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J. Am. Chem. SOC.1988, 110, 3191-3198
Widely Varying Olefin Rotation Geometry in Platinum( 11)-Olefin Complexes Containing the q3-Allyl Ligand. Molecular Structure, Solution Stability, and Molecular Orbital Studies Kunio Miki,l' Kazuhiko Yamatoya,lPNobutami Kasai,*ln Hideo Kwosawa,*le Akira Urabe," Mitsuhiro Emoto,l' Kazuyuki Tatsumi,lb and Akira Nakamuralb Contribution from the Department of Applied Chemistry, Osaka University, Suita 565. Osaka, Japan, and the Department of Macromolecular Science, Osaka University, Toyonaka 560, Osaka, Japan. Received October 5, 1987
Abstract: The molecular structures of six olefin complexes ( [Pt(s3-CH2CMeCH2)(olefin)(PPh3)]PF6 (2) (olefin = CH2=CH2 ( 2 4 , CH2=CHPh (2b), CH2 a, >
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