Pittcon 94 Feb. 27-March 4,1994 Chicago, IL | Analytical Chemistry

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illing itself as "The Greatest Sci;nce Show Ever," the 45th Pitts­ burgh Conference and Exposi­ tion on Analytical Chemistry and Applied Spectroscopy will convene Feb. 27March 4 at Chicago's McCormick Placeon-the-Lake Convention Center. Pittcon will celebrate its 45th anniversary by look­ ing back on the scientific progress made since the first conference in 1950 and by looking forward to tomorrow's scientific challenges. This year's technical program is scheduled to include 40 symposia, more than 1350 contributed papers and poster sessions, six workshops, and two plenary sessions dealing with scientific literacy and the synergy between analytical chem­ istry and the Pittsburgh Conference. Highlights will include sessions devoted 126 A

to emerging scientists and pioneers in analytical chemistry; memorial symposia for I. M. Kolthoff and Wilhelm Simon; a session providing a CEO's perspective on the future of analytical instrumentation; the Waters symposium, devoted this year to MS; a tribute to William G. Fateley in recognition of his tenure as Editor of Applied Spectroscopy; nine award presenta­ tions; and miniconferences in the fields of bioanalytical chemistry, process analytical chemistry, and quality assurance. The Exposition of Modern· Laboratory Equipment will be held Monday through Friday in the East and North Exhibit Halls and will feature more than 1000 exhibitors in more than 3000 booths displaying the latest in analytical laboratory instrumenta­ tion, equipment, supplies, and services. Organizers have also arranged an Antiqui­

Analytical Chemistry, Vol. 66, No. 3, February 1, 1994

ties Display Museum in the East Hall. This special exhibit will include histori­ cally significant analytical instrumenta­ tion, such as early pH meters, single- and double-beam IR instruments, chromatographs, and mass spectrometers; a labora­ tory of the 1950s; and a visual display of the history of analytical chemistry. On-site registration for conferees, stu­ dents, and family program participants will take place at both the East and North Halls of McCormick Place. Hours are Sun­ day, Feb. 27, from 10 A.M. to 7:30 P.M.; Monday, Feb. 28, from 7:30 A.M. to 5 P.M.; and Tuesday, March 1, through Thursday, March 3, from 8 A.M. to 5 P.M. Fees are $100 for conferees and for family program participants and $15 for students. Special conference rates for hotel ac­ commodations and airline flights can be

Technical Sessions

Monday Morning Symposium: Pioneers of Analytical Chemistry Analysis of Mercury and Other Environmentally Important Elements Computer-Based Solutions to Problems in Analytical Chemistry Materials Characterization: Polymers, Composites, and Inorganics Specialty Gas Analysis Monday Afternoon Symposium: Applications of Synchrotron Radiation in the Chemical Sciences Symposium: Emerging Scientists Fuels and Energy: New Solutions to Old Problems Polymer Analysis—Separation and Detection Surface Analysis and Microscopy Tuesday Morning Advances in Thermal Analysis Tuesday Afternoon Plenary Session: The Codevelopment of Analytical Chemistry and the Pittsburgh Conference, 45 Years and Beyond Quality Miniconference: The ISO 9000 Series and Global Harmonization of Standards Symposium: The Future of Analytical Instrumentation—A CEO's Perspective Computers in Chemistry—LIMS Process Analytical Chemistry Miniconference: Controlling Recycling Processes with Process Analytical Instrumentation Environmental Sensor Developments Environmental Laboratory Issues Wednesday Morning Process Analytical Chemistry Miniconference: The Role of the Analytical Laboratory in Process Analysis Workshop: Image Processing for the Scientific Community Panel Discussion: Automated Sample Preparation in the Laboratory Chemometrics I Environmental Analysis: Radioactive Species and Field Methods SAM, SLM, AIM, and DIM: A New Paradigm for Laboratory Automation

Wednesday Afternoon Plenary Session: Scientific Literacy: What It Is, Why We Don't Have It, and How We Can Get It Quality Miniconference: Laboratory Accreditation Chemometrics II Environmental Problems in Soil, Groundwater, and Seawater Process Analytical Chemistry Miniconference: Process Control Applications Standards for Automating the Analytical Sciences I Thursday Morning Symposium: Analysis of Environmental Biohazards Process Analytical Chemistry Miniconference: Transferring Analytical Technology from the Laboratory to the Plant Industrial Hygiene Air-Monitoring Techniques Pharmaceutical Analysis Quality Miniconference: Quality Systems and LIMS-Aided Quality Control Standards for Automating the Analytical Sciences II Thursday Afternoon Symposium: Indoor Air Measurements Process Analytical Miniconference: Fiber-Optic Probes for IR Process Analysis/Environmental Monitoring by IR Spectroscopy Workshop: Lead Laboratory Accreditation Quality Miniconference: Managing Quality in the Pharmaceutical Industry Process Analytical Chemistry Miniconference: Portable Instrumentation for Process Measurements Sample Preparation-Waste Characterization Using Microwave Technology Microwave Sample Preparation Techniques Friday Morning Symposium: Advances in Environmental Remediation Workshop: Cooperation on International Traceability in Analytical Chemistry (CITAC) Workshop: Detection/Quantitation Definitions and Issues

Bioanalytical Chemistry Miniconference: Capillary Electrokinetic Methods Bioanalytical Chemistry Miniconference: Food Analysis Tuesday Morning Symposium: Bioanalytical Chemistry Miniconference: On-Line Process Analysis on the Micron Scale Bioanalytical Chemistry Miniconference:Environmental Analysis, Including Immunoassay HPLC—Bioanalytical Tuesday Afternoon Bioanalytical Chemistry Miniconference: Pharmaceutical Analysis Bioanalytical Chemistry Miniconference: Interfaces, Colloids, and Luminescence Wednesday Morning Symposium: Near-IR Medical and Biomedical Applications Bioanalytical Chemistry Miniconference: Biological Applications of MS Bioanalytical Chemistry Miniconference: Pharmaceutical Analysis Wednesday Afternoon Bioanalytical Chemistry Miniconference: Answering Biochemical Questions Bioanalytical Chemistry Miniconference: Microbioanalytical Chemistry Thursday Morning Bioanalytical Chemistry Miniconference: Separations and Detectors Thursday Afternoon Bioanalytical Chemistry Miniconference: Clinical Analysis

Monday Morning Electrochemistry: Coupled with Spectroscopy or Chromatography Monday Afternoon Electrochemistry: Characterization of lectrochemistry: Ch Electrode Processes

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Tuesday Morning Symposium: I. M. Kolthoff Memorial Symposium

Monday Morning Bioanalytical Chemistry Miniconference: Bioanalytical Techniques for Food Safety and Environmental Monitoring Bioanalytical Chemistry Miniconference: Sensors Monday Afternoon Bioanalytical Chemistry Miniconference: Chemical Sensors: A Tribute to Wilhelm Simon

Tuesday Afternoon Symposium: I. M. Kolthoff Memorial Symposium Electrochemistry: Bioelectrochemistry Wednesday Morning Symposium: Charles N. Reilley Award Wednesday Afternoon Symposium: Chemical Sensors for In Vivo Monitoring Symposium: Molecular-Scale Probes of Electrode Interfaces

Analytical Chemistry, Vol. 66, No. 3, February 1, 1994 127 A

PITTCON U Thursday Morning Electrochemistry: Modified Electrodes Friday Morning Symposium: Electrochemistry: Sensors and Voltammetry

Monday Afternoon CE GC: Pesticide Analysis Ion Chromatography Pharmaceutical Analysis Using HPLC SFE in Environmental Analysis Tuesday Morning GC: Fuels and Energy GC: Multidimensional GC: New and Novel Techniques and Instrumentation Instrument Development/Improvement: Chromatography SFE in Pharmaceutical Products, Petroleum Hydrocarbons, and Polymers

Monday Morning Symposium: New Approaches to Elemental MS—Innovations in Ion Sources and Mass Analyzers Symposium: Surface MS—Probing RealWorld Samples Monday Afternoon Symposium: James L. Waters 5th Annual Symposium Recognizing Pioneers in the Development of Analytical Instrumentation—MS Tuesday Morning Symposium: FTMS of Biomolecules Air Analysis/APIMS ICPMS—Instrumentation and Applications Tuesday Afternoon Symposium: Pittsburgh Analytical Chemistry Award GC/MS Instrumentation—Air Analysis Wednesday Afternoon Symposium: Low-Energy Ion Surface Collisions (Surface-Induced Dissociation) Thursday Morning Symposium: Environmental MS Bio/Polymer MS—Ion-Molecule Reactions Thursday Afternoon LC/MS and Electrospray Friday Morning Symposium: Ion Trap MS/SIMS

Monday Morning Environmental and Pesticide Analysis by HPLC Extraction Methods in Environmental Analysis GC/MS GC: Purge-and-Trap Analysis Sample Handling in SFE

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Tuesday Afternoon GC Columns Wednesday Morning Symposium: Chiral Separations Symposium: Dal Nogare Award GC: Detectors GC/MS: Environmental Analysis HPLC: Automation and Software Applications Novel Separation Techniques Wednesday Afternoon Symposium: Mechanisms in SFE GC: Food and Fragrance Analysis SPE Methodology Thursday Morning Symposium: Advances in Purge-and-Trap GC Methods for the Analysis of VOCs Down to 0.1 ppb GC: Injection Techniques and Optimizing Performance Food Analysis Using HPLC Thursday Afternoon Symposium: Keene P. Dimick Award Countercurrent Chromatography GC: Volatile Organic Analysis I HPLC: Detectors Friday Morning Workshop: Field Water Sampling Using In Situ SPE GC: Volatile Organic Analysis II Symposium: HPLC-Columns Symposium: Separations by CE

Monday Morning Symposium: Williams-Wright Award Instrument Development/Improvement: Spectroscopy Recent Advances in Fluorescence and Luminescence

Analytical Chemistry, Vol. 66, No. 3, February 1, 1994

Monday Afternoon Symposium: The Direct-Reading Polychromator—45 Years Later ICPMS Matrix Effects and Instrumental Optimization Mid-IR I: Photoacoustic and Reflection Spectroscopy Spectroscopic Investigation of Biological Systems Kinetic Problems in Spectroscopy Tuesday Morning Symposium: 1994 Pittsburgh Spectroscopy Award Mid-IR II: Analysis of Gases Novel Plasma Sources for Atomic Spectroscopy Spectroscopic Solutions to Environmental Problems Tuesday Afternoon Array Detectors and Spectrometer Improvements for ICP-AES New Developments in Spectroscopic Instrumentation GC/Atomic Emission Detection Mid-IR III: Microspectroscopy New Dimensions in Spectral Data Interpretation Wednesday Morning Graphite Furnace Analysis Methods Mid-IR IV: Various Topics Wednesday Afternoon Symposium: Bomem-Michelson Award Process Analytical Chemistry Miniconference: Near-IR Spectroscopy— The Ultimate Process Monitor? Atomic Absorption and Atomic Fluorescence Probes and Modifiers in Fluorescence Spectroscopy Raman I: Near-IR Thursday Morning Symposium: A Tribute to William G. Fateley on the Occasion of His Retirement as Editor of Applied Spectroscopy X-ray Fluorescence Near-IR I Thursday Afternoon Symposium: Recent Advances in Fluorescence Spectrometry Spectrochemical Imaging: Advances in Raman, Near-IR, and Fluorescence Microscopy Hyphenated Sample Introduction Techniques for ICP Analysis Mid-IR V: Various Topics Near-IR II Raman III Friday Morning Symposium: Advances in Raman Spectroscopy. Symposium: Direct Elemental Analysis of Solids and Gases Mid-IR VI Near-IR III (Tomas Hirschfeld Award)

obtained by contacting the Executive Transportation and Accommodations (ETA) service of the Chicago Convention and Tourism Bureau (800-945-7488; 312567-8507; fax 312-567-8577). Continuing education has always been an important component of Pittcon, and this year is no exception. Three organiza­ tions are offering short courses: the Amer­ ican Chemical Society (48 courses), the Pittsburgh Conference (43 courses), the and the Society for Applied Spectroscopy (5 courses). For additional information, see pp. 132 A 136 A and 145 A or consult the preliminary program. An employment bureau will be avail­ able to conferees and exhibitors during the meeting. Located on Level 2 of the East Hall, the bureau will be open Sunday afternoon through Thursday afternoon. Job candidates and employers who have not preregistered should register on site with the bureau Sunday or Monday. Conferees who bring their families to Pittcon will find a variety of activities avail­ able. Child care and activities for children ages 3 months to 12 years will be available in the Hyatt Regency Hotel. Provided by Accent on Arrangements, a full-day Con­ vention Camp program includes meals, entertainment, and age-appropriate activi­ ties under the supervision of trained pro­ fessionals. Care is also available on an hourly basis with a three-hour minimum. For more information and a registration packet, contact Accent on Arrangements, 938 Lafayette, Suite 410, New Orleans, LA 70113 (504-524-1227). The family program, which will oper­ ate from a hospitality suite located in the Hyatt Regency Hotel, has planned activi­ ties that include craft classes, tours of the Art Institute and the Museum of Science and Industry, presentations on science in the kitchen by Harold McGee and science by Bassam Shakhashiri, and shopping at North Pier. Mixers are scheduled for Sunday night at McCormick Place and Tuesday night at the Field Museum. Admission is free to all conferees who present their badges. For additional information about any aspect of the conference or exposition, contact the Pittsburgh Conference Office, 300 Penn Center Blvd., Suite 332, Pitts­ burgh, PA 15235-5503 (800-825-3221; 412825-3220; fax 412-825-3224). The technical program begins on p. 131A The New Products section (p. 182 A) features instruments and other products that will be introduced at the conference.

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Analytical Chemistry, Vol. 66, No. 3, February 1, 1994 129 A

PITTCON 9:30 9:50 10:25 10:45 11:05 11:25

11:45

(049) Automated Dissolution System Re­ ports. T. A. Rooney, C. W. Crandell (050) Automated Structure Elucidation Based on Spectroscopic Data. R. Neudert (051) Understanding Isomerization in the Cyanines: The Importance of Steric Fac­ tors. K. McCarthy, G. J. Blanchard (052) How "Good" are Routine NMR Spectra? First Impressions from a Round Robin Test. M. Grzonka, A. N. Davies (053) Speciation of Lead in Water by Computer Simulation. S. Ren, L. Gao (054) Use of Artificial Intelligence in the Experimental Design and Optimization Quantitative Methods Using Vibrational Spectroscopy Data. M. P. Fuller, R. C. Weiboldt (055) Application of Modified Statistical Model of Overlap to Gas Chromatograms Having Variable Peak Densities. J. M. Davis, M. Johll

Materials Characterization: Polymers, Composites, and Inorganics Lenox Lohr Theatre, East Hall R. Grab, Presiding

Technical Program

8:30

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Monday Morning Symposium: Pioneers of Analytical Chemistry (Arrangea by K. J. McKaveney) Earl McMahon Room A, East Hall J. L. Waters, Presiding Introductory Remarks. K. J. McKaveney (011) Reflecting on the Past; Creating for the Future. H. V. Malmstadt 9:10 (012) Tales of a Reluctant Instrument Maker. J. Lovelock 9:45 (013) The First 50 Years of Commercial IR—and Beyond. P. Wilks 10:35 (014) Laser-Based Chemical Analysis. R. N. Zare 11:10 (015) Highways and Byways in MS. K. Biemann

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A n a l y s i s of M e r c u r y a n d O t h e r Environmentally Important Elements David Mayer Theatre, East Hall J. Paterson, Presiding 8:30 8:50 9:10

(026) Determination of Mercury at Ultratrace Concentration. S. A. Jankowski, R. J. Gill, T. Gerdei (027) Improving Mercury Detection Limits Using a Dedicated Flow Injection System. S. Mcintosh, J. Baasner, C. Hanna (028) Development of a Simple Trap To

11:25 11:45

Remove Acetate Interference for Mercury Determination in TCLP Leachates. J. S. Thompson, D. J. Hassett (029) On-Line Analysis of Total Mercury Levels in Plant Applications by Atomic Fluorescence. P. B. Stockwell W. T. Corns, J. Cloud (030) Atomic Fluorescence/Gold Amal­ gamation Techniques for the Determina­ tion of Environmental Mercury. W. H. Kammin R. Knox, J. Ross, D. Thomson (031) Use of Atomic Fluorescence Detec­ tors as Specific Detectors for Mercury, Arsenic, and Selenium Speciation. P. B. Stockwell, W. T. Corns (032) Comparative Evaluation of Extrac­ tion Procedures To Determine the Mobility of Selenium in Sediments. C. M. Lillemoen, U. J. Hassett (033) Survey of Lead in Environmental Matrices by Atomic Spectroscopy Tech­ niques. Z. A. Grosser (034) Intelligent Automation of the EPA QA/QC Procedure for Inorganic Analyses. K. L. Seace, D. Plat, S. G. Hurt (035) Closed-Vessel Extraction Proce­ dure for Trace Metals from Airborne Par­ ticles Collected on Quartz Fiber Filters. D. Hobro, E. Fumal, R. J. Carley

