FOR THE CHEMICAL INDUSTRY AT A GLANCE - C&EN Global

Jul 4, 1994 - Most U.S. chemical makers were probably ready to have a year like 1993. Few would call it outstanding, certainly not when compared with ...
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ACT» FORTHE CHEMICAL INDUS AT A GLANCE PRODUCTION

Chemical production in the U.S. rose 3% in 1993, following a similar rise in 1992. The biggest volume commodity chemicals also posted 3% growth in output, as did thermoplastic resins. Almost all sectors showed similar steady, if unspectacular, expansion. Page 30

4

MARKETS

Most major markets for chemicals posted their second year of solid growth in 1993, as the U.S. economy generally confirmed that its most recent recession was over. Demand for new homes and for cars and trucks was up strongly, thanks largely to lower interest rates. Farmers, however, did not do well, as bad weather cut crop production 14%. Page 58

FOREIGN TRADE FINANCES U.S. chemical exports managed to rise a modest 2.5% in 1993, despite a U.S. Sales, earnings, profitability, and return on economy that was strong compared with stockholders' investment all grew last year, those of many of the industry's leading though sales, in particular, did so only mod- trading partners. But chemical imports estly. After four years of falling income, the rose faster, up 5.4%, causing the chemicombined earnings of 30 major chemical cal trade balance, always strongly posifirms rose 8%, well above the 2% gains in tive, to dip below $16 billion for the first both sales and prices. Profits came by cutting time since 1989. Page 60 costs, particularly payrolls but also capital spending. R&D budgets were unchanged from the previous year. Page 37

m

FOREIGN CHEMICALI INDUSTRIES

EMPLOYMENT

Cautious optimism is beginning to characterize the chemical industries in Europe and Canada as sales and earnings Companies cut their work forces in 1993, began to turn around last year for most with chemical firms collectively dropping of these countries. As in the U.S., job 14,000 people from their payrolls. Worst hit trimming was a major contributor to inwere workers in big companies making or- creased profitability. In Japan, sales ganics, agricultural chemicals, or plastics. slipped and earnings plummeted. For The slide continued into early 1994, al- many of its less-developed Asian neighthough there are some signs it may now be bors, however, 1993 was a strong year for easing. Employment at drug and soap man- chemicals, thanks to generally booming Page 62 ufacturers grew in 1993. Page 54 economies. 28 JULY 4,1994 C&EN

ost U.S. chemical makers were probably ready to have a year like 1993. Few would call it outstanding, certainly not when compared with the sort of growth companies were racking up year after year as recently as the late 1980s. But earnings rose substantially, particularly in the year's second half, and most other indicators of industry health—such as sales, shipments, and profitability— moved upward as well. After four years of decline when earnings for ma-

M

jor chemical firms fell 40% from their 1989 peak, the change was certainly welcome. The earnings gains came, for the most part, not from stronger demand and rising prices, but through cutting costs and increasing productivity. Chemical companies that had held on to their employees through the economically lean years of the early 1990s decided in 1993 that they could no longer do so. The industry as a whole ended the year with 14,000 fewer employees than it be-

gan with, and these cuts have continued well into 1994. Job loss has been even greater at the companies that are the biggest producers of commodity chemicals. Capital spending, too, dropped 10% at the largest chemical firms last year, and even R&D budgets were held to 1992 levels. The picture was largely the same for chemical makers in Canada and much of Europe, although changes in data collection in some of Europe's key chemical-producing nations cloud the

picture there. Turnaround has been slower to reach Japan, however, where chemical profits at 12 leading companies dropped a stunning 40%. There are signs that the belt tightening may have eased in the U.S. and the now trim chemical industry may find 1994 an even better year than 1993. Chemical sales are up in the early months of 1994, as are company earnings; job cuts have slowed; and plans, at least, call for an increase in capital spending later in the year. JULY 4,1994 C&EN

29

Ρ

PRODUCTION BY THE U.S. CHEMICAL INDUSTRY

Growth continues in chemical production roduction by the U.S. chemical in­ dustry grew 3% in 1993. That's the increase measured by the in­ dustry's index of production, prepared by the Federal Reserve Board. C&EN's own tally of production of the largest volume chemicals, the Top 50, shows the same 3% increase. Output by both mea­ sures grew 3% in 1992 as well, after be­ ing essentially unchanged in 1991. Production for individual chemical cat­ egories varied widely, however. Output for organic chemicals in C&EN's Top 50 rose an overall 9%, whereas that for inor­ ganics fell 1%. A 10% drop in production of sulfuric acid, the chemical that heads the Top 50 list, contributed much to inor­ ganics' overall poor performance. The Federal Reserve Board found out­ put of basic chemicals, which is the board's classification for inorganics, un­ changed in 1993, after a 10% rise in 1992. Production in the board's chemical prod­ ucts category—which includes pharma­ ceuticals, soaps, and paints—grew 3%, as it has annually for a decade. As might be expected, increased use of methyl tert-butyl ether (MTBE) as a gasoline additive continued to send its production soaring. MTBE output more than doubled in 1993 to 24 billion lb, making it the ninth largest volume chemical. Production of MTBE precursor isobutylene rose 20% to 1.1 billion lb. Production of phosphate rock nose­ dived 24% in 1993. A decline in exports of phosphate products, especially of diammonium phosphate to China, was re­ sponsible for the cutback in output, ac­ cording to analysts at the Bureau of Mines. Production of diammonium phos­ phate fell 11% in 1993, according to data from the Fertilizer Institute. U.S. con­ sumption of phosphate fertilizers, on the other hand, rose a healthy 6%. All categories of plastics posted gains in production last year. Output of ther­ mosetting resins rose 8%, with the in­ crease for individual resins varying from 5% for phenolics to 16%? for melamines. Production of thermoplastic resins was up 3%.

P

30

JULY 4,1994 C&EN

All chemical sectors, except inorganics, picked up in 1993 Production, % running annual growth rate3 10

-5

M Inorganics • Organics D Plastics H Fibers • Totalb

-10

I l l l ι ι ι ι ι ι Ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι I I I I I I I I I 1989 1990 1991 1992 1993 a Average running annual growth rates in production of major plastics, inorganic and organic chemicals, and in shipments of man-made fibers, b Average running annual growth rate for products in the above four categories taken as a whole. Sources: International Trade Commission, Bureau of the Census, Society of the Plastics Industry, Textile Economics Bureau

Chemicals production posts modest but steady growth Production index3, 1987 = 100 140 D All industry ϋ Chemicals & allied products • Synthetic materials • Basic chemicals 130

120

110

100

Qnlι ι ι ι η η ι ι ι Ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι Ι ι ι ι ι ι Μ ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι ι Ι ι ι ι ι ι ι ι ι ι ι ι 1989 1990 1991 1992 1993 1994 a Seasonally adjusted. Source: Federal Reserve Board

TOP 50 CHEMICALS: Strong 9% rise in organics boosted total production 3% Rank 1993

Billions of lb

Rank

Billions of lb 1992a

1993

1992

1993

1992a

Sulfuric acid Nitrogen Oxygen Ethylene Limeb

80.31 65.29 46.52 41.25 36.80

89.72 60.51 43.46 40.93 35.71

26 27 28 29 30

24 27 28 26 30

1993

1992

Hydrochloric acid Toluene' p-Xylene Ethylene oxide Ethylene glycol

6.45 6.38 5.76 5.68 5.23

7.13 6.01 g 5.66 5.83 5.13 4.78 4.67 3.719 3.59 _3.86^

1 2 3 4 5

1 2 3 4 6

6 7 8 9 10

5 8 9 19 7

Ammonia Sodium hydroxide Chlorine Methyl ferf-butyl ether Phosphoric acid

34.50 25.71 24.06 24.05 23.04

36.59 24.50 23.51 10.88 25.58

31 32 33 34 35

31 32 34 35 33

Ammonium sulfate Cumene Phenol1 Acetic acid Potash^

4.80 4.49 3.72 3.66 3.31

11 12 13 14 15

10 11 15 13 14

Propylene Sodium carbonate6 Ethylene dichloride Nitric acid Ammonium nitrated

22.40 19.80 17.95 17.07 16.79

23.43 20.84 15.15 16.09 15.66

36 37 38 39 40

38 37 36 40 41

Propylene oxide Carbon black Butadiene1 Vinyl acetate Titanium dioxide

3.30 3.22 3.09 2.83 2.56

2.90 3.02 3.23 2.66 2.51

16 17 18 19 20

12 17 16 18 19

Ureae Vinyl chloride Benzene Ethylbenzene Carbon dioxide*

15.66 13.75 12.32 11.76 10.69

17.96 11.31 11.98s 11.11 10.88

41 42 43 44 45

39 42 44 43 45

Acrylonitrile Acetone Aluminum sulfate Cyclohexane Sodium silicate

2.51 2.46 2.23 2.00 1.97 _

2.83 2.43 2.09 2.24 1.82

21 22 23 24 25

23 21 29 22 25

Methanol Styrene Terephthalic acid9 Formaldehyde*1 Xylene

10.54 10.07 7.84 7.61 6.84

8.08 9.00 5.64g 8.28 6.39

46 47 48 49 50

46 47 48 49

Adipic acid Sodium sulfate"1 Calcium chloride" Caprolactam η-Butyl alcohol

1.56 1.44 1.40 1.36 1.33

1.56 1.52 1.39 1.38 1.26

257.38 427.95 685.33

235.24 431.18 666.42

-

TOTAL ORGANICS TOTAL INORGANICS GRAND TOTAL

a Revised, b Except refractory dolomite, c Natural and synthetic, d Original solution, e 100% basis, f Liquid and solid only, g Includes both acid and ester without double counting, h 37% by weight, i All grades, j Synthetic only, k K 2 0 basis. I Rubber grade, m High and low purity, η 75% basis, solid and liquid.

PRODUCTION: Drugs and medicines rose, paints and some inorganics declined % annual change

Industrial production indexes, 1987 = 100

1983

1984

1985

1986

1987

1988

1989

1990

1991

1992

1993

Total index Manufacturing, total Nondurable manufacturing Chemicals & products Chemicals & synthetic materials

84.9 80.9 87.0 87.5 88.6

92.8 89.3 90.8 91.4 92.8

94.4 91.6 91.5 91.4 92.2

95.3 94.3 94.9 94.6 93.9

100.0 100.0 100.0 100.0 100.0

104.4 104.7 102.3 106.0 107.5

106.1 106.4 103.7 109.2 112.2

106.0 106.1 104.4 111.8 114.5

104.1 103.7 103.5 111.4 111.3

106.5 106.8 106.5 114.3 114.8

110.9 111.7 108.7 117.8 118,6

Basic chemicals Alkalies & chlorine Inorgan c pigments Inorgan c chemicals, nee

92.1 87.9 87.3 94.3

96.9 95.3 89.0 98.0

96.1 93.6 95.1 97.2

95.1 92.1 96.2 94.7

100.0 100.0 100.0 100.0

104.7 104.9 111.4 103.5

108.4 107.4 114.0 107.7

118.9 107.2 109.0 123.8

116.0 104.2 101.5 120.0

128.0 105.4 118.2 133.6

128.1 108.4 116.3 131.4

0 3 -2 -2

3 2 3 3

Industrial organic chemicals

89.9

93.4

94.1

95.1

100.0

111.6

117.8

119.4

115.7

111.6

117.0

5

3

Synthetic materials8 Plastics materials Man-made fibers

84.3 74.4 92.3

88.9 81.1 93.3

86.9 84.1 86.6

91.6 88.2 93.7

100.0 100.0 100.0

104.3 104.0 103.5

107.7 106.1 110.5

105.8 106.7 102.8

102.9 101.5 103.3

110.2 108.2 110.1

114.6 112.4 114.6

4 4 4

3 4 2

Chemical products Drugs & medicines Soaps & toiletries Paints

86.6 86.1 91.4 84.6

89.0 86.9 90.6 91.8

90.2 88.5 91.3 95.7

95.9 96.7 96.7 97.5

100.0 100.0 100.0 100.0

104.7 104.9 106.4 103.8

106.3 108.6 107.3 98.9

108.8 112.6 109.4 97.1

110.9 120.6 108.4 91.0

113.1 127.2 106.4

116.4 134.8 106.7

90.6

87.8

Agricultural chemicals

87.5

102.0

96.1

88.5

100.0

106.5

115.3

119.3

116.2

122.0

125.8

3

4

Petroleum products

89.6

92.8

92.6

98.9

100.0

101.9

102.3

103.3

101.6

102.7

104.9

2

2

Rubber & plastics products

74.3

83.8

85.8

90.8

100.0

102.6

106.0

107.2

104.5

110.8

115.9

1992-93

4% 5 2 3 3

1983-93

3% 3 2 3 3

a Includes synthetic rubber, nee = not elsewhere classified. Source: Federal Reserve Board

JULY 4,1994 C&EN 31

π

PRODUCTION RY THF ILS. CHEMICAL INDUSTRY

ORGANIC CHEMICALS: Output was up in more cases than down in 1993 Mini h„n,»M otherwise noted

1983

1984

1985

1986

1987

1988

1989

1990

1991

1992

1993a

Acetic acid, synthetic Acetone Acrylonitrile Aniline Benzene, mgb c

2,807 1,859 2,035 663 1,232

2,619 1,862 2,146 786 1,318

2,897 1,788 2,219 716 1,283

2,728 1,910 2,349 824 1,362

3,246 1,846 2,182 829 1,575

3,159 2,303 2,452 1,029 1,608

3,294 2,524 2,609 1,016 1,631

3,751 2,329 2,676 989 1,699

3,615 2,347 2,647 996a 1,569

3,594 2,435 2,829 1,009 1,636a

3,656 2,462 2,508 1,011 1,677

2% 1 -11 0 3

Bisphenol A 1,3-Butadiened 1-Butanol Caprolactam Carbon tetrachloride

643 2,353 833 977 573

762 2,452 908 1,027 713

949 2,340 716 1,089 646

956 2,546 881 1,109 627

1,000 2,931 1,155 1,156 672

1,340 3,169 1,194 1,261 761

1,241 3,121 1,751 1,307 na

1,149 3,088 1,269 1,379 413

1,181a 3,054 1,320 1,284 315

1,197 3,232 1,279 1,377 na

1,286 3,092 1,328 1,359 na

7 -4 4 1

7 3 5 3





Chloroform Cumene Cyclohexane Dioctyl phthalate Ethanol, synthetic

362 3,345 1,656 300 1,077

405 3,754 1,994 301 1,060

275 2,627 1,657 275 649

422 3,745 2,070 296 529

462 4,105 2,276 343 574

524 4,455 2,297 344 562

588 4,426 2,273 306 549

484 4,311 2,460 310 546

505 4,284a 2,307 270 526

na 4,666 2,242 270 698

476 4,489 2,000 245 740

% annual change

4 4





1 18

4 5

2 2 -1 -8 20

2 2 6 4 4

-15 -3 30 121 -12

0 4 3 40 8

556 1,088 452 354 271

16 -10 -35 -2 11

1 3 -3 -5 -7

a a 3,562 3,806 3,538 3,484 3,707 3,718 854 898 874a 940 917 999 21,224 20,571 21,846 21,549 23,421 22,398 885 509 666 754 805 840 9,003a 9,000 10,063 8,984 8,337 8,017

0 -5 4 74 -12

3 0 5 6 4

-28 6 6 -22 -4 2

3 1 4 7 1 3

4,823 5,699 541 5,815 883

4,178 5,430 536 5,606 na

4,771 5,430 571 5,549 1,124

5,183 4,785 662 5,733 1,035

5,517 5,953 743 6,280 1,244

5,461 5,031 612 5,893 1,193

5,070 5,355 650 6,720 1,212

4,809 5,248 657 6,612 972

Isopropyl alcohol Maleic anhydride Methanol, synthetic Methyl fe/f-butyl ether Methyl chloride

1,209 299 7,982 839 409

1,394 359 8,186 1,376 482

1,235 394 5,003 1,891 410

1,301 359 7,205 3,375 605

1,371 382 7,537 3,514 373

1,389 448 8,142 5,680 597

1,474 475 8,167 8,227 461

1,456 424 8,344 8,884 772

1,236 1,342 1,463 424 436 381 8,704 8,082 10,542 9,570g 10,877g 24,0539 849 966 916

531 844 586 584 547

543 917 675 607 573

537 858 869 467 678

600 943 652 566 414

672 1,029 694 516 473

482 1,100 724 504 498

450 1,161 783 482 481

465 1,182 803 461 372

513 1,102 644 389 239

Terephthalic acid, dimethyl ester* Toluene, mg b k Vinyl acetate Vinyl chloride o-Xylene p-Xylene

5,626 780 1,963 6,875 781 4,114

5,912 728 2,024 6,084 688 4,264

6,490 6,257 698 611 2,112 1,710 9,463 8,439 675 788 4,779 5,035

3 3 1

2 6

504 468 694a 537 706 658 727 667 627 608 543 7,876 7,562 7,386 9,020 9,346 9,929 9,235 8,369 11,446a 11,108 11,758 282 na na 171 na 162 152 164 290 149 155 28,680 31,383 29,847 32,859 34,951 37,204 34,988 36,467 39,955 40,924 41,244 11,506 10,710 12,101 12,940 12,197 13,028 13,383 13,849 13,713 15,150 17,945

2,841 2,638 3,351 3,115 2,889 838 870 1,035 863 820 13,959 15,559 14,887 16,522 19,019 484 462 747 573 500 6,802 7,709 7,622 7,888 8,014

3% 3 2 4 3

-4

4,425 5,534 387 5,465 760

Phenol, synthetich Phthalic anhydride Propylene1 Propylene glycol Styrene



1983-93

-4 -11 -9 6

Ethylene glycol Ethylene oxide 2-Ethylhexanol Formaldehyde, 37%f Isobutylene

Methyl ethyl ketone Methyl methacrylate Methylchloroform Methylene chloride Perchloroethylene

1992-93

5,128 5,829 692 8,278 952

479 1,208 692 362 245

5,228 5,684 688 7,604 1,146

7,601 10,234 8,426 7,773 7,654a 5,637a 7,837 967 892 806 861 873 833a 833 1,813 2,561 2,552 2,659 2,732 2,657 2,827 8,402 9,058 10,135 10,623 11,142 11,307 13,746 940 971 983 943 935a 918 884 5,155 5,601 5,344 5,200 5,431 a 5,656 5,757

