Hamilton Solidum discovers ICAP.*
Glines & Rhodes refines recoverable precious metals from a wide variety of waste and by-product materials. But before refining can begin, the metals to be extracted must be known and measured. With confidence and accuracy.
Other methods require complex sample preparation and a high degree of operator skill to get reliable results. Running the ICAP Spectrometer couldn't be easier. Just introduce the sample, enter a few simple keyboard commands, and a complete multi-element analysis is printed out in less than a minute.
That's why Mr. Solidum's discovery of •Inductively Coupled Argon Plasma spectroscopy from Jarrell-Ash has become so Thanks to their ICAP Spectrometer from important at Glines & Rhodes. Jarrell-Ash, the folks at Glines and Rhodes are spending more time recoverOther methods of elemental analysis, like ing more precious metals, and a lot less fire assay and atomic absorption, can time in the lab. analyze just one element at a time. Mr. Solidum's ICAP Spectrometer detects and Jarrell-Ash has prepared detailed applicaquantifies eighteen target metals from the tion notes for a number of laboratory and same sample, in the same test, regardless industrial uses. Precious metals analysis is of concentration. Even difficult metals one of them. For more information about like platinum and palladium. So precious how ICAP spectroscopy from Jarrell-Ash metals that someone else may not even can make your elemental analysis easier, think to look for are routinely discovered faster and more accurate, call or write and turned into profits. Customer Service at the address below. Jarrell-Ash Division Fisher Scientific Company 590 Lincoln Street Waltham, Massachusetts U.S.A. 02254
(617) 890-4300
CIRCLE 95 ON READER SERVICE CARD 36
C&ENJan. 18, 1982
Reinforced plastics on road to recovery If reinforced plastics producers are correct, 1982 will bring them back close to 1979's record production level after a disasterous 1980 and a so-so 1981. And next year's level may even exceed the record. A consensus of producers is that 1982 volume growth will fall short of last year's; thus demand for reinforced plastics will not hit 2 billion lb yet this year. They predict that shipments will grow 5.2% from last year to 1.92 billion lb in 1982. Last year, reinforced plastics shipments rose 7.5% from 1980 levels to 1.82 billion lb. These figures were revealed last week at the annual conference of the Reinforced Plastics/Composites Institute of the Society of the Plastics Industry held in Washington, D.C. The figures are part of a survey of producers and others in the industry compiled by Laura Morrison of the public relations firm Morrison-Gottlieb, New York City. According to the survey, the biggest growth category for reinforced plastics in 1981 was the aircraft industry. This market, though the smallest charted by the survey, increased 12% from 1980 to 28 million lb. Aircraft use of reinforced plastics is expected to maintain its growth lead again in 1982, climbing 10.7% to 31 million lb. The biggest use of reinforced plastics—land transportation—had one of the slowest demand increases in 1981. This was, of course, because of the sluggish automobile market. However, in spite of the cries of woe coming from Detroit, reinforced plastics managed a 7% increase in use for land transportation in 1981 to 445 million lb. However, reinforced plastics makers see demand for their products for land transportation struggling for only a 2.7% gain in 1982 to 457 million lb. The reinforced plastics market hardest hit by the recession has been marine uses, suffering longer and harder than other markets. Unlike the other markets, marine uses, mainly for small, recreational boat hulls, reached their peak in 1978 at 430 million lb and then declined solidly for two straight years, followed by only a 5.5% increase in 1981 to just 290 million lb. For this year, producers expect no growth in marine uses, so consumption by the end of 1982 still will be 33% less than peak demand in 1978. This is
Inspire R & D breakthroughs with these Du Pont "Idea Intermediates! AvailaMe now in sample and commercial quantities. 3-Pentenenitrile CH3CH = CHCH2CN
Dimethyl Glutarate CH3OOC (CH2)3 C00CH 3
Acrylonitrile CH 2 = CHCN
Methylglutaronitrile CH 3 NCCHCH2CH2CN
DBE CH3OOC (CH2)nCOOCH3
Acetonitrile CH3CN
PACM-20
Polymeric Acrylonitrile CH2-CH-\ (
CN Λ
Adiponitrile NC(CH2)4CN BHMT Amine NH 2 (CH 2 ) 6 NH(CH 2 ) 6 NH 2 2-Methyl-2-Butenenitrile CH 3 CH3CH = CCN 2-Methyl-3-Butenenitrile CH 3 CH 2 =CHCHCN 2-Pentenenitrile CH3CH2CH = CHCN
n = 2,3,4
Cyclododecane OH NH,
2, 4, Bis (p-aminobenzyl) aniline NH
Cyclododecanol
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J
1,5,9-Cyclododecatriene
r^cJ^HrQ-NH,
Methyl Benzoate/ Methyl p-Toluate ICOOCH,
ICOOCH,
ICH 3
Dimethyl Terephthalate ICOOCHJ
TcoocHj Dodecanedioic Acid HOOC (CH2)10 COOH Adipic Acid HOOC (CH2)4 COOH Dimethyl Succinate CH3OOC (CH2)2 C00CH 3
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Business
Reinforced plastics demand in 1982 still below 1979 levels |
1982a
1981 a
1980
Transportation, land Marine
457
445
416
290
290
275
Construction
327
309
287
Anticorrosion
302
275
252
Electrical
196
178
Appliance
117
Consumer goods
Millions of lb
Aircraft Other TOTAL
% change 1981-82 1980-81
Average annual change 1977-82
1978
1977
550
535
374
2.7%
385
430
400
nc
5.5
-1.0% -5.9
335
320
266
5.8
7.7
2.7
238
216
192
9.8
9.1
9.5
162
190
170
147
10.1
9.9
5.9
112
104
130
123
112
4.5
7.7
0.9
118
110
103
126
116
107
7.3
6.8
2.0
31
28
25
23
22
21
10.7
12.0
8.1
5.4
5.7
2.2
5.2%
7.5%
1.1%
1979
78
74
70
79
74
70
1916
1821
1694
2056
2006
1810
7.0%
I
a Estimates, nc = no change. Source: Reinforced Plastics/Composites Institute of the Society of the Plastics Industry
hardly surprising, though, because during a recession recreational markets for any product are usually the first to slip. Construction uses for reinforced plastics, in spite of continued recession and high interest rates, chalked up a relatively good increase in 1981 of 7.7% to 309 million lb. However, growth in this area is expected to slow in 1982 to 5.8%, with demand likely hitting about 327 million lb.