Computer-Based Solutions to P r o b l e m s in A n a l y t i c a l C h e m i s t r y R o o m 20W2, East Hall B. Megargle, Presiding 8:30

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Specialty Gas Analysis R o o m M1A, North Hall J. D. Hogan, Presiding 8:30

(046) Using a Windows-Based Database for Review and Management of HPLC Data Acquisition System Results. S. Maykowski, R. Giuffre (047) Automatic, Interactive System Suit­ ability in a PC-Based HPLC System. T. A. Rooney, L. White, C. Chell (048) Software Design Considerations for a New Approach to HPLC System Com­ munication. D. M. Fan, J. A. Schibler

Analytical

(105) Effect of Aging on the Enthalpic Relaxation of Amorphous PET. S. R. Sauerbrunn, R. L. Blaine, J. A. Foreman (106) Effect of Temperature on Monomer Production of Polymer Pyrolysis. I. P. Wampler, M. J. Matheson (107) Relating TG/IR and GC/IR Informa­ tion Using Least-Squares Curve Fitting. B. J. McGrattan (108) How Much Disorder Can Monomers Induce in a Polymer? G. J. Blanchard, L. DeWitt (109) Linear Dichroism for Determining the Molecular Orientation of Planar Macrocycles. K. F. Stork, H. Chou, P. W. Bohn, K. S. Suslick, J. S. Moore, C. T. Chen, J. Zhang (110) Fluorescence Characterization of Thermal Damage in Fiber-Reinforced Polymer-Matrix Composites. W. G. Fisher, Ε. A. Wachter, C. J. Janke, G. L. Powell (111) Structure and Reactivity of Nanoscale Platinum Clusters in Synthetic Glassy Carbon Matrix. W. Huang, O. Schueller, H. Hutton, M. Callstrom, R. L. McCreery, P. Allen, M. Wilson, S. Conradson (112) Thermal Conductivity of Polymers, Glasses, and Ceramics by Modulated DSC. R. L. Blaine, S. M. Marcus (113) Studies of Structure and Trans­ parent Conductive Property Doped Oxide Films by XRD and UV Absorption Spec­ tra. Z. Tan, P. Ren, W. Luo (114) IR Spectroscopy Studies of Laser Annealing a-Si:H Films. P. Ren, W. Luo, Z. Tan

8:50

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Chemistry,

(135) On-Line Determination of Moisture in HCI. R. T. Talasek, J. D. Hogan (136) Pulsed-Discharge Helium Ionization Detector for Analysis of Permanent Gases. J. V. Madabushi, S. D. Stearns, W. E. Wentworth (137) Analysis of Liquid-Phase Tungsten Hexafluoride Residue by ICPMS with Ultrasonic Nebulization. R. L. Sutton

Vol. 66, No. 3, February

1, 1994

131 A

PITTCOH\ 9:30

(138) Gas Analysis by GC/MS: How To Deal with Large-Volume Injections. E. R. Kebbekus 9:50 (139) Moisture Effect and Measurement of Semiconductor Gases. A. F. Amato, Y. W. Chen, Ε. Τ. Flaherty 10:25 (140) Trace-Level Moisture Analysis in Specialty Gases. S. Jhaveri, G. M. Jursich, V. Olchowka 10:45 (141) Determination of Moisture in a Cor­ rosive Gas in the ppb Range Using FTIR. P. B. Henderson, D. L. Grieble

11:05 (142) Analysis of ppb Impurities in HighPurity Gases by GC/MS Using Micropacked Columns. C. J. Meyer, W. M. Geiger, F. Feyerherm 11:25 (143) Determining Limits of Detection in GC for Electronic-Grade Gases. M. L. Markowski 11:45 (144) Analysis of Metallic Contaminants in Inert Semiconductor Process Gases by Direct Inlet Atomic Emission Detection. J. S. McWilliams

Monday Afternoon Symposium: Applications of Synchrotron Radiation in the Chemical Sciences (Arranged by R. F. Hirsch) Lindheimer Room C, East Hall R. F. Hirsch, Presiding 1:30 Introductory Remarks. What Is a Syn­ chrotron and What Do You Do at One? R. F. Hirsch

ACS Short Courses For more information, contact ACS Short Courses, 1155 16th St., N.W., Washington, DC 20036 (800-227-5558, 202-872-4508; fax 202-872-6336) Activated Carbon Adsorption: Principles and Applications. Feb. 24-25. Milton Manes and Henry Nowicki Making the Right Connections: Understanding Microcomputers and Electronic Instrumentation. Feb. 24-26. Howard Malmstadt, Christie Enke, and Stanley Crouch New Sample Preparation Methods for Chemical Analysis. Feb. 25-26. Stuart Cram, Steven Hawthorne, and Craig Markell Analytical Methods for Proteins. Feb. 25-27. Robert Copeland Applied Optical Microscopy for Chemical Scientists. Feb. 25- 27. Barbara Foster, Mary McCann, and Jan Hinsch Experimental Design for Productivity and Quality in R&D. Feb. 25-27. Stanley Deming and Stephen Morgan On-Line Process Analyzers: The Key to Maximizing Industrial Process Efficiency. Feb. 25-27. Kenneth J. Clevett X-Ray Fluorescence Spectrometry. Feb. 25-27. Ronald Jenkins and John Crake Analytical FT-IR Spectroscopy: Techniques, Applications, Computer Methods. Feb. 26-27. Howard J, Sloane and John Coates Air Toxics Analysis by U.S. EPA Methods. Feb. 26-27. William T. Winberry and Reinhold Rasmussen Building a Winning Scientific and Technical Team. Feb. 26-27. David E. Gootnick Capillary GC: Techniques and Problem Solving. Feb. 26-27. Milos Novotny and Stuart Cram The Computer-Integrated Technical Center. Feb. 26-27. Raymond E. Dessy Effective Management of Chemical Analysis Laboratories. Feb. 26-27. Claude A. Lucchesi 132 A

Effective Supervision of Scientists and the Technical Staff. Feb. 26-27. Margaret M. Gootnick Environmental Laboratory Data Quality Assurance QA/QC. Feb. 26-27. Henry Nowicki and William Purves Environmental Law and Regulations. Feb. 26-27. J. Herbert O'Toole and Marcus Cooke Electrochemical Sensors and Detectors. Feb. 27. Joseph Wang Essentials of Process Validation. Feb. 27. Robert Nash GC/MS. Feb. 26-27. J. Throck Watson and O. David Sparkman Good Laboratory Practices and ISO 9000 Standards: Quality Standards for Chemical Laboratories. Feb. 26-27. Owen Mathre, Aldos Barefoot, and Oliver Hunt Laboratory Information Management Systems: From Problem Definition to System Evaluation. Feb. 26-27. Gerst Gibbon and Joseph Golden Laboratory Waste Management. Feb. 26-27. Cynthia L. Salisbury and Russell W. Phifer Light Scattering and the Charac­ terization of Polymers. Feb. 26-27. Philip Wyatt and Patricia Cotts Lotus in the Laboratory: Putting Spreadsheets, Graphics, and Database Management Software to Work. Feb. 26-27. Glenn Ouchi Maintaining and Troubleshooting Chromatographic Systems. Feb. 26-27. M. P. Timothy Bradley Microwave Sample Preparation: Theory and Practice. Feb. 26-27. H. M. Kingston Modern Methods of Particle Size Distribution: Assessment and Characterization. Feb. 26-27. Theodore Provder Modern NMR Spectrometry. Feb. 26-27. Joseph B. Lambert Modern Techniques in GC. Feb. 26-27. Harold McNair, Patrick Sandra, and Carl Cramers Practical Analytical Atomic Spec­ troscopy: AAS, ICP-AES, ICPMS. Analytical Chemistry, Vol. 66, No. 3, February 1, 1994

Feb. 26-27. Theodore Rains and Howard E. Taylor Practical Capillary Electrophoresis. Feb. 26-27. Robert Weinberger Practical Environmental Sampling and Analysis. Feb. 26-27. Lawrence H. Keith Practical HPLC Method Development. Feb. 26-27. J. J. Kirkland, Lloyd R. Snyder, and Joseph L Glajch Practical LC/MS, SFC/MS, and CZE/MS. Feb. 26-27. Jack Henion and David Games Practical Near-IR Analysis. Feb. 26-27. Donald A. Burns, Emil Ciurczak, and Jerome Workman Quality Assurance for Analytical Chemistry. Feb. 26-27. Anthony Rattonetti Quality Management/Quality Assurance in Industry and in the Laboratory. Feb. 26-27. Alan Riga Size Exclusion Chromatography and Related Methods. Feb. 26-27. Theodore Provder Solid-Phase Extraction in Environ­ mental and Clinical Chemistry. Feb. 26-27. E. Michael Thurman, Margaret Mills, and Lynn Jordan Spectroscopic Characterization of Polymers. Feb. 26-27. Jack L. Koenig and Bruce Chase Technical Writing Workshop. Feb. 26-27. Anne Eisenberg Thermal Analysis in Polymer Characterization. Feb. 26-27. Edith A. Turi, Richard P. Chartoff, and Harvey E. Bair Water and Waste Analysis by U.S. EPA Methods. Feb. 26-27. Marcus Cooke and Marvin Miller Winning at Chemometrics. Feb. 26-27. Steven Brown and Barry Lavine Chromatography Data Handling. March 4-5. Glenn Ouchi Chiral Separations by Chromatography. March 4-6. Satinder Ahuja and William H. Pirkle Supercritical Fluid Fractionation/ Extraction/Chromatography. March 4-6. Larry T. Taylor and Angela L. Howard

PITTCOHU 1:45 2:15 2:45 3:30 4:00 4:30

(145) Applications of Synchrotron Radiation in Chemistry. K. O. Hodgson (146) Applications of Synchrotron Radiation in Structural Biology. J. L. Smith (147) Applications of Synchrotron Radiation in Pharmaceutical Research. N. D. Jones (148) Applications of Synchrotron Radiation in Geochemistry. J. V. Smith (149) Applications of Synchrotron Radiation in Polymer Characterization. H. Ade (150) Development of New Instrumentation for Experiments at Synchrotrons. E. M. Westbrook

3:25

Symposium: Emerging Scientists (Arranged by K. J. McKaveney) Earl McMahon R o o m A, East Hall H. Blount, Presiding 1:30 1:35 2:10

2:45

3:35 4:10

Introductory Remarks. K. J. McKaveney (156) Enhancement of Sensitivity and Selectivity at Enzyme-Modified Electrodes. W. G. Kuhr (157) Radio-Frequency-Powered Glow Discharges for Atomic and Molecular Spectroscopy: Operating Characteristics, Figures of Merit, and Future Prospects. R. K. Marcus (158) Developments in Miniaturized Chemical Sensors and the Role of Surface Chemistry. M. D. Porter, C. J. Zhong, S. W. Watson, S. G. Burns, G. J. Bastiaans, M. K. Ho, A. Schwabacher (159) Analysis of Neuropeptides Using Multichannel CE. J. V. Sweedler (160) Surface-Induced Dissociation of Peptides: Energetics and Mechanisms. V. H. Wysocki, J. L. Jones, A. Dongre, A. Somogyi

Barry Miller Charles Ν. Reilley Award

Tuesday Morning 4:25

4:45

R o o m M6A, North Hall G. J. Lynch, Presiding 3:25 3:45

Lenox Lohr Theatre, East Hall G. D. Dupré, Presiding

4:05

1:50

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2:30

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3:25

3:45

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(210) Monitoring of Coal Liquefaction Processes Using Fiber-Optic FT-IR Spectrometry. A. S. Bonanno, M. A. Serio, S. Farquharson, D. S. Pines, K. S. Knight, E. Kroo (211) Characterization of Coal Liquid Samples Using Novel Phase-Resolved Fluorescence Spectroscopic Techniques. J. M. Shaver, L. S. McGown (212) Quantitative Analysis of Unidentified Analytes by HPLC Utilizing Differential Refractive Index Detection: Application to Compound Class Analysis of Liquid Hydrocarbon Aviation Fuels. C. W. Sink, D. R. Hardy (213) Adsorption Effects as Investigated by Inverse LC Techniques. R. C. Striebich, W. A. Rubey, S. D. Anderson (214) Automatic Hydrocarbon GroupType Separation for Fuel Sample Characterization by On-Line LC/GC. F. Andreolini, A. Trisciani, F. Munari (215) Toward a Complete Analysis of Petroleum Product Mixtures by Comprehensive Multidimensional GC. C. J. Venkatramani, J. B. Phillips (216) Characterization of Bioleached Coals by Controlled-Atmosphere Programmed-Temperature Oxidation. R. B. Lacount. W. P. King, D. G. Kern, R. B. Lacount, Jr., T. J. Schroyer, D. K. Walker (217) Analysis of Coal Sulfur Forms Using Thermal Analytical Techniques. J. T. Riley, R. F. Forsythe, B. Wang, D. Zhang, M. Guo, L. M. Lewis

134 A

Analytical

Chemistry,

(218) Quantitative Comparison between ASTM D4815, C-AED, and GC-FT-IR for the Analysis of Oxygenates in Gasoline. V. Giarrocco, B. Quimby, J. Jegla (219) Automated Simulated Distillation Using an Articulated Laboratory Robot. W. F. Berry, V. Giarrocco, W. Schmidt

Polymer Analysis—Separation and Detection

Fuels and Energy: N e w Solutions to Old Problems

1:30

(295) High-Sensitivity FT-IR Microspectroscopy of Dried Sample Droplets on Chalcogenide Fiber Supports. K. Taga, B. Mizaikoff, R. Kenner 3:45 (296) Subnanomole Samples by FT-IR: FT-IR Microscopy or Micro-ATR? J. A. Van Gompel 4:05 (297) Atomic Force Microscopy Investigation of Substrates Pretreated for CVD Diamond Deposition. G. Friedbacher, E. Bouveresse, G. Fuchs, M. Grasserbauer, D. Schwarzbach, R. Haubner, B. Lux 4:25 (298) How To Build a Better PC Using Scanning Probe Microscopy. D. A. Chernoff 4:45 (299) Imaging with a Scanning Tunneling Microscopy Under a Flowing Liquid. J. Noll, M. L. Myrick Poster Sessions for all topics will be held from 9:00 A.M. to 5:00 P.M. in the East Hall (Level 2) and in the North Hall (Level 2 and Room M3).