C\J

Ethanolamines6 Ethylbenzene Ethyl chloride Ethylene Ethylene dichloride

Production

Note: In 1992, the International Trade Commission changed its format for presenting revised data in its annual synthetic organic chemicals report to conform to the format of the Harmonized Tariff Schedule (HTS) of the U.S. For this reason, revised data for 1992 for some organic chemicals—in this table benzene, phenol, terephthalic acid, and toluene—are not comparable with either revised data for previous years or preliminary data for 1993. Thus, preliminary data for 1992, which are comparable, are reported for these chemicals, mg = millions of gallons, a Preliminary, calculated from quarterly data, b Tar distillers and coke-oven operators not included, c Specification grades, d Rubber grade, e Mono-, di-, and triethanolamines. f By weight. g C&EN estimate, h Does not include data for coke ovens and gas-retort ovens, i All grades, j Includes both acid and dimethyl ester (DMT), without double counting, k All grades, includes material used in blending motor fuel, na = not available. Source: International Trade Commission

32

JULY 4,1994 C&EN

INORGANIC CHEMICALS: Largest volume product, sulfuric add, fell 10% in year of mixed results % annual change

Production

Thousands of tons unless otherwise noted

1983

1984

1985

1986

1987

1988

1989

1990

1991

1992

1993a

Aluminum sulfate Ammonia, 100%cd Ammonium nitrate, 100%e Ammonium sulfate, 100%f Chlorine gas9

1,119 14,072 6,240 1,956 9,960

1,129 16,692 7,146 2,067 10,700

1,268 17,319 7,149 2,093 10,402

1,222 14,487 6,091 2,080 10,436

1,227 16,098 6,547 2,189 11,078

1,237 16,821 7,504 2,333 11,257

1,243 16,468 7,871 2,384 11,413

1,227 17,003 7,713 2,519 11,809

1,185 17,169 7,819 2,243 11,421

1,047 18,295 7,832 2,391 11,757

1,113 17,252 8,394 2,398 12,028

Hydrochloric acid, 100%h Hydrogen, bcf, 100%'J Hydrogen peroxide, 100%k Nitric acid, 100%k Nitrogen gas, bcf, 100%iJ Oxygen, bcf, 100%iJ

2,468 103 117

2,732 109 139

2,807 121 144

2,413 136 152

2,996 173 153

3,228 177 168

3,268 146 204

3,140 148 238

3,301 153 254

3,567 161 na

3,224 178 na

-10 11 na

3 6 na

6,768 560 346

7,726 661 375

7,631 665 393

6,734 677 383

7,225 685 405

7,991 722 452

8,349 744 460

7,932 749 462

7,927 770 470

8,043 835 525

8,537 901 562

6 8 7

2 5 5

Phosphoric acid, 100% P2O5 Phosphorus"1 Sodium chlorate, 100% Sodium hydroxide, 100% Sodium phosphate"

9,767

11,370

10,607

9,578

10,599

11,659

11,737

12,035

12,109

12,792

11,521

-10

2

366 323 10,039 669

386 295 10,914 675

359 259 10,811 625

364 267 10,691 617

344 289 11,553 586

343 267 10,533 549

353 290 11,470 610°

346 327 12,030 497

306 449 11,713 462

271 554 12,249 na

267 544 12,854 na

-1 -2 5 na

-3 5 3 na

Sodium silicate*3 Sodium sulfate, 100%q Sulfuric acid, 100%r Titanium dioxide, 100%s Urea

710 914 36,583 760 6,137

685 901 41,802 835 7,433

692 1,203 39,890 860 6,975

812 791 952 837 819 799 35,993 39,256 42,580 1,022 968 931 7,914 6,264 7,433

912 870 761 794 43,466 44,860 1,253 1,095 8,981 8,133

983 718 40,153 1,280 7,832

8 -6 -10 2 -13

3 -2 1 5 2

13

816 833 786 755 43,301 44,337 1,077 1,101 8,004 8,216

1992-93

1983-93

0% 2 3 2 2

6% -6 7 0 2

Note: bcf = billions of cubic feet, a Preliminary, b Commercial, 17% Al 2 0 3 ; includes municipalities, c Synthetic anhydrous, d Excludes by-product ammonia liquor and ammonium sulfate, e Original solution, f Synthetic and noncoke by-product, g Includes quantities liquefied for use, storage, or shipment, h Includes anhydrous hydrochloric acid production, i High- and low-purity gas. j Liquid and gas; excludes amounts vented and used as fuel, and amounts produced in petroleum refineries for captive use. k Includes unspecified amounts produced but not withdrawn from the system. I Excludes amounts produced and consumed in making synthetic ammonia or ammonia derivatives, m Elemental, white (yellow), and red (technical), η Tripolyphosphate (100% Na5P3O10). ο Includes tetrabasic (pyro) phosphate, ρ Soluble silicate glass (water glass), solid and liquid (anhydrous); excludes amounts produced and consumed in making meta-, ortho-, and sesquisilicates. q Anhydrous, high and low purity, and Glauber's salt, r Gross (new and fortified), s Composite and pure, na = not available. Sources: Department of Commerce, Bureau of the Census

MINERALS: Phosphate rock production tumbled 24%, potash output dropped 12% % annual change Thousands of tons

1983

Bromine, sold or used

b

Calcium chloride, production

185 0

Lime, production6

912 14,867

0

Lithium, consumption ·* Phosphate rock Production Exports

2.2

46,928 13,239

1984

193 1,036d

1985

160

1986

155

1987

168

1988

180

1989

193 628d

1990

195 691 d

1991

187 620d

d

1983-93

0%

1%

na

na

na

15,922 15,690 14,474 15,733 17,052 17,152 17,452 17,270d 17,857 18,427

3

2

2.8

12

2

51,770 39,125 4,104 3,525

-24 -14

-2 -12

1,653d -12 4,809d 3 5,988d 2

0 0 0

9,878

-4

2

-1 1 -5 0 -1

1 4 -4 1 1

3.2

940

2.5

780

2.6

658

2.6

677

3.0

3.0

3.0

2.9

54,230 56,035 44,445 45,144 50,032 54,913 51,084 53,016 12,707 10,071 8,651 9,319 8,920 8,644 6,876 5,602

821

2.5

1,575 4,894 6,231

1,724 5,323 6,638

1,429 5,063 5,893

1,325 4,643 5,338

1,391 4,490 5,609

1,677 4,648 5,803

1,758 3,758 4,960

1,888 4,590 6,011

1,928 4,990 6,186

1,879 4,683 5,898

Sodium carbonate, production'

8,467

8,511

8,511

8,438

8,891

9,632

9,915 10,093

9,926

10,338

10,240 5,462 3,530 1,249 12,112

1992-93

185

183

Potash (K 2 0 equivalent)9 Production Imports Apparent consumption

Sulfur, production Recovered elemental Frasch Other production Apparent consumption

1993a

1992

11,742 12,797 12,221 11,616 11,845 12,778 12,743 11,928 5,747 5,857 6,411 6,791 7,103 7,176 7,205 7,326 4,622 5,524 4,457 3,530 3,499 4,286 4,107 3,162 1,372 1,416 1,354 1,296 1,243 1,316 1,431 1,440 13,976 13,192 11,669 12,481 14,012 13,983 14,392 14,255

d

11,759 11,684 7,769 7,826d 2,557 2,425d 1,433 1,433d 14,056 13,889d

a Preliminary data, except those for phosphate rock, b Elemental bromine sold as such or used in preparation of bromine compounds by primary producers, c 75% CaU2 equivalent, d Estimated, e Sold or used by producers for commercial or captive use. Produced from limestone and dolomite, does not include amount regenerated by paper industry; excludes Puerto Rican production. f Lithium content basis, g Includes muriate and sulfate of potash, potassium magnesium sulfate, and parent salts; excludes other chemical compounds containing potassium, h Calculated from shipments plus imports minus exports, i Natural and synthetic until 1986, natural only in 1987-92. j Sulfur content basis, na = not available. Sources: Bureau of Mines, Bureau of the Census

JULY 4,1994 C&EN

33

PLASTICS: Strong year for thermosets, thermoplastics gain as well IProduction Millions of lba

1985

1986

1987

1988

1989

1990

1991

1992

1993

406 210 2,502 1,232 1,199

385 192 2,621 1,223 1,210

398 173 2,735 1,271 1,271

433 212 2,869 1,367 1,382

486 207 3,066 1,404 1,425

509 222 2,879 1,319 1,477

499 202 2,946 1,221 1,496

497 196 2,658 1,075 1,483

457 232 2,923 1,175 1,548

5,247

5,549

5,631

5,848

6,263

6,588

6,408

6,364

5,909

8,041 5,689 4,433

8,413 6,085 4,940

8,889 6,671 5,139

8,903 7,182 5,812

9,599 7,995 6,647

10,397 8,400 7,274

9,695 8,102 7,238

11,148 8,337 8,310

3,570 93 1,889

3,838 99 2,127

4,054 87 2,036

4,470 92 2,196

4,780 126 2,254

5,187 148 2,418

5,104 113 2,394

5,021 135 2,351

4,954 109 2,287

5,096 113 2,610

5,367 105 2,920

5 -7 12

4 1 4

321 6,067

396 6,760

399 6,772

465 7,256

507 7,971

566 8,350

569 8,478

558 9,096

576 9,164

768 668 9,989 10,257

15 3

9 5

778

899

965

1,175

1,394

1,652

1,630

1,879

2,115

2,413

5

12

THERMOSETTING RESINS Epoxyb 334 Melamine 180 Phenollccd 2,477 Polyester6 1,084 Urea 1,172 TOTAL THERMOPLASTIC RESINS Polyethylene Low density* High density9 Polypropylene Styrene polymers Polystyrene Styrene-acrylonitrile Acrylonitrile-butadienestyrene and other styrene polymersh Polyamide, nylon type Polyvinyl chloride and copolymers Thermoplastic polyester TOTAL

% annualI change

1984

1983

1992-93

1983-93

510 270 3,078 1,264 1,743

12% 16 5 8 13

4% 4 2 2 4

6,335

6,865

8%

3%

11,582 11,917 9,808 9,213 8,421 8,330

12,044 9,912 8,614

1% 1 2

4% 6 7

2,536

30,881 33,557 35,012 37,551 41,273 44,392 43,323 46,835 48,330 51,035 52,524

3%

6%

Note: Totals are for those products listed and exclude some small-volume plastics, a Dry-weight basis unless otherwise specified, b Unmodified, c Includes other tar-acid resins, d Gross-weight basis, e Unsaturated, f Density 0.940 and below, g Density above 0.940. h Includes styrene-butadiene copolymers and other styrene-based polymers. Source: Society of the Plastics Industry

SYNTHETIC RUBBER : Shipments rose 3% in 1993, continuing previous year's upswing Shipments9 Thousands of metric tons

1983

Styrene-butadiene rubber Polybutadiene Ethylene-propylene Nitrile-solid Polychloroprene Other" TOTAL

1984

1985

1986

1987

1988

% annual change 1989

1992

1991

1990

1993

1992-93

1983-93

881 391 155 56 88 303

888 433 185 65 93 323

753 392 174 58 82 289

736 384 188 64 82 310

847 414 205 72 81 336

829 430 224 75 82 355

827 427 225 72 79 295

791 431 208 69 79 329

727 416 192 71 70 298

796 463 206 74 72 315

817 473 227 78 70 328

3% 2 10 5 -3 4

- 1 % 2 4 3 -2 1

1,874

1,987

1,748

1,764

1,955

1,995

1,925

1,907

1,774

1,926

1,993

3%

1%

a Includes Canada, b Includes butyl styrene-butadiene rubber latex, nitrile latex, polyisoprene, and miscellaneous others. Source: International Institute of Synthetic Rubber Producers

SYNTHETIC FIBERS: Nylon, olefin posted healthy gains, acrylic fell for ninth consecutive year Production

Millions of lb

1983

% annual change

1984

1985

1986

1987

1988

1989

1990

1991

1992

1993

671 2,412 997 3,392

631 2,343 1,249 3,341

616 2,514 1,393 3,305

592 2,689 1,494 3,541

588 2,669 1,588 3,681

543 2,740 1,639 3,594

506 2,662 1,822 3,195

454 2,535 1,866 3,411

439 2,556 2,002 3,576

433 2,664 2,138 3,557

558

619

605

614

580

505

486

495

505

8,122

8,447

8,921

9,140

9,096

8,690

8,752

9,068

9,297

1992-93

1983-93

NONCELLULOSIC FIBERS

Acrylic3 Nylon Olefin5 Polyester

671 2,419 906 3,544

CELLULOSIC FIBERS Acetate6 r 229 J 40^ R TOTAL

8,168

199 421

8,092

-1% 4 7 -1

-4% 1 2 0

ι I

2 3%

-2 1%

a Includes modacrylic. b Includes olefin yarn and monofilaments and olefin and vinyon staple, tow, and fiberfill. c Includes diacetate and triacetate; excludes production for cigarette filters. Source: Fiber Economics Bureau

34 JULY 4,1994 C&EN

Plastics

Synthetic noncellulosic fibers

Chlorofluorocarbons

Billions of lb

Billions of lb

Millions of lb 500 I 400

CFC-12

CFC-22

300

\

Et

^ V X * 200

20

CFC-11-"

100

Ζ _ι_

_L

1983 84 85 86 87 88 89 90 91 92 93

0

_L_

_]_

ι

J

1983 84

1983 84 85 86 87 88 89 90 91 92 93

85

86

87

88

1

90 91 92 93

PAINTS AND COATINGS: Shipments for aixhkectui^ uses grew fastest in year of steady expansion % annuaI change

Shipments Millions of gal

1983

1984

1985

1986

1987

1988

1989

1990

1991

1992

19933

Architectural Product6 Special purpose TOTAL

433 294 130 857

457 336 145 938

478 352 145 975

498 368 135 1,001

527 340 146 1,013

536 364 154 1,054

537 360 179 1,076

557 346 197 1,100

538 320 180 1,038

562 334 169 1,065

586 342 172 1,100

1992-93

1983-93

4% 2 2 3%

3% 2 3 3%

a Calculated from quarterly data, b For original equipment manufacturers. Source: Department of Commerce

AEROSOLS: Production decreased 2% in 1993 as volume fell for many end uses Production8 Millions of units

Personal products Household products Automotive & industrial products Paints and finishes Insect sprays Food products Animal products Miscellaneous TOTAL

1983

1984

1985

1987

1986

% annual change

1988

1989

1990

1991

1992

1993

1992-93

1983-93

747 586 303

832 603 337

879 630 342

952 635 375

964 640 379

1,100 650 440

1,015 680 475

1,050 680 415

905 690 450

990 695 455

930 738 420

-6% 6 -8

2% 2 3

300 180 132 19 15 2,282

307 184 138 16 15 2,432

290 190 140 15 23 2,509

297 193 136 22 18 2,628

307 190 140 22 80 2,722

331 190 157 8 31 2,907

350 197 175 8 12 2,912

350 190 175 8 15 2,883

350 200 192 8 19 2,314

380 200 190 8 71 2,989

390 207 205 6 44 2,940

3 4 8 -25 -38 -2%

3 1 -4 -11 11 3%

a Includes Puerto Rican production Source: Chemical Specialties Manufacturers Association

CHLOROFLUOROCARBONS: CFC-12 rose 13% as other nonhydrogenated products dropped % annual change

Production Millions of lb

Chlorodifluoromethane (CFC-22) Dichlorodifluoromethane (CFC-12) Trichlorofluoromethane (CFC-11) All other fluorinated hydrocarbons15 TOTAL

1983

1984

1985

1986

1987

1988

1989

1990

1991

1992

1993a

236 290 215 279 1,020

254 337 185 337 1,113

235 302 176 306 1,019

271 322 202 344 1,139

275 335 198 354 1,162

333 414 249 379 1,374

343 392 192 385 1,312

306 209 135 na na

314 157 99 239 809

330 163 100a na na

291 185 72 na na

1992-93

1983-93

-12% 13 -28

2% -4 -10

— —

— —

a Preliminary, b Includes other fluorohalogenated hydrocarbons, na = not available. Source: International Trade Commission

JULY 4,1994 C&EN

35

|ΙΤ|τ-

RODUCTION BY THE U.S. CHEMICAL INDUSTRY

PESTICIDES: Herbicides and insecticides production recovered in 1992 Production Millions of lb

1982

Herbicides Insecticides Nematicides Fungicides Plant growth regulators

1983

734 229 71 b 77 9b

TOTALc

1,137

1984

587 206 76b 43 5b

1985

688 211 53b 78 8

975

647 213 50b 75 8

1,074

1,014

1986

1987

625 204 66 70 5

623 185 76 62

982

964

% annual change 1988

2b

1990

1989

1992

1991

1991-92

1982-92

6% 5 -1

-1% -2 0 1

696 190 71 b 85

676 203 85 193a 4

676 208 112 207a 5b

643 264a 67b 85 6b

657 181 72 17

12

1,183a

1,222a

1,093a

1,054

1,083

na

-3 3%

0%

a These seemingly anomalous values have been verified by the source, b Does not include production intended for sale outside the U.S., which is included in annual total, c Includes miscellaneous other pesticides and, in some cases, production, usually intended for sale outside the U.S., not reported by subcategory, na = not available. Source: National Agricultural Chemicals Association

Pesticides

Fertilizer consumption

Millions of lb 1,400|

Millions of tons 30 Total

Potash (K 2 0)

\ 20

/ /

10 !

Nitrogen (N)

Phosphates (P 2 0 5 ) I

J

198283 84 85

86 87 88 89

90

1983 84

L

91 92

I

I

85

86

1

1

1

1

1

1

87

88

89

90

91

92

93

Note: Years ending June 30.

