Colored Diamonds - Industrial & Engineering Chemistry (ACS

May 18, 2012 - Colored Diamonds. Ind. Eng. Chem. , 1960, 52 (11), pp 42A–42A. DOI: 10.1021/i650611a736. Publication Date: November 1960. Copyright ...
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VISCOSITIES SLOWING YOU UP?

blankets, saddle pads, or warm-up bandages, M r . Fitz is all for trying. Grooms may never learn to call it polyurethane, but they agree that there is something to be said for a durable and all-but-weightless material, unaffected by acids, alcohols, and liniments, that can be washed and re-used again and again. " N o point of hanging on to the old way of doing things, just because it is the old way," so says M r . Fitz, who is approaching his 86th birthday.

SEDIMENTATION GETTING YOU I DOWN?

Colored Diamonds

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INDUSTRIAL A N D ENGINEERING CHEMISTRY

REPORTS

IB#IAMONDS are generally considered to be clear crystals. But since 1900 almost everyone has devised a coloring technique, largely based on radiation and exposure to modestly high temperatures. For the last 60 years it has been a real snap to make yellow, or brown-green crystals with 10-hour radium irradiation treatments. They have also been made brownred, brown, or brown-green with 1200-hour irradiation. These coloring methods are generally conceded to be results of complex Frenkel defects. It is now possible by using radiation and higher temperature to produce a single Frenkel defect in the actual diamond lattice. This produces a pure blue color which is more than a surface effect and cannot be removed by polishing or grinding. In the past, alpha particles have been responsible for the surface color change, but it is now possible to use gamma rays. Energies of about one million electron volts and above with an integrated flux of about 10 to 20 gamma rays per sq. cm. are used. Several years' irradiation would, however, be required to obtain this flux from known gamma rays sources such as cobalt 60 or a Van der Graaf machine with a suitable target. Now that new techniques have been developed from radiation, no telling what may be done with cheaper starting materials.