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4:45

(245) SEC Using Fluidity-Enhanced Liquid Mobile Phases. S. V. Olesik, I. Souvignet, H. Yuan (246) Estimating the Precision of Molecular Weights Determined by Multiangle Light Scattering. D. W. Shortt (247) Separation of Macromolecules by Reversed-Phase LC: Retention Behavior of Poly(L-tryptophan)s and Poly(DL-tryptophan)s. C. Jiang, C. H. Lochmiiller (248) Determination of Degradation Products from Polymer Additives in Polyolefins Utilizing PDA Detection and Particle Beam LC/MS. M. J. Dilts (249) New Dimension in High-Temperature Gel Permeation Chromatography of Polymers. F. P. Warner, S. J. O'Donohue, E. Meehan

Surface Analysis and Microscopy

A d v a n c e s in T h e r m a l A n a l y s i s Room 20W2, East Hall M. Jaroniec, Presiding 8:30 8:50

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R o o m 20W7, East Hall B. Strohmeier, Presiding 1:30

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2:30

2:50

(290) Auger Electron Emission Angular Distributions from Single Crystals and Ordered Thin Films. C. A. Doyle, D. G. Frank, A. T. Hubbard (291) Study of Reaction Mechanism of Benzotriazole on Cuprous Oxide Using Optical and Electron Spectroscopies. S. Lau, Z. Xu, P. W. Bohn (292) Scanning X-ray Analytical Microscope for High-Precision Element Analysis. Y. Hosokawa, K. Kashihara, G. Setou, O. Sumito, H. Kawahara, H. Nakazawa, S. Shimomura (293) Assessing the Relationship between the Effectiveness of Freon-Substitute Cleaners and the Adhesion of Metal-Epoxy Interfaces. E. Francisco, J. Domingue (294) Biomedical Applications of IR and Raman Microscopy. V. F. Kalasinsky, J. A. Centeno, F. B. Johnson, J. L. Luke

Vol. 66, No. 3, February 1, 1994

11:45

(321) Single-Run Heat Capacity Measurement Using Oscillating Differential Scanning Calorimetry. W. J. Sichina (322) Effect of Pressure on Melting Temperatures of Thermal Analysis Calibration Materials. R. L. Blaine, C. W. Schaumann, I. S. Rhee (323) Factors Affecting Glass Transition Event of Oriented, Semicrystalline PET. W. J. Sichina (324) Thermoanalytical Characterization of Reactant Levels on Durable Press Treated Cotton Fabrics. B. J. Trask-Morrell (325) Calorimetric and Dynamic Mechanical Analysis of Thermal Transitions in Collagen. B. Twombly, B. Cassel, S. Goodkowsky (326) Predictions of Long-Term Physical Properties of Engineering Thermoplastics Using Thermal Analysis. J. A. Foreman, C. J. Lundgren, P. S. Gill (327) Detection of Thin Coatings by Thermomechanical Analysis. J. H. Defrancis, W. J. Sichina (328) TGA/FT-IR Analysis of Outgassing and Decomposition in Polyurethane Foams. D. E. Roberts (329) Development of a Technique to Characterize Pozzolanic/Cementitious Materials by Heat of Hydration. D. J. Hassett, D. F. Pflughoeft-Hassett, C. M. Lillemoen, J. R. Lucht (330) Further Advances in Flow Adsorption Microcalorimetry: New Data on Wetting and Dissolution, Sorption at Elevated Temperatures and Pressures. M. Templer

Tuesday Afternoon Plenary Session 1 2 : 1 5 - 1 : 3 0 p.m: T h e C o d e v e l o p m e n t of A n a l y t i c a l Chemistry and the Pittsburgh Conference, 45 Years and Beyond Pittsburgh Conference Analytical Chemistry Applied Spectroscopy: A Synergistic Trio. Foil A. Miller Pittcon and the Nineties: Bore, Bore, Bore or More, More, More? David C. Nelson Title TBA. James L. Waters

PITTCON U Quality Minlconference: The ISO 9000 Series and Global Harmonization of Standards

Symposium: The Future of Analytical Instrumentation—A CEO's Perspective

(Arranged by S. Caola)

(Arranged by R. S. Danchik)

Lindheimer Room C, East Hall S. Caola, Presiding

Earl M c M a h o n Room B, East Hall R. S. Danchik, Presiding

1:30 1:35

1:30 1:35

2:15 3:10 3:50 4:30

Introductory Remarks. S. Caola (455) ISO 9000: The International Quality Standard. J. E. Small (456) Doing Business Internationally with ISO 9000. C. M. Ludolph (457) U.S. Conformity Assessment Measures. S. Warshaw (458) Impact of Liability and Safety in the Application of ISO 9000. J. W. Kolka (459) ISO 9000: Its Evolution and the Future. J. Nagano

2:00 2:45 3:15 3:45

Introductory Remarks. R. S. Danchik (459a) R. W. Howe, University of Pittsburgh (459b) G. N. Kelly, Perkin-Elmer Corp. (459c) W. J. Kennedy, Analytical Technology, Inc. (459d) J. N. Driscoll, HNU Systems, Inc. Panel Discussion

Computers in Chemistry—LIMS R o o m M5, North Mall D. R. Weill III, Presiding 1:30 1:50 2:10 2:30 2:50 3:25

(480) Creating and Managing Distributed Lab Operations. J. N. Bower, J.J. Fitzgerald (481 ) Development of a LIMS for a Multifunctional Laboratory. R. J. Lilly (482) Implementation and Benefits of LIMS in a Research Environment. C. Gonzalez (483) Configuring LIMS on a Commercial Database. G. Barton (484) The Value of Prototyping Laboratory Automation Systems. J. Hawley (485) Development of a Windows-Based Automatic Sample Scheduler. G. F. Gostecnik, M. P. Kelly

Pittsburgh Conference Short Courses Fundamentals of Preparing Successful Statistical Tests Applied to Analytical Grant Proposals. March 1. Rebecca Chemistry. March 2. James E. De D. Claycamp Muth An Introduction to Data Format Interpretation of Dynamic Mechanical Standards in Analytical Chemistry. Spectra Structure-Property Relationships. March 2. Charles L. March 1. Jim Currie The Fiscal Physical: Using Ratio Rohn Microscopy and Microanalysis. March Analysis To Improve Your Bottom 2D NMR: Theory and Experiment. 1. Mark Germani and Skip Palenik Line. Feb. 27. Carl G. Forssen March 2-3. Gheorghe D. Mateescu FT-IR Characterization of Polymers. Feb. Process Sensors and Analyzers: An The Art of Sample Preparation for Introduction for Chemists. March 1. 27. Clara D. Craver Spectrochemical Analysis. March 3. Harvey S. Gold An In-Depth Overview of Near-IR Theodore C. Rains Professional Analytical Chemists in Spectroscopy. Feb. 27. Edward Stark Chemical Applications of Neural Industry: What Does an Analytical and Karen Luchter Networks. March 3. Peter C. Jurs Chemist Do? March 1. Alan Ullman Principles of Ion Chromatography. Feb. Introduction to the Chromatographic SFE: Practical Considerations and 27. Hamish Small Separation of Enantiomers. March 3. Applications in Environmental Purchasing Mass Spectrometers. Feb. Analysis. March 1. Viorica Lopez-Avila Daniel W. Armstrong and W. L. Hinze 27. Kenneth L. Busch and Mary Ellen McNally Laboratory Accreditation. March 3. The Scientist's Interview: A Powerful A Strategic Approach to Laboratory Peter van de Leemput Weapon. Feb. 27. Rubye P. Torrey Automation and Computing. March 1. Microdialysis Sampling for Joe Liscouski The Scientist's Résumé: A Report Card Pharmacokinetic and Metabolism for Position Seeking or Laboratory Studies. March 3. Craig E. Lunte and Setting up Your Laboratory Safety Record of Activities. Feb. 27. Rubye Peter T. Kissinger Program. March 1. Charles R. Lay, Pharmaceutical Bioanalysis: Sample Donald A. Spaeth, and James A. P. Torrey Preparation and Derivatization Kaufman Introduction to Pharmacokinetics: A Techniques. March 3. Henk Lingeman Conceptual Approach Based on TOFMS: Instrumentation and and John Stobaugh Applications to Biological Research. Physiology. Feb. 27-28. Ron Burnette Statistically Sound Procedures To March 1. Robert J. Cotter LIMS for Laboratory Managers: Compute Method Detection Limits and Practical Quantitation Limits Strategies and Tactics. Feb. 27-28. Introduction to Environmental MS. from Calibration Data. March 3. David R. D. McDowall March 2. Ronald A. Hites Coleman Understanding and Implementing the Mathematical Calculations for Principles and Practice of ISO 9000/Q90 Series of Quality Sampling and Analyte Spectroscopic Calibration. March Standards In Your Organization. Feb. Concentrations for Gas, Liquid, and 3-4. Howard Mark Solid Samples. March 2. Robert L. 27-28. Michael Demma Headspace GC: Equilibrium and Grob Advanced Laboratory Data Management Purge-and-Trap Analysis. March 4. Using a Personal Computer. Feb. 28. Practical MS/MS Analysis: Strategies Leslie S. Ettre for Analytical Problem Solving with LC/GC for Technicians. March 4. John Glenn I. Ouchi Tandem MS. March 2. Jodie V. Q. Walker and Forrest L. Bayer Basic Statistics. Feb. 28. James E. Precontrol: An Effective Alternative to Johnson and Richard A. Yost De Muth Control Charts. March 4. Sermin Principles and Applications of Introduction to Laboratory Data Caola Step-Scan FT-IR. March 2. Richard A. Management Using a Personal Testing of Pharmaceutical Products. Palmer Computer. Feb. 28. Glenn I. Ouchi March 4. Charles C. Collins, Lawrence Setting up, Maintaining, and H. Block, and Christianah Moji Adeyeye Managing for Quality within the Troubleshooting Gas Analytical Laboratory. Feb. 28. Chromatographs. March 2. John V. Anthony J. Montana Hinshaw For more information, contact the Pittsburgh Conference, Short Course Registration, 300 Penn Center Blvd., Suite 332, Pittsburgh, PA 15235-5503 (800-825-3221, 412-825-3220; fax 412-825-3224)

136 A

Analytical Chemistry,

Vol. 66, No. 3, February

1, 1994

PITTCON U 3:45

4:05 4:25 4:45

(486) Using Visual Basic to Provide Custom Calculations within a Chromatography Data System. L. L. Robison, S. Saadat (487) Intelligent Linked Portability for Measuring Instruments. R. S. Szymansky, X. F. Gonzalez (488) Analytically Precise Software Selection. R. C. Hlce (489) Toward Virtual Electronic Classrooms. V. Karanassios

Process Analytical Chemistry Miniconference: Controlling Recycling Processes with Process Analytical Instrumentation Room 20W7, East Hall I. Black, Presiding 1:30 1:50

2:10 2:30 2:50

(490) Rapid Near-IR Analysis for Plastics Recycling. J. M. Pope, G. Asimopoulos (491) Identification and Characterization of Polymers and Coatings by Near-IR Spectroscopy. P. H. Dallin. F. A. DeThomas (492) Toward a Universal Metals Identifier: A Compact CCD Array Spectrometer. T. Smith (493) Alloy Sorting with X-ray Fluorescence Using a Pattern Recognition Method. E. M. LeBlanc, A. L. Heilveil (494) Technology Review of Waste Processing Converting. T. J. Peters

2:10

2:30

2:50

(510) Incorporating Temporal Response Factors into Pattern Recognition Schemes for Gas-Phase Sensor Arrays. K. Hool, M. B. Seasholtz, R. Saunders, D. Schlicker (511) Chemical Sensors Based on Powdered Phosphors. L. R. Sharpe. M. Patel (512) Automation of Commercial Environmental ELISAs for High-Throughput Screening of Environmental and Agricultural Samples. C. Shumate, J. Johnson, K. Andrée, C. Charan (513) Design of Prototype Gas Analyzer Based on Array of Semiconductive Polymer Chemical Sensors. A. M, Korolev, E. B. Voevodina, Ο. Υ. Frolov, V. A. Fedin, T. K. Somina, L. V. Ivanova (514) Optimized Digital Filter Designs for FT-IR Interferograms: Application to Re­ mote Sensing Measurements. A. S. Ban­ galore, G. W. Small

Room M6A, North Hall P. M. Castle, Presiding

3:45 4:05 4:25

4:45

(515) CRF Replacement Alternatives. H. R. Ross, C. Bourgeois, K. Knox, J. Watkins, L Gandy (516) Mercury in Analytical Laboratories: Uses, Alternatives, Regulatory Status, and Treatment. R. Berman (517) Maintaining ICP Spectrometer Compliance with EPA Regulations. D. D. Nygaard, M. Almeida, F. Bulman (518) Unattended HPLC Sample Prepara­ tion and Analysis of PAHs and Phenols in Environmental Solid Waste Samples. D. R. Gere, C. R. Knipe, L. G. Randall, L. Altmayer, C. Wurm (519) Alternative Method to Total Kjeldahl Nitrogen for Water and Wastewater Anal­ yses. Y. Takahashl

138 A

Analytical

Chemistry,

Earl M c M a h o n R o o m A, East Hall E. Baughman, Presiding 8:30 8:35

Introductory Remarks. E. Baughman (585) The Process Analytics Laboratory in the Plant: Fit, Function, and Future. P. van Vuuren 9:10 (586) Quality Assurance of the Process Analyzer System Output. L. Lane 9:45 (587) Process Analytical Chemistry in a GMP Environment. P. K. Aldridge 10:35 (588) Analytical and Process Analytical Chemistry Laboratories: Partnership for a Successful Program in Process Analyzer Implementation. S. Mehta. P. Brimmer, D. Corrigan, C. Kettler, M. Pearce 11:10 (589) Analytical Laboratory Calibrate and/or Verify Process Analyzers. E. Baughman, G. H. Vickers, D. R. Van Hare

8:30

Environmental Laboratory Issues

3:25

Process Analytical Chemistry M i n i c o n f e r e n c e : T h e R o l e of t h e A n a l y t i c a l L a b o r a t o r y in P r o c e s s Analysis (Arranged by E. Baughman)

R o o m 20W8, East Hall J.A. Burnstein, Presiding

Room M6A, North Hall P. M. Castle, Presiding

1:50

Wednesday Morning

W o r k s h o p : I m a g e P r o c e s s i n g for the Scientific Community

Environmental Sensor Developments

1:30

Poster sessions for all topics will be held from 9:00 A.M. to 5:00 P.M. in the East Hall (Level 2) and the North Hall (Level 2 and Room M3)

(602) Summary of Scientific Imaging Mar­ ket Study. T. Gibson (603) Sensor Technology Enhancements. D. Hunter (604) Future Research Requirements for Universities. T. Skimina (605) The Trek from Laboratory to Commerciality. K. Phillips (606) Commercial Laboratories' Imaging Requirements. A. Wak

Panel Discussion: Automated S a m p l e P r e p a r a t i o n in t h e Laboratory

D. B r u c e Chase Pittsburgh Spectroscopy Award

11:05 (614) Enhanced Sample-Handling Auto­ mation for Sample Concentration. M. Cava, R. K. Brown 11:25 (615) Automated Preparation and Derivatization of Selected Analytes Employing Integrated Sample Preparation and GC/MS Analysis. W. Mlles, L. G. Ran­ dall, P. Castelli, K. Fogelman, M. Fogel­ man 11:45 (616) Instrumentation for Automated SFE. R. K. Houck, D. J. Koebler, G. P. Williams, J. M. Levy Chemometrics I C h i c a g o R o o m A, East Hall S. L. Morgan, Presiding 8:30 8:50

9:10 9:30

Room 20W2, East Hall A. Clayton, Presiding 8:30

(607) Coordination of Sample Preparation and Analysis Instruments via Supervisory Software To Form Integrated Systems. P. Snipes, W. Ballaughey, S. Jupiter, C. Wurm, S. Engel 8:50 (608) The Chemist's Workceii-Automation Strategy from Sample Preparation to Final Report. C. R. Knlpe 9:10 (609) Flexible Robotic Workbench for Au­ tomated Enzyme Kinetics. A. B. Todtenkopf, M. F. Russo, D. J. Balaban 9:30 (610) Automated Soft Drink Analysis: A Case Study for Nonrobotic Sample Han­ dling. D. M. Sullivan 9:50 (611) Laboratory Automation: Method De­ velopment and Product Validation for the Pharmaceutical Industry. S. G. Kelley, A. L. Martin 10:25 (612) Calibrating Detector Response in EPA Methods Using an Automated Sys­ tem Integrated to GO P. Castelli, M. Fogelman, W. Miles, K. Fogelman, L. G. Randall 10:45 (613) Trends in Automated Sample Prep­ aration: SFE and SPME. I. Davies, E. Almasi

Vol. 66, No. 3, February

1, 1994

9:50 10:25

10:45

11:05 11:25 11:45

(636) Quantitative Analysis of FT-IR Interferogram Data. M. J. Mattu, G. W. Small (637) Advances in Calibration Transfer and Instrument Standardization for Multi­ variate Quantitative Analysis. J. Work­ man, Jr., L. McDermott, B. DeSimas, J. Coates (638) From Mixtures to Pure Component Spectra: Inducing Variance via Microsam­ pling. T. W. Brueggemeyer, C. Machal (639) Collective Optimization of Piecewise Linear Discriminants: Application to FT-IR Remote Sensing. R. E. Shaffer, G. W. Small (640) Optimal Fuzzy Decision Making. P. S. Harrington (641) Comparison of Back-Propagation and Counter-Propagation Neural Net­ works for Quantitative Analysis of Ion Mobility Spectra. P. Zheng, P. B. Har­ rington, D. Davis (642) Reduction of Dimensionality Con­ cepts for Spectroscopic and Chromato­ graphic Data. S. L. Morgan, M. K. Higgins (643) Studies on Chemical Equilibria Sys­ tems with Target Transformation Evolving Factor Analysis. H. Shen, S. Cai (644) Problems Specifying Outlying Data Using the Median Method for the Straight Line Case. A. H. Kalantar, M. O. Moen (645) Neural Network-Assisted Rapid Screening of Large Spectral Databases. C. Klawun, C. L. Wilkins