FERTILIZER CONSUMPTION: Use of phosphates grew substantially last year % annual change 1984

1985

1986

1987

1988

1989

1990

1991

1992

1993

9,127 4,138 4,831

11,092 4,901 5,797

11,493 4,658 5,553

10,424 4,178 5,053

10,210 4,008 4,837

10,512 4,129 4,973

10,593 4,117 4,838

11,076 4,345 5,203

11,287 4,201 5,001

11,446 4,218 5,042

11,358 4,458 5,110

-1% 6 1

2% 1 1

18,096

21,790

21,704

19,655

19,055

19,614

19,548

20,624

20,489

20,706

20,926

1%

1%

Thousands of tons

1983

Nitrogen (N) Phosphates (P 2 0 5 ) Potash (K20) TOTAL

1992-93

1983-93

Note: Years ending June 30 Source: Fertilizer Institute

FERTILIZER PRODUCTION: Phosphate rock plunged 24% in dismal year for major products % annual change Thousands of tons

1983

1984

1986

1987

1988

1989

1992

1990

1993

1992-93 1983-93

NITROGEN PRODUCTS. Ammonia Ammonium nitrate Ammonium sulfate Urea

13,361 16,613 16,594 12,565 13,357 14,136 14,052 14,446 13,790 13,309 12,587 3,232 3,365 3,178 2,250 2,472 2,765 2,703 2,579 2,551 2,487 2,700 1,969 2,078 2,343 2,058 2,153 2,260 2,327 2,460 2,195 2,342 2,379 4,112 4,889 3,975 3,564 4,253 4,501 4,430 4,287 4,241 4,164 3,863

-5% - 1 % 9 -2 2 2 -7 -1

PHOSPHATE PRODUCTS. Diammonium phosphate Monoammonium phosphate Concentrated superphosphate Phosphate rock Phosphoric acid (P 2 0 5 )

10,264 12,35810,800 7,492 9,537 11,575 13,160 13,226 13,573 14,119 12,635 1,423 1,654 1,641 1,416 1,679 1,818 1,862 2,252 2,227 2,342 2,693 na 2,684 2,404 2,570 2,127 2,049 2,032 1,777 1,988 1,914 2,074 40,664 47,465 49,348 36,227 39,330 42,220 47,676 44,269 44,877 45,941 34,800 9,182 10,899 9,837 8,085 8,903 10,234 10,742 11,036 10,934 11,354 10,348

-11 15 — -24 -9

POTASH PRODUCTS Potassium chloride

1,928

2,168 1,713

1,715

1,810

2,243

2,316

2,351

2,387

Note: Figures are based on Fertilizer Institute surveys and may not represent the entire industry, na = not available. Source: Fertilizer Institute

36 JULY 4,1994 C&EN

2,337

1,927

-18

2 7 — -2 1

2

FTIVAIVrFÇ O F T H F Τ Τ Ç ΓΙΤΡΜΤΓΑΪ TlVnTTSTRY

Chemical industry begins to recover A t last, the U.S. chemical industry / % has had a reasonable year. AlJL J L though 1993 will not go down in history as a particularly good year for chemical makers, it was the first year since 1988 in which the industry increased earnings over the previous year. Earnings and profitability are nowhere near the levels they were in the late 1980s, but the industry once again appears to be growing. The upward move came after four years of sagging performance for the industry during which earnings plum-

meted more than 40% and various measures of profitability fell dramatically. The result was a massive contraction of chemical employment and cuts in capital spending. The reason for capital spending cuts was easy to see— major markets had turned down, so there was no need to increase production capacity. Now, however, many of these same markets are growing once again: Motor vehicles and housing, both big users of chemical products, are prime examples. As a result, chemical companies

Earnings, profitability finally started to improve last year Sales, $ billions

Earnings, $ billions

100 80

/^'>;;.;

60

,, ,,,,,,,;,,^,,,,,,,,,,,,;,,^ 40

20

1 ...J 1 1 1. 1 I I 0 0I i_ ! 1983 84 85 86 87 88 89 90 91 92 93 1983 84 85 86 87 88 89 90 91 92 93

Return on stockholders' equity, %' 25

Profit margin, % b 10[

1983 84 85 86 87 88 89 90 91 92 93 1983 84 85 86 87 88 89 90 Note: Based on data for 30 major chemical companies, a After-tax earnings as a percentage of year-end stockholders' equity, b After-tax earnings as a percentage of sales.

93

in 1993 began to see business increase. Since these companies have spent the past few years cutting costs, especially in white-collar employment, earnings were high. For instance, in 1993, sales increased only about 2% for the 30 major chemical companies C&EN regularly monitors, while earnings rose a much greater 8%. Thanks to the earnings increase, profit margins for the group rose to 5.3% from 5% in 1992, and return on stockholders equity increased to 12.4% from 12.0%. Further evidence that the earnings growth was caused as much by cutting costs as by growing markets can be found in several other measures of industry performance. Shipments of chemicals and allied products increased just 4% for the year, and demand for industrial chemicals rose only 3%. Pricing was anything but good. The government's producer price index for chemicals and allied products increased 2% from the year before, but most of this increase came from drugs and pharmaceuticals, up 5% for the year. Other more basic chemical sectors showed little or no change. However, these lackluster indicators are not necessarily bad news for the industry's future. If chemical companies can manage an average 8% earnings increase with the price and demand situations that prevailed in 1993, all they need is to have a small rise in prices to begin reaping greater returns. In fact, Wall Street's financial community is betting on better days to come. Chemical stock prices set new record highs in 1993 and continue to rise this year, indicating that investors believe there is still plenty of room for improvement in the chemical industry. But there are danger signals for a chemical recovery. Chief among these are interest rate increases that may slow demand for housing and automobiles. The recent decline of the dollar may force further rate increases as the U.S. tries to bolster its currency and fight inflation coming from higher priced imports. JULY 4,1994 C&EN

37

TOP 100 CHEMICAL PRODUCERS: Most of the largest companies saw big gains in profits in 1993 Chemical Change sales 1993 from ($ millions) 1992

Rank 1993 1992

1 2 3 4 5

38

1 2 3 4 5

DuPont Dow Chemical Exxon Hoechst Celanese Monsanto d

$15,603 12,524 10,024 6,347 5,651

0.4% -3.1 -5.7 -2.3

5.0

6 7 8 9 10

7 6 8 9 10

11 12 13 14 15

14 Shell Oil 12 Amoco



11 Mobil 16 Rohm and Haas

3,875 3,773 3,565 3,533 3,269

6.7

16 17 18 19 20

15 19 18 13 21

Arco Chemical Miles Air Products® W. R. Grace AlliedSignal

21 22 23 24 25

17 23 22 20 26

26 27 28 29 30

27 25 29 35

31 32 33 34 35

28 31 30 36 34

36 37 38 39 40

Chemical sales as % of total sales

Industry classification

42.1°/j Diversified 69.3 Basic chemicals 9.2 Petroleum 92.0 Basic chemicals 71.5 Basic chemicals

Chemical operating Change profits8 from ($ millions) 1992

$750

773 638 561 731

Chemical operating profits as % of total profits

51.7% 53.7

-45.9% 30.6 -3.3 26.9 17.5

155.8 90.2 12.7 100.0 84.8

7.6

Identifiable Operating chemical profit b assets margin ($ millions)

4.8%> $13,957 6.2 12,530 6.4 8,478

Chemical assets Operating as % of return on total chemical assets assets0

45.1%> 49.1 10.1

5.4%

8.8

na

na

6.2 7.5 na

12.9

5,312

61.5

13.8

16.5

8,181 4,419 5,780

3.3

10.2

100.0 33.8

Diversified Basic chemicals Petroleum Basic chemicals Basic chemicals

834 354 184 na 476

12.7 12.0 100.0

na

na

7.6 4.5 na

na

na

8.0 3.2 na

-5.7

100.0

12.2

4,341

100.0

11.0

328 321 188 25 267

89.6

23.0 10.5 100.0

4,312 3,938

16.1 13.8

na 3,451 3,200

na 8.5

100.0

Petroleum Petroleum Basic chemicals Petroleum Basic chemicals

100.0

7.6 8.5 na 0.7 8.3

3,192 3.0 3,053 4.7 2,906 3.6 2,895 -16.7 2,791 7.3

100.0 47.3 87.3 65.7 23.6

Basic chemicals Diversified Basic chemicals Specialty chemicals Diversified

425 na 417 392 309

12.1

Chevron Ashland Oil 6 Ciba Praxair Phillips Petroleum

2,708 2,586 2,519 2,438 2,308

-5.7

7.5

3.9

25.4 55.2 100.0 18.8

Petroleum Petroleum Specialty chemicals Basic chemicals Petroleum

225 108 na 341 97

Akzo Rhône-Poulenc Dow Corning Ethyl Huntsman Chemical

2,241 2,200 2,044 1,938 1,850

11.7 -4.3

100.0 100.0 100.0 100.0 100.0

Basic chemicals Specialty chemicals Specialty chemicals Basic chemicals Basic chemicals

196 na 236 168 na

Hercules

-12.7

National Starch Great Lakes Chemical Elf Atochem

1,843 1,837 1,808 1,792 1,700

66.5 48.9 100.0 100.0 100.0

Basic chemicals Machinery Specialty chemicals Specialty chemicals Basic chemicals

252 197 288 415 na

38 24 40 39 42

Lubrizol American Cyanamid d Nalco Chemical Lyondell Petrochemical Morton International·*

1,526 1,411 1,389 1,326 1,274

6.4 8.5 1.1

100.0 33.0 100.0 34.4 55.2

Specialty chemicals Specialty chemicals Specialty chemicals Petroleum products Specialty chemicals

190 na 263 57 135

41 42 43 44 45

58 45 44 46 47

Witco Solvay America Cabot 6 International Flavors PPG Industries

1,233 1,200 1,192 1,189 1,150

47.3

57.5 100.0 73.8 100.0 20.0

Specialty chemicals Basic chemicals Basic chemicals Specialty chemicals Glass products

108 na 149 311 138

46 47 48 49 50

49 37 41 52

Olin Texaco BP America Henkel Cytec

1,117 1,114 1,038 1,010 1,008

12.1 -23.9 -19.8 14.6 -3.5

46.1

Basic chemicals Petroleum Petroleum Specialty chemicals Basic chemicals

na na 26 na na



General Electric Union Carbide Occidental Petroleum BASF Eastman Chemical

ICI Americas

FMC

JULY 4,1994 C&EN

5,042 4,640 4,065 4,037 3,903

3.9

8.3

-4.8 -3.8 -0.3

100.0 47.6 77.6 100.0

2.4 18.2

2.2 20.0 -4.6

-0.2 -6.4

3.7

4.5 14.5 15.6

1.0 -1.0 19.7

0

-5.9

3.2

4.4 0.9 5.5 3.4

18.6 13.2 100.0

5.5

3.2 6.6 100.0 100.0

45.7 -82.4 -21.9

100.0

8.5 8.5 5.3 0.7 8.2

-7.0

100.0

13.3

3,502

100.0

na

na

na

na

na

na

-16.6 -9.9 26.1

113.0 103.2 32.4

14.3 13.5 11.1

3,646 2,115 2,502

87.5 39.5 23.1

11.4 18.5 12.4

94.0 12.5

8.2

2,457

7.1

9.2

36.4

958 na

17.3

11.3

na

na

100.0 18.5

10.5

def

0.5

na

na

8.3 4.2 na

23.6 148.7

100.0

14.0

9.1

4.2

3,255 2,011

28.9

100.0

na

na

8.8 na

na na

na na

11.9 -22.9

100.0 100.0

11.5

3,265 2,009

100.0 100.0

na

na

8.6 na

na

na

na na 7.2 8.3 na

1.2

15.0

81.8 52.5 100.0 100.0

13.7 10.7 15.9 23.2

1,375 1,522 1,672 1,901

61.0 54.1 100.0 100.0

18.3 13.0 17.2 21.8

na

na

na

na

na

na

2.6 na 1.0

100.0

12.5

1,055

89.2

18.0

na

na

na

na

na

18.9

1,212

21.7

-58.7 -18.1

100.0 61.3 42.9

45.7

94.5

10.4

na

-7.5

3.3

4.8

4.3

688

10.6

1,273

100.0 55.9 56.8

8.8 na

1,037

56.4

na

na

na

na

-3.8 16.0 -25.4

89.9 100.0 18.5

12.5 26.2 12.0

1,117 1,225 1,092

75.0 100.0 19.3

13.3 25.4 12.6

na na

na na 1.8 na na

na na 2.5 na na

na na na na na

na na na na na

na na na na na

-59.4

na na

8.3 10.6

Chemical Change sales 1993 from ($ millions) 1992

Rank 1993 1992

Chemical sales as % of total sales

Industry classification

Chemical operating Change profits8 from ($ millions) 1992

51 52 53 54 55

52 — 50 — 51

H. B. Fuller9 Geon Tenneco Hanson Engelhard

56 57 58 59 60

57 54 48 54 —

Uniroyal Chemical CF Industries IMC Fertilizer* Farmland Industries'1 Wellman

908 906 897 893 842

6.1 0.8 -15.2 -0.6 1.7

100.0 100.0 100.0 18.9 100.0

Specialty chemicals 110 -21 Agrochemicals Agrochemicals 19 Agricultural supplies 49 Basic chemicals 76

0.1 def -90.1 -55.3 -31.3

61 62 63 64 65

32 62 69 65 59

BF Goodrich CBI Industries Arcadian Partners Fina Aristech

830 826 799 793 788

-53.3 10.7 34.8 12.3 -1.4

45.6 49.4 100.0 23.2 100.0

Basic chemicals Construction Agrochemicals Petroleum Basic chemicals

53 113 69 60 na

66 67 68 69 70

61 66 56 64 60

Georgia Gulf Vista Chemicals NL Industries Betz Laboratories Freeport-McMoRan

769 701 697 685 619

-1.4 3.9 -22.0 -3.1 -22.5

100.0 100.0 86.6 100.0 38.5

71 72 73 74 75

71 67 71 70 75

Sigma-Aldrich Loctite Kerr-McGee Intl. Specialty Products GenCorp

613 613 556 548 519

10.8 0.8 8.0 -3.9 7.7

76 77 78 79 80

80 73 68 73 86

Sterling Chemical Union Camp Merck Huls America Degussa

519 519 510 500 481

81 82 83 84 85

76 63 77 79 82

Aluminum Co. of America Unocal Ferro Stepan Borden Chemicals

86 87 88 89 90

— 85 83 79 81

91 92 93 94 95 96 97 98 99 100

Chemical Chemical operating Identifiable assets Operating profits as Operating chemical as % of return on % of total profit assets total chemical profits margin" ($ millions) assets assets0

5.5% 2.5 9.1 na 15.0

$565 721 721 na 788

100.0% 9.5% 100.0 3.4 4.7 11.5 na na 17.4 61.6

100.0 def 100.0 63.6 100.0

12.1 def 2.1 5.5 9.1

1,225 951 2,056 325 1,015

100.0 100.0 100.0 18.9 100.0

8.9 -6.7 0.9 15.1 7.5

92.0 4.8 -10.0 -39.4 na

62.6 95.7 100.0 117.3 na

6.4 13.6 8.6 7.6 na

687 na 1,015 402 na

29.1 na 100.0 16.0 na

7.7 na 6.8 15.0 na

111 Basic chemicals Basic chemicals na Basic chemicals 36 Specialty chemicals 101 Agrochemicals -56

-14.2 na -55.9 -22.8 def

100.0 na 57.9 100.0 def

14.4 na 5.2 14.8 def

405 na 1,008 521 1,194

100.0 na 83.6 100.0 32.2

27.3 na 3.6 19.4 -4.7

82.9 100.0 16.9 100.0 27.2

Specialty chemicals Specialty chemicals Petroleum Specialty chemicals Rubber products

149 na 70 65 47

8.5 na -11.4 -39.6 4.4

89.7 na 35.2 100.0 38.8

24.2 na 12.6 11.9 9.1

658 na 733 na na

87.4 na 20.7 na na

22.6 na 9.5 na na

20.5 3.7 -14.2 0 30.8

100.0 16.6 4.9 100.0 84.0

Basic chemicals Diversified Drugs Specialty chemicals Specialty chemicals

15 49 na na na

-12.4 56.9 na na na

100.0 23.1 na na na

3.0 9.4 na na na

540 385 na na na

100.0 8.2 na na na

2.9 12.7 na na na

479 460 449 439 433

0.7 -37.2 -4.2 0.7 7.8

5.3 5.5 42.1 100.0 100.0

Nonferrous metals Petroleum Specialty materials Specialty chemicals Basic chemicals

na 65 24 20 17

na 75.7 20.2 -35.7 -63.9

na 10.6 24.9 100.0 100.0

na 14.1 5.3 4.5 3.8

na 387 238 300 444

na 4.2 37.2 100.0 100.0

na 16.8 10.0 6.5 3.7

Rexene Lonza Crompton & Knowles Mallinckrodt Sun Co.

429 420 407 395 389

3.5 10.5 3.1 -10.3 -5.7

100.0 100.0 73.0 22.0 4.2

Basic chemicals Specialty chemicals Specialty chemicals Specialty chemicals Petroleum

15 na 68 na na

34.2 na 7.3 na na

100.0 na 72.4 na na

3.4 na 16.7 na na

430 na 282 na na

100.0 na 77.6 na na

3.4 na 24.2 na na

84 88 92 87 89

Vulcan Materials Petrolite* Mississippi Chemical First Mississippi1 Calgon Carbon

377 333 289 285 269

-3.8 10.3 20.6 -9.3 -9.7

33.2 94.5 74.8 66.3 100.0

Nonmetallic minerals Specialty chemicals Farm cooperative Agrochemicals Basic chemicals

17 30 23 38 33

-66.1 21.7 -27.7 -4.6 -29.2

12.9 94.1 473.5 155.8 100.0

4.6 8.9 7.8 13.2 12.3

na 259 287 168 337

na 86.0 89.4 50.7 100.0

na 11.5 7.9 22.5 9.8

91 90 — 94 96

Georgia-Pacific Agricultural Minerals Terra Industries Nova Cambrex Corp.

267 260 229 222 197

11.3 6.7 82.4 -1.4 9.9

2.2 100.0 18.5 100.0 100.0

Wood products Agrochemicals Agrochemicals Basic chemicals Specialty chemicals

na 53 29 na 17

na -5.3 93.9 na 20.4

na 100.0 58.5 na 100.0

na 20.4 12.5 na 8.4

na 286 na na 167

na 100.0 na na 100.0

na 18.5 na na 10.0

$975 973 914 911 910

4.5°/c> 100.0% Specialty chemicals $54 8.7 24 100.0 Basic chemicals -3.9 6.9 Diversified 83 12.2 na 12.6 Diversified -4.1 137 42.3 Diversified

-25.1% 100.0% -384.7 100.0 6.7 6.4 na na 7.2 81.5

a Operating profit is sales less administrative expenses and cost of sales, b Chemical operating profit as a percentage of sales. c Chemical operating profit as a percentage of identifiable chemical assets, d Chemical sales include significant amounts of nonchemical products, e Fiscal year ended Sept. 30 f Fiscal year ended June 30. g Fiscal year ended Nov. 3C). h Fiscal year ended Aug. 31. i Fiscal year ended Oct. 31. na = not available, def = defic t.