Other than aircraft markets, the best growing outlets for reinforced plastics last year were in corrosionresistant equipment and electrical products. Corrosion-resistant equipment uses increased 9.1% to 275 million lb in 1981, and electrical markets grew about 9.9% to 178 million lb. These two markets are expected to continue to do well this year. The survey indicates that the market in corrosion-resistant equipment may
increase a further 9.8% in 1982, and that in electrical uses may rise at an even faster 10.1% Thus, reinforced plastics, many of whose uses are closely tied to the economy and are therefore highly cyclical, are beginning to recover. But, even with a 5.2% growth this year, the industry still will be almost 7% below consumption levels in 1979, its most recent good year. William Storck, New York
If three Glymes have 140 patented applications, think what you can do with Grant's seven Glymes· B.P.85.2C Monoglyme (Ethylene G lycolDi methyl Ether) 99.6 + % pure.
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C&ENJan. 18, 1982
Grant Chemical's family of glycol diethers. Available in commercial quantities in a wide range of boiling points, these aprotic solvents have reagent grade quality but technical grade pricing. For our comprehensive brochure with over 200 references, please call or write. GRANT CHEMICAL DIVISION Ferro Corporation P.O. Box 263 Baton Rouge, LA 70821 (504) 654-6801 Telex 98-0165
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CHECKOFF NEW PLANTS
decabromodiphenyl oxide plant at Magnolia, Ark.: startup is slated for January 1983.
• Alumina—Aluminum Co. of America will build $16.5 million facility at Vidalia, La., to make line of specialty alumina products such as catalyst-support prod ucts, absorbents, and the like; for use by petrochemical and petro leum and gas refining industries; scheduled to begin operation in 1983, first stage will have capacity of 20 million lb per year.
• Industrial gases—Liquid Air will build new plant and expand another in Rocky Mountain area for obtaining liquid nitrogen and oxygen. At site yet to be selected, company will build plant with capacity of 240 tons of oxygen and nitrogen per day by summer 1983. Provo, Utah, existing plant will be expanded by 100 tons per day.
• Chromium dioxide—Du Pont will modernize facilities and increase capacity 50% of unit at Newport, Del., to make this in organic chemical as magnetic particles for application in audio, video, data storage tapes; con struction has begun with com pletion scheduled for late 1982.
• Sodium sulfate—OzarkMahoning, subsidiary of Pennwalt, will expand capacity of Seagraves, Tex., plant 50% from undisclosed amount over twoyear period to make this ingre dient in glass and detergents, and used as aid in making Kraft paper.
• Flame-retardant addi tives—Ethyl Corp.'s Saytech subsidiary will build $7 million
• Specialty organics—Mallinckrodt will expand St. Louis, Mo., plant for undisclosed cost to
make three new products, butanetetracarboxylic acid, oxydianiline, and stearoyl-p-aminophenol, and to use new com pany-developed technology to make phenylhydroxylamine and some of its derivatives. Comple tion will be in stages from sec ond-quarter 1982 to first-quarter 1983.
PLANTS COMPLETED • Alpha olefins—Ethyl has completed $50 million expansion of Houston, Tex., plant to 800 million lb per year; with other facilities in chain-growth opera tions to make primary alcohols, total capacity is now more than 1 billion lb per year. • Ethanol—Perkin Energy Co., joint venture of Texaco and CPC International Inc., has started up its 60 million gal-per-year plant in Perkin, 111., to make fuel-grade ethanol from corn.
l^wP^iMyr: P R O S P E C T U S
How sample € injectors affect LC accuracy.
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F r e e r e p o r t tells h o w t o i m p r o v e precision b y choice of injection technique. This 8-page Rheodyne technical note reports the results of experiments using 5 different sample loading techniques —and '/ discusses eight popular injectors from ;; * various manfacturers. Among the questions $? answered are: \' • What analytical precision can be expected : ' in HPLC? · Which injection techniques \, provide the highest reproducibility? · What role is played by variations in flow rate, solvent | composition and temperature? f· Send for Tech N o t e # 1 Rheodyne, Inc., PO. Box 996, Cotati, Calif. 94928, U.S.A. Phone (707) 664-9050.
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D o n ' t miss this unique opportunity to acquire hands-on experience with the latest techniques for large scale isolations involving enzymes, hor mones and antiviral proteins. The workshop is sponsored by the N.E. Enzyme Center and the Department of Chemical Engineering. Subjects will include unit operations for protein purification, fermenta tion, hybridoma and recombinant DNA technology detection methods, and many more. Enrollment is limited, so don't de lay your inquiry. Write us today for a workshop brochure plus cost and registration details. lïimlr.
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