PITTCOKU 10:25 (721) Data Interpretation in the Auto­ mated Environmental Analysis Labora­ tory. L. N. Klatt, J. W. Elling, W. P. Unruh 10:45 (722) Development of an Object-Oriented Database for the Department of Energy's Contaminant Analysis Automation Pro­ gram. F. S. Smutniak, P. A. Medvick 11:05 (723) Electronic Laboratory Notebooks. R. E. Dessy 11:25 (724) Validation of an Automated Extrac­ tion System for Semivolatile Constituents. M. Monagle 11:45 (725) Contaminant Analysis Automation Commercialization Plan. S. Bourgeois, D. Salomaki, R. M. Hollen

Environmental Analysis: Radioactive Species and Field Methods Room 20W7, East Hall D. C. Grant, Presiding 8:30

8:50 9:10 9:30

9:50 10:25

10:45

11:05

11:25

11:45

(646) Open-Path FT-IR Monitoring of Plant Bioremediation of VOCs. V. P. Visser, L. C. Davis, C. T. Chain, Jr., N. Muralidharan, W. G. Fateley, R. M. Hammaker, L. E. Erickson, R. M. Hoffman, V. S. Makepeace, T. L. Mar­ shall, J. M. Poholarz, N. K. Russell, M. D. Tucker (647) Quantification of Alcohol and Ke­ tone Retention on Glass Fiber Filters. S. K. Brendecke C. A. Turner (648) Interference Effects in Environmen­ tal Monitoring of Multicomponent Stack Gases. R. S. Ramachandran. A. Boehm (649) Passive Remote Sensing at Indus­ trial Sites Using FT-IR Spectroscopy. M. D. Tucker, C. T. Chaffin, Jr., R. M. Hammaker, W. G. Fateley, M. Davis, J. Arello, J. Helvig, B. J. Fairless (650) Tailoring ICPMS to the Application. R. C. Hutton. P. Brown, J. Clark, C. Tye (651) An Open, New, and Cost-Effective System for Purchase, Reporting, Review, and Upload of Organic, Inorganic, and Radiochemical Environmental Data with Nonproprietary Off-the-Shelf Software. A. D. Sauter (652) Application of Passive Monitoring Technology to Multiple Environmental Media. J. D. Petty, J. N. Huckins, J. A. Lebo, J. L Zajicek, D. Martin, V. L. Gib­ son, R. C. Clark (653) How to Squeeze High Precision from Segmented Flow Analysis. II. Appli­ cation to Actinides. D. A. Burns, E. Lujan, C. M. Huff (654) Characterization of Nuclear Waste Materials by Remote Raman Spectros­ copy. T. J. Vickers, C. K. Mann, D. Lom­ bard!, F. L. Kohlasch, J. Douglas (655) Tritium Content as an Indicator of Environmental Character in Taiwan Is­ land. C. W. Huang, J. M. Chen, S. E. Chiou

Herbert L. Strauss Bomem-Michelson Award

Wednesday Afternoon Plenary Session 1 2 : 1 5 - 1 : 3 0 p.m.: Scientific Literacy: What It Is, Why We Don't Have It, and How We Can Get It. J. Trefil

SAM, SLM, A I M , and DIM: A New Paradigm for Laboratory Automation

Quality Miniconference: Laboratory Accreditation

Room 20W1, East Hall L. N. Klatt, Presiding

Lindheimer R o o m C, East Hall R. Kaarls, Presiding 1:30 Introductory Remarks. R. Kaarls 1:35 (750) Experiences with Laboratory Ac­ creditation in the U. S. J. Locke 2:10 (751) The (Future) Development of a Northern American Laboratory Accredita­ tion Scheme. J. Donaldson 2:45 (752) Laboratory Accreditation in Europe. R. Kaarls 3:20 RECESS 3:35 (753) Laboratory Accreditation in a Worldwide Perspective. A. J. Russell 4:10 (754) Accreditation for Analytical Chemi­ cal Laboratories. B. King

8:30 8:50

9:10 9:30

9:50

(716) Standardizing the Automated Envi­ ronmental Chemical Laboratory. R. M. Hollen (717) Standard Laboratory Module for Performing Sonication Extraction (EPA Method 3550). T. H. Erkkila, R. M. Hol­ len, L. E. Bronisz, J. Roybal (718) Control System for Modular Auto­ mation of Chemistry. T. D. Urenda, J. M. Griesmeyer (719) Integrating a Broad Variety of Lab­ oratory Modules into the CAA Architec­ ture. R. M. Pacetti J. J. Ferguson, T. D. Turner, M. L. Clark, K. M. Klinger (720) Planning Automated Chemistry Laboratories Using Advanced 3D Simula­ tions. M. G. Dodson, D. C. Elegy, J. T. Smalley, S. L. Owsley

(Arranged by R. Kaarls)

Chemometrics II Chicago Room A, East Hall P. D. Harrington, Presiding 1:30

Committee Chairs Activities: Rita M. Windisch Antiquities Museum: Richard Obrycki and Andrew G. Sharkey Audio-Visual: N. Curtis Radcllffe Committee Arrangements: Jane N. Valenta Computer Utilization: Dennis R. Balya Employment: Kathy J. Rygle Exposition: Jon N. Peace Family Program: Rachel J. Carlson

1:50 Philatelic: Sameul S. Oliverio Pittsburgh Conference Memorial National College Grants: John P. Auses

2:10

Printing and Mailing: Denton M. Albright

2:30

Program: Vincent B. Conrad Program Subcommittee Continuing Property, Insurance and Equipment: John P. Baltrus Publicity/Public Relations: Charles W.

Finance/Treasurer: John D. Sember Foreign Buyer Program: John F. Jackovitz Housing: William A. Straub

Registration: Hyman Schultz Security: Robert E. Witkowski

Coordinator: Michael Theodore Transportation: Sarah L. Shockey

Negotiations: Richard S. Danchik

140 A

3:45

Science Week: Grace Ann Bello

Site Selection: Ann Cibulas Puskaric Marketing/Trade Show Exhibiting: John Special Projects: Victor C. Zadnik P. Auses Special Projects Subcomittee Student McKaveney

3:25

Gardner

Label Service: Denise C. Wilkins

Meetings Coordination: Kevin J.

2:50

Education: Christine McCreary

Analytical Chemistry, Vol. 66, No. 3, February 1, 1994

4:05 4:25 4:45

(785) Pattern Recognition of Environmen­ tal Samples by Use of 3D Multivariate Visualization. F. O. Geiser, C. Gait, J. D. Justice (786) Environmental Applications of Pat­ tern Recognition Techniques. B. Lavine, H. T. Mayfield (787) Automated Analysis of Complex IR Spectra Using Pattern Recognition. D. Qlan, M. L. Spartz, J .S. Eldridge, G. D. Hippie, W. K. Reagen, J. W. Stock (788) Comparison of Mid-IR Gasoline Calibrations for a Variety of Gasoline Data Sets. J . McGuire (789) Determination of Main Reaction Products Formed During Hydrolysis of Sugars in Water by Evolving Factor Anal­ ysis. F. O. Libnau, A. A. Christy, Ο. Μ. Kvalheim (790) Intelligent Algorithm for Peptide Se­ quence Identification. L. Hu, P. B. Har­ rington, E. Saulinskas (791) Filter for Spectrochemical Data with an Autoassociative Back-Propagation Neural Network. B. W. Wabuyele, P. B. Harrington (792) Quantitative Spectra-Retention Re­ lationship. D. Wuersig, P. B. Harrington (793) Chemometric Analysis of Trilinear Fluorescence Data. M. V. Benthem, B. Mitchell, G. D. Gillisple (794) Speciation of Copper (II) Triethanolamine by Evolving Factor Analysis. S. Ren, L. Gao

p/rrcoii/u 2:10

(865) Worldwide Analytical Data Inter­ change and Storage Standards (ADISS) for Analytical Chemistry and Spectros­ copy: Progress Update. R. Lysakowski 2:30 (866) The netCDF System: Defacto Pub­ lic-Domain Standard for Analytical Chemistry Data Transfer, Storage, and Archival Design. Features and Benefits. R. Lysakowski 2:50 (867) ΑΙΑ Standards Program: New Ap­ plications of the Standards to IR Spec­ troscopy. D. R. Mattson, M. Tonsager 3:25 (868) Portable Tools and Distributed Hetergenous Databases in Molecular Biol­ ogy. J. M. Ostell 4:05 (869) Current Status of LASF: Programs and Advancements. J. G. Liscouski 4:25 (870) ASTM E-31 Standards for Clinical and Analytical Laboratory Automation. R. Megargle 4:45 (871) Facilitating GLP Compliance through Centralized Control of Laboratory Instruments. B. M. Jackson, D. J. Haas Graduate student poster session and poster session on Quality will be held from 8:30 A.M. to 12:00 P.M. in the East Hall (Level 2 and Lindheimer Room C, respectively)

Thursday Morning Adler

Planetarium

S y m p o s i u m : A n a l y s i s of Environmental Biohazards (Arranged by G. Bakale)

E n v i r o n m e n t a l P r o b l e m s in Soil, Groundwater, and Seawater Room M6B, North Hall G. O'Neill, Presiding 1:30

1:50

2:10

2:30

2:50

3:25 3:45

4:05

4:25

4:45

(795) New Approach to Automating Derivatization and Trace Enrichment of En­ vironmental Pollutants for HPLC Analy­ ses. V. Nau, F. Lai, R. Wu (796) Use of Gas-Permeable Electrodes in the Field at a Gasoline-Contaminated Site Undergoing Enhanced Bioremediation. R. Guisto, J. D. Stuart, R. Jennings, K. Liu, P. C. Clark, P. D. Zack, E. S. Atwood, C. Wood (797) Problems Associated with Determi­ nation of Petroleum Hydrocarbons in Soil/ Bioslurry: Comparative Study with EPA and APHA Standard Methods. J. Hawarl, C. Beaulieu, D. Ouellette, R. Samson (798) Military Base Closure: Site Assess­ ment for a Shooting Range Containing Lead Shot and Clay Pigeon Remnants. R. King, G. Under, M. Bollman, G. Hen­ derson, C. Callahan (799) Cold Trap for GC as a Means of Decreasing the Time of TOC Analyses of Soil Samples. T. P. Yavaraskl, S. SuryaAtmadja, W. J. Weber, Jr. (800) New HPLC Method To Quantify Phenols, Cresols, and Xylenels in Sedi­ ment. P. J. Chen, B. Gainer (801) Impact of Industrial Activities on Magnetic Properties of Suspended Matter in the English Channel. A. Boughrlet, C. Cordier, I. L. Deram, M. Wartel (802) Determination of Low Levels of Ammonia, Nitrate, Orthophosphate, and Silica in Saline Waters Using FIA. D. Dia­ mond (803) Development of Solid-State Microelectrodes for Voltammetric Determina­ tion of 0 2 , H2S, Fe, and Mn in the Marine Environment. P. J. Brendel, G. W. Luther III (804) Determination of Dissolved Cr(lll) and Cr(VI) Species in Seawater by Elec­ trothermal Atomization AAS and Their Seasonal Variability in the English Chan­ nel. A. Boughriet, I. L. Deram, M. Wartel

142 A

Analytical

Chemistry,

Process Analytical Chemistry Miniconference: Process Control Applications Earl M c M a h o n R o o m B, East Hall B. J. Sparr, Presiding 1:30 1:50 2:10

2:30

2:50 3:25 3:45

4:05 4:25

4:45

(824) Continuous Analysis of Water by IR Absorption in Process Streams. E. Gosart, P. Wilks (825) On-Line Ion Chromatograph Moni­ toring of Trace Contaminants in HighPurity Water. S. Songnian, Z. Yanping (826) Comparison of Raman and Evanes­ cent Raman Spectroscopies in the Cure of an Epoxy Resin. K. E. Chike, M. L. Myrick, W. Egan, S. L. Morgan (827) Vaporization of Liquefied Petroleum Gases Prior to Analysis by GC Using a Heated Pressure Regulator Sample Va­ porizer System. P. H. Johnson (828) Stepper Motor-Controlled Gas Valve Inlet System for Process GC. R. Sacks, M. Nowak (829) Carbon and Chlorine Balance of CCL4 Decomposition via GC and StandAlone MS. M. Koch (830) Analysis of Highly Reactive Pro­ cess Streams Using Multidimensional GC. T. J. Lechner-Flsh, M. J. Lund, S. L. Ryder (831) Determination of Olefin Content of Gasolines by Reaction with Ozone. R. S. Hutte, Ν. Johansen, M. Bykhovskii (832) On-line Monitoring of Aromatic Hy­ drocarbons Using a Fiber-Optic UV Ab­ sorption Spectrometer. T. E. Barber, W. G. Fisher, E. A. Wachter, R. L. Newmark (833) Process Analysis of Lubricating Oil Using Viscometry. G. T. Gianninl, M. Bauman, R. E. Tarrant

S t a n d a r d s for A u t o m a t i n g t h e Analytical Sciences I R o o m 2 0 W 1 , East Hall R. Lysakowski, Presiding 1:30

(864) FDA Information Standards Initia­ tive. G. L. Green

Vol. 66, No. 3, February

1, 1994

R o o m M3, North Hall G. Bakale, Presiding 8:30 8:35

Introductory Remarks. G. Bakale (877) Solid-Phase Extraction Uses in the Environmental Lab. C. G. Markell 9:10 (878) SFE of Environmental Solids: What Works and What Doesn't. S. B. Haw­ thorne, D. J. Miller, M. D. Burford, J. L. Langenfeld, S. Eckert-Tilotta, V. Schmidt 9:45 (879) New Bioassay-Directed Chemical Analysis Approaches for Assessing Syn­ ergistic Biological Effects of Air Pollut­ ants. D. D. Schuetzle, J. M. Daisey, L. A. Gundel, L.R.F. de Carvalho, C. Gennings, J. Tukey 10:35 (880) New Approaches to Bioassay- and Biomarker-Directed Identification of Genotoxic Components in Complex Mix­ tures: DNA Adduct Identification. J. Lewtas, L. C. King 11:10 (881) Application of a Liquid-Phase Elec­ tron-Capture Detector to the Analysis of Environmental Biohazards. G. Bakale, R. D. McCreary Process Analytical Chemistry Miniconference: Transferring Analytical Technology from the Laboratory to t h e Plant (Arranged by E. Baughman) Earl M c M a h o n R o o m B, East Hall E. Baughman, Presiding 8:30 8:35

Introductory Remarks. E. Baughman (887) Raman Spectroscopy—Academic Laboratory to the Process. A. Garrison, M. Z. Martin, M. J. Roberts 9:10 (888) Evaluation and Application of "Hand-Held" GC for Refinery Air Moni­ toring. P. A. David, S. A. Ness 9:45 (889) Near-IR Octane from University to Refinery. K. L. Gallaher, R. Lester, F. L. Baudias, R. Combs, J. F. Binette, D. Cameron 10:35 (890) SFC from the Laboratory to the Process. J. demons

PITTCONJm 11:10 (891) New Near-IR Technology tor Pro­ cess Analysis: A Collaboration between Academia, Industry, and Instrumentation Manufacturers. J. Coates, D. Tracy, J. Workman, Jr.

