Urethanes set for five excellent years - ACS Publications

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Expansions to add 7225 tons per day to chlorine capacity Tons per day

1976

Dow Chemical Plaquemine, La.

1977

500

Dow Chemical Plaquemine, La. Freeport, Tex. Du Pont Corpus Christi, Tex. PPG Industries Lake Charles, La. Vulcan Geismar, La; Hooker Tacoma, Wash. Pennwalt Portland, Ore.

1978

500 500 1000 750 600 275 200

Olin Corp. Mcintosh, Ala. Dow Chemical Freeport, Tex. Hooker Niagara Falls, N.Y.

1979

1000 500 400

Dow Chemical Freeport, Tex.

1000

TOTAL

7225

3% of the 1975 chlorine market. However, Brunt believes that it has potential for replacing fluorocarbons as both a blowing agent for urethane foam and as an aerosol propellant. Its many diversified uses could support a growth rate of up to 14%

annually, but Dow pegs 9% as the most likely rate for methylene chloride. Weak chlorine markets include pulp and paper and fluorocarbons. As far as pulp and paper is concerned, Dow has made allowances for development of se­ quential and oxygen bleaching technology in the early 1980's. Fluorocarbon use in aerosols is in jeopardy, says Brunt, even though the ozone issue never may be re­ solved scientifically. Caustic soda demand last year was 9.6 million tons, down 14% from 1974. The drop, says Brunt, was caused by the combined effects of the economy, inven­ tory adjustments, improved methods of using caustic, and competition from al­ ternate alkalies. Exports were strong during the first part of 1975, but dropped dramatically in May and remained depressed the rest of the year. They accounted for 12% of U.S. caustic production last year and are ex­ pected to remain weak through 1985. Alumina, textiles, and rayon also are expected to be weak markets for caustic. However, caustic will benefit from the organic chemicals market, which ac­ counted for 34% of caustic use last year. The diversification of this group is strength in itself, says Brunt. Many new agricultural chemicals are entering the market. Nylon 6 and 66 intermediates continue to show signs of healthy longterm growth. He expects caustic demand in this group to grow 5% per year, with a low of 4% and a high of 7%. π

PRODUCT $m

NEW EXCEED NBS PURITY AT EVERYDAY PRICES KB

= 2.34

X 10-

5

high purity

ERUCICACID BEHENICACID

4.63)

0.002%

$30.00/100 g 2-Furoic

OLEYL ALCOHOL ERUCYL ALCOHOL BEHENYL ALCOHOL

Acid

KA = 8.63 X 10- 4 (pKA = 3.06) Purity: 100.000 ±

0.002%

$12.00/100 g B o t h m a t e r i a l s a r e o f f e r e d in t h e f o r m of s u b l i m e d c r y s t a l s . T h e p u r i t y of e a c h has b e e n e s t a b l i s h e d by h i g h - p r e c i s i o n titration. Write for data

sheets.

HACHJ

CHEMICAL COMPANY

^

Fine Chemicals

^

PROSPECTUS

Base

(P*B =

Purity: 100.000 ±

The urethane polymer market is back on the track. Urethanes survived the 1974-75 recessionary period and the market has recovered to match the sales rates recorded in 1973. In fact, Mobay expects polyurethane consumption this year to top the record 1.59 billion lb consumed in 1973. Speak­ ing at a meeting of the Chemical Mar­ keting Research Association in New York City, G. Thomas Harrick, director of product development in Mobay's polyurethane division, pegged this year's consumption at 1.68 billion lb. That's 8.2% better than last year. The future for polyurethanes is just as bright. He estimates that demand will increase an average 9% annually, hitting 2.37 billion lb by 1980. Flexible and rigid urethane foams will continue to be the mainstays of ure­ thane demand. However, first prize for rapid growth will go to the microcellular urethanes. Use of these products, used in shoe soles, structural foams, and au­ tomotive exterior parts, likely will in­ crease from its relatively low base of 28 million lb last year to 100 million to 200 million lb by 1980. That's a hefty 25 to 30% average annual growth rate. Taking 40% as a likely estimate, Harrick says that 1980 demand for microcellular ure­ thanes will be 150 million lb.

Calling your attention to

PRIMARY STANDARDS

4-Aminopyridine,

Urethanes set for five excellent years

Division

P.O. Box 907 A m e s , Iowa 50010 U.S.A. • 5 1 5 / 2 3 2 - 2 5 3 3 CIRCLE 14 O N READER SERVICE CARD

η

FALLEK CHEMICAL CORP

*>v-

460 Park A v e n u e N e w Y o r k , N.Y. 10022

ÇÂ^I

P h o n e : (212) 752-0250 T W X : 710-581-4361

CIRCLE 1 1 O N READER SERVICE CARD

^ CIRCLE 12 O N READER SERVICE CARD

Total recovery of solids from 20 to 50 liters of solution or more? It's easy with Biichi/ Brinkmann Pilot Plant Rotary Evaporators.

ROTAVAPOR R-50EX (Height approx. 8 ft.)

These Rotary Evaporators make the recovery of solids from 20 to 50 liters or more of liquid an easy matter. There is no loss of material, and the result is a dry, solvent-free residue. Fast evaporation rates are possible by working under vacuum. Available in explosion-proof models with 20 and 50 liter flasks for batch and continuous feed operations. For literature, just write: Buchi/Brinkmann, Cantiague Road, Westbury, N.Y. 11590. In Canada: 50 Galaxy Blvd., Rexdale (Toronto), Ont.

Biichi/ Lu! Brinkmann

CIRCLE 3 O N READER SERVICE CARD

C&EN READER IVffl A V IVDM I ADV 1 14 27 40 53 66

1"7 • /

ERTISED PRODUCTS 4 2 6 3 5 15 16 17 18 19 28 29 30 31 32 41 42 43 44 45 54 55 56 57 58 67 68 69 70 71

NEV\ 100 113 126 139 152 165 178 191 204 217 230

SERVICE VALID THROUGH September 1976

7 20 33 46 59 72

8 21 34 47 60 73

PRODUCTS, N E W LITERATURE: 101 102 103 104 105 106 107 1 14 115 116 117 118 119 120 127 128 129 130 131 132 133 140 141 142 143 144 145 146 153 154 155 156 157 158 159 166 167 168 169 170 171 172 179 180 181 182 183 184 185 192 193 194 195 196 197 198 205 206 207 208 209 210 211 218 219 220 221 222 223 224 231 232 233 234 235 236 237

9 22 35 48 61 74

10 23 36 49 62 75

11 24 37 50 63 76

12 25 38 51 64 77

108 121 134 147 160 173 186 199 212 225 238

109 122 135 148 161 174 187 200 213 226 239

110 123 136 149 162 175 188 201 214 227 240

111 112 124 125 137- 138 150 151 163 164 176 177 189 190 202 203 215 216 228 229 241 242

13 26 39 52 65 78

PLEASE CHECK YOUR F U N C T I O N : 1 D MANAGEMENT

4 Π PRODUCT

2 D PRODUCTION. CONTROL

5 Π PURCH., SERVICE, SLS.

3 Π

6 Π OTHER

PROCESS DESIGN & DEV.

NAME TITLE COMPANY STREET

_

CITY. STATE

ZIP

TELEPHONE PLEASE CHECK: D ACS M E M B E R D NON M E M B E R

R&D

ο

co 2 2 D

û.