Harshaw NICKEL CATALYSTS - C&EN Global Enterprise (ACS

Nov 6, 2010 - Harshaw NICKEL CATALYSTS. Chem. Eng. News , 1967, 45 (4), p 1. DOI: 10.1021/cen-v045n004.p001. Publication Date: January 23, 1967...
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Harshaw NICKEL CATALYSTS Tableted ·Extruded •Spherical Granular · Powdered · Flaked

Ni-0914R3/4" Used in gas reforming. A gray ring containing 1.5% nickel present as oxide mounted on inert, alumina· silica. ABD 68#/cu. ft. SA 1 m2/g Ni-lOOOP Used for batch process hydrogénations in low to moderate temperature ranges. This catalyst containing about 50% nickel and 50% aluminum, is inactive as supplied but is easily activated by a caustic leaching treatment. Please consult your Harshaw representative for details. ABD 137#/cu.ft. Screen Analysis: on 325 mesh 5% minimum on 325 mesh 16% average thru 325 mesh 84% average

Ni-OlOlTl/8", 3/16", 1/4"

Ni-0122 Ε 1/16"

Used for hydrogénation and methanation. Green tablets containing 44% Ni present as hydrate mounted on kieselguhr. This catalyst must be reduced before use. ABD 75-85#/cu.ft. Strength 1M7#

An extruded hydrogénation catalyst supported on kieselguhr, active but stable and not pyrophoric as shipped, containing 28% nickel. ABD 45#/cu.ft. SA 168 m2/g Strength 10# PV 0.53 cc/g

NÎ-1404T1/8", 3/16" A versatile hydrogénation catalyst containing about 70% nickel on a proprietary support, activated but stabilized and not pyrophoric as shipped. ABD 75-80#/cu. ft. SA 132 m2/g Strength 8-10# PV 0.40 cc/g

NÎ-0301T1/8"

Ni-1406T5/32", 7/32" A hydrogénation catalyst containing 46% nickel on a proprietary support. This catalyst must be activated by reduction in situ before use. Suggested activation procedure is available by request. ABD 80-85#/cu.ft. Strength 36-40#

Ni-0102Tl/8", 3/16", 1/4" This hydrogénation catalyst must be reduced before use. The dark gray tablets contain 55% nickel present as nickel oxide mounted on kieselguhr. ABD 94-104#/cu. ft. depends on size Strength 10-25#, depends on size

The sulfided form of this catalyst is used for the selective hydrogénation of diolefins to mono-olefins. These gray tablets contain 1 1 % nickel present as oxide supported on activated alumina. ABD 68#/cu. ft. SA 64 m2/g Strength 13# PV 0.32 cc/g

Ni-0104 G

Ni-0302 Τ 1/8"

A hydrogénation catalyst particularly for trickle bed or liquid phase reactions, active but stable and not pyrophoric as shipped. Contains 60% nickel on kieselguhr SA 110m 2 /g ABD 65#/cu. ft. PV 0.35 cc/g

A hydrogénation catalyst containing 15% nickel present in oxide form mounted on activated alumina. ABD 83#/cu. ft. SA 65 m2/g Strength 17# PV 0.20 cc/g

Ni-0104 Ρ

Selective hydrogénation catalyst containing 32% nickel oxide on active alumina. ABD 87#/cu. ft. SA 52 m2/g Strength 23# PV 0.23 cc/g

A versatile hydrogénation catalyst, reduced and stabilized but not pyrophoric as shipped. Contains 58% nickel on kieselguhr with a ratio of reduced nickel to total nickel of 0.60-0.65. ABD 70#/cu.ft. SA 155-165 m2/g

Ni-0502 F A reduced nickel catalyst in flake form containing about 24% nickel on kieselguhr protected by hardened oil. Used in hydrogénation reactions. ABD 38#/cu.ft.