S t a n d a r d s for A u t o m a t i n g t h e Analytical S c i e n c e s II R o o m 2 0 W 1 , East Hall P. Lysakowski, Presiding 8:30

Industrial Hygiene Air-Monitoring Techniques R o o m M6A, North Hall R. Mindrup, Presiding 8:30

8:50 9:10

9:30 9:50

(927) Development of Sampling and Ana­ lytical Methodology for the Determination of Glycols in Air: Application to Theatrical Smokes. B. R. Bellnky, S. M. Pendergrass (928) Gas-Phase Monitoring of Chlorine Dioxide in the Presence of Chlorine. B. Bubnls, G. Gordon, G. Pacey (929) Enhanced FT-IR Capable of Both Air-Monitoring and Laboratory Measure­ ments. D. K. Walker, W. P. King, R. B. Lacount, D. G. Kern, R. B. Lacount, Jr., T. J. Schroyer (930) NIOSH Manual of Analytical Meth­ ods, 4th Edition. M. E. Casslnelll (931) Desorption Efficiencies of Air Sam­ ples Collected on Thermal Desorption Tubes. S. A. Hazard, J. L. Brown

9:10 9:30

10:10 10:30 11:05

11:25 11:45

(997) Development of Interagency Stan­ dards for Environmental Data Transmis­ sion and Exchange. J. F. Fisk (998) Implementing the TechnologyIndependent ADISS Data Architecture. R. D. Weimar, Jr. (999) The NIST Consortium on Auto­ mated Analytical Laboratory Systems— Standards for Automated Systems Used in Analytical Chemistry. G. W. Kramer (1000) NIST CAALS: Behaviors for In­ strument Controllability. M. L. Salit, J. M. Griesmeyer (1001) An Overview of STEP: The Stan­ dard for Exchange of Product Model Data. J. A. Carpenter (1002) Approaches to GLP Compliance through Laboratory Information Manage­ ment. G. Moller, B. Goodrick, R. Haws, J. Snow (1003) Business Solutions for the Envi­ ronmental Laboratory. J. Webber (1004) As We May Think: The Application of Knowledge Management in Science and Engineering. G. Moller

J o h n M. C h a l m e r s Williams - Wright Award

3:35

4:10

Pharmaceutical Analysis R o o m M6B, North Hall M. Woodman, Presiding

Thursday Afternoon

8:30

S y m p o s i u m : Indoor Air Measurements (Arranged by R.G. Lewis)

8:50

9:10 9:30 9:50

(957) Understanding the Characteristics of Biological Samples in SPE Methods. L. Jordan (958) Nondestructive Determination of Parthenolide in Intact Tanacet 125 Tab­ lets with Near-IR Spectroscopy. J. W. Hall, X. H. Zhang, P. Pekos (959) Biologically Relevant UV-Based Solubility Assays. C. A. Liplnskl, A. L. Davis, P. K. Aldridge, C. W. Brown (960) A Comprehensive Solution to Sta­ bility Data Management. M. Rank, B. Dyer, M. Misroch (961) An Object-Oriented Approach to Stability Data Management. M. Misroch, T. Loomis, J. Chang, M. Rank

Workshop: Lead Laboratory Accreditation (Arranged by J. E. Wreen) R o o m 2 0 W 7 , East Mall J . Ε Wreen, Presiding

Room M1B, North Hall R.G. Lewis, Presiding 1:30 1:35 2:10

2:45

1:30 1:35

Introductory Remarks. R. G. Lewis (1005) The Use of Passive Samplers To Determine VOCs in Indoor Air. B. Seifert (1006) Indoor-Outdoor Measurements of Ozone and Nitrogen Oxides for a Full Year at a Commercial Building in South­ ern California. C. I. Weschler, O. V. Naik (1007) Aldehyde Concentrations from In­ door Air Investigations Utilizing Passive and Active DNPH/HPLC Methodologies. M. J. Meiners, B. Walsh, T. Cockrell

Quality Miniconference: Quality Systems and LIMS-Aided Quality Control Lindhelmer Room C, East Hall S. W. Kanick, Presiding 8:30 8:50 9:10 9:30 9:50 10:25 10:45 11:05

11:25 11:45

(967) Navigating the Seas of Regulatory Compliance. K. Benson (968) ISO Guidance—Keys to Implemen­ tation. G. W. Zubritsky (969) In Defense of ISO 9000. G. A. Newman (970) ISO 9001 Certification in Analytical Services. M. L. Markowski (971) An Empirical Assessment of WECC Lab Accreditation. R. C. Geib (972) A Quality Assurance Program for Meeting Risk Assessment Studies. M. M. Khalll, W. Kubilius, R. C. Tuckfield (973) Total Quality Management in an R&D Analytical Laboratory. B. S. Gray­ son, K. F. Dahnke (974) Approaches to Quality Assessment for Environmental Laboratories. W. R. Kammln (975) Use of LIMS to Improve Quality Control. M. J. Herdlick (976) Methodology for the Validation of a LIMS. S. Weinberg, G. C. Stein

(1008) Carpets and Pesticides: A Case Study of Extractable Contaminants in a Large Environmental Chamber. M. A. Mason, L. S. Sheldon (1009) Standardization of Indoor AirMonitoring Methods. R.G. Lewis

2:05 2:35 3:20 3:50 4:20

Process Analytical Chemistry Miniconference: Fiber-Optic Probes for IR P r o c e s s Analysis/ E n v i r o n m e n t a l M o n i t o r i n g by IR Spectroscopy

SAS Short Courses

Earl McMahon R o o m A, East Hall A. Garrison, Presiding

For more information, contact the Society for Applied Spectroscopy, P.O. Box 837, Frederick, MD 21705-0837 (301-694-8122; fax 301-694-6860)

1:30

A p p l i e d Near-IR S p e c t r o s c o p y . Feb. 26-27. David L. Wetzel and Gabor J. Kemeny Biological IR a n d Raman S p e c t r o ­ s c o p y . Feb. 26-27. Robert J.

1:50

2:10

Jakobsen and David G. Cameron Fourier T r a n s f o r m IR S p e c t r o m e t r y . Feb. 26-27. Peter R. Griffiths and James A. de Haseth Modern Furnace A t o m i c A b s o r p t i o n . Feb. 26-27. Slavin

Walter

Plasma S p e c t r o c h e m i c a l A n a l y s i s . Feb. 26-27. Ramon M. Barnes and Andrew T. Zander

Analytical

Introductory Remarks. J. E. Wreen (1020) Environmental Lead Proficiency Analytical Testing Program. F. Grunder (1021) A2LA's Lead Laboratory Accredi­ tation. W. Kavanagh (1022) Standard Reference Materials for Lead-Based Paint. J. S. Kane (1023) Laboratory Accreditation: A Pri­ vate Industry Perspective. G. O'Neil (1024) National Lead Laboratory Accredi­ tation Program. EPA Representative (1025) Laboratory Accreditation, a Gov­ ernment Laboratory Perspective. J. E. Wreen

2:30 2:50 3:25

Chemistry,

(1044) Fiber-Optic Spectroscopy from UV to Mid-IR. S. Artjushenko, A. Kryukov, A. Lerman, A. Prokhorov, K. Moran, W. Neuberger (1045) A Novel Cooled Mid-IR FiberOptic Probe for In Situ Analysis at High Temperature. D. Coombs, L. L. Day, G. Poulter (1046) Fiber-Optic Chemical Probes Us­ ing Near-IR Dyes. F. Meadows, G. Casay, T. Czuppon, N. Narayanan, G. Patonay (1047) Fiber-Optic Interfaces for Near-IR Process Measurements. F. A. DeThomas, S. L. Monfre (1048) Mid-IR Fiber-Optic Probes: RealTime In Situ Reaction Analyses. J. A. Van Gompel (1049) Factors Affecting Photometric Ac­ curacy, Linearity, and Reproducibility in FT-IR Gas-Phase Environmental Mea­ surements. C. R. Anderson

Vol. 66, No. 3, February

1, 1994

145 A

PITTÛON 3:45

4:05

4:25 4:45

h 4:05

(1149) Improving Accuracy and Precision of EPA Methods 3051 through the Devel­ opment of Standard Leach Materials. P. J. Walter, H. M. Kingston, D. B. Taylor 4:25 (1150) Stopped-Flow Microwave Diges­ tion. G. Légère, E. D. Salin 4:45 (1151) Clean Room and Microwave Digestion Techniques to Improve Detection in Environmental Metals Methods. W. R. Kammin, I. Chamberlain, S. Cull, R. Knox, M. Mcintosh, J. Ross, D. Thomson Poster session on Process Analytical Chemistry will be held from 8:30 A.M. to 12:00 P.M. in the East Hall (Earl McMahon Room A)

(1050) An Implementation of Pattern Recognition Methods for Passive FT-IR Remote Sensing. R. T. Kroutil, R. J. Combs, R. B. Knapp, G. W. Small (1051) IR Monitoring: A Case Study of Emission Control Systems and Process Streams. W. K. Reagen, J. S. Eldridge, G. D. Hippie, J. W. Stock (1052) Reliability Aspects of an FT-IRBased Continuous Emissions Monitoring System. D. Gravel, A. Rilling, H. Buijs (1053) On-Line Transient IR Analysis of Polyethylene Encapsulated Nuclear Waste Streams. S. L. Wright, R. W. Jones, J. F. McClelland

Friday Morning

Quality Minlconference: Managing Q u a l i t y In t h e P h a r m a c e u t i c a l Industry

Thomas L. Chester Keene P. Dimick Award

Lindheimer R o o m C, East Hall K. Vohra, Presiding 1:30 1:50

2:10

2:30 2:50 3:25

3:45

4:05 4:25 4:45

(1093) Quality Assurance Support by a Pharmaceutical Technical Services Group. A. E. Straub (1094) Managing Continuous Quality Improvements through the Use of Work Activity Control Systems. Κ. Β. Bradfield, K. Kastigar, D. Kelley, D. McCool, A. Thorn (1095) Improving the Pharmaceutical Dosage Form Testing Process: Easier, Faster, and Less Expensive. R. E. Buechsenschuetz, R. K. Brown, L. Jor­ dan (1096) Quality Perspectives on Labora­ tory Projects, Methodologies, and Tools. W. Hoffman (1097) Requirements for HPLC System Performance Qualification in the Valida­ tion Process. J. B. Li, J. Sweeney (1098) New LC Method Development Ap­ proaches for the Improvement of Produc­ tivity in Regulated Laboratories. M. E. Swartz, M. Andrews (1099) Noninvasive Determination of Tablet Formulation through a Plastic Bot­ tle Using Short-Wavelength Near-IR Spectroscopy. A. G. Cavlnato, D. M. Mayes, P. K. Aldridge (1100) Simultaneous Near-IR Analysis of Pharmaceuticals and Their Packaging. C. Kradjel, O. Muller (1101) In-Process Particle Size Distribu­ tion Measurements and Control. D. J. Holve, T. L. Harvill (1102) Monitoring Nitroglycerine in Trans­ dermal Patches by Near-IR Spectros­ copy. D. E. Grzybowskl, S. L. Monfre

Process Analytical Chemistry Minlconference: Portable I n s t r u m e n t a t i o n for Process Measurements Earl McMahon R o o m B, East Hall J. C. Butler, Presiding 1:30

1:50

2:10

(1123) Remote Monitoring of Sub-ppb Levels of Vinyl Chloride Dichloroethylene and Trichloroethylene via Modem-Oper­ ated Automated GC. N. J. Lander, A. Linenberg (1124) High-Boiling Compounds Ana­ lyzed within Two Minutes Using a Micromachined Gas Chromatograph with Heated Internal Sample Lines. P. H. Johnson, A. Loux (1125) Portable Instrument Employing a Surface Acoustic-Wave Sensor with Re­ generate Reagent Coatings for Direct Measurement of Olefin Gases and Va­ pors. G. Z. Zhang, E. T. Zellers

146 A

Analytical

Chemistry,

S y m p o s i u m : A d v a n c e s in Environmental Remediation (Arranged by D. C. Grant) Earl McMahon Room A, East Hall D. C. Grant, Presiding

2:30 2:50

3:25

3:45

4:05

(1126) Field-Transportable Tunable La­ ser Analysis System. R. St. Germain, G. D. Gillispie (1127) Preconcentration Method for the Detection of Inorganic Contaminants by a Field-Portable XRF Spectrometer. C. Wood, A. Robbat, R. Simpson (1128) Detection of Halogenated and Aromatic Solvents and Fuels in Environ­ mental Samples Using Reflectance Colorimetry. J. D. Hanby, E. S. Atwood (1129) Analytical Applications of a Com­ pact Microoptic Spectrograph. E. A. Wachter, T. E. Barber, W. G. Fisher, R. D. Herrold (1130) Novel Hand-Portable TOFMS. S. J. Mullock, C. A. Corlett, D. M. Martin, S. A. Spencer, B. W. Griffiths

8:30 8:35

Introductory Remarks. D. C. Grant (1152) Soil Washing. A Versatile, Effective Approach to Soil Remediation. D. C. Grant, E. J. Lahoda, C. Y. Lin, A. I. Dietrich, C. P. Keegan 9:15 (1153) Applications of Advanced Magnetic Separation Technology to Waste Minimization and Environmental Remediation. R. R. Oder 9:55 (1154) Mineral Processing Technology. A Simple, Cost-Effective Approach to Environmental Remediation. S. Hearn, D. Malhotra 10:50 (1155) Advances in Bioredmediation of Soil and Groundwater. T. C. Hazen 11:30 (1156) Electromagnetic Methods for Soil Vapor Extraction Enhancement. R. S. Kaseovlch, D. L. Faust, S. L. Price

Sample Preparation—Waste Characterization Using Microwave Technology

Workshop: Cooperation on I n t e r n a t i o n a l T r a c e a b i l l t y in Analytical Chemistry (CITAC)

Room M6A, North Hall L. B. Jassie, Presiding

Room 2 0 W 1 , East Hall B. King, Presiding

1:30

8:30

1:50

2:10 2:30

2:50

(1142) Microwave-Assisted Extraction of Organic Compounds from Soils and Sedi­ ments. V. Lopez-Avila, R. Young, R. Kim, W. F. Beckert (1143) Preparation of Hazardous Waste Samples for Mercury Analysis by Micro­ wave Digestion. L. Witry, R. Maw, T. Emond (1144) Total Petroleum Hydrocarbon De­ termination by Microwave Solvent Extrac­ tion. E. Hasty, R. Revesz (1145) Comparison of Open-VesselFocused Microwave Digestion and Con­ ventional Digestion Methods for Environ­ mental Applications. L. W. Collins, E.M.L. Lorentzen, H. M. Kingston (1146) Microwave Extraction for the De­ termination of PAHS in Environmental Samples. L. B. Jassie, M. J. Hays, S. A. Wise

Microwave Sample Preparation Techniques Room M6A, North Hall L. B. Jassie, Presiding 3:25

3:45

(1147) Sample Preparation for the Speciation of Tin and Selenium Compounds Using Microwave Digestion Techniques. O.F.X. Donard, B. Lalere, F. M. Martin, R. Munoz (1148) Alternative to HF Digests. W. Johnson, Β. Τ. Buckley

Vol. 66, No. 3, February 1, 1994

(1162) An Overview of the CITAC Initiative. B. King 8:50 (1163) What CRMs Are Available? A Directory of CRMs in the Pipeline. R. Rasberry 9:10 (1164) Accreditation of CRM Work. R. Walker 9:45 (1165) International Guide for the Accreditation of Chemical Laboratories. A. Squlrrell 10:05 (1166) Who Does What in Chemical MeIrology: CIPM Tasks to Specialist National Facilities. R. Watters 10:25 (1167) Criteria for Establishing Traceability to the Mole. P. De Blevre 10:45 Panel Discussion Workshop: Detectlon/Quantitation Definitions and Issues (Arranged by B. R. Nott) R o o m 20W2, East Hall B. R. Nott, Presiding 8:30 8:40 8:55 9:10 9:25 9:40 9:55 10:10 10:25

B. Nott W. Telllard B. Bathija R. Maddalone P. Brltton R. Gibbons S. Koorse N. Grams Panel Discussion

PITTCOH

Monday Afternoon

2:10

Bioanalytlcal Chemistry Mlnlconference: Chemical Sensors: A Tribute to Wilhelm Simon (Arranged by M. E. Meyerhoff)

2:30 2:50

Room M3, North Hall M. E. Meyerhoff, Presiding 1:30 1:35

Monday Morning

1:55

Bioanalytlcal Chemistry Mlnlconference: Bioanalytlcal T e c h n i q u e s for Food Safety a n d Environmental Monitoring (Arranged by R. A. Durst)

2:15 2:35

R o o m M3, North Hall R. A. Durst, Presiding 8:30 8:35

Introductory Remarks. R. A. Durst (001) Strategies and Needs for Food and Environmental Bioanalysis. R. A. Durst 8:55 (002) Immunoassays To Monitor Human and Environmental Exposure to Pesti­ cides. B. D. Hammock, S. Gee 9:35 (003) SFE-ELISA Solutions to Pesticide Analysis. J. M. Van Emon, V. LopezAvila, C. Charan 10:30 (004) Biosensors for Pesticides and Bac­ terial Contamination. G. G. Gullbault 11:10 (005) Gene Probes and PCFt: Food Safety Applications. W. E. HIM

2:55

Bioanalytlcal Chemistry Mlnlconference: Capillary Electroklnetlc Methods R o o m M2, North Hall A. Guttman, Presiding 1:30