JULY 4,1994 C&EN

39

2

FINANCES OF THE U.S. CHEMICAL INDUSTRY

FINANCIAL ANALYSIS: Most ratios at chemical companies continued to fall

Profit margin3

Return on investment 6

Debt as % of debt plus equity

% total sales abroad6

% total assets abroad"

Sales per employee6

Dividends as % of net income

CAPITAL SPENDING' As% As% of net of plant sales

R&D as % of sales

Sales as % of assets

Net plant as % of gross plant

Air Products9

1993 1992

6.0% 8.6

2.8% 4.1

32.6% 31.3

25.2% 27.6

31.0% $236 222 33.3

American Cyanamid

1993 1992

8.1 7.5

5.6 6.1

20.1 13.0

39.8 38.8

27.3 24.4

161 161

44.5 37.0

7.1 7.8

17.3 19.3

13.9 10.7

70.6 97.3

57.0 53.0

Arco Chemical

1993 1992

6.7 8.5

5.1 6.1

36.0 39.0

34.5 42.9

36.4 36.6

na 728

112.1 94.9

5.7 9.9

8.3 13.2

2.3 2.2

91.1 83.0

66.7 70.5

Betz Laboratories

1993 1992

10.7 11.6

9.6 11.5

24.6 24.8

20.7 21.2

23.3 22.2

166 170

64.6 54.8

9.2 10.5

21.0 25.8

4.2 4.0

131.4 138.5

54.2 56.6

Cabot9

1993 1992

3.5 4.0

3.2 3.4

50.9 49.3

41.5 46.1

42.7 46.7

299 288

40.2 36.5

4.0 5.0

10.1 11.1

2.8 2.4

108.4 100.2

51.7 55.2

Calgon Carbon

1993 1992

7.1 9.6

4.6 7.2

2.6 2.8

38.4 40.2

31.9 33.0

204 202

34.3 22.8

5.6 8.1

7.7 11.8

2.4 2.1

79.9 89.2

69.4 74.2

Crompton & Knowles

1993 1992

9.3 8.4

13.2 11.7

5.5 10.2

18.5 20.1

22.8 23.3

240 237

37.5 34.2

2.6 2.5

14.3 13.0

2.0 2.0

153.7 147.6

57.7 60.6

Dow Chemical

1993 1992

3.6 2.9

2.2 1.9

42.4 43.4

48.6 49.7

41.6 42.6

326 309

111.6 128.9

7.8 8.5

16.5 18.3

7.0 6.8

70.8 74.8

39.7 41.0

Eastman Chemical

1993 1992

6.8 7.9

3.6 4.2

62.9 0

21.7 23.5

10.7 8.2

216 206

6.7 23.3

9.4 12.3

12.0 15.3

4.5 4.3

89.9 90.7

47.9 49.3

Ethyl

1993 1992

5.8 9.1

4.3 11.1

47.7 24.8

32.5 17.2

31.3 5.0

352 472

63.2 26.4

10.6 5.3

20.5 19.0

3.9 2.5

96.5 32.3

52.3 50.6

First Mississippi*1

1993 1992

0.6 0.8

0.5 0.7

41.4 43.4

13.7 15.5

na na

na na

223.4 140.1

2.6 6.4

5.5 12.1

1.2 0.8

112.1 112.1

55.8 56.6

Freeport-McMoRan

1993 1992

def 11.3

def 4.4

99.9 80.5

na na

na na

na na

def 95.7

35.3 38.8

20.5 28.2

na na

43.4 46.7

65.9 68.9

H. B. Fuller1

1993 1992

2.8 3.8

3.8 5.1

19.5 17.3

46.3 47.4

77.9 71.2

163 161

27.8 18.0

4.3 3.7

18.0 15.4

2.2 2.2

172.8 166.4

55.4 56.5

Georgia Gulf

1993 1992

5.5 5.9

7.5 8.5

143.4 164.9

na na

na na

684 691

0 0

3.8 1.8

13.2 6.7

na na

189.7 185.8

57.3 59.9

BF Goodrich

1993 1992

0.8 0.4

0.7 0.3

35.2 32.7

11.0 11.2

7.0 7.8

136 189

422.2 638.6

8.0 7.9

17.5 16.5

3.7 3.3

77.0 103.0

61.4 55.5

W. R. Grace

1993 1992

3.0 4.0

2.8 4.1

43.6 46.7

35.2' 37.0j

20.1 j 11.3j

130 125

95.5 57.4

7.0 7.2

21.3 23.3

3.1 2.7

72.2 98.6

52.3 51.9

Great Lakes Chemical

1993 1992

14.9 15.6

16.2 15.4

4.6 4.2

51.7 49.0

41.7 45.0

na na

9.2 9.5

4.3 4.6

16.9 16.1

3.0 3.1

96.2 86.4

56.3 58.2

Hercules

1993 1992

7.5 5.9

4.6 3.8

18.8 19.8

28.1 29.4

19.9 19.2

197 186

45.6 59.9

5.4 5.2

11.4 11.1

2.7 2.5

87.7 88.8

40.0 42.1

IMC Fertilizer*1

1993 1992

def 8.6

def 3.5

67.5 50.6

15.9 14.2

14.3 16.5

na na

def 26.2

11.8 16.8

8.0 14.0

na na

43.6 57.6

54.8 54.6

International Flavors

1993 1992

17.0 15.7

13.6 11.6

0 0

67.5 68.9

50.1 43.3

272 266

56.6 59.1

6.9 4.4

25.4 17.3

6.3 6.3

97.0 88.9

53.0 51.7

40

JULY 4,1994 C&EN

50.7% 33.7

14.7% 13.3

18.1% 15.6

2.8% 2.6

69.9% 45.5% 71.6 47.5

î*WF«:

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CIRCLE 12 ON READER SERVICE CARD

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eiF atochem CIRCLE 2 4 ON READER SERVICE CARD

Profit margin8

Return on investment"

Debt as % of debt plus equity

% total sales abroad0

% total assets abroadd

Sales per employee6

Dividends as % of net income

CAPITAL , SPENDING1 As% As% of net of plant sales

R&D as % of sales

Sales as % of assets

Net plant as % of gross plant

82.2% 50.3% 46.6 89.4

Lawter International

1993 1992

14.5% 16.1

10.9% 13.0

3.7% 3.7

45.6% 45.1

26.7% $321 366 27.5

71.7% 65.0

7.5% 4.5

29.3% 20.6

2.6% 2.4

Loctite

1993 1992

11.1 11.9

11.2 12.9

0.8 3.6

54.1 60.4

56.7 64.2

155 165

41.0 36.2

7.6 6.6

28.1 28.9

4.4 4.3

101.6 109.1

58.6 57.1

Lubrizol

1993 1992

7.5 8.1

6.8 8.0

7.0 2.8

55.8 53.0

42.7 39.6

329 335

50.8 44.8

8.4 6.2

29.2 25.5

11.3 5.9

128.3 137.0

40.2 39.2

Monsanto

1993 1992

5.8 4.8

4.2 3.2

34.5 32.1

34.7 36.1

31.1 32.7

263 230

59.8 72.0

5.5 7.5

15.6 19.5

7.9 8.4

91.5 85.4

38.0 39.5

Morton International11

1993 1992

7.0 7.1

6.6 6.5

15.4 15.4

24.2 27.1

20.6 23.6

194 191

29.0 32.2

8.7 9.8

22.0 24.0

3.0 3.0

103.2 96.8

58.2 58.9

Nalco Chemical

1993 1992

11.0 10.5

10.1 9.3

31.4 41.8

35.9 40.7

32.9 31.9

204 205

47.1 47.5

8.5 9.5

21.1 24.6

3.6 3.5

114.6 101.8

49.4 51.1

Olin

1993 1992

1.7 2.3

1.2 1.7

60.9 39.2

7.5 6.5

7.1 9.0

195 176

147.5 105.5

5.4 7.3

14.9 18.5

1.7 1.6

125.5 117.0

35.3 37.5

Petrolitek

1993 1992

5.8 5.2

4.9 4.3

19.7 0

34.2 32.8

24.5 29.3

176 159

61.5 77.2

5.4 5.8

15.2 17.1

3.9 3.8

116.8 131.9

43.0 40.4

PPG Industries

1993 1992

7.1 5.7

5.1 4.1

23.1 23.7

31.8 35.8

30.5 32.4

183 180

54.0 60.5

4.5 4.9

9.2 9.5

3.5 3.5

101.8 102.7

46.1 48.3

Praxair

1993 1992

5.9 3.2

2.6 1.6

60.3 55.2

51.3 57.3

56.0 56.3

145 140

22.4 19.0

9.8 12.8

10.6 14.4

2.4 2.4

74.9 77.9

48.0 50.4

Quaker Chemical

1993 1992

3.1 5.7

3.2 6.6

15.0 15.5

43.6 44.1

36.5 36.8

194 219

90.6 42.1

4.6 3.4

15.8 13.8

5.7 5.2

114.0 127.5

52.8 53.4

Rohm and Haas

1993 1992

5.5 6.9

3.7 4.5

32.4 32.9

41.8 43.4

35.4 32.6

252 221

53.6 41.7

11.7 9.2

20.4 16.0

6.3 6.5

92.8 88.9

50.6 51.0

Sigma-Aldrich

1993 1992

14.5 14.6

12.2 12.8

2.8 3.5

28.3 30.1

29.9 28.5

145 152

13.9 13.6

10.2 4.7

29.2 16.4

na na

98.1 106.3

60.5 57.2

Stepan

1993 1992

2.5 2.4

2.2 2.2

46.2 47.6

16.0 16.1

14.7 13.9

337 331

47.4 40.0

5.8 7.9

15.1 20.5

4.0 2.6

146.0 146.7

44.7 47.4

Sterling Chemicals9

1993 1992

def 1.1

def 0.7

78.5 77.0

23.0 3.1

39.1 39.4

421 351

def 297.3

2.3 3.7

3.9 4.6

na na

96.1 71.7

70.3 77.2

Union Carbide

1993 1992

3.6 2.4

2.3 1.6

39.5 47.3

25.8 27.6

18.5 21.2

356 323

75.2 109.2

8.5 7.4

12.3 11.3

3.0 3.2

99.0 98.6

57.0 55.7

Witco

1993 1992

3.7 3.9

3.8 3.3

41.0 22.0

29.1 22.2

35.9 37.7

261 199

55.9 60.2

4.8 4.2

14.9 10.1

2.3 1.7

116.5 95.4

52.8 56.0

AVERAGE 1993

5.3%

3.6%

38.6%

35.9%

31.7% $226

64.7%

7.9%

15.3%

5.2%

84.7% 48.1%

AVERAGE 1992

5.6%

4.0%

33.5%

36.7%

29.6% $221

58.5%

8.4%

16.7%

4.9%

83.4% 49.1%

Note: Net income is from continuing operations, excluding significant nonrecurring and extraordinary items, a Net income as a percentage of sales, b Net income as a percentage of current assets plus gross plant, c Consolidated sales only, d Foreign identifiable assets as a percentage of total assets, e Thousands of dollars, f Actual spending on new facilities and purchase of land and new equipment in consolidated companies, g Fiscal year ended Sept. 30. h Fiscal year ended June 30. i Fiscal year ended Nov. 30. j Excludes Canada, k Fiscal year ended Oct. 31. na = not available, def = deficit.

JULY 4,1994 C&EN

41

FINANCES OF THE U.S. CHEMICAL INDUSTRY

Chemical capital spending continued to fall in 1993 apital spending declined for the third year in a row at major chemical companies in 1993. Bigbudget projects continued to feel the lingering effects of the 1991-92 recession as capital spending at 24 major chemical makers surveyed by C&EN dropped an average of 10% last year to a collective $6.9 billion. Capital spending as a percentage of sales also declined in 1993 to 8.0%. The last time spending as a percentage of sales was so low was in 1987. The drop in capital spending follows an average 9% decline in 1992 and a 13% cutback in 1991. Still, none of these drops are as large as the 25% downturn a decade ago in 1983 when industry overcapacity and recession forced capital outlays to hit their 10-year low of $4.7 billion. The chemical industry had more than adequate capacity in place as the U.S. came out of recession in late 1992 and early 1993. Because of hefty investments between 1988 and 1990, coupled with falling earnings for the past four years for the industry as a whole, most major chemical

C

try, which also includes manufacturers of pharmaceuticals, soaps, toiletries, and paints. For 1994, the government survey projects an 8% increase in capital outlays for the broadly defined chemical industry. All manufacturing companies increased capital spending 3% in 1993 to $179 billion, the Commerce Department finds. That follows two years of declining overall investment in new plants and equipment. Generally, the turnaround for manufacturing companies coupled with solid evidence of growth in many key markets for chemicals—such as housing and motor vehicles—suggests that the chemical industry, too, may soon increase its capital outlays. A separate Commerce Department survey of capital spending abroad shows that U.S. chemical companies have slowed their capital outlays outside the U.S. as well. Spending declined 2% to $6.2 billion in 1993, following bigger drops of 3% in 1992 and 6% in 1991. The Commerce Department predicts a recovery in 1994, with chemical firms planning to spend $6.6 billion abroad, more than 6% above the 1993 level. The survey also indicates that all U.S. manufacturing firms dropped their overseas capital investment 3% in 1993 to $27.7 billion—a figure that is likely to increase a substantial 9% in 1994.

companies opted to cut back further on building new plants in 1993. Between 1988 and 1990, the major chemical companies invested heavily in their operations. As both profits and demand for products rose during those years, capital spending was increased at double-digit rates. Capital expenditures for the group reached a 10-year peak of $9.7 billion in 1990. The Department of Commerce's survey of the chemical industry, based on a much larger number of companies than those surveyed by C&EN, shows capital spending also declined in 1993. That survey registered a 6% spending decline last year to $21.8 billion. The reason for the discrepancy in the two surveys is that the 24 major chemical companies C&EN monitors are all identified by the Commerce Department as producers of industrial chemicals and synthetic materials. Such producers make up less than half of the companies in the Department of Commerce's survey of the chemical indus-

INDUSTRY CAPITAL SPENDING: Resumed growth for all manufacturing last year $ Billions

All manufacturing Chemicals & allied products Iron & steel Nonferrous metals Paper Petroleum Rubber Stone, clay, glass

1984

1986

1987

1988

1989

1990

1992

1993

1994a

$138.82 15.32

$153.48 16.44

$142.69 16.81

$145.90 16.42

$165.70 19.25

$183.80 18.47

$192.61 20.63

$182.81 21.52

$174.02 23.15

$179.18 21.78

$191.60 23.50

3.54 2.13

4.12 1.88

3.32 1.93

4.69 2.16

6.16 2.77

7.87 2.64

7.78 2.88

6.53 2.81

5.64 2.67

5.60 2.57

7.71 2.24

7.21 25.53 3.11 3.09

8.59 26.71 3.86 3.40

8.77 17.92 3.89 3.14

9.01 17.12 3.52 3.37

11.23 19.93 3.86 3.59

15.58 30.08 3.79 4.00

16.53 34.79 3.48 3.29

11.50 35.59 3.43 2.89

10.53 29.59 3.85 3.36

10.30 28.54 3.30 4.30

10.79 27.95 3.61 4.81

a Estimated. Source: Department of Commerce

U.S. chemical makers decreased capital spending abroad in 1993, but plan increases in 1994 $ Billions8

All manufacturing Chemicals & allied products Metals, primary & fabricated Petroleum

1985

$13.6 2.4 1.0 14.1

$14.9 2.7 0.9 13.7

$16.4 3.1 0.9 9.6

$17.2 3.7 0.8 9.8

a By majority-owned affiliates of U.S. companies, b Planned. Source: Department of Commerce

42

JULY 4,1994 C&EN

$22.4 4.9 1.2 13.3

1989

1990

1991

$28.6 6.4 1.8 14.5

$31.1 6.9 1.9 15.9

$28.5 6.5 1.1 18.6

$28.6 6.3 1.1 18.4

$27.7 6.2 1.2 19.2

$30.1 6.6 1.2 20.8

Chemical capital spending down for third year in a row $ Billions3 10

Capital spending as % of sales3 12 10

8

••.•

8 6 6 4

4

2 0

2 ι

19 83 84

ι

ι

ι

ι

ι

ι

ι

ι

85

86

87

88

89

90

91

92

0 93

1983 84 85 86 87 88 89 90 91 92

93

aW orldwide data for 24 major chemical producers. Sour ce: Compa ny data

CHEMICAL CAPITAL SPENDING: At lowest level in six years for major chemical companies $ Millions

1984

1985

1986

1987

1988

1990

1991

1992

1993

Air Products Cabot8 Crompton & Knowles Dow Chemical DuPontb

$246 80 2 630 888

$263 505 3 781 989

$392 184 3 806 1,176

$367 80 4 890 1,229

$323 83 4 995 1,357

$387 170 7 1,267 1,735

$414 192 13 1,764 2,106

$468 174 16 2,119 2,608

$506 198 11 1,908 2,045

$428 78 13 1,608 2,058

$491 65 14 1,414 1,667

Ethyl H. B. Fuller BF Goodrich W. R. Grace Great Lakes Chemical

85 15 115 353 20

103 13 153 380 29

90 15 202 348 21

134 13 144 199 18

139 30 143 243 35

151 40 181 418 47

119 41 240 485 40

152 31 243 514 49

166 30 219 447 71

157 34 200 398 69

205 42 146 310 69

Hercules Loctite Lubrizol Monsanto Nalco Chemical

168 9 25 560 41

218 10 30 614 53

234 9 40 645 60

257 11 41 520 64

205 17 42 505 57

251 15 55 590 62

293 24 65 607 86

273 29 77 750 115

214 34 82 591 137

150 40 96 586 131

149 46 128 437 118

Olin PPG Industries Petrolite Praxairc Quaker Chemical

123 450 9

165 315 11

154 452 24

128 498 25

115 499 19

147 410 20

142 671 19

187 567 18

177 335 22



















2

4

6

5

4

5

8

13

8

173 282 18 333 7

132 258 19 240 9

Rohm and Haas Stepan Union Carbide Witco

72 10 761 55

124 12 670 85

159 19 649 76

179 14 524 60

222 26 502 69

338 20 671 72

385 34 785 70

412 38 744 91

265 34 817 74

283 34 359 73

382 25 395 104

$4,719 $5,530 $5,764 $5,404 $5,634 $7,059 $8,603 $9,688 $8,391 -25% 17% 4% -6% 4% 25% 22% 15% -13%

