Rhenium Complexes. J. G. Morse. J. L. Hubbard. D. W. Lee 11:40—148. Synthesis and Reactions of Rhenium Alkyl Iodide Complexes [(η6C5H5)Re(NOXPPh3XIR)]+BF4-. A. Igau, J. A. Gladysz 12:00—149. Testing of Rh and Pd Hydrous Titanium Oxide Catalysts for the Dehydrogenation of Methyl eye lohexene. E. P. Boespflug FRIDAY AFTERNOON
T. S. Livinghouse, Presiding
Transition-Metal Organometalllcs Β
9:00—167. Polyene Cyclizations Mediated by Boron Complexes. S. R. Harrlng, T. S. Livinghouse 9:20—168. Group IV Imido [2 -I- 2] Cy cloadditions onto Alkynes. P. L. McGrane, M. D. Jensen, T. S. Livinghouse 9:40—169. Platinacycles as Stable Interme diates in Organic Synthesis. F. F. Stewart, P. W. Jennings 10:00—170. Mechanism of Platinum(ll) Cat alyzed Hydration of Alkynes. W.C. HIscox, P. W. Jennings 10:40—171. Reactions of Cyclopropenones with Rhodium Complexes. L. Song, P.J. Stang 11:00—172. Mechanisms of Metal-Cata lyzed Carbalkoxylation of Organic Electrophiles. Z. Zhong, P. J. Stang 11:20—173. Reactivity of 3-O-Allyl Hexose Derivatives with [(PPh^]. K. P. Gable 11:40—174. Use of CREN as a Relaxation Agent for C-13 NMR Analyses of Kraft Black Liquor Organics. K. P. Wilson, M. L Laver, W.J. Frederick Jr.
Μ. Ε. Wright, Presiding 2:00—150. Bridged bis(Pentadienyl) Metal Complexes. W.-Q. Weng, R. D. Ernst, A. M. Arif 2:20—151. Chiral Polyarylcyclopentadienyls: Novel Ligands for Asymmetric Catal ysis. J. Ramsden, C. White 2:40—152. Synthesis and Reactivity of (Pentamethylcyclopentadienyl)lridium bisThiolate and (Thiolate)Hydride Complexes. D.P. Klein, G. M. Kloster. D.A. Dobbs. R. G. Bergman 3:00—153. Metal-Promoted Binuclear O H Activation of Ethylene and Formation of a Novel Heterobimetallic Ir-Pt Complex. Y.H. Huang, P. J. Stang 3:20—154. Metal-Assisted Arbuzov Reac tions of Triallylphosphite. H.L. Ji, J.H. Nelson 3:40—155. Transition-Metal-lnduced Topotactic C-C Bond Formation. W. L. Wilson, J. H. Nelson 4:00—156. C-H Bond Activation and C-C Bond Formation Induced by Electron Transfer. C. Roger, C. Lapinte 4:20—157. Oxygen Atom Transfer Reac tions of the Nitro/Nitrito Linkage Isomers fa6-C5H5)Cr(NO)2-N02 and ft5-C5H5)Cr (NO)2-ONO. J. L. Hubbard, W. L. Eteesser 4:40—158. Electron Self-Exchange of Hexakis(2,6-Diisopropylphenyl Isocyankte) Chromium (O.l) and Chromium (I,II) in Non aqueous Solvents. K. A. Anderson, S. Wheriand
ORGANIC CHEMISTRY
J. S. Bradshaw, Chairman
J. L. Hubbard, Presiding
INORGANIC
J. L. Hubbard, Chairman THURSDAY MORNING Room 110 General Session A R. L. Kirchmeler, Presiding 9:00—123. Synthesis and Structures of New Borophosphanes. D. Dou, W. Westerhausen, E.N. Duesler, R.T. Paine 9:20—124. N-MethylmorphoHne Carbamoryboranes: Synthetic Approaches and Re activity. D. A Feakes. K. W. Morse 9:40—125. Reactions of Per- and Polyfluoroazaalkenes with Silylated Nucleophiles. N. R. Patel. R. L. Kirchmeier, J. M.
9:00—140. Metals and Organometallic Complexes of NF2 Containing Tetrazoles. E. O. John, R. L. Kirchmeier, J. M. Shreeve 9:20—141. New Carbon-Hydrogen Bond Activation Reaction: "Vinylic" Deprotonation of Cationic Rhenium Alkene Complex es. T.-S. Peng, J. J. Kowalczyk, J. A. Gla dys* 9:40—142. Reaction Chemistry of Tungsten (II) Halides. T.G. Richmond, M.J. Poss, M.A.King, A.M. Arif 10:00—143. Rhenium Alkylidene and Bridg ing bis-Alkylidene Complexes: Synthesis and Thermal Decomposition. C. Roger, G. S. Bodner, J. A. Gladysz 10:20—144. New Syntheses and Reactions of Rhenium AcetylkJe Complexes (η6C5Hs)Re(N0XPPh3)C = CR). J. Ramsden, F. N. Agbossou, J. A. Gladysz 10:40—145. Substitution of Carbonyl and T76-C5Me5 Ligands Bound to Re(l): the Re activity of fo5-C5Me5)Re(CO)2NO+ with Halides and the Reactivity of ft5C5Me5)Re