Bioanalytlcal Chemistry Mlnlconference: Sensors

1:50

R o o m M2, North Hall S. G. Weber, Presiding

2:10

8:30

8:50

9:10

9:30 9:50

10:25

10:45 11:05

11:25

11:45

(036) "Microsize" Conducting Polymer Sensor for the Determination of Some Organic and Biological Molecules. A. Galal, N. F. Atta, H. Zimmer, H. B. Mark, Jr. (037) Evaluation of Nation-Modified Car­ bon Microelectrodes as Sensors for Ra­ diopharmaceutical Imaging Agents. Β. Η. Swaile, E. A. Blubaugh, W. R. Meineman (038) Hardly Plasticized Tecoflex Mem­ branes as Biocompatible Alternatives of PVC Matrices in a Planar Ion Sensor De­ sign for Chronic Applications. E. Lindner, V. V. Cosofret, S. Ufer, R. P. Buck (039) Application of Laser-Radiation Im­ mobilization Schemes in Analytical Chemistry. D. L. Maniak, K. D. Hughes (040) Near-IR Biosensors: Enzymes Im­ bedded on Conductive Polymers. C. W. Brown, C-S. Chen, L Sun, S. C. Yang, A. G. Rand, A. F. Santos (041) Progress in Organic-Phase Biosen­ sors. J. Wang, Y. Lin, A. Eremenko, D. Lopez, N. Naser, J. Reviejo, L. Angnes, J. Liu, F. Dempsey, M. R. Smyth (042) Immobilization of Biomolecules Us­ ing Aldehyde-Functionalized Silanes. C. Bruning, J. Grobe (043) Development of a Biocompatible Potassium-Selective Electrode. L. G. Baches, J. R. Allen, P. Feldhoff, K. A. Brooks (044) Optical Sensing of Macromolecular Heparin and Other Polyanions with Thin Polymeric Films. E. Wang, M. E. Meyerhoff (045) Biomedical Applications of Flexible Microfabricated Array Electrodes. R. P. Buck, V. Cosofret, E. Lindner

148 A

Analytical

Chemistry,

Introductory Remarks. M. E. Meyerhoff (151) From Selective Interactions to Se­ lective Sensors. E. Pretsch (152) Ion Sensors in Clinical Chemistry: The Legacy of Professor Wilhelm Simon. P. D'OrazIo (153) Biomedical Applications of Flexible Microfabricated Array Electrodes. R. P. Buck (154) Spatial Imaging and Equilibrium Measurements of the Processes Inside an Ion-Selective Membrane. D. J. Harri­ son (155) Designing Selectivity for Fiber­ optic and Electrochemical Sensors. M. A. Arnold

2:30 2:50

3:25 3:45 4:05

4:25 4:45

(171) Protein Digestion and Analysis with Immobilized Enzymes Coupled with MS Analysis. L. Licklider, R. Takigiku, T. Keough, W. G. Kuhr (172) Postcolumn 35 S Detection for CE. S. Tracht, G. Forbes, V. Toma, J. V. Sweedler (173) Determination of Amino Acids by CE with Amperometric Detection. L. A. Colon, R. Dadoo, R. N. Zare (174) Mixed Micellar Electrokinetic Chro­ matography of Steroids. J. Bumgarner, M. G. Khaledi (175) Accurate Molecular Mass Determi­ nation of Proteins by Capillary SDS Gel Electrophoresis Using Programmed Fer­ guson Method. A. Guttman, J. Lindahl, P.C. Shieh, N. Cooke (176) Water-in-Oil Microemulsions as Nonaqueous Media for CE. C.F.K. Fung, J. G. Dorsey (177) On-Column Concentrator/Reactor for the Trace Analysis of Peptides in CE. L. Cruz, K. Seggebrush, J. V. Sweedler (178) On-Line Protein Analysis Using Coupled Capillaries for Covalent Immobi­ lization of Multiple Enzymes and CE. L. Licklider, W. G. Kuhr (179) Isoelectric Focusing of Proteins without Carrier Ampholytes in ConeShaped Capillaries. J. Pawliszyn, J. Wu (180) Universal and Selective Imaging Detection for Capillary Isoelectric Focus­ ing. J. Wu, J. Pawliszyn

3:25

3:45

4:05

4:25

Tuesday Morning Bioanalytlcal Chemistry Mlnlconference: On-Line Process Analysis on the Micron Scale (Arranged by W. G. Kuhr and D. J. Harrison) Room M3, North Hall W. G. Kuhr, Presiding 8:30 8:35

Introductory Remarks. W. G. Kuhr (310) Micromatching a Chemical Lab: Chemical Processing and Separation on a Chip. D. J. Harrison 9:05 (311) Microminiaturized Chemical Instru­ ments: The Ultimate Chemical Sensors? J. M. Ramsey, S. C. Jacobson, L. B. Koutny, R. Hergenroder 9:35 (312) High-Speed CZE. J. W. Jorgenson, E. Moore, Jr. 10:20 (313) Capillary Enzymphoresis of Biologi­ cal Molecules. Z. El Rassi, Y. Mechref 10:50 (314) On-Line Generation, Separation, and Detection of Protein Digests by CE. W. G. Kuhr, L. Licklider 11:20 (315) Continuous Sampling, Separation, and Detection with CE and Array Detec­ tion in Channels. A. G. Ewing, J. M. Mesaros, P. F. Gavin Bioanalytlcal Chemistry Mlnlconference: Environmental Analysis Including Immunoassay Room M2, North Hall K. Cammann, Presiding 8:30

Bioanalytlcal Chemistry Mlnlconference: Food Analysis

8:50

R o o m M1B, North Hall C. W. Brown, Presiding

9:10

1:30 1:50

(181) Food Packaging: Its Contribution to Your Diet? A GC/MS and LC/MS Investi­ gation. G. Lawson, C. Barkby (182) Degassing of Beer Samples Using "The Membrane Separating Technique." A. Nagal, M. Kobayashi, A. Sato, K. Imai, C. Ikeda, H. Yamashita, S. Yabuuti

Vol. 66, No. 3, February

1, 1994

(183) Combining SFE with Ion Chroma­ tography for Food Analysis. J. Jekot, A. Henshall, B. E. Richter (184) Thermal-Scanning Rheometer for Gelation and Cure Studies. R. E. Wetton, F. S. Baker (185) Rapid, Sensitive Spectroscopic De­ tection of E. coli on Meat. S. Chadha, F. Ge, Y. Yao, K. Mustafa, J. Vessella, C. W. Brown, W. H. Nelson, J. F. Sperry (186) In Situ Fermentation Analysis with a Fiber-Optic Near-IR Monitor. Y. LI, C-S. Chen, G. W. Brown, J. W. McCrady, F. M. Sun, R. W. Traxler (187) SEC with Nitrogen Detection of Peptides and Food-Grade Protein Hydrolysates by HPLC-CLND. E. M. Fujinarl, J. D. Manes (188) HPLC Determination of Sugars and Organic Acids in Food and Beverages Using a Fully Automated On-Line Dialy­ sis Technique for Complex Matrix Purifi­ cation. E. Verette, F. Qian, F. Mangani (189) Simultaneous Homogenous En­ zyme-Linked Binding Assay for Folate and Biotin. J. M. Buckwalter, K. Pummill, M. E. Meyerhoff

9:30

(341) Isolation and Identification of RootInhibiting Compounds from Corn Gluten Meal. D. L. Liu, N.E. Christians (342) Characterization of Biologically Ac­ tive Asphalt Fume Fractions Using GC/ MS. L. D. Olsen (343) Direct UV Absorptiometry for Ex­ amination of Wastewater Quality. O. Thomas, F. Theraulaz, S. Gallot (344) Fast Determination of Index of Mat­ uration of Compost and Soil Organic Mat­ ter. P. Prudent, C. Massiani, O. Thomas

PITTCONU 9:50 10:25

10:45 11:05

11:25

11:45

4:45

(345) Immunoassay for Determination of Triazine Herbicides Based on Sequential Saturation. U. Karst, K. Cammann (346) Development of a Capillary Enzyme Immunoassay for the Determination of Atrazine in Water Sample. T. Jiang, H. B. Halsall, W. R. Heineman (347) An Instrument for Use with Immu­ noassays. J. P. Mapes, T. S. Withers, R. E. Almond, S. S. Friedman (348) Explosives Field Analysis Kit for TNT. J. P. Mapes, P. P. McDonald, S. P. Arrowood, W. B. Studabaker, S. B. Fried­ man (349) Development of an Immunoassay for Detection of PAHs in Soil Samples. J. P. Mapes, P. P. McDonald, R. E. Al­ mond, S. B. Friedman (350) Rapid, On-Site Immunoassay for Detecting Petroleum Products in Ground­ water. J. P. Mapes, P. P. McDonald, R. E. Almond, S. B. Friedman

Wednesday Morning Symposium: Near-IR Medical and Biomedical Applications (Arranged by D. E. Honigs) Lenox Lohr Theatre, East Hall D. E. Honigs, Presiding 8:30 8:35

William Fred McClure Tomas Hirschfeld Award

HPLC—Bioanalytical Room M6B, North Hall

1:55

T. E. Wheat, Presiding 8:30 8:50

9:20

9:30 9:50

10:25

10:45

11:05 11:25

11:45

(371) Chromatographic Studies of Molec­ ular Recognition of Silica-Immobilized Proteins. V. Tlttelbach, R. K. Gilpin (372) Mobile-Phase Effects on Recovery of Proteins from Polybutadiene-Coated Ceramic Supports. L. Sun, A. V. McCormick, P. W. Carr (373) Separation of Enantiomers by Cyclodextrin Mobile-Phase HPLC: Thermo­ dynamic and Molecular Modeling Studies. L. J. Cline-Love, J. J. Tang, G. Tsodikov, E. Mularz (374) Semimicrobore HPLC Analysis of Porphyrins Using Fluorescence Detec­ tion. F. Lyabaya, R. DeMuro, D. Fiore (375) New Stable and Sensitive HPLC Method for Determination of Enantiomeric Purity of Amino Acids and Amines. T. E. Beesley, J. A. Lupia, D. W. Armstrong (376) Comparison of Catecholamine Analysis Using Different Modes of HPLC. H. H. Freiser, M. N. Schmuck, Κ. Μ. Gooding (377) HPLC and LC/MS for the Study of Photoproducts from Reactions of Psor­ alens with Olefins. D. J. Semin, K. L. Rowlen (378) Use of RPLC for Prediction of Bioaccumulation. C. O. Desantis, J. G. Dorsey (379) Activity and Fluorescent Probe Studies of Enzymes Adsorbed in Hydro­ phobic Interaction Chromatography Sys­ tems. A. J. Aschman, C. H. Lochmuller (380) Quantitation of Charge on Solutes by SEC. P. L. Dubin, M. Potschka, Y. Zhu

2:15 2:35 2:55

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Chemistry,

R o o m M1B, North Hall C. Fenselau, Presiding 8:30

9:10

R o o m M2, North Hall M. J. Wirth, Presiding

9:30

1:30

1:50

2:10

2:30 2:50

3:45

4:05

Room M3, North Hall D. A. Roston, Presiding Introductory Remarks. D. A. Roston (441 ) Survey of Near- IR Reflectance Analysis Applications to Pharmaceuticals. O. MacDonald

Bioanalytical Chemistry Miniconference: Biological A p p l i c a t i o n s of M S

8:50

Tuesday Afternoon

1:30 1:35

(442) SFE Method Development for a Controlled-Release Drug Formulation. D. A. Roston (443) Characterization of Polymorphic Behavior in Pharmaceutical Solids by Solid-State NMR and IR. H. G. Brittain (444) Advances in Chiral Protein BondedPhase HPLC Columns. T. C. Pinkerton (445) CE in Pharmaceutical Analysis: Characterization of Anionic Cyclodextrin Mixtures and Their Application in Stereo­ isomer Separations. J. F. Stobaugh

Introductory Remarks. D. E. Honigs (580) Near-IR Fluorophores in Bioanalyti­ cal Applications. G. Patonay 9:10 (581) Near-IR Spectrometric Imaging in Symptomatic Carotid Occlusive Disease. R. A. Lodder, R. Dempsey, R. Moore 9:45 (582) Depth-Resolved Near-IR Spectros­ copy. J. K. Drennen, N. G. Nerella 10:35 (583) Methods for Measuring Glucose in Biological Matrices by FT-Near-IR Spec­ troscopy. M. A. Arnold, G. W. Small 11:10 (584) Healthy Measures by Near-IR Spectroscopy. J. W. Hall, A. Pollard

Bioanalytical Chemistry Miniconference: Interfaces, Colloids, and Luminescence

3:25

Bioanalytical Chemistry Miniconference: Pharmaceutical Analysis (Arranged by D. A. Roston)

(479) Spectroscopic Probing of Phospho­ lipid Interfaces. M. J. Wirth, J. L. Sassaman, J. M. Kovaleski

4:25

(470) Solid Matrix Luminescence Charac­ terization of DNA Adducts Adsorbed on 1% α-Cyclodextrin/NaCI and 25% Trehalose/NaCI Solid Matrices. Y. Chu, R. J. Hurtubise (471) Synthesis of Near-IR Labeled Oligo­ nucleotides Using Postsynthesis Labeling Techniques and Direct Labeling via Phosphoramidite Chemistry. D. B. Shealy, N. Narayanan, B. Fowler, S. Sut­ ter, L. Strekowski, G. Patonay (472) Studies of DNA Binding Interactions Using Lifetime-Resolved FluorescenceDetected Circular Dichroism. M. J. Jo­ seph, L. B. McGown (473) Diagnostics of Peroxidase Oscilla­ tory Dynamics. A. Scheeline, D. L. Olson, V. Lvovich (474) Binding Interference Methodology To Probe Protein Contact Interactions. S. C. Beale, Y. H. Huang, J. Lebowitz (475) Assembly and Properties of Col­ loid-Based Macroscopic Surfaces for SERS. M. Natan, Κ. Allison, R. Bright, K. Grabar, J. Davis, D. Walter, P. Smith (476) Study of Resonance-Enhanced Second Harmonic Generation of Hemicyanine Dye Langmuir-Blodgett Film. Z. Xu, W. Lu, P. W. Bohn (477) Determination of Molecular Orienta­ tions in Planar Membrane Models with Waveguide Imaging Instruments. J. L. Moore, K. D. Hughes (478) Routine Double-Beam Spectros­ copy of Lipid Films at the Air-Water In­ terface. A. Haywood, K. D. Hughes

Vol. 66, No. 3, February 1, 1994

9:50 10:25 10:45

11:05

11:25

(617) Analysis of Blood Serum Sphinganine and Sphingosine by Thermospray MS. R. A. Thakur, J. S. Smith (618) Matrices for MALDI Analysis of Electroblotted Proteins and Protease Di­ gests. C. Fenselau, M. M. Vestling (619) Research on Sample Preparation Alternatives for MALDI-MS. J. Bai, Y. Liu, D. M. Lubman (620) Ion Trap MALDI-TOFMS for DNA Sequencing. Y. Liu, J. Bai, D. M. Lubman (621) Gas-Phase Peptide Analysis by High-Resolution MS. Β. Ε. Winger, B. Becker, R. Hein, J. E. Campana (622) Peptide Sequencing by MALDI-MS/ MS/MS. J. E. Campana, J. Covey, L-S. Sheng, J. Haas (623) High-Speed Mass Detector for Chromatography. J. G. Boyle, T. Dresch, E. Gulcicek, J. F. Banks, Jr., C. W. Whitehouse (624) Application of MALDI for Quantita­ tive Analysis of Biomolecules. A. I. Gusev, W. R. Wilkinson, A. Proctor, D. M. Hercules (625) LC/MS Applications with ESI and Ultrasonic Nebulization: To Split or Not To Split? J. F. Banks, Jr., S. Shen, J. Quinn, C. M. Whitehouse

Bioanalytical Chemistry Miniconference: Pharmaceutical Analysis R o o m M2, North Hall J. Stobaugh, Presiding 8:30

8:50

(626) Multidimensional HPLC Approaches for Determining the Pharmacodynamics of the New Anticancer Agent Cyclopentenyl Cytosine. R. Agbaria, H. Ford, F. Xie, Jr., D. G. Johns, J. A. Kelley (627) Comparative Study of Solid Extrac­ tion Using Particle-Loaded Membranes and Large-Particle Packed Columns for the Extraction of Mexiletine and Flecainide from Serum. D. A. Wells, G. L. Lensmeyer

PITTCOH U 9:10

9:30 9:50

10:25 10:45 11:05

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11:45

(628) Further Investigations of the Enhanced Extraction of Phénobarbital from Serum. J. N. Valenta, S. G. Weber, A. D. Hamilton, R. P. Dixon (629) Drug-Cyclodextrin Binding Constants by Potentiometry. A. Avdeef, J.E.A. Comer, K. J. Box (630) LC Investigation of the Reaction between C0 2 and Amines: Application to Amino Acids and Peptides. J. G. Chen, M. Sandberg, S. G. Weber (631) Optimization of Enantiomeric Separation of Chiral Pharmaceuticals by CE. A. Guttman, N. Cooke (632) Determination of Enantiomer Ratios Using a Near-IR/HPLC Detector. E. W. Ciurczak, E. R. Murphy, L. J. Cline-Love (633) Improvement of Resolution in Chiral Separations of Pharmaceutical Compounds by Cyclodextrin-Modified CE. C. Quang, M. G. Khaledi (634) Determination of Peptide Drug Chiral Purity through Hydrolysis, Derivatization, and LC-ES/MS Analysis. J. B. Crowther, P. A. Savage, P. A. Abuaf, D. R. Goodlett, J. W. Tolan (635) Separation of Prostaglandins by CE. Υ. Ζ. Hsieh, Κ. L. Kuo