$7,608 -9%

TOTAL ANNUAL CHANGE

$6,865 -10%

Note: Figures are for worldwide spending on construction, equipment, and land in consolidated businesses. Where possible, acquisition costs and investments in nonconsolidated businesses are excluded. Prior years are not restated to reflect company revisions, a Includes acquisitions and investments, b Excludes Conoco, c Spun off from Union Carbide in 1992. Source: Company data

JULY 4,1994 C&EN 43

R&D share of sales continues to rise at chemical companies $ Billions3

R&D spending as % of sales3 6Γ

[fl

πΠ

1983 84 85 86 87 88 89 90 91 92 93

1983 84 85 86 87 88 89 90 91 92 93

a R&D spending by 15 major chemical producers. Source: Company data

Chemicalfirmshold on to 1992 gains as other companies cut back $ Millions

1983

1984

1985

1986

1987

1988

1989

1990

1991

1992

1993

CHEMICAL COMPANIES Air Products8 Dow Chemical Ethylb W. R. Grace Hercules

$40 492 39 73 74

$44 507 40 81 72

$51 547 47 92 76

$61 605 47 94 71

$57 670 50 107 74

$72 772 59 119 74

$71 873 61 125 79

$72 1,136 65 148 92

$80 1,159 69 150 86

$85 1,289 73 151 70

$92 1,256 76 135 76

International Flavors Lubrizol Monsanto Morton lnternationalc,d'e Nalco Chemical

32 37 290 23 30

32 33 370 30 32

34 44 470 25 32

39 51 596 29 33

45 62 615 31 35

50 65 648 35 37

52 70 598 38 41

57 74 612 48 45

62 80 627 59 47

71 90 651 61 48

75 172 626 69 50

49 13

52 12





Olin Petrolite Praxairf Rohm and Haas Union Carbide TOTAL ANNUAL CHANGE

100 109 245 265 $1,537 $1,679 7% 9%

41 39 12 14 62 58 — — — — — — — 199 205 183 142 175 178 124 156 133 155 139 190 191 181 159 159 148 275 $3,084 $2,844 $3,056 $2,442 $2,796 $2,121 $2,316 $1,882 $1,975 7% 2% 1% 14% 7% 5% 9% 12% 5% 53 12

56 12

62 12

58 12

66 12

66 12

41 11

PHARMACEUTICAL & DIV ERSIFIED COMPANI ES AlliedSignal0 American Cyanamid AT&T Bell Labs Bristol-Myers Squibb Du Pont

$280 208 2,000 301 966

$295 232 1,900 344 1,097

$343 251 1,900 412 1,144

$459 278 2,100 474 1,156

$400 314 2,250 563 1,223

$415 365 2,660 688 1,319

$381 406 2,800 789 1,387

$426 460 2,900 881 1,428

$381 492 3,100 993 1,298

$320 566 3,200 1,083 1,277

$313 596 3,069 1,128 1,132

Eli Lilly FMC IBM Merck & Co. 3M

294 102 2,500 356 396

341 121 3,148 393 454

370 149 3,457 426 520

427 146 3,975 480 586

466 132 3,998 566 650

512 144 4,419 669 721

605 150 5,201 751 784

703 158 4,419 854 865

767 135 5,001 998 914

925 145 5,003 1,112 1,007

955 149 4,431 1,173 1,030

Pfizer PPG Industries Procter & Gambled Schering-Plough Upjohn TOTAL ANNUAL CHANGE

974 757 863 531 640 473 401 230 255 287 336 201 203 220 218 232 233 227 127 204 150 176 861 956 786 693 628 615 327 549 369 479 400 522 578 327 426 380 164 298 145 212 251 175 549 642 407 427 491 247 380 218 284 314 356 $9,510 $10,294 $11,626 $12,346 $13,910 $15,380 $15,452 $16,759 $17,636 $17,327 $8,450 -2°/< 5% 9% 11% 1% 13% 12% 13% 6% 13% 8%

Note: Prior years are not restated to reflect company revisions, a For fiscal year ending Sept. 30. b Beginning in 1989, excludes Tredegar Industries, spun off in 1989. c Includes all company-financed R&D but excludes contract R&D. d Fiscal year ends June 30. e Data for Morton Thiokol prior to 1985. f Spun off from Union Carbide in 1992. Source: Company data

44

JULY 4,1994 C&EN

m

FINANCES OF THE U.S. CHEMICAL INDUSTRY Except for drugs, chemical categories grew less than all manufacturing

$ Billions

1983

1984

1985

1986

1987

1990

1988

1991

1992

% annual change 1992-93 1983-93

1993

All manufacturing $2,070.7 $2,288.2 $2,334.5 $2,335.9 $2,475.9 $2,682.5 $2,792.7 $2,873.6 $2,821.9 $2,934.1 $3,100.7 industries Chemicals & allied 189.6 206.0 204.8 205.7 229.5 259.7 278.1 288.2 289.0 301.5 312.5 products Industrial chemicals 157.3 152.3 156.4 160.9a 119.4 109.1 114.7 112.2 145.5 126.2 156.2 Drugs, soaps & 95.2 101.9 110.4 118.0a 57.7 54.6 61.3 66.4 81.8 74.0 88.0 toiletries Petroleum & coal 172.7 160.4 154.6 147.0 187.8 130.4 184.5 176.6 122.6 131.4 143.7 products Rubber & plastic 101.4 103.6 103.3 104.5 62.9 75.6 72.9 86.6 94.2 98.4 78.4 products Paper & allied 122.6 131.4 131.4 124.4 131.3 129.2 94.7 84.8 95.5 109.0 99.9 products

6%

4%

4

5

3

4 8

7 -2

-5 5

1 4

-2

Preliminary. Source: Department of Commerce

CES Little change for either chemicals or all commodities Producer price indexes, 1982 = 100

Annual average 1989 1988

% annual change 1990

1991

1992

1993

112.2

116.3

116.5

117.2

106.3

111.6

115.8

116.5

105.4

108.0

113.6

119.2

102.5 91.5 107.0 104.4 129.9 80.5 94.2

106.4 95.5 108.1 107.3 139.1 92.7 96.4

116.3 106.8 112.2 115.7 148.4 110.9 104.5

123.0 114.8 119.5 129.1 160.0 95.5 108.7

107.5 105.2

104.4 105.8

110.3 107.0

132.4 111.9

101.9

101.9

103.0

109.3

1983

1984

1985

1986

1987

All commodities

101.3

103.7

103.1

100.2

102.8

106.9

Industrial commodities

101.1

103.3

103.7

99.9

102.6

Finished goods

101.6

103.7

104.7

103.2

Chemicals & allied products Industrial chemicals Prepared paint Paint materials Drugs & pharmaceuticals Fats & oils, inedible Agricultural chemicals & chemical products Plastic resins & materials Other chemicals & allied products

100.2 97.3 100.7 100.3 107.7 106.2 96.0

102.9 96.8 103.7 108.2 114.2 139.1 97.4

103.7 96.0 105.3 109.5 122.2 110.6 96.2

102.4 101.3

108.9 102.7

Rubber & plastic products

100.8

102.2

1992-93

1983-93

118.9

1%

2%

117.4

119.0

1

6

121.7

123.2

124.7

1

2

123.6 113.2 124.8 136.3 170.8 88.1 107.4

125.6 111.8 129.9 135.8 182.6 86.8 111.7

125.9 109.3 131.6 131.1 192.2 93.0 110.3

128.2 110.4 133.2 131.5 200.9 95.6 109.9

2 1 1 0 5 3 0

3 1 3 3 6 -1 1

133.4 117.3

124.1 118.9

120.0 121.5

116.4 123.3

117.1 125.5

-1 2

1 1

112.6

113.6

115.1

115.1

116.0

Source: Department of Labor

Chemical stock prices set new highs in 1993 and early 1994 Stock price index, 1954 = 100a 800 Γ~ 700

r

600

High Close Low

i-m

500

300 200

>r π 1983

^

l4

rfU

400

rt Ι-Γ vr

f,

^

TT Ll· 1984

1985

1986

1987

1988

1989

1990

1991

1992

1993

1994

a C&EN stock price index of Air Products, Dow Chemical, W. R. Grace, Hercules, Monsanto, Rohm and Haas, and Union Carbide, weighted according to number of shares outstanding for each company.

JULY 4,1994 C&EN 45

H

FINANCES OF THE US. CHEMICAL INDUSTRY

Major biotechnologyfirmspost good year

B

iotechnology companies that have major biopharmaceutical products on the market had sub­ stantially increased sales in 1993. Com­ bined sales of six industry leaders rose 26% to $2.4 billion. However, 54% of the total sales for the six companies com­ bined were from two major products sold by Amgen. Four of the six companies reported profits in 1993. A fifth company, Genzyme, posted a relatively small $6 mil­ lion loss, the net result of R&D acquisi­ tion and restructuring costs. Similarly, Immunex's $430 million net loss resulted largely from a $346 million charge for acquiring R&D at the time of its merger with Lederle Laboratories' oncology business. Biotechnology is such a young indus­

try, however, that many key companies have yet to bring a major product to mar­ ket or show a profit. C&EN's biotechnolo­ gy stock index, which includes six firms that do not have major products and five that do, offers some measure of how in­ vestors feel about the industry as a whole. This index fluctuated from a high of 264 to a low of 163 in 1992. It remained vola­ tile in 1993 as well. Uncertainties brought about by the specter of health care reform and setbacks for a few major products be­ ing developed scared investors away from biotechnology stocks. After drop­ ping 89 points from the start of 1993 to reach a two-year low early in the second quarter, the index recovered most of its losses, ending 1993 just 14 points below where it ended 1992, only to fall again in early 1994.

Biotechnology stock prices remain volatile Stock price index, close 1990 = 100a 280 240

200 160

r „+

*t

h

120 80

1991 b

1992

1993

High

Close

Low

1994

a C&EN biopharmaceutical stock price index of Am­ gen, Applied Bioscience, Biogen, Centocor, Chiron, Cytogen, Genentech, Genetics Institute, Immunex, Repligen, and Xoma. b Based on Friday close each week, all other years based on daily close.

JITS Sales ιup strongly for major biotechnology companies NET INCOME

%of

Net plant

Net

sales

Net

income

R&D

spending

R&D as % of sales

Total assets

and

equipment

Stockholders' equity

%of

sales

stockholders' equity

$per share

Stock price range, $ per share

Priceearnings ratio

(Money figures in millions of dollars unless otherwise indicated)

Amgen $255.3 1993 ί£1,306.3 $374.6a 182.3 357.6b 1,050.7 1992 C 120.9 97.9 645.3 1991 e d 72.4 3.9 281.4 1990 Biogen $79.3 $32.4 $136.4f 1993 60.4 38.3 121.7f 1992 7.2 56.5f 1991 44.3 f 36.2 7.7 44.9 1990 Chiron $18.4 1993 $147.9 $140.0 142.9 111.6 (95.9)hi 1992g h j (425.2) 79.4 1991 28.2 k 50.2 14.7 4.0 1990 Genentech $457.4 $299.4 1993 $58.9 278.6 391.0 20.8 1992 1991 383.3 221.3 44.3 hJ 1990 367.2 (98.0) 173.1 Genzyme $(6.1)h,m $48.3 1993 $233.9 39.7 39.5n 1992 180.0 27.2 1991 81.1 11.2° h p (27.2) 1990 34.6 18.6 Immunex 1993 $119.1 q $(430.3)h>q-r $72.5q 37.1 (77.6)h,t 1992 51.9 29.4 0.8 1991 34.2 h 23.2 (9.9) 1990 4.9

19.5% 17.4 18.7 25.7

$1,765.5 1,374.3 865.5 459.5

$586.9 426.0 245.7 150.0

$1,172.0 933.7 531.1 309.1

28.7% 34.0 15.2 1.4

32.0% 38.3 18.4 1.3

$2.67 2.43 0.67 0.30

$703/4-311/2 773/4-50 753/4-187/8 213/16-7V2

19.1 26.3 70.6 478.1

58.1% 49.6 78.4 80.6

$357.0 311.2 253.1 158.5

$38.5 32.3 28.7 23.6

$325.2 284.9 239.0 145.7

23.8% 31.5 12.7 17.1

10.0% 13.4 3.0 5.3

$0.93 1.12 0.15 0.07

$47 3 / 4 -24 1 /4 493/4-181/4 49-24V4 293/8-14%

38.7 30.4 244.2 312.5

94.7% 128.0 281.6 341.5

$968.6 712.4 895.3 265.4

$204.0 89.6 78.0 24.5

$522.3 492.9 524.4 120.3

12.4%

3.5%

— —

$85 1 /2-41 1 /8 733/4-343/4 77V2-37V4 443/4-23V2

115.1

— —

$0.55 (3.18) hi (22.12 h-j 0.24fc

65.5% 71.3 57.7 47.1

$1,468.8 1,305.1 1,231.0 1,157.7

$456.7 432.5 342.5 300.2

$1,116.8 1,007.3 949.7 893.2

$0.50 0.18 0.39 (1.05)h

$50 1 /2-31 1 /4 39 1 /2-25 7 /8 361/4-203/4 30 7 /8-20 1 /8

81.8 181.6 73.1

20.6% 22.1 29.1 53.8

$542.1 480.7 390.5 118.1

$196.2 87.9 32.1 29.5

$334.1 322.9 259.9 96.2

$(0.25)h 1.83n 0.50° (1.70)h

$46 1 /4-25 1 /4 66V2-32V2 58 3 /4-23 3 /8 285/8-121/2

60.0%q 71.5 86.0 473.5

$204.1s 235.8 254.0 121.1

$100.5s 97.0 73.1 36.3

$137.9s 134.0 212.2 106.5

27.2

3.3

12.9% 5.3 11.6

5.3% 2.1 4.7









21.9% 13.8

12.2% 4.3





— —

— —

2.3%

0.4%





hr

$(9.58) (5.21 )h 0.05 (1.10)h

s

$343/4-133/4s

68-22V2 61V2-33V4 40V4-15V2

— —

142.2

— —

27.0 82.1

— — —

947.5



a Includes $13.9 million legal award, b Includes $77 million pretax legal award, c Includes $129 million pretax legal assessment, d Figures reflect change in fiscal-year end from March 31 to Dec. 31 that occurred in 1991. e Includes $54.7 million royalty buyout, f Includes royalty income from licensees' sales of several major products, g Includes results of Cetus following Dec. 12, 1991, acquisition, and of Intraoptics following Jan. 8, 1992, acquisition, h Net loss, i Includes $40 million write-off of technologies but excludes $6.7 million loss from retirement of debt ($0.22 per share), j Includes $426 million charge for acquiring Cetus but excludes $100,000 gain for operating loss carryforward ($0.01 per share), k Excludes $2.8 million gain for operating loss carryforward ($0.16 per share). I Includes $167.7 million charge related to merger with Hoffmann-La Roche, m Includes $49 million purchase of R&D and $26.5 million goodwill and restructuring costs, η Excludes $51 million purchase of R&D, $17 million purchase of option rights, and $1.8 million charge for Vivigen acquisition ($3.24 per share), ο Excludes $8.4 million gain for operating loss carryforward ($0.37 per share), ρ Includes $20.8 million purchase of R&D and $9.1 million repurchase option, q Merged June 2, 1993, with Lederle Laboratories oncology business; combined figures for predecessor and successor company, r Includes $346.4 million for acquisition of in-process R&D, $14.8 million for merger costs, and $25.6 million for modified stock option plan, s Merged June 2, 1993, with Lederle Laboratories oncology business; figures for successor company only, t Includes $58.7 million purchase of R&D.

46 JULY 4,1994 C&EN

2

FINANCES OF THE U.S. CHEMICAL INDUSTRY

Explanation of column headings in tables of company results Vear. Data are for calendar year unless otherwise indicated. Data for earlier years are not restated to reflect subsequent acquisitions or divestitures. Net sales. Gross sales, less discounts, allowances, and returns; generally excludes excise taxes and other operating income or revenues. Net sales and other income, less operating costs, nonoperating charges, depreciation, depletion, interest expense, deferred charges, minority interest in income, and taxes. Nonrecurring or extraordinary credits and charges have been excluded in most cases, and are indicated by a footnote. Sum at year's end of current assets, investments, prepaid expenses, net plant and equipment, and other tangible assets. Excludes insofar as possible intangible assets including goodwill, value of patents, and the like. Net plant and equipment. Value at

stock splits, but no adjustment has been made for earlier years as a result of stock dividends or for dilution that might result from the conversion of preferred stock or debt to common stock or the exercise of stock options outstanding. Dividends per share. Cash dividends paid (or declared) on each share of common stock; excludes the value of stock dividends, which are indicated by a footnote. Dividend yield. Dividends per share divided by the average of the high and low prices of the common stock during the year. Stock price range. High-low market prices of common stock during the year, adjusted for stock splits but not for stock dividends. Price-earnings ratio. Average of the high and low prices of the common stock during the year divided by net income per share.

year's end of fixed assets, less accumulated depreciation, amortization, and depletion. Capital expenditures. Total spending during the year for new fixed assets, such as plant, equipment, and land, and for replacement and modernization of facilities. Stockholders' equity. Equity at year's end of preferred and common stockholders, including value of capital stock, capital and earned surplus, and surplus reserves, as well as contingency and miscellaneous reserves for which no definite purpose is stated. Intangible assets are deducted insofar as possible. Net income (breakdown). Percent of sales: net income divided by net sales. Percent of stockholders' equity: net income divided by stockholders' equity. Dollars per share: net income, less preferred dividends, divided by the number of shares of common stock outstanding. All figures are adjusted for

COMPANY RESULTS: About half of chemical firms increased sales in 1993 Year

Net sales

Net income

Total assets

Net plant and equipment

Capital Stockholders' equity expenditures

% of sales

NET INCOME %of stockholders' equity

$per share

Dividend, $per share

Dividend yield, % of price

Stock price range, $ per share

Priceearnings ratio

(Money figures in millions of dollars unless otherwise indicated)