Ni-0104 Τ 1/8', 3/16 \ 1/4" Tableted form of Ni-0104 P. ABD 90#/cu. ft. Strength 9#

Ni-0304 Τ 5/32"

SA 155-165 m2/g

Ni-0107T5/32"x 1/8" A partially reduced and stabilized hydrogénation catalyst containing 56% nickel on kieselguhr with a ratio of reduced nickel to total nickel of 0.5. ABD 90#/cu. ft. SA 130 m2/g Strength 10# PV 0.18 cc/g NÎ0108T1/4" An unreduced nickel hydrogénation catalyst containing 66% nickel oxide mounted on kieselguhr. Must be reduced before use. ABD 77#/cu. ft. Strength 16# Ni-0109F A reduced nickel catalyst in flake form containing2530% nickel on kieselguhr protected by hardened oil. This is a so-called dry reduced hydrogénation catalyst for certain specific problems in hardening some fatty oils. Please consult your Harshaw representative for details. NÎ-0109T1/4 L A fully reduced hydrogénation catalyst containing 60% nickel on kieselguhr with a ratio of reduced nickel to total nickel of 0.75. This catalyst is pyrophoric and is shipped under a protecting liquid. ABD 81-84#/cu. ft. Strength 35# N i 0 1 1 6 T l / 8 , 3/16", 1/4" A hydrogénation catalyst, with unusually high physical strength in a kieselguhr supported type, activated but stabilized and not pyrophoric as shipped. Contains about 60% nickel: ABD 8 8 1 0 0 # / c u . ft. SA 155-165 m2/g Strength 25-35# PV 0.20 cc/g

Ni-0704 Ε 5/32" Used for hydrogénation. Gray extrusions containing 18% nickel present as nickel oxide mounted on kieselguhr. ABD 51#/cu.ft. SA 4 m2/g Strength 45# PV 0.50 cc/g

NÎ-1430E 1/16" An extruded hydrogénation catalyst supported on alumina, active, but stable and not pyrophoric as shipped, containing 40% nickel. ABD 40#/cu. ft. SA 160 m2/g Strength 9# PV 0.69 cc/g Ni-1501 S I " A gas reforming catalyst containing 5% nickel as oxide promoted with 1.2% magnesium mounted on inert alumina-silica spheres. ABD 78#/cu._ft. SA 1 m2/g Ni-1600 S 1/4" A decomposition catalyst containing 3 to 4% each nickel oxide, cobalt oxide and iron oxide mounted on inert alumina-silica spheres. SA 1 m2/g ABD 82#/cu. ft. Ni-1601Tl/8" A decomposition catalyst containing 3 to 4% each nickel oxide, cobalt oxide and iron oxide mounted on activated alumina. ABD 62#/cu. ft. SA 78 m2/g Strength 16# PV 0.28 cc/g

Ni-0707 Τ 1/8"

NÎ-1800G4-6 A hydrogénation catalyst containing 10% nickel promoted with 1% copper, both metals present as oxides, mounted on a silica containing support. ABD 37#/cu. ft. SA 3 m2/g

Contains 14% nickel oxide on high activity alumina. This catalyst used for hydrogénations and aminations. SA 140 m2/g ABD 52#/cu. ft. Strength 22# PV 0.38 cc/g

NÎ-1901G2-1 Gas reforming catalyst containing a minimum of 3% nickel present as oxide mounted on activated alumina. ABD 53#/cu.ft.

NI-0901S3/8", 1/2", 3/4", 1" Used to reform low molecular weight hydrocarbons. Contains 5% nickel, present as oxide mounted on inert alumina-silica spheres. ABD 75#/cu. ft. SA 1 m2/g NÎ-0910S 1" Used to reform low molecular weight hydrocarbons. Inert alumina-silica spheres containing 10% nickel présentas nickel oxide. ABD 79#/cu. ft. SA. 1 m2/g Ni-0912 S 1" This gas reforming catalyst contains a minimum of 5% nickel as nickel oxide mounted on inert alumina spheres. ABD 75#/cu. ft. SA 1 m2/g

Ni-2002 C 1" Spec. 102 Gas reforming catalyst containing 5% nickel present as nickel oxide on inert cubes. ABD 37.5#/cu.ft. Ni-3201 F A catalyst capable of superior selectivity in the hydrogénation of edible oils, producing steepest dilatometric curves. NYSEL® is also effective in hydrogénation of inedible oils, fatty acids, nitrites, esters and other organics. Contains 25% or 30% fully active nickel on a proprietary support protected by 60% stéarine in flake form. Ni-5000 F This is the world renowned Rufert® Nickel'Catalyst Flakes. Used principally in hydrogénation of fatty oils and fatty acids. Ni-5000 F is also effective for hydrogénation of methyl esters, tall oils, fatty nitrogen compounds, etc.

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