Bioanalytical Chemistry Mlniconference: Microbioanalytical Chemistry R o o m M2, North Hall G. G. Wallace, Presiding 1:30

1:50

2:10 2:30

2:50 3:25 3:45

Wednesday Afternoon Bioanalytical Chemistry Mlniconference: Answering Biochemical Questions

4:05 4:25

R o o m M1B, North Hall L. B. McCown, Presiding 1:30

1:50

2:10 2:30

2:50 3:25

3:45

4:05

4:25

4:45

(765) Studies of Structure Modifications of High-MW Urokinase Caused by Oxida­ tion and Deamidation. E. Kentzer, A. Buko, J. Jandora, G. Menon, V. Sarin (766) Application of the Protocol for As­ signment of Conformation-Sensitive IR Bands of Proteins. R. J. Jakobsen, J. R. Powell (767) Optimizing Synthesis of DNA/RNA Momomers with Near-IR Spectroscopy. J. W. Hall, N. Lazarowych (768) Computational Chemical Analysis of Selective Glycation Mechanism. T. Hanai, H. Hatano, C. Ikeda, N. Nimura, T. Kinoshita (769) Fluorescence Probe Studies of Or­ ganized Bile Salt Media In Apolar Sol­ vents. S. Lee, L. B. McGown (770) Identification and Quantitation of Two Cholecystokinin Peptides In Rat Brain by HPLC Combined with FABMS. G. A. Qureshi, J. Silberring, F. Nyberg, P. Sodersten (771) Investigation of Biodegradable Polymer Production in Strains of Pseudomonas. K. D. Crawford, F. Young, J. Kastner, S. W. May, K. D. Hughes (772) Analysis of Post-Translational Modifications Appearing in Human Eye Lens Crystallins by MS. R. Orlando, S. He, S. Pan, I. J. Amster (773) Effect of Side Group Absorption on the Estimation of Albumin Conformation by FT-IR Spectroscopy. X. LI, Y. Xu, T. Zhang, H. Li, B. XU, Z. Xu, J. Wu, G. Xu (774) FT-IR Study on Calcium Copper Coprecipitate Bilirubinate. W. LI, G. Shen, R. Soloway, Z. Xu, S. Weng, J. Wu, G. Xu

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(775) In Vivo Nanosampling for RealTime Biochemical Monitoring on Single Intact Rat Conceptuses and Single Cells. W. Tan, C. Harris, R. Kopelman (776) Determination of Blood Constitu­ ents in Freely Moving Animals by Microdialysis and CE Coupled to LIF Detec­ tion. N. A. Guzman, P. Rada, L. Her­ nandez, S. Park, K. Iqbal (777) Amperometric Detection of Exocytosis at Single Insulin-Secreting Pancreas Cells. L. Huang, R. T. Kennedy (778) Amperometric Enzyme Sensors for Choline and Acetylcholine Artificially Re­ leased into Extracellular Fluid of Brain Tissue. M. G. Garguilo, A. C. Michael (779) Submicrometer Intracellular Optical Fiber Calcium Sensor. M. Shortreed, W. Tan, Z. Y. Shi, M. Kuhn, R. Kopelman (780) New Rapid Electrochemical Immu­ noassay Technology. G. G. Wallace, O. A. Sadik, D. Barnett, S. Skopec (781) Highly Sensitive Homogenous As­ say for Biotin Based on Bioluminescent Recombinant Protein. S. Daunert, A. Witkowski, S. Ramanathan (782) Rapid Immunoassay by CZE with LIF Detection. N. Schultz, R. T. Kennedy (783) Fluorescent Immunoassays Using Near-IR Fluorophores as Labels. R. J. Williams, L. Strekowski, V.C.W. Tsang, M. Lipowska, N. Narayanan, G. Casay, J. Peralta, G. Patonay (784) Ultramicro Fiber-Optic Chemical Sensors and Real-Time Biochemical Measurements on Single Rat Embryos. W. Tan, Z. Y. Shi, C. Harris, R. Kopel­ man, B. Thorsrud

11:05 (904) Development of a New Flow Cell for High-Performance Detection of Positron-Emitting Nuclides in Flow Scin­ tillation Analyzer Systems. K. J. Borowski, R. Ehrenkaufer, H. F. Vanbrocklin 11:25 (905) Identification and Characterization of Proteins in SEC/HPLC with LALLS. I.S. Krull, R. Mhatre, R. L Qian, W. J. Matin 11:45 (906) Multichannel Fluorescence Detec­ tion in CE. A. Timperman, K. Khatib. J. V. Sweedler

Thursday Afternoon Bioanalytical Chemistry Mlniconference: Clinical Analysis R o o m M2, North Hall F. B. Melnick, Presiding 1:30

1:50 2:10 2:30

2:50

3:25

3:45

Thursday Morning 4:05 Bioanalytical Chemistry Mlniconference: Separations and Detectors

4:25

R o o m M2, North Hall P.L. Dubin, Presiding 8:30

(897) Correspondence between SEC Cal­ ibration Curves for Spherical vs. Rodlike Molecules. P. L. Dubin 8:50 (898) Use of Fluoride-Modified Zirconia for Analytical and Preparative IgG Sepa­ rations. J. E. Morris, C. G. Tolppi, J. L. Zeller, P. W. Carr, M. Flickinger 9:10 (899) Use of Zirconia Supports for Fluidized-Bed Separations of Proteins. J. E. Morris, C. G. Tolppi, P. W. Carr, M. Flickinger 9:30 (900) Synthesis and Characterization of Porous Zirconia Supports for HPLC and Perfusion Chromatography. M. J. Annen, F. Lorenzano-Porras, R. Kizhappali, A. V. McCormick, P. W. Carr, M. Flickinger, L. Sun 9:50 (901) The Direct Resolution of Enantiomers by CE. M. E. Swartz, M. Merion, J. Petersen, J. Mazzeo, E. Graver, P. R. Brown 10:25 (902) Penicillin-Binding Protein Analysis: Novel Fluorescent and Spectroscopic Probes for HPLC and SDS-PAGE. Y. Du, R. Ahluwalia, R. A. Day 10:45 (903) Practical Uses of a New Fluores­ cence HPLC Detector: In Trace Analysis and for Light Scattering To Obtain Molec­ ular Weights of Proteins. R. Gard

Vol. 66, No. 3, February

1, 1994

4:45

(1026) Investigation of the Enzyme β-glucuronidase in Serum as a Potential Marker for Bladder Carcinoma. F. B. Mel­ nick, L. H. Block (1027) Systematic Analysis of Accumulat­ ing Solutes in Uremia. G. A. Qureshi (1028) Myoglobion Electron-Transfer and Ligand-Binding Reactions. B. C. King, D. J. Cohen, F. M. Hawkridge (1029) Quantitative Determination of Free and Total Calcium in Human Serum by High-Performance CZE with Indirect Photometric Detection. Y. Ma, R. Zhang (1030) Simultaneous Measurement of Essential, Trace, and Ultratrace Elements in Biomedical Samples by Direct Injection Nebulization Plasma Optical Emission MS. M. A. Wlngerd, K. Hu, J. Helfrich, G. Kunselman, O. Wiederin (1031) Determination of Metallothioneins in Mouse Tissues by Silver-Saturated Methods. F. Tie, W. Y. Luk, L. Y. Li, B. Ru (1032) Factors Influencing the Separation of Metallothioneins by High-Performance CZE. X.Q. Shan, G. O. Liu, W. Wang (1033) Determination of Lead in Blood by Flow Injection Potentiometric Stripping Analysis. H. D. Dewald, J. H. Aldstadt (1034) Gold Binding Sites in Red Blood Cells—An Application of FIA and HPLC Coupled with ICPMS. Y. Zhang, R. C. Elder, J. G. Dorsey, K, Tepperman, E. V. Hess, K. G. Pryhuber (1035) Trace Metals Toxicology and the Potential of Quantitative Screening of Bi­ ological Specimens by ICPMS. R. J. Audette. L. Yakymyshvn

Monday Morning Electrochemistry: Coupled with S p e c t r o s c o p y or C h r o m a t o g r a p h y Room 2 0 W 1 , East Hall W. Sharpe, Presiding 8:30 8:50

(056) Paper Withdrawn. (057) Mechanistic and Dynamic Investi­ gation of Electrochemical Redox Pro­ cesses Using Rapid-Scan and StepScan FT-IR Spectrometry. C. M. Pharr, P. R. Griffiths

PITTCOH U 9:10 9:30 9:50

10:25

10:45 11:05

11:25

(058) Imaging of Anodic Evolution of Oxy­ gen Using Quinine Fluorescence. J. E. Vltt, R. C. Engstrom (059) Electrode Imaging of the Reduction of Oxygen. W. J. Bowyer, R. C. Eng­ strom (060) Using Electrochemistry To Trap a Photoisomerized Photochromic Molecule. M. T. Stauffer, M. J. Preigh, S. G. We­ ber, F-T. Lin (061) Formation and Characterization of a Monolayer Mercaptosilane as a Spa­ tially Reversible Adhesion Promoter. W. Lu, Ζ. Xu, P. W. Bohn (062) LC Separation with Pulsed Electro­ chemical Detection of Organosulfur Com­ pounds. P. J. Vandeberg, D. C. Johnson (063) LC Separation with Pulsed Electro­ chemical Detection of Aliphatic Amines and Diamines. D. A. Dobberpuhl. D. C. Johnson (064) EXAFS Spectroelectrochemical Analysis of Gold Electrodes Modified with Ruthenium-Purple Films. R. O. Rigney, R. C. Elder, W. R. Heineman

Tuesday Morning S y m p o s i u m : I. M . K o l t h o f f M e m o r i a l Symposium (Arranged by J. F. Coetzee) Earl M c M a h o n R o o m A , East Hall J. F. Coetzee, Presiding 8:30 8:55

Introductory Remarks. J. F. Coetzee (306) Studies of Electroactive Polymers with the Quartz Microbalance. S. Bruckensteln 9:35 (307) Electron Transfer to Redox-Active Counterions in Soluble Polyelectrolyte Metal Complexes. F. C. Anson 10:30 (308) Sensitive and Selective Analytical Methods Based on Electrogenerated Chemiluminescence. A. J. Bard 11:10 (309) Surface Vibrational Spectroscopy of Electrodes. A. T. Hubbard

Tuesday Afternoon

Monday Afternoon

S y m p o s i u m : I. M . Kolthoff M e m o r i a l Symposium (Arranged by J. F. Coetzee)

Electrochemistry: Characterization of E l e c t r o d e P r o c e s s e s

Earl M c M a h o n R o o m A, East Hall J. F. Coetzee, Presiding

R o o m 2 0 W 1 , East Hall D. C. Johnson, Presiding

1:30 1:35

1:30

1:50

2:10

2:30

2:50

3:25

3:45

4:05

4:25

4:45

(200) Electrochemical Quartz Crystal Mi­ crobalance Studies of Tetracyanoquinodimethane-Conducting Salt Electrodes. D. C. Evans, J. O. Chambers, W. Adeniyi (201 ) Application of an Electrochemical Quartz Crystal Microbalance to a Study of the Anodic Response of Cysteine at Gold Electrodes in Alkaline Media. A. Tudos, D. C. Johnson (202) In Situ Electrochemical Quartz Crystal Microbalance Study of Copper Underpotential Deposition on Gold(111). K. Ashley, G. L. Borges, Κ. Κ. Kanazawa, J. Richer, J. G. Gordon II (203) Sliver Coverage During Underpo­ tential Deposition on AU(11 1) in Sulfuric Acid. J. G. Gordon II, G. L. Borges, J. N. Howard, Κ. Κ. Kanazawa (204) Determination of the Capacitance of Platinum Electrodes by Chronocoulometry and ac Impedance. R. L. Turner, L. R. Faulkner (205) Electrochemical Characterization of Modified Surfaces for Microscopically Lo­ calized Derivatization. M. D. Koppang, R. Carson, J. Li, R. C. Engstrom (206) Dependence of Electron-Transfer Kinetics at Carbon Electrodes on the Electronic Structure of the Carbon Mate­ rial. R. L. McCreery, K. R. Kneten, M. McDermott (207) Characterization of Pretreated Glassy Carbon Surfaces. M. A. Fryling, R. L. McCreery (208) Impedance Spectroscopy Studies of Ion Transport across Polycarbonate Membranes Modified with Ion Exchanger. G. Sandl, P. Vanysek (209) Electrodeposition of Cobalt-Chro­ mium Alloy from Trivalent Chromium Baths. H. Dasarathy, C. Riley, H. D. Coble

Adrian C. Michael Young Investigator Award

2:15 2:55 3:50

4:30

Introductory Remarks. J. F. Coetzee (446) Can Chemical Probes Determine Generally Valid Properties of Solvent Mixtures? Y. Marcus (447) Ambient-Temperature Ionic Liquids: Real Nonaqueous Solvents. R. A. Osteryoung (448) Studies of the Hydrophobic Effect and Its Implications for the Retention Mechanism in RPLC. P. W. Carr (449) Immobilized Metalloporphyrins as Versatile Stationary Phases in LC. M. E. Meyerhoff (450) Voltammetry: Kolthoff's Creation and Its Use To Sample Microenvironments. R. M. Wrlghtman

Electrochemistry: Bioelectrochemistry R o o m 2 0 W 1 , East Hall A. G. Ewing, Presiding 1:30

1:50

2:10

2:30

(500) Development of Electrochemical Sensors for Characterization and Deter­ mination of Radiopharmaceuticals. Y. Deng, G. Reeder, W. R. Heineman, C. J. Seliskar (501) Polymer-Modified Microelectrode as a Sensor for Analogues of TC-Based Radiopharmaceuticals. B. L. Ramos, E. A. Blubaugh, A. J. Horn, W. R. Heineman (502) Optimizing Screen-Printed, Microfabricated, Potentiometric Solid-State Ion/Biosensor Arrays. D. Llu, H. D. Gold­ berg, R. W. Hower, R. B. Brown, M. E. Meyerhoff (503) Poly(binaphthyl-20-Crown-6) as a Receptor-Based Molecule-Selective Po­ tentiometric Electrode for Catechola­ mines. S. Lunsford, Y. Ma, Z. Huang, A. Galal, C. Striley, H. Zimmer, P. S. Bishop, H. B. Mark, Jr.