CHEMICALS Air Products 1993a $3,328 1992a 3,217 1991a 2,931 a 1990 2,895

$200.9b 271.0 248.9 229.9

$4,697 $2,705.6 4,420 2,745.7 4,163 2,622.6 3,845 2,485.1

$490.6 427.5 506.4 467.5

$2,037 2,026 1,777 1,634

6.0% 8.4 8.5 7.9

9.9% 13.4 14.0 14.1

$1.76b 2.40 2.22 2.07

$0.89 0.805 0.75 0.69

2.1% 1.7 2.6 2.7

$491/8-37V2 491/2-313/4 37-21 1 / 2 301/2-21V2

24.6 19.4 13.2 12.5

Arco Chemical 1993 $3,192 1992 3,098 1991 2,837 1990 2,830

$214.0 197.0C 188.0 308.0d

$3,502 3,599 3,676 3,739

$2,173.0 2,230.0 2,166.0 1,768.0

$181.0 295.0 435.0 539.0

$1,576 1,630 1,696 1,758

6.7% 6.4 6.6 10.9

13.6% 12.1 11.1 17.5

$2.23 2.05c 1.96 3.21 d

$2.50 2.50 2.50 2.50

5.8% 6.0 6.4 6.8

$471/4-391/4 47V4-36V2 44V4-33V8 44V4-293/4

19.4 20.4 19.7 11.5

Betz Laboratories $63.4e 1993 $685 82.0 1992 707 1991 666 75.5 1990 597 65.5

$517 506 471 421

$300.7 288.4 254.6 233.5

$63.2 74.3 58.4 57.5

$295 293 254 214

9.3% 11.6 11.3 11.0

21.5% 28.0 29.8 30.6

$2.05e 2.71 2.47 2.12

$1.39 1.33 1.20 1.01

2.7% 2.3 2.4 2.7

$6278-^0 661/4-481/4 62-38% 43 1 /4-30 3 /4

24.3 21.1 20.4 17.5

Borden Chemicals & Plastics 1993 $433 $444 ($1.4)f 1992 402 27.1 467 1991 410 51.6 507 1990 421 45.3 544

$306.0 335.1 369.2 395.8

$15.0 10.5 18.0 22.1

$230 261 293 315

6.7% 15.7 10.8

10.4% 17.6 14.4



($0.04)f 0.739 1.39s 1.229

$0.789 1.599 1.989 1.959

6.1% 9.0 17.1 19.0

$17 1 /8-8 1 /4 9 2278-123/e 9 14 3 /4-8 3 /e 9 12 3 / 4 -7 3 /4 9

24.1 8.3 8.4

Cabot 1993a 1992a 1991a 1990a

$646.5 703.2 670.4 878.7

$65.0 78.1 198.0 174.4

$363 406 329 466

2.3% 4.0 2.7 4.2

10.3% 15.3 12.1 15.2

$1.80h 3.18 1.69' 2.73

$1.04 1.04 1.04 1.04

2.2% 2.6 3.5 3.3

$561/4-371/4 52V4-28V8 3578-23 37Y2-25

26.0 12.6 17.4 11.4

$1,614 1,557 1,482 1,673

$37.4h 62.2 39.8' 71.0

$1,411 1,467 1,365 1,627





a Fiscal year ends Sept. 30. b Includes charge for cost of work force reduction of $76.0 million ($0.67 per share), c Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $2.0 million ($0.02 per share), d Excludes net gain from cumulative effect of change in accounting for income taxes of $43.0 million ($0.45 per share), e Excludes net gain from cumulative effects of changes in accounting for health benefits for retirees, pensions, and income taxes of $2.1 million ($0.07 per share), f Net loss, g Per partnership preference unit, h Excludes net loss from cumulative effect of changes in accounting for health benefits of retirees and for income taxes of $26.1 million ($1.39 per share), i From continuing operations; excludes net income from discontinued operations of $9.5 million ($0.45 per share) and net gain on disposition of discontinued operations of $77.9 million ($3.66 per share).

JULY 4,1994 C&EN 4 7

INTRODUCING O N E O F

The Worlds Bejt Performing CHEMICAL COMPANIES. Haven't We Met Somewhere Before? Albemarle...Albemarle...If the name doesn't ring a bell, maybe the name Ethyl will.

They're the people who make petroleum additives for high-performance fuels and engine

oils. Alpha olefins for plastic bags and bottles. Flame retardants for computers and

televisions. Even ibuprofen for those days that are, well, a real headache. Now the

company that produces all these chemical products, and more, will do so as two

companies: Ethyl and Albemarle. Ethyl will continue to produce petroleum additives.

Albemarle will focus on specialty chemicals. With the same dedicated people. The same

uncompromising safety and environmental standards. With better service than ever before

for customers all over the world. Albemarle. For a new company, we really get around.

4 ALBEMARLE" «JSSWc

O R P O R A T I O N

CIRCLE 1 ON READER SERVICE CARD

Net sales

Year

Net income

Total assets

Net plant and equipment

Capital Stockholders' expenditures equity

% of sales

NET INCOME %of $per stockholders' share equity

Divi­ dends, $per share

Divi­ dend yield, % of price

Stock price range, $ per share

Priceearn­ ings ratio

(Money figures in millions of dollars unless otherwise indicated)

Crompton & Knowles $52.0 $558 1993a 43.3a 518 1992 450 1991 35.9 30.0 390 1990

$330 316 276 252

$99.9 98.8 80.2 76.7

$14.3 12.8 11.4 16.4

$207 177 108 87

9.3% 8.4 8.0 7.7

25.1% 24.5 33.2 34.5

$1.00 0.87a 0.73 0.61

$0.38 0.31 0.25 0.195

1.7% 1.6 1.6 2.1

$27V4-175/8 23%-16 201/4-83/s 111/2-65/8

22.4 22.9 21.8 15.0

Dexter 1993 1992 1991 1990

$748 726 721 697

$310.0 298.9 299.3 274.1

$47.0 52.0 61.5 43.9

$244 260 250 278

3.8% 4.0

14.0% 14.7 15.1

$0.88 0.88 0.88 0.88

3.6% 3.6 3.9 4.1

$287/8-203/s 281/8-207/8 261/8-181/2 24V2-18

17.6 15.5

4.6

$1.40° 1.58 (0.29)c 1.74

Dow Chemical 1993 $18,060 $644.0 276.0d 18,971 1992 942.0 18,807 1991 19,773 1,384.0 1990

$21,071 20,978 20,418 19,764

$8,580.0 8,801.0 8,775.0 8,249.0

$1,397.0 1,595.0 1,908.0 2,119.0

$3,600 3,682 5,132 4,539

3.6% 1.5 5.0 7.0

17.9% 7.5 18.4 30.5

$2.33 0.99d 3.46 5.10

$2.60 2.60 2.60 2.60

4.7% 4.6 5.1 4.6

$62-49 627/8-511/4 58-44V8 753/4-37

23.8 57.6 14.8 11.1

DuPont 1993 $37,098 $555.0 975.0e 37,799 1992 38,695 1,403.0 1991 40,047 2,310.0 1990

$36,775 $21,423.0 38,409 21,882.0 35,596 20,610.0 37,332 21,102.0

$3,621.0 4,448.0 5,065.0 5,383.0

$10,952 11,304 16,218 15,622

1.5% 2.6 3.6 5.8

5.1% 8.6 8.7 14.8

$0.81 1.43e 2.08 3.40

$1.76 1.74 1.68 1.62

3.6% 3.5 4.1 4.3

$537/8-441/2 547/8-431/2 50-323/4 423/8-313/s

60.7 34.4 19.9 10.8

$887 951 938 908

$34.1 b 38.2 (7.1 )c 42.1







12.2

Ethyl 1993f 1992 1991 1990

$1,938 2,975 2,575 2,514

$90.0g 269.4h 206.7 232.2

$2,009 9,070 7,785 6,589

$998.3 829.8 766.7 677.0

$205.0 157.4 166.1 151.8

$640 1,267 1,100 947

4.6% 9.1 8.0 9.2

14.1% 21.3 18.8 24.5

$0.76g 2.27h 1.75 1.95

$0.60 0.60 0.60 0.60

2.5% 2.2 2.2 2.2

$307/8-163/4 301/2-233/4 33-22V4 33-20V2

31.3 11.9 15.8 13.7

Ferro 1993 1992 1991 1990

$1,066 1,098 1,057 1,125

$57.5j 58.8 36.5j 19.4

$714 674 668 672

$257.8 227.6 234.7 255.9

$43.7 44.8 39.0 59.7

$305 323 301 292

5.4% 5.4 3.5 1.7

18.9% 18.2 12.1 6.6

$1.83' 1.90 1.16j 0.55

$0.51 0.45 0.43 0.43

1.7% 1.6 2.4 2.7

$343/4-261/8 311/2-231/2 255/8-101/8 191/2-111/2

16.6 14.5 15.4 28.1

$2.7m 4.2 5.3 4.4

$384 468 476 512

$206.1 277.3 294.6 310.0

$39.1 33.6 47.2 64.6

$161 188 188 190

0.6% 0.8 1.0 0.9

1.7% 2.2 2.8 2.3

$0.13m 0.21 0.27 0.22

$0.30 0.30 0.30 0.30

3.2% 2.6 3.0 1.9

$113/4-7V4 147/8-8 125/8-73/4 191/4-115/8

73.1 54.5 37.3 70.2

$41.0n 192.6° 173.1° 155.3

$2,721 2,763 2,753 2,889

$1,390.2 1,502.1 1,484.2 1,507.1

$244.5 314.5 216.8 324.3

$125 156 247 79

1.1% 4.8 4.4 4.2

32.8% 123.5 70.1 196.6

$1.1Γ 5.04° 4.68° 4.30

$53-41V2 53-425/s 515/8-291/2 383/4-253/e

42.7 9.5 8.7 7.5

9.5% 15.0 14.3 12.1

$1.55r 2.55 2.00 1.53

1.5% 1.1 1.4 2.4

$423/4-311/4 531/4-32% 383/8-187/8 191/8-133/4

23.9 16.8 14.3 10.7

— — — —

$233A-161/2 285/8-153/4 243A-87/8 11-4%

19.9 12.7 9.6 2.6

4.7% 4.5 5.3 5.5

$537/8-391/2 166.7 581/8-387/8 — 475/8-36 — 9.2 473/8-291/2

First Mississippi $430 1993k·' 525 1992k k 537 1991 k 498 1990 FMC 1993 1992 1991 1990

$3,754 3,974 3,899 3,722

H. B. Fuller $975 1993q 934 1992q 1991 q 853 792 1990q

$21Τ 35.6 27.7 21.1

$544 543 484 468

$232.5 223.2 207.4 202.3

$41.8 34.4 30.0 31.5

$229 237 194 175

2.2% 3.8 3.2 2.7

Georgia Gulf 1993 $769 1992 779 838 1991 932 1990

$42.2S 46.3 61.5 95.3

$406 419 416 457

$222.8 211.7 220.6 214.7

$29.6 14.3 28.3 58.1

$(111)11 (161) (358)t (424)1

5.5% 5.9 7.3 10.2

$15.3V

$1,781 2,206 2,038 2,198

$836.0 1,215.8 1,171.0 1,109.3

$146.2 200.2 211.2 243.0

$316 583 989 1,200

BF Goodrich 1993u $1,818 1992 2,526 2,472 1991 1990 2,433

(9 > 4 )c,w

(80.6)c 115.8X

0 0 0 0 $0.54 0.46 0.41 0.40

— — — —

$1.01 s 1.18 1.75 3.07

0.8%

4.8%

— —

— —

$2.20 $0.28u (0.69)cw 2.20 c 2.20 (3.50) 2.12 4.20x

4.8

9.6

0 0 0 0

— — —

a Excludes net loss from early extinguishment of debt of $3.0 million ($0.06 per share) and net loss from cumulative effect of changes in accounting for health benefits for retirees of $5.8 million ($0.12 per share), b Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and income taxes of $9.9 million ($0.41 per share), c Net loss, d Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $765.0 million ($2.82 per share), e Excludes net loss from early extinguishment of debt and from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $4.90 billion ($7.28 per share), f Excludes insurance business, spun off in 1993. In 1992, this business contributed $162.5 million to net income; spin-off reduced stockholders' equity by $677.5 million. Company data for 1992 and earlier years have not been restated, g Excludes extraordinary loss for early retirement of debt of $5.0 million ($0.04 per share), h Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $14.4 million ($0.12 per share), i Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and income taxes of $20.5 million ($0.70 per share). j Excludes restructuring charge, after taxes, of $31.7 million ($1.11 per share), k Fiscal year ends June 30. I Excludes coal, oil, and certain other technology businesses discontinued in the 1992-93 fiscal year. In the year ending June 30, 1992, these businesses contributed $71.5 million to net sales and decreased net income by $11.9 million. Company data for 1992 and earlier years have not been restated, m From continuing operations; excludes loss from discontinued coal, oil, and other technology businesses of $26.0 million ($1.30 per share), η Excludes net loss for early retirement of debt of $4.7 million ($0.13 per share), ο From continuing operations; excludes loss from discontinued operations of $73.2 million ($1.99 per share), also excludes extraordinary loss for early retirement of debt of $11.4 million ($0.31 per share) and for cumulative effect of changes in accounting for health benefits for retirees of $183.7 million ($4.99 per share), ρ Excludes extraordinary loss from refinancing debt of $9.2 million ($0.25 per share), q Fiscal year ends Nov. 30. r Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $11.7 million ($0.84 per share), s Excludes extraordinary loss for early retirement of debt of $13.3 million ($0.32 per share) and net gain from cumulative effect of change in accounting for income taxes of $13.0 million ($0.32 per share), t Deficit, u Excludes major portion of vinyl business, spun off as a separate company in 1993. In 1992, this business contributed $894.3 million to net sales and decreased income by $79.6 million; spin-off did not affect stockholders' equity. Company data for 1992 and earlier years have not been restated, ν From continuing operations; excludes gain from sale of vinyl business of $113.0 million ($4.40 per share), w Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees of $286.5 million ($11.21 per share), χ From continuing operations; excludes income from discontinued operations of $20.5 million ($0.25 per share).

50

JULY 4,1994 C&EN

|Î2 Year

FINANCES OF THE U.S. CHEMICAL INDUSTRY

Net sales

Net income

Total assets

Net plant and equipment

Stockholders' Capital equity expenditures

% of sales

NET INCOME %of $per stockholders' equity share

Divi­ dend, $per share

Divi­ dend yield, % of price

Stock price range, $ per share

Priceearn­ ings ratio

(Money figures in millions of dollars unless otherwise indicated)

W. R. Grace 1993 $4,408 1992 5,518 1991 6,049 6,754 1990

$134.4a 79.4b 219.2e 202.8

$5,627 $1,454.1 5,300 1,707.9 5,698 2,558.2 5,876 2,462.1

$309.6 398.4 447.0 513.7

$1,036 1,246 1,744 1,562

3.0% 1.4 3.6 3.0

13.0% 6.4 12.6 13.0

$1.46a 0.88b 2.51 e 2.36

$1.40 1.40 1.40 1.40

3.7% 3.6 4.4 5.5

$411/4-345/8 45-32 403/4-233/8 335/8-17

26.0 43.8 12.8 10.7

Great Lakes Chemical 1993 $1,792 $272.8 1,496 1992 232.7 1,308 1991 157.5 1990 1,066 140.8

$1,560 1,432 1,420 1,201

$468.0 429.8 405.6 363.7

$79.3 69.4 71.2 48.6

$916 753 672 538

15.2% 15.6 12.0 13.2

29.8% 30.9 23.4 26.2

$3.82 3.27 2.23 2.00

$0.35 0.31 0.27 0.23

0.5% 0.5 0.6 0.9

$84-64V2 713/8-501/4 58-30% 33%-20%

19.4 18.6 19.8 13.3

Hercules 1993 $2,773 1992 2,865 2,929 1991 1990 3,200

$208.4d 167.9 94.9 96.0

$3,162 $1,309.3 3,228 1,348.3 3,467 1,476.3 3,700 1,449.9

$149.5 150.1 214.5 272.6

$1,368 1,746 1,918 1,942

7.5% 5.9 3.2 3.0

15.2% 9.6 4.9 4.9

$4.86d 3.69 2.01 2.04

$2.24 2.24 2.24 2.24

2.5% $114%-631/4 63%-44% 4.1 50%-31 3 / 4 5.5 41V2-25% 6.7

18.3 14.7 20.4 16.5

IMC Fertilizer Group $897 ($120.0) 1993e 1992e 1,059 90.9h e 1991 95.8 1,131 1990e 1,106 82.6

$2,056 $1,326.5 1,778 1,266.8 1,739 1,220.9 1,144.1 1,585

$106.1 177.7 168.5 94.3

$430 615 699 820





8.6% 8.5 7.5

14.8% 13.7 10.1

($5.44)f·9 $0.81 4.12h 1.08 1.08 3.85 1.08 3.13

2.3% 2.0 2.3 3.0

$457/8-24% 68-423/e 60-33 393/4-311/8

13.4 12.1 11.3

$39%-33 383/4-311/2 35-23 25-18V4

20.5 23.0 19.7 15.8



International Flavors & Fragrances $1,225 1993 $1,189 $202.4 1992 1,126 1,268 176.6' 1,017 1991 168.7 1,217 1990 963 156.7 1,129

$323.4 286.4 289.6 266.9

$82.3 51.1 54.1 42.9

$892 977 960 898

17.0% 15.7 16.6 16.3

22.7% 18.1 17.6 17.4

$1.78 1.53' 1.47 1.37

$1.02 0.93 0.83 0.74

3.3% 2.6 2.8 3.3

International Specialty Products $29.6 $548 1993 $786 571 1992 57.2j 800 k 1991 526 667 50.6

$478.5 452.1 415.3

$62.9 70.5 34.4

$77 46 0

5.4% 10.0 9.6

38.4% 12.4

$0.30 0.57j 0.56

$0.05 0.05 0

12.9% 4.0

Loctite 1993 1992 1991 1990

$523 479 447 458

$164.5 139.0 120.6 104.0

$46.3 40.2 33.5 29.4

$278 305 279 289

11.1% 11.9 12.8 12.1

24.6% 23.7 25.8 23.3

$1.92 1.99 1.91 1.82

$0.79 0.74 0.68 0.59

2.0% 1.6 1.7 2.3

$45%-343/4 50%-39% 50V8-28 30 3 / 4 -20%

20.9 22.7 19.7 13.8

$1,146 1,112 1,154 1,097

$437.6 375.6 380.0 353.6

$127.9 95.8 82.4 77.4

$696 804 777 718

5.6% 8.1 8.4 8.8

12.2% 15.5 15.9 17.7

$1.25m 1.81 1.78 1.77n

$0.85 0.81 0.77 0.73

2.7% 2.7 3.0 3.6

$36%-26% 34%-24% 293A-22 241/2-161/2

25.2 16.4 14.5 11.5

$494.0 $7,451 $2,802.0 (126.0)f-° 8,019 3,005.0 p 7,937 3,362.0 296.0 546.0q 7,811 3,492.0

$437.0 586.0 591.0 750.0

$1,666 1,939 2,364 2,664

6.3%

29.7%

$2.30 2.20 2.045 1.88

3.7% 3.6 3.4 3.8

$75-48% 711/4-493/4 76-46 601/s-383/4

15.1 26.2 11.7

$613 608 561 555

Lubrizol 1993 $1,518 1,545 1992 1991 1,468 1,445 1990 Monsanto 1993 $7,902 1992 7,763 1991 8,864 1990 8,995

$68.3 72.3 71.9 67.4 $85.0m 124.6 123.7 127.Γ



3.3 6.1

12.5 20.5

$4.10 (101)f-° 2.33p 4.23q







$93/4_53/4

25.8 21.6 15%-8% 1 16 Vs-11V2 28.3



Morton International 1993e $2,310 $126.9r 1992e 2,044 144.5 1991e 1,906 138.3 e 1990 1,639 129.0s

$1,894 1,755 1,563 1,448

$914.3 835.2 722.3 646.2

$201.4 200.1 163.6 113.3

$856 867 741 642

5.5% 7.1 7.3 7.9

14.8% 16.7 18.7 20.1

$2.57r 2.95 2.85 2.68s

$0.96 0.96 0.94 0.86

1.5% 1.6 2.0 2.3

$79%-503/4 64%-513/4 57%-35% 443A-311/2

25.3 19.8 16.3 14.2

Nalco Chemical 1993 1,389 1992 1,375 1991 1,237 1990 1,212

$1,212 1,232 1,186 992

$558.5 533.3 493.6 419.3

$117.8 131.0 136.8 114.9

$438 458 390 410

11.0% 10.5 10.9 10.8

34.9% 31.7 34.5 31.9

$1.88* 1.90 1.78u 1.71

$0.885 0.84 0.83 0.755

2.6% 2.4 2.4 2.9

$37%-301A 40%-30% 42V4-26V8 30%-22

18.1 18.8 19.2 15.4

$152.7* 145.0 134.6U 131.1

a From continuing operations; excludes loss from disposal of cocoa, battery separators, certain engineered materials, and other businesses of $108.4 million ($1.18 per share), b From continuing operations; excludes net loss from discontinued operations of $183.9 million ($2.05 per share) and net loss from cumulative effect of changes in accounting for health benefits for retirees of $190.0 million ($2.12 per share), c From continuing operations; excludes net loss from discontinued operations of $0.6 million ($0.01 per share), d Excludes losses from early retirement of debt and from cumulative effect of changes in accounting for health benefits to retirees and for income taxes of $241.8 million ($5.63 per share), e Fiscal year ends June 30. f Net loss, g Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees of $47.1 million ($2.13.per share), h Excludes net loss from cumulative effect of changes in accounting for income taxes of $165.5 million ($4.12 per share), i Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $6.1 million ($0.16 per share). j Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees of $7.1 million ($0.07 per share), k Became a publicly held company June 21, 1991 ; prior to that was part of GAF; data for earlier part of 1991 are pro forma. I From June 21 only, m Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $39.4 million ($0.58 per share), but includes special charge for shutting down certain manufacturing units and reducing personnel of $86.3 million ($0.83 per share) and a gain from the sale of Genentech stock of $42.4 million ($0.41 per share), η From continuing operations; excludes gain, after taxes, on sale of Genentech stock of $62.9 million ($1.79 per share) but includes charge for write-off of inventories and receivables due from a former affiliate of $9.7 million, ο From continuing operations; excludes income and gain from sale of Fisher Controls of $578.0 million ($4.68 per share) and net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $658.0 million ($4.38 per share), ρ Includes net restructuring expense of $325.0 million ($2.54 per share), q Includes net gain on divestitures of $56 million ($0.43 per share), r Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and future costs of disability benefits of $94.4 million ($1.91 per share), s Excludes extraordinary net gains of $5.8 million ($0.12 per share), t Excludes net losses from retirement of debt of $10.6 million ($0.15 per share) and from cumulative effect of change in accounting for health benefits for retirees of $56.5 million ($0.81 per share), u From continuing operations; excludes net income from discontinued operations of $3.2 million ($0.04 per share).

JULY 4,1994 C&EN

51

Net sales

Year

NL Industries 1993 $805 1992 893 1991 840 1990 907

Net income

$(83.2)a'b (44.6)a-d (24.0 a>e 93.5f

Occidental Petroleum $74.0g 1993 $8,116 126.0h 1992 8,494 1991 9,498 317.0' 1990 21,694 (1,695.0)a Olin 1993 1992 1991 1990

Total assets

NET INCOME Net plant %of and Capital Stockholders' % of stockholders' $per equipment ιexpenditures equity sales equity share (Money figures in millions of dollars unless otherwise indicated)

$378.6 746.0 738.6 577.1

$48.0 85.2 195.1 195.3

$(280)c (165)c (81 )c 13

$17,123 $14,284.0 17,877 14,051.0 15,763 11,279.0 19,743 13,887.0

$1,083.0 860.0 1,007.0 1,446.0

$3,958 3,440 4,340 4,112

$1,191 1,453 1,808 1,941

Divi­ dend, $per share

$(1.63) ab 0 (0.88)a,d $0.35 (0.40 a,e 0.60 0.60 719.2% 10.3% 1.42'

— — —

0.9% 1.5 3.3

— — —

1.9% 3.7 7.7





Divi­ dend yield, % of price



4.1% 4.8 3.5

Stock price range, $ per share

$61/8-33/8 1278-4 16 3 /4-8 1 / 2 243/4-91/4

Priceearn­ ings ratio

— — —

12.0

$0.129 0.41 h 1.04' (5.82)a

$1.00 1.00 1.00 2.50

$(4.52)a 2.17J 3.32k 4.03

$2.20 2.20 2.20 2.15

4.9% 4.8 5.0 4.8

$50 1 /2-39 7 / 8 543/4-37V4

54-33V2 605/8-281/8

21.2 13.2 10.7

$0.25 0.25°

1.5% 1.6°

$181/4-15 17V8-135/8p

15.7 24.0°





$62-471/4 595/8-423/4

31.4 20.2 16.6 9.9

5.0% $23 1 /2-16 7 / 8 231/8-153/4 5.1 253/8-16V2 4.8 30V4-173/4 10.4

168.2 47.4 20.1



$2,423 2,376 2,275 2,592

$(92.0)a 55.0J 67.0k 84.0

$1,816 1,904 1,880 1,760

$885.0 934.0 899.0 829.0

$132.0 173.0 177.0 187.0

$482 615 534 609

2.3% 2.9 3.2

8.9% 12.5 13.8

Praxair1 1993 $2,438 2,604 1992 2,469 1991

$143.0m 84.0n 107.0

$3,188 3,283 3,417

$2,273.0 2,315.0 2,338.0

$240.0 333.0 417.0

$568 483 616

5.9% 3.2 4.3

25.2% 17.4 17.4

$1.06m 0.64n

Rohm and Haas 1993 $3,269 3,063 1992 2,763 1991 2,824 1990

$126.0q 174.0r 163.0 207.0s

$3,394 3,297 2,867 2,645

$1,869.0 1,768.0 1,470.0 1,390.0

$382.0 283.0 265.0 412.0

$1,311 1,280 1,201 1,176

3.9% 5.7 5.9 7.3

9.6% 13.6 13.6 17.6

$1.74q 2.53r 2.45 3.10s

$1.36 1.28 1.24 1.22

2.5% 2.5 3.1 4.0

Sigma-Aldrich $739 1993 654 1992 589 1991 529 1990

$107.2* 95.5 79.8 71.2

$753 616 597 546

$257.3 188.3 191.7 192.4

$75.2 30.9 26.1 32.5

$591 512 441 368

14.5% 14.6 13.5 13.5

18.1% 18.7 18.1 19.3

$2.15* 1.92 1.60 1.44

$0.30 0.26 0.23 0.205

0.6% 0.5 0.6 0.7

353/8-253/8

23.8 26.3 25.3 21.1

$10.8 10.4U 12.5 14.5

$300 297 271 247

$168.9 167.9 157.1 143.3

$25.4 34.4 33.7 38.4

$104 100 91 83

2.5% 2.4 3.0 3.7

10.4% 10.4 13.8 17.5

$1.92 1.91u 2.30 2.64

$0.81 0.74 0.66 0.58

5 1 2.6% $37 / 8 -25 /8 453/4-26V4 2.1 293/4-213/8 2.6 27 1 /4-16 5 / 8 2.6

16.3 18.8 11.1 8.3

$482 536 361 352

$314.3 343.8 230.6 216.0

$12.2 16.0 34.4 19.9

$13 24 112 108



$(0.10)a 0.08w 0.67 1.07

$0.06 0.245 0.65 1.00

1.5% 4.2 11.2 14.4

$165.0X 119.0y (116.0)a 308.0bb

$4,645 4,856 6,705 8,587

$2,420.0 2,539.0 2,499.0 4,325.0

$395.0 359.0 400.0 744.0

$1,384 1,153z 2,118 2,227

$0.75 0.875z 1.00 1.00

3.8% 6.3 5.3 5.1

$23V8-16

$19.8 53.9CC 73.5 68.0

$1,622 1,562 1,129 1,136

$696.5 721.2 474.8 471.0

$103.7 72.6 74.3 90.8

$496 364 556 544

$0.94 0.92 0.89 0.86

3.3% 4.1 4.9 5.6

$32V4-24

Stepan 1993 1992 1991 1990

$439 436 414 390

Sterling Chemicals $(5.4)a $519 1993v 431 1992v 4.5W 543 1991v 36.8 59.1 506 1990v Union Carbide 1993 $4,640 4,872 1992 1 1991" 4,877 7,621 1990 Witco 1993 1992 1991 1990

$2,143 1,729 1,631 1,631



1.0% 6.8 11.7

18.8% 32.8 54.6

3.6% 2.4

11.9% 10.3



4.0

13.8

$1.00x 0.76y (1.06)a 2.19bb

0.9% 3.1 4.5 4.2

4.0% 14.8 13.2 12.5

$0.46 1.19CC 1.605 1.475









48V2-323/4

37-24V4 $58-441/2 59V4-413/4

53-28

$5-31/8

51/8-37/8 7V8-4V2 8 5 / 8 -5V4

17 1 / 8 -10 7 /8 22 5 / 8 -15 1 /8 24 7 /8-14V 8

25V2-20 1

22-14 /2 20-10%



71.9 8.7 6.5 19.6 18.4



8.9

61.1 19.1 11.4 10.4

a Net loss, b Excludes net loss from retirement of debt of $27.8 million ($0.55 per share) and net gain from cumulative effect of changes in accounting for marketable securities of $1.2 million ($0.02 per share), c Deficit, d Excludes extraordinary net loss from cumulative effect of changes in accounting for health benefits for retirees and other extraordinary items of.$43.5 million ($0.62 per share), e Excludes extraordinary net gain of $7.5 million ($0.13 per share), f Excludes extraordinary net loss of $1.1 million ($0.02 per share), g From continuing operations; excludes net income from sale of coal business of $221 million ($0.72 per share); also excludes net loss from early retirement of debt of $12 million ($0.04 per share), h From continuing operations; excludes net loss from discontinued coal business of $622 million ($2.06 per share); also excludes loss from early retirement of debt of $2 million ($0.01 per share) and from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $93 million ($0.31 per share). I From continuing operations; excludes extraordinary gain on sale of agricultural business of $143 million ($0.48 per share), j Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $46.0 million ($2.11 per share), k Excludes special charge for restructuring of operations of $80 million ($4.24 per share). I Became an independent company on June 30, 1992; prior to that was part of Union Carbide; data for 1991 and the first half of 1992 are pro forma and are not included in Union Carbide data, m Excludes net loss from cumulative effect of change in accounting for future severance benefits for employees of $25 million ($0.19 per share), η Excludes net loss from cumulative effect of changes in accounting for health benefits of retirees and for income taxes of $144 million ($1.10 per share), ο On full-year basis, ρ From June 30 only, q Excludes net loss from cumulative effect of changes in accounting for future costs of disability benefits of $19 million ($0.28 per share), r Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees of $179.0 million ($2.69 per share), s Includes net gain on sale of surfactant and alkylphenol businesses of $26 million ($0.39 per share), on sale of forest property of $20 million ($0.20 per share), and net loss for write-off of intangible assets in electronic materials business of $187 million ($0.27 per share), t Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $10.8 million ($0.22 per share), u Excludes net gain from changes in accounting for income taxes and investment tax credits of $5.4 million ($1.02 per share), ν Fiscal year ends Sept. 30. w Excludes net loss from changes in accounting for health benefits for retirees of $10.4 million ($0.19 per share), χ Excludes net loss from cumulative effect of changes in accounting for future severance benefits for employees of $97 million ($0.64 per share), y From continuing operations; excludes net gain from spin-off of industrial gases business of $67.0 million ($0.51 per share) and net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $361.0 million ($2.73 per share), ζ On June 30, stockholders received one share in the newly formed industrial gases company Praxair for every share of Union Carbide stock; the effect of this spin-off was to reduce Union Carbide stockholders' equity by $733.0 million, aa Excludes industrial gases business, spun off during 1992. bb Includes net loss from sale of 50% interest in carbon product business of $86 million ($0.61 per share) and net gain from sale of other businesses of $80 million ($0.57 per share), cc Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $14.7 million ($0.59 per share).

52

JULY 4,1994 C&EN

2

FINANCES OF THE U.S. CHEMICAL INDUSTRY

Net

Net income

Year

Total assets

Net plant and equipment

Capital expenditures

Stockholders' equity

%of sales

NET INCOME %of $per stockholders' share equity

Dividends, $ per share

Dividend yield, % of price

Stock price range, $ per share

Priceearnings ratio

(Money figures in millions of dollars unless otherwise indicated) PHARMACEUTICALS Abbott Laboratories $7,689 $3,511.0 1993 $8,408 $1,399.1 6,941 3,099.2 1992 7,852 1,239.1 a 6,255 2,662.1 1991 6,877 1,088.7 5,563 2,375.8 1990 6,159 965.8 American Cyanamid 1993b $4,277 ($163.7)cd $5,752 $1,770.3

1992

$3,675 3,348 3,203 2,834

16.6% 15.8 15.8 15.7

38.1% 37.0 34.0 34.1

$1.69 1.47 1.28a 1.11

2,119.8 2,018.9 1,906.0

.$305.5 410.0 392.1 375.5

$1,062 2,518 2,387 2,335

— 7.5% 7.2 2.4

— 15.7% 15.0 4.6

($1.82)cd $1.725 4.35 1.61 3.85 1.46 1.15e 1.35

3.3% $591/4-46 — 2.7 663/8-521/8 13.6 1 2.5 69-48 /2 15.3 2.2 61V2-42 5.3

$6,971 $2,059.8 6,433 1,777.8 5,684 1,476.8 5,354 1,437.4

$517.9 428.1 227.9 247.7

$3,160 2,854 3,046 2,392

17.7% 14.6 19.4 18.2

46.5% 40.3 45.2 51.4

$4.73 3.66f 4.36 3.92g

$2.86 2.66 2.375 2.15

4.6% 3.6 3.6 4.3

$69-551/2 84V4-63V4 861/4-471/e 55-44

13.2 20.2 15.3 12.6

$11,413 $1,959.0 $11,910 $3,374.0 11,727 1,603.0h 10,651 3,141.0 9,246 2,936.0 11,159 2,056.0 9,023 2,631.0

$570.0 647.0 633.0 526.0

$5,749 5,867 5,625 5,226

17.2% 13.7 18.4 17.0

34.1% 27.3 36.6 33.4

$3.80 3.09h 3.95 3.33

$2.88 2.76 2.40 2.12

4.9% $671Λ-507/8 3.7 901/8-60 3.2 893/s-611/e 3.6 68-501/2

15.5 24.3 19.1 17.8

$11,317 $4,406.0 11,168 4,115.0 9,775 3,667.0 9,506 3,247.0

$975.0 1,103.0 987.0 830.0

$4,643 4,455 4,888 4,900

12.6% 11.8 11.7 10.2

38.5% 36.5 29.9 23.3

$2.74 2.46' 4.39 3.43j

$1.01 0.89 0.77 0.655

2.3% $503/8-35% 1.7 583/4-43 1.7 581/8-32Ve 2.1 37-251/2

15.7 20.7 20.7 18.3

$9,624 $4,200.2 8,213 4,072.1 7,873 3,782.5 6,674 2,936.7

$633.5 912.9 1,142.4 1,007.3

$4,164 4,440 4,540 2,998

7.6% 13.4 23.0 21.7

11.8% 18.6 29.0 37.6

$1.67k 2.81 ' 4.50 3.90

$2.42 2.20 2.00 1.64

4.5% $62^5 3.0 873/4-573/4 2.6 847/8-69 2.2 893/4-593/e

32.0 25.8 17.1 19.1

2,446.6m 2,121.7 1,781.2

$13,282 $4,894.6 10,933 4,271.1 9,349 3,504.5 7,873 2,721.7

$1,012.7 1,066.6 1,041.5 670.8

$3,376 4,849 4,767 3,677

20.6% 25.3 24.7 23.3

64.2% 50.5 44.5 48.4

$1.87 2.12m 1.83 1.52

$1.03 0.92 0.77 0.64

2.8% $441/8-255/e 1.9 565/8-401/2 1.9 555/s-273/8 2.4 303/e-223/8

19.5 22.9 22.7 17.3

$657.5 1,093.5n 917.1° 801.2

$9,100 $2,632.5 9,222 2,305.1 9,251 2,381.0 8,553 2,109.8

$634.2 674.2 593.8 547.5

$3,634 4,350 4,643 4,593

8.8% 15.1 13.2 12.5

18.1% 25.1 19.8 17.4

$2.05 3.25n 2.71° 2.38

$1.68 1.48 1.32 1.20

2.6% $755/s-521/2 1.9 87-651/e 2.1 861/e-363/4 3.5 407/s-271/4

31.3 23.4 22.7 14.3

$825.0° 720.4 645.6 565.1

$4,134 $1,967.7 3,967 1,748.5 3,822 1,490.4 3,937 1,284.4

$365.2 403.2 339.4 242.9

$1,399 1,407 1,155 1915

19.0% 17.8 17.9 17.0

59.0% 51.2 55.9 29.5

$4.23° 3.60 3.01 2.50

$1.74 1.50 1.27 1.065

2.8% 2.5 2.4 2.4

$71-51% 701/8-497/e 671/8-403/4 503A-37

14.5 16.7 17.9 17.6

$402.5q 547.2r 537.4 458.1s

$4,816 $1,771.3 4,605 1,670.4 4,147 1,540.7 3,668 1,421.6

$323.5 295.4 258.1 246.8

$2,086 2,016 2,005 1,780

11.1% 15.0 15.8 15.2

19.3% 27.1 26.8 25.7

$2.19q 3.04r 2.96 2.48s

$1.48 1.42 1.26 1.04

4.9% 3.8 3.0 2.7

$35-25% 457/e-295/8 491/4-343/4 445/s-33

13.8 12.4 14.2 15.7

$285.0t 643.7 452.8U 484.9

$4,514 $1,599.3 3,921 1,507.1 3,444 1,350.0 3,100 1,301.4

$347.1 334.3 326.0 239.9

$1,076 1,372 1,013 1,241

4.9% 11.5 9.0 10.3

26.5% 46.9 44.7 39.1

$2.11l 4.78 4.16U 3.61

$2.28 2.04 1.76 1.52

3.4% $763/e-593/4 32.2 3.0 791/4-583/e 14.4 2.4 821/4-613/4 17.3 2.5 703/β-495/8 16.6