ο ο Ε —J

UJ

Χ Ο

View of Chicago's Chinatown

154 A

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Vol. 66, No. 3, February

1, 1994

neighborhood

PITTCOIIU 2:50

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3:45

4:05 4:25 4:45

(504) Electrochemical Monitoring of Dopamine Exocytosis from Giant Dopam­ ine Cells of Planorbis Corneus. G. Chen, G. Luo, A. G. Ewing (505) Evidence of the Electrocatalytic Ef­ fect of the Heteroatom in a Conducting Polymer for Detection of Organic and Bi­ ological Compounds. A. Galal, K. Petticrew, N. F. Atta, H. Zimmer, H. S. Mark, Jr. (506) Electrochemical Investigation of Biomolecules and Affecting Factors on Ultrathin Films with Different Degrees of Hydrophobicity. 0. Cheng, A. BrajterToth (507) Reductive Activation of Mitomycin C by Electrochemistry/MS. M. V. Thompson, A. Brajter-Toth (508) CE Separations with Pulsed Elec­ trochemical Detection of Carbohydrates. R. E. Roberts, D.C. Johnson (509) Capillary Enzyme Electrochemical Immunoassay Coupled with Ultrafiltration for Digoxin. K-J. Yu, H. B. Halsall, W. R. Heineman

Wednesday Morning Symposium: Charles N. Rellley Award (Arranged by J. M. Rosamilia)

10:40 (593) Award Address: Amperometric En­ zyme Sensors with Neurochemical Appli­ cations. A. C. Michael, M. G. Garguilo, D. M. Cannon, Jr. 11:15 (594) Myoglobin Electron-Transfer and Ligand-Binding Reactions. F. M. Hawkridge. B. C. King, D. J. Cohen

Wednesday Afternoon Symposium: C h e m i c a l Sensors for In Vivo Monitoring. (Arranged by A.P.F. Turner and G. S. Wilson) R o o m M3, North Hall A.P.F. Turner, Presiding 1:30 1:35 2:10 2:45 3:35 4:10

Introductory Remarks. A.P.F. Turner (730) Chemical Sensors for In Vivo Moni­ toring. A.P.F. Turner (731) Sensors for Monitoring Neurotrans­ mitters. R. M. Wightman (732) In Vivo Sensing Using ISEs. R. P. Buck, V. V. Cosofret, G. Under (733) Implantable Sensors for Glucose Monitoring. G. Reach (734) Current Status and Future Pros­ pects for Commercialization of Implant­ able Biosensors. K. W. Johnson

Symposium: Molecular· Sea le P r o b e s of E l e c t r o d e I n t e r f a c e s (Arranged by H. S. White)

8:30 8:35

Lenox L o h r Theatre, East Hall H. S. White, Presiding

8:40 9:15 9:50

3:50

4:30

Earl McMahon Room 5, East Hall J . M. Rosamilia, Presiding Introductory Remarks. J. M. Rosamilia Presentation of the 1994 Charles N. Reilley Award and the 1994 Young Investiga­ tors Award of Electroanalytical Chemistry. D. Evans (590) Award Address: Some Recent Electrochemical Glances at Carbon and Silicon. B. Miller (591) Electron Transfer Across SelfAssembled Monolayers. C.E.D. Chldsey (592) Amperometric Biosensors Based on Electron Conductivity Redox Hydrogels. A. Heller

2:55

1:30 1:35 2:15

Introductory Remarks. H. S. White (745) Characterization of Electrode-Con­ fined Nanoporous Membranes by STM and Molecular Probes. R. M. Crooks (746) Structure of the Double Layer at a Ag(111) Electrode as Measured with Sur­ face X-ray Scattering. M. F. Toney

(747) Applying IR Spectroscopy to Probe Adsorption and Reactivity at SingleCrystal Electrodes. C. Korzeniewski (748) STM and Atomic Force Microscopy of Molecular Crystal Interfaces during Electrochemical Crystal Growth. M. D. Ward (749) Structural Investigations of Halo­ gen-Coated Ag(111) Surfaces. H. S. White

Thursday Morning Electrochemistry: Modified Electrodes R o o m 20W7, East Mall A. C. Michael, Presiding 8:30

8:50 9:10

9:30

9:50

10:25

10:45 11:05

11:25

11:45

(917) Charge Transport Properties of Electrodes Modified by the Spontaneous Adsorption of Asymmetric Dialkylsulfides. M. R. Anderson, M. Zhang (918) Paper Withdrawn. (919) Mediated Bromate Reduction and Interfacial Kinetics of Glassy Carbon Electrodes Modified by Spontaneously Adsorbed Polyoxometallates. R. L. Turner, L. R. Faulkner (920) Anthracene Voltammetry in CO, at Polyethylene oxide)-Coated Electrodes. S. F. Dressman, E. P. Sullenberger, A. C. Michael (921) Voltammetry of Quinones in C0 2 Based Fluids with a Platinum Microdisk Electrode Coated with Polyethylene ox­ ide) Films Containing Various Electro­ lytes. E. F. Sullenberger, S. F. Dressman, A. C. Michael (922) Preferential Anodic Generation of p-Quinone at Bismuth-Doped Lead Diox­ ide Electrodes by Electrochemical Degra­ dation of Benzene and Phenol. Κ. Τ. Kawagoe, D. C. Johnson (923) Electrochemical Reaction Rates and the Predictions of Butler-Volmer Ki­ netics. R. J. Forster, L. R. Faulkner (924) Electrode Fabrication by Chemical Vapor Deposition Methods. J. R. Kirchhotf, M. Kummer, G. Zhao, D. M. Giolando (925) Novel Coatingless Low-Polarization Pacemaker Electrodes. S. Often, F. Callaghan, A. Rebell (926) Catalytic Oxidation and Flow De­ tection of Acetaminophen in LC at Dicyano-bis(1,10-phenanthroline)lron(ll)Modified Electrode. E. Wang, H. Li

Friday Morning Symposium: Electrochemistry— Sensors and Voltammetry R o o m 20W7, East Hall L Bâchas, Presiding 8:30 8:50

9:10

9:30

Wrigley Field—home

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Vol. 66, No. 3, February

1, 1994

(1196) Application of Solid-State pH Electrodes to Difficult Samples. M. S. Frant, S. J. West, R. A. Turpin, C. Ewing (1197) Development of a Polymer Membrane-Based Sulfite-Selective Electrode. R. S. Hutchins, L. J. Sun, P. Molina, M. Alajarin, L. G. Bâchas (1198) Novel Tin(IV)-Based Potentiometric Phosphate Carriers. N. A. Chaniotakis, J. K. Tsagatakis, M. Vamvakaki, K. Jurkschat (1199) Response of Aminated PVCBased and Neutral Carrier-Based pH Microchemical Sensors in the Presence of Aminos of Different Lipophilicities. V. V. Cosofret, E. Lindner, R. P. Buck

P/TTCONU 9:50

10:25

10:45 11:05 11:25 11:45

(1200) Determination of Nitrite in Foods and Wastewater Using a Nitrite-Selective Electrode. M. S. Frant, N. A. Chaniotakis, S. J. West, X. Wen (1201) Instrumentation and Applications of Programmed Background Compensation in Voltammetry. P. E. Sturrock, G. E. O'Brien (1202) Large-Amplitude ac Voltammetry at Microelectrodes. J. K. Cullison, W. G. Kuhr (1203) Automation for Total Organic Halide Analysis. W. L. Robinson, Y. Takahashi (1204) Technique for Measuring Total Fluorine Contents. D. Smith, Q. Yao (1205) Formation of Antiomonites and Thioantimonites of Zinc as a Function of pH, and pH-Metric Determination of Thioantimonite Anions. S. Prasad

Monday Afternoon S y m p o s i u m : J a m e s L. W a t e r s 5 t h Annual Symposium Recognizing P i o n e e r s i n t h e D e v e l o p m e n t of Analytical Instrumentation—MS (Arranged by R. E. Witkowski) Earl M c M a h o n R o o m B, East Hall R. E. Witkowski, Presiding 1:30 1:35 2:10 2:45 3:35 4:10

Introductory Remarks. R. E. Witkowski (166) MS: From an Unpredictable Laboratory Device to a Sophisticated Analytical Tool. A. O. Nier (167) Development and Early Applications of Commercial Mass Spectrometers. A. G. Sharkey (168) MS and the Pittsburgh Conference: Parallel Spectacular Developments. F. W. McLafferty (169) Metamorphosis of Organic MS from Black Magic to Chemistry. S. Meyerson (170) Early Development and Commercialization of Quadrupole Mass Spectrometers. R. E. Finnigan

Tuesday Morning S y m p o s i u m : F T - M S of Biomolecules (Arranged by F. W. McLafferty)

Monday Morning

R o o m M1B, North Hall F. W. McLafferty, Presiding

Symposium: N e w Approaches to E l e m e n t a l M S : Innovations in Ion Sources and Mass Analyzers (Arranged by P. B. Farnsworth) Lindheimer Room B, East Hall P. B. Farnsworth, Presiding 8:30 8:35

Introductory Remarks. P. B. Farnsworth (006) Novel Instrumental Configurations for Atomic MS. G. M. Hieftje, T. W. Burgoyne, D. P. Myers, G. Li, P. Yang 9:10 (007) TOF Mass Analyzers for Elemental MS. P. B. Farnsworth, Y. Chen, M. Wu, J. Sin, M. L Lee 9:45 (008) Laser Ablation Ion Trap MS. M. Blades, C. Gill 10:35 (009) Plasma MS: Consider the Source. J. A. Caruso 11:10 (010) Elemental Electrospray MS. G. Horllck, G. R. Agnes, I. Stuart Symposium: Surface MS—Probing Real-World Samples (Arranged by A. Benninghoven) Lindheimer Room C, East Hall A. Benninghoven, Presiding 8:30 8:35

Introductory Remarks. A. Benninghoven (016) Surface Analysis by TOFMS of Sputtered Ions. A. Benninghoven 9:10 (017) Polymer Analysis Using TOFSIMS. D. M. Hercules 9:45 (018) Laser Postionization: Choosing the Right Laser for a Variety of Chemical Analyses. C. H. Becker 10:35 (019) Laser Desorption MS—High Spatial Resolution and High Mass Resolution Analysis of Oxide Samples. M. Pellin 11:10 (020) SIMS as a Detector for Planar Chromatography. K. L. Busch

158 A

Analytical Chemistry,

8:30 8:35

Introductory Remarks. F. W. McLafferty (300) FT-ICR Remeasurement Techniques for Large Biomolecules. D. A. Laude, Jr. 9:05 (301 ) Chemical Reactivity Studies with FT-ICRMS. N.M.M. Nlbberling 9:35 (302) Protein Structural Elucidation by Tandem FT-MS. E. R. Williams, D. S. Gross, P. D. Mills, P. J. Johnson 10:20 (303) High-Performance MALDI of Biomolecules Using FT-MS. C. L. Wilkins 10:50 (304) Strategies for Improved High Massto-Charge Measurements in FT-MS. M. L. Gross 11:25 (305) High - Resolution Tandem MS of Biomolecules. F. W. McLafferty, R. A. Chorush, M. W. Senko, J. P. Speir

Pat J. Sandra Dal Nogare Award

11:05 (338) TOFMS on Parent Ions of Benzene Analogues Produced by Chemical API. A. F. Schreiner, J. W. Carnahan, C. H. Sin 11:25 (339) Determination of VOCs in Ambient Air with GC Flame Ionization and Ion Trap Detection. S-L. Liu, R. J. Carley, J. Kang, J. Chen, J. D. Stuart 11:45 (340) Performance of an Atmospheric Pressure Corona Discharge Ion Source with Ultrasonic Nebulization. B. A. Andrien, J. Quinn, C. M. Whitehouse ICPMS—Instrumentation and Applications Chicago R o o m A, East Hall M. A. Feldman, Presiding 8:30

8:50 9:10 9:30

Air A n a l y s i s / A P I M S J o h n Evers Theatre, East Hall D. N. Lineman, Presiding 8:30

(331) Air Toxics Analysis: A QA/QC Overview. R. Isaacs, J. Soroka, R. F. Weston, R. Shinghvi 8:50 (332) Fully Automated Air Canister Analysis (EPA TO-4) by Ion Trap Technology. W. C. Schnute, J. M. McMillian, S. Reise 9:10 (333) Compact TOF Mass Spectrometer for Residual Gas Analysis. E. Gulcicek, C. M. Whitehouse 9:30 (334) GC/MS Identification of Paint Discoloration Agent of a Ship's Interior Surface. J. R. Dannecker, Jr., A. E. Comeau 9:50 (335) High Concentration Levels and Increased Dynamic Range on an Ion Trap Mass Spectrometer Configured for Headspace Analysis of Drinking Water. J. M. McMillian, W. C. Schnute, G. Woffendin, X. Hong 10:25 (336) Identification of Volatile Mosquito Attractants by GC/MS and GC/MS/MS. U. R. Bernier, R. A. Yost, C. E. Schreck, D. R. Barnard 10:45 (337) Gas-Phase API: RF Discharge vs. Corona Discharge. J. J. Zhao, T. J. Korniski, M. A. Dearth, D. M. Lubman

Vol. 66, No. 3, February 1, 1994

9:50 10:25

10:45 11:05 11:25

11:45

(381) Evaluation of Two Ion-Optic Configurations for an Orthogonal ICP TOF Mass Spectrometer. D. P. Myers, G. Li, P. Yang, G. M. Hieftje (382) Novel Microwave Source for Elemental MS Performance and Prospects. Y. Duan, G. Li, M. W. Wu, G. M. Hieftje (383) MS of Helium ICP Discharges with Frequency and Free-Running Generators. S-H. Nam, L. lacone, A. Montaser (384) Environmental Sample Analysis by ICPMS—A Real-Life Study. K. Kawaba, D. Potter (385) Selection Criteria for ICPMS Sample Introduction Systems. K. Sakata, S. Muramoto, D. Potter (386) Determination of Wear Metals in Lubricating Oils by Electrothermal Vaporization ICPMS. M. P. Escobar, B. W. Smith, J. D. Winefordner (387) Direct Analysis of Solids by Slurry Nebulization ICPMS. C. Bi, J. J. Giglio, J. Wang, J. A. Caruso (388) Direct Analysis of TEOS Vapor by ICP High-Resolution MS. J. M. Rosamllia (389) Comparison of Pneumatic and Thermospray Nebulization for the Speciation of Chromium Using HPLC/ICPMS. M. J. Tomlinson, J. Wang, J. A. Caruso (390) Chromatographic Detection Using Mixed-Gas ICPMS. L. K. Olson, J. Wang, J. A. Caruso, B. S. Sheppard

PITTCONU Tuesday Afternoon Symposium: Pittsburgh Analytical Chemistry Award (Arranged by J. R. Parina) Lenox Lohr Theatre, East Hall J. R. Parina, Presiding 1:30 1:35

1:40 2:20 3:15 3:55

Introductory Remarks. J. R. Parina Presentation of the 1994 Pittsburgh Ana­ lytical Chemistry Award by Sarah L. Shockey, Society for Analytical Chemists of Pittsburgh (451) Award Address: Analytical MS in the 90s. C. L. Wllkins (452) Solving Biological Problems with TOFMS. R. J. Cotter (453) Understanding and Utilizing Ion Chemistry in an Ion Trap. G. L. Glish (454) Tandem Four-Sector MS: A Method for Determining Structures of Biomolecules. M. L. Gross

GC/MS I n s t r u m e n t a t i o n — A i r Analysis J o h n Evers Theatre, East Hall R. A. Yost, Presiding 1:30

1:50

2:10 2:30

(540) Analysis of Air Canister Samples for Polar and Nonpolar Volatile Com­ pounds Using Modified Method TO-14. A. S. Williams, A. T. Madden (541 ) Temporal Distribution of Com­ pounds in Chromatographic Run by GC/MS in Ambient Air Sampling on Staten Island, NY. H. Y. Hur, J. R. Oppenheimer (542) Ambient Air Monitoring Using a Benchtop Quadrupole Mass Spectrome­ ter. J. M. Kowalski, A.D. Bashall (543) Homologous Identification of VBOCs in Ambient Air. H. Y. Hur, J. R. Oppenheimer, O. M. Zha

Wednesday Afternoon

8:35

(882) Identification of Components in Waste Streams by Electrospray and Tan dem MS. B. M. Hughes 9:10 (883) Identification of Chlorine Dioxide and Ozonation Disinfection Byproducts in Drinking Water. S. D. Richardson 9:45 (884) Toxaphene in the Great Lakes. D. Swackhamer 10:35 (885) Identification of Volatile Hazardous Air Pollutants in Urban Air. T. J. Kelly 11:10 (886) An Investigation of the Natural Pes­ ticide Rotenone in Water. W. L. Budde

11:25 (915) Multiple- Excitation Collisional Acti vation in FT-MS. S. A. Lee, C. Q. Jiao, Y. Huang, B. S. Freiser 11:45 (916) IR Photochemistry of TransitionMetal-Containing Ions Using FT-MS: MC 2 H 2 + , MC 4 H 6 *, and MC„H 2n (n = 2-5, m = Fe, Co, Ni). P. I. Surjasasmita, E. R. Ranatunga, B. S. Freiser

Thursday Afternoon LC/MS a n d Electrospray

Bio/Polymer M S — I o n - M o l e c u l e Reactions J o h n Evers Theatre, East Hall A.G. Sharkey, Presiding (907) Separation and Analysis of Biologi­ cal Macromolecules by CE-Matrix-Assisted Laser Desorption MS. K. L. Walker, R. W. Chiu, C. A. Monnig, C. L. Wilkins 8:50 (908) Fragmentation of Peptides and Biomolecules in an Ion Trap/TOF Mass Spectrometer. S. T. Fountain, H. Lee, D. M. Lubman 9:10 (909) Analysis of Polyisoprenes by TOFSIMS. K. Xu, D. M. Hercules, A. Proctor 9:30 (910) Analysis of Starburst Polymers by Electrospray Ionization MS. P. B. Smith, A. P. Snyder 9:50 (911) Characterization of Dirhodium Carboxylate Complexes Using SIMS. G. M. Haas 10:25 (912) Gas-Phase Reactivity of the Bime­ tallic Cluster Ions VFe n+ and CuFen* ( f t - 1 - 7 ) . Y. Byun, S.A. Lee, B. S. Freiser 10:45 (913) Differentation of FeC6H6