5,268

395.1

1991 4,986 358.8 1990 4,570 107.8e American Home Products

1993 1992 1991

$8,305 $1,469.3 7,874 1,150.7f 7,079 1,375.3

1990 6,775 1,230.6g Bristol-Myers Squibb

1993 1992 1991

1990 10,300 1,748.0 Johnson & Johnson

1993 1992 1991 1990

Eli Lilly 1993 1992 1991 1990 Merck 1993

$14,138 $1,787.0 13,753 1,625.0' 12,447 1,461.0 11,232 1,143.0j $6,452 6,167 5,726 5,192

$10,498 $2,166.2

1992 1991

9,663 8,603

1990 Pfizer 1993 1992

7,671 $7,478 7,230

1991

6,950

1990 6,406 Schering-Plough

1993

$491.1k 827.6' 1,314.7 1,127.3

$4,341

1992 4,056 1991 3,616 1990 3,323 Upjohn $3,611 1993 3,639 1992 3,402 1991 3,021 1990 Warner-Lambert 1993 $5,794 1992 5,598 1991 5,059 1990 4,687

5,209 4,838 4,864

$0.68 0.60 0.50 0.42

2.5% $307/8-225/8 2.0 341/8-261/8 1.8 343/4-195/e 2.2 231/4-155/e

$952.7 1,007.2 770.6 641.4

15.8 20.5 21.3 17.5

a Excludes extraordinary net gain on sale of investment in Amgen of $128.2 million ($0.15 per share), b Excludes chemical business, spun off in 1993. In 1992, this business contributed $1,074 million to net sales and $16.0 million to net income; spin-off reduced stockholders' equity by $52.9 million; company data for 1992 and earlier years have not been restated, c Net loss, d From continuing operations; excludes losses from chemical business, spun off in 1993, of $622.2 million ($6.92 per share); also excludes losses from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $322.6 million ($3.70 per share), e From continuing operations; excludes net income from discontinued operations of $245.0 million ($2.56 per share) but includes special net charge of $206.2 million ($2.15 per share) to consolidate product lines, reduce carrying costs, increase environmental remediation costs, and reduce number of employees. f Excludes net loss from cumulative effect of changes in accounting for income taxes and a charge for research acquired from Genetics Institute of $310.1 million ($0.99 per share), g Includes gain on sale of household products and depilatory businesses, before taxes, of $999.5 million, h From continuing operations; excludes net gain on sale of Drackett of $605.0 million ($1.17 per share) and net loss from cumulative effect of changes in accounting for health benefits for retirees of $246.0 million ($0.47 per share), i Excludes net loss from cumulative effect of changes in accounting for health and other benefits for retirees and for income taxes of $595.0 million ($0.90 per share), j Includes charge for damage to operations in Latin America of $125 million ($0.38 per share). k Excludes net loss from cumulative effect of change in accounting for disability benefits for former employees of $10.9 million ($0.04 per share). I Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $118.9 million ($0.40 per share), m Excludes net loss from cumulative effect of changes in accounting for health and other benefits for retirees and for income taxes of $462.4 million ($0.40 per share), η Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $282.6 million ($0.84 per share), ο Excludes special charge for projected payments in connection with potential future Shiley C/C heart valve fractures of $195 million ($0.58 per share). ρ Excludes net loss from cumulative effect of change in accounting for health benefits for retirees of $94.2 million ($0.48 per share), q From continuing operations; excludes earnings from and gain from sale of discontinued agricultural chemical business of $8.8 million ($0.04 per share); also excludes net loss from cumulative effect of several accounting changes of $18.9 million ($0.10 per share), r Excludes net loss from cumulative effect of changes in accounting for health benefits for retirees and for income taxes of $223.0 million ($1.26 per share), s From continuing operations; excludes loss on discontinued operations and their disposal of $2.4 million ($0.01 per share) but includes partial pension settlement net gain of $37.8 million, t Excludes net gain from cumulative effect of changes in accounting for disability benefits of former employees and income taxes of $46.0 million ($0.34 per share) but includes nonrecurring restructuring costs of $525.2 million. u Excludes nonrecurring net charges for restructuring of $418.0 million ($3.11 per share) and for cumulative effect of accounting change of $106.0 million ($0.79 per share).

JULY 4,1994 C&EN 53

m

EMPLOYMENT IN THE U.S. CHEMICAL INDUSTRY

Chemical employment tumbled in 1993 our years of falling earnings and sliding profit margins took their toll on employment in the U.S. chemical in­ dustry in 1993. After actually increasing through much of the 1991-92 recession, chemical employment started to slip in the early months of last year. By August, staff cuts had be come widespread in the chemical industry, as companies scrambled—usually successfully—to make 1993 more profit­ able than 1992. By April 1994, after nine consecutive months of decline, the chemicals and allied products industry set a six-year employment low of a seasonally adjusted 1.057 million, ac­ cording to figures from the Department of Labor. Prelimi­ nary figures for May show that level unchanged, the first indication that the slide may have ended. If so, the industry's most recent downsizing leaves it with 29,000 fewer employees than it had in August 1992. About 14,000 of those jobs were lost in 1993, most of the rest came in the early months of 1994. As is usually the case in downsizings, job loss in 1993 was not uniform throughout the chemical industry. It was great­ est at the big commodity chemical makers, particularly those that produce industrial organic chemicals and poly­ mers. Total employment at 22 of the largest of these firms fell more than 28,000 in 1993. These companies alone cut many more jobs than did the industry as a whole, and thus the total industry decline would have been larger had not other parts of the industry added to their work force. The biggest gainers, by far, were pharmaceutical companies, which increased their employment 3% during 1993. That growth may have ended, however; drug industry employ­ ment held steady through the early months of 1994. Just what these trends mean for chemists and engineers is

F

By April 1994, jobs in chemical industry had dropped 3%fromtheir 1992 high Millions of employees3 1.09 Γ

1.08

1.07

1.06 1.05 1.00

1990

1993

1992

1991

1994

a Seasonally adjusted employment in U.S. chemicals and allied products industry; April and May 1994 figures are preliminary. Source: Department of Labor

uncertain. The National Science Foundation, which keeps track of the number of scientists and engineers in the chem­ ical and other industries, has yet to release 1993 data. NSF expects to do so later this summer. As of January 1992, NSF's latest available survey, more than 82,000 scientists and engineers were working in the chemicals and allied products industries, almost 45% of them at drug firms. At that time, science and engineering employment at drug companies was 8% higher than the previous year; it was 6% lower at industrial chemical companies.

INDUSTRIAL EMPLOYMENT: Drugfirmsgrew in 1993 but chemicals, allindustry downsized % annual change Thousands

All manufacturing Chemicals & allied products Industrial inorganic chemicals

1983

1984

1985

1986

1987

1988

1989

1990

1991

1992

1993

18,432 19,372 19,248 18,947 18,999 19,314 19,391 19,076 18,406 18,040 17,802 1,043 1,049 1,044 1,021 1,025 1,057 1,074 1,086 1,076 1,083 1,074 151

143

143

135

131

133

135

138

129

136

1992-93

1983-93

-1%

0%

-1

0

135

-1

-1

Plastics materials & synthetics

177

178

172

168

168

177

182

180

178

173

166

-4

-1

Drugs

201

206

206

208

215

228

232

237

247

257

265

3

3

Soap, cleaners & toilet goods

142

146

152

159

160

159

155

154

157

2

1

58

0

0

146

148

60

62

63

63

63

63

62

61

58

58

163

162

160

154

148

146

150

155

155

154

151

-2

-1

Agricultural chemicals

61

61

59

54

51

52

54

56

57

58

56

-3

-1

Miscellaneous chemical products

89

92

94

93

97

100

99

100

97

94

92

-2

0

Petroleum & coal products

196

189

179

169

164

160

156

157

160

158

151

-4

-2

Rubber & miscellaneous plastics products

743

813

818

823

842

866

888

888

862

872

886

2

2

Paints & allied products Industrial organic chemicals

Note: Average annual domestic employment. Source: Department of Labor

54

JULY 4,1994 C&EN

PRODUCTION WORKERS: Declines of recent years halted in 1993 in most chemical fields % annual change Thousands

1983

1984

1985

1987

1986

1988

1989

1990

1993

1992

1991

12,528 13,280 13,084 12,864 12,952 13,193 13,230 12,947 12,434 12,241 12,143

All manufacturing

1992-93

1983-93

-1%

-1%

579

583

578

568

575

596

603

600

580

567

568

0

0

Industrial inorganic chemicals

77

73

72

69

67

69

70

70

64

61

58

-5

-2

Plastics materials & synthetics

115

117

114

113

111

116

119

116

110

104

104

0

-1

112

117

4

2

Chemicals & allied products

Drugs

98

Soap, cleaners & toilet goods Paints & allied products

99

101

102

93

97

102

101

98

95

94

96

2

1

30

31

31

32

31

30

30

30

0

0

82

81

83

86

88

86

81

76

78

3

-1

37

33

32

33

34

34

34

35

33

-6

-1

58

56

54

-4

1

96

95

96

89

93

93

29

30

31

Industrial organic chemicals

84

82

Agricultural chemicals

37

38

Miscellaneous chemical products

51

54

54

53

58

55

105

109

59

59

Petroleum & coal products

118

111

109

106

107

104

102

103

103

103

99

-4

-2

Rubber & miscellaneous plastics products

574

633

632

639

654

675

694

689

663

678

685

1

2

Note: Average annual domestic employment. Source: Department of Labor

WORKWEEK: Unchanged for chemicals overall, shorter at drug companies

EMPLOYMENT OF WOMEN: Decade brings greater numbers to all chemical fields 1982 Thousands

All manufacturing 5,990.0 Chemicals & allied products 279.2 Industrial inorganic chemicals 25.2 Plastics materials & synthetics 40.4 Drugs 85.7 Soap, cleaners & toilet goods 58.4 Paints & allied products 11.6 Industrial organic chemicals 27.4 Agricultural chemicals 10.0 Miscellaneous chemical products 20.5 Petroleum & coal products 31.0 Rubber & miscellaneous 247.8 plastics products

1992 %of total

Thousands

32% 26 16 21 43 41 19 16 15 23 15 34

%of total

5,942.0 334.6 30.3 40.3 116.7 68.8 12.0 31.5 10.4 24.7 26.1 298.2

Hours

1990

1991

All manufacturing

40.8 42.6 42.9 42.5 41.8 40.8 41.9 45.2 44.1 42.4 44.6 41.1

40.7 42.9 43.6 42.6 42.5 40.9 41.8 45.6 44.4 42.3 44.1 41.1

Chemicals & allied products

33% 31 22 23 45 44 21 21 18 26 16 34

Industrial inorganic chemicals

Plastics materials & synthetics Drugs Soap, cleaners & toilet goods Paints & allied products Industrial organic chemicals Agricultural chemicals Miscellaneous chemical products Petroleum & coal products Rubber & miscellaneous plastics products

1993

41.0 43.1 43.5 43.8 42.5 41.3 41.6 45.6 44.5 42.6 43.8 41.7

41.4 43.1 43.8 44.1 41.4 41.9 42.2 45.4 44.7 42.8 44.2 41.8

Note: For production workers in domestic employment. Source: Department of Labor

Note: Average annual domestic employment. Source: Department of Labor

EMPLOYMENT OF SCIENTISTS, ENGINEERS: Gains at drug firms, losses elsewhere in 1992 Thousands

1987

1988

1989

1990

1991

671.0

695.8

708.6

720.2

730.9

704.1

683.7

75.8

75.2

75.8

77.6

78.9

78.8

82.2

30.8

31.8

32.6

33.0

34.0

33.5

34.2

36.9

25.6

23.5

24.9

22.4b

22.5b

23.1 b

23.0b

22.7 b

21.4b

12.1

13.4

16.7

19.1

20.2

20.3

20.5

22.4

21.9

23.9

14.7

13.3

13.5

10.4

9.9

9.5

10.3

10.2

10.0

9.7

1983

1984

1985

509.8

540.9

584.1

622.5

61.6

67.3

69.8

71.1

Drugs & medicines

25.6

28.2

30.8b

Industrial chemicals

25.9

26.6

Other chemicals

10.1 15.6

Total, all industry Chemicals & allied products

Petroleum refining & extraction

Note: Full-time equivalent number of R&D scientists and engineers in industry, as of January of each year, b Partly estimated. Source: National Science Foundation

JULY 4,1994 C&EN 55

1

I

EMPLOYMENT IN THE U.S.CHEMICAL INDUSTRY

CHEMICAL EMPLOYMENT: More than 28,000 jobs cut at major firms in 1993 Thousands

1983

1984

1987

1985

1990

1988

1992

1993

Air Products Betz Laboratories Cabot Crompton & Knowles Dow Chemical

16.7 2.3 7.2 2.4 54.5

17.7 2.5 7.5 2.3 49.8

18.7 2.5 1.1 2.3 53.2

16.6 2.6 6.6 1.3 51.3

12.1 2.0 5.1 1.3 53.1

13.3 3.1 5.2 1.6 55.5

14.1 3.4 5.5 1.7 62.1

14.0 3.7 6.0 1.8 62.1

14.6 4.0 5.3 2.0 62.2

14.5 4.2 5.4 2.2 61.4

14.1 4.1 5.4 2.3 55,4

Ethyl H. B. Fuller BF Goodrich W. R. Grace Hercules

13.0 4.1 29.4 95.5 24.2

11.0 4.3 28.8 102.6 26.3

10.5 4.4 26.2 116.9 25.4

10.5 4.5 11.9 41.4 25.1

10.0 4.6 12.0 39.4 23.2

10.4 5.2 12.3 45.7 22.7

5.5 5.5 11.9 46.4 23.3

5.7 5.6 14.7 49.0 19.9

6.0 5.6 14.4 46.6 17.3

6.3 5.8 13.4 44.1 15.4

5.5 6.0 13.4 34.0 14.1

International Flavors Loctite Lubrizol Monsanto Nalco Chemical

3.7 2.4 4.2 48.8 4.6

3.7 2.5 4.2 50.8 4.8

3.7 2.6 5.2 56.1 5.1

3.8 2.9 4.8 51.7 4.9

4.1 3.2 4.8 49.7 5.1

4.2 3.3 4.8 45.6 5.4

4.2 3.5 5.3 42.2 5.5

4.2 3.7 5.2 41.1 5.9

4.2 3.6 5.3 39.3 6.8

4.2 3.7 4.6 33.8 6.7

4.4 4.0 4.6 30.0 6.8

Olin PPG Industries Praxair8 Rohm and Haas Stepan

18.2 37.0

17.8 37.7

14.9 37.5

13.2 36.5

14.1 36.8

16.4 36.3

15.4 35.5

15.2 35.1

14.4 33.7



















11.4 0.9

11.9 0.9

11.8 0.9

12.1 0.9

12.0 1.0

12.4 1.0

13.0 1.2

12.9 1.3

12.9 1.3

13.5 32.3 18.6 13.8 1.3

12.4 31.4 16.8 13.0 1.3

Union Carbide Witco

99.5

98.4 8.5

91.5 8.1

50.3 8.0

43.1 7.8

44.0 7.6

46.0 7.4

38.8 7.3

36.7 6.9

15.1 8.4

13.1 8.2

TOTAL EMPLOYEES ANNUAL CHANGE SALES PER EMPLOYEE ($ thousands)

8.2

488.2 — $112.4

353.2 358.6 343.1 328.7 300.3 360.9 494.0 505.2 344.5 356.0 0.7% -1.5% -2.9% -4.2% -8.6% 1.2% 2.3% -28.6% -4.5% 3.3% $117.5 $104.4 $143.7 $169.3 $191.9 $200.1 $213.1 $204.0 $222.3 $232.6

Note: Data are not restated for acquisitions, divestitures, or similar developments, a Spun off from Union Carbide in 1992. Source: Company data

WAGES: Rising for chemical production workers except at plastics makers Weekly earnings

Hourly earnings

All manufacturing Chemicals & allied products Industrial inorganic chemicals Plastics materials & synthetics Drugs Soap, cleaners & toilet goods Paints & allied products Industrial organic chemicals Agricultural chemicals Miscellaneous chemical products Petroleum & coal products Rubber & miscellaneous plastics products

1990

1991

1992

1993

1990

1991

1992

1993

$10.83 13.54 14.66 13.97 12.90 11.71 11.99 15.97 13.73 12.28 16.24

$11.18 14.04 15.05 14.79 13.49 12.02 12.48 16.54 14.22 12.61 17.04

$11.46 14.51 15.73 15.37 14.11 12.00 12.67 17.29 14.83 13.06 17.91

$11.76 14.84 16.42 15.26 14.70 12.31 12.69 17.67 15.11 13.49 18.55

$441.86 576.80 628.91 593.73 539.22 477.77 502.38 721.84 605.49 520.67 722.30

$455.03 602.32 656.18 630.05 573.33 490.42 521.66 754.22 632.79 533.40 751.46

$469.86 625.38 684.26 673.21 599.68 494.40 527.07 788.42 662.90 556.36 784.46

$486.86 639.60 719.20 672.97 608.58 515.79 535.52 802.22 675.42 577.37 819.91

10.07

10.37

10.60

401.14

413.88

432.43

443.08

9.76

Note: For production workers in domestic employment. Source: Department of Labor

56 JULY 4,1994 C&EN

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