Southwide Chemical Conference - C&EN Global Enterprise (ACS

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Instrumentation Symposium o n Gas Chromatography (Instrument Society of America)

ASSOCIATIONS

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1. W. L. JONES. Physical Parameters in Gas Chromatography. 2. M. DnviBAT. Factors W h i c h I n ­ fluence Efficiency in Gas-Liquid Partition Chromatography.

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AFTERNOON

Instrumentation Symposium on Mass Spectrometry (Instrument Society of America) 1. W. D O N N E R .

Characteristics of the

RF Gas Analyzers. 2 . J. K. W A L K E R , W. D . SCHXJLTZ, R. E. QUACKENBUSBL, C . K. H I N E S . Exploit-

ing the Mass Spectrometer. Good resistance t o hot mineral acids, weak alkalies, common solvents, oils, greases, neu­ tral salts, most acid salts and chlorine.

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N O V . 12, 195 6

H.

Evaluation of Flue-Cured Tobacco. 3. L. J. D E W E Y . Recent Advances in the Field of Nicotine Biosynthesis.

W e s t e r n Office e n d F a c t o r y : S a l t L a k e C i t y 2 , U t a h

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of Engine

1. W . J. PETERSON,

he national filter Media © « r j ^

5552

Studies

Opportunities and Challenges Chemist in Tobacco Research.

3 . F. C. B U M E , M. L. MARKS.

ment of a Laboratory Chromatograph.

Develop-

Vapor

Phase

Nuclear Energy 1. W. J. LACY. Effects of Ion Exchange Parameters on t h e Removal of Radiostrontium and Stable Calcium from Aqueous Solutions. 2.

W„

SECHRIST,

Tobacco Chemistry

Literature a n d pilot test sample a v a i l a b l e on request. W e also w e a v e filter cloth of VINCELt, SARAN, DYNEL, N Y L O N , V I N Y O N N * * , GLASS, D A C R O N t t , T E F L O N * * * , POLY­ ETHYLENE.

N.

Radiotracer Formation.

B. K A H N ,

E.

R. EASTWOOD,

W.

J.

LACY. U s e of Ion Exchange Resins to Concentrate Radionuclides for Subsequent Analysis. 3 . P. L. PARKER, P. K. KURODA.

Radio-

chemical Measurements of the Spontaneous Fission Half-Life of Uranium-238. 4.

F.

T.

ASHIZAWA,

P.

K.

KURODA.

Relative Yields of t h e Short-Lived Iodine Isotopes from t h e Spontaneous Fission of Uranium-238. 5. G.

D.

O'KELLY,

Q.

V.

LARSON.

KILL

FOAM

T H E EASY

WAV...

Half-Life of Technethim-98 and Its Abun­ dance im Fission-Product Technetium. 6. G. JC, SCHWEITZER, H . A. MAHLACAN.

Radiatiosi-Induced Nitrite Formation from Concentrated Nitrate Solutions. Organic

Chemistry

1. V. J. SHINER, J R . Deuterium Iso­ tope Rate Effects and Kyperconjugation. 2. NATTHAN KORNBLUM, ROBERT E. SMILEY, ROBERT K. BLACKWOOD, D O N C. IFFLAND, LEON FISHBEIN. The Contrast­

ing Reactions of Silver and Alkali Metal Salts w i t h Alkyl Halides. The Alkylation of Ambident Anions.

New G-E silicone Anti-Foam 60 disperses easily-pays for itself CONVENTIONAL ANTI-FOAM

NEW G-E ANTI-FOAM 60

3. ERNEST GRUNWALD, A. LOEWENSTEIN, S- ΜΕΓΒΟΟΜ. Study of t h e Protol-

ysis of IMethylammonium Ion i n Water by Proton Magnetic Resonance. 4. C.

G. OVERBERGERÏ

Oxidation

Be-

havior oE 1,1- and 1,2-Disubstituted Cyclic Hydrazioes. 5. ERJNTEST L . ELTJEL.

Conformational

Factors in Reactions of Simple Alicyclic Compounds. 6. KEI>ÎNETH H. ADAMS.

Kinetic Study

of Competitive Carbonium Ion Reactions in the Rearrangement of Aryl Pinacols. Petroleum Chemistry 1. J. A . RIDGWAY. Free Radical Alkylation wfcth Ethylene. I. Effect of Reaction Conditions. 2. N.

W. HOUGHTON.

Determination

of Trace Amounts of Combined and Elemental Sulfur in Petroleum Fractions. 3. J. V . LAWSON. The Science Club in Industry4. A. IELLIOTT. Electrochemical Analysis of Phenyl Sulfides, Benzothiophenes, and Thiophenes.

Conventional high-viscosity silicone antifoam agents ( a b o v e ) do n o t disperse readily in water—require vigorous stirring.

Low-viscosity G-E ANTI-FOAM 60, how­ e v e r , can fee poured — and d i s p e r s e s instantly!

Physical and Inorganic Chemistry Symposium on Electron Exchange Reactions 1. C. H. CHEEK, N . A. BONNER, A . C.

WAHL. A Study of the Electron-Exchange Reaction» Between Sb(III) and S b ( V ) in HydrochJoric Acid Solution. 2. Ε. RONA. Exchange Reactions of Uranium. Ions in Solution. 3. B.

J. SWOLINSKI,

R.

J.

MARCUS.

Electron Transfers in Chemical Kinetics.

Costly, t r o u b l e s o m e f o a m i n g c a n n o w be c o n t r o l l e d — m o r e easily— witL· General Electric's n e w silicone ANTI-FOAM 60. E a s y to d i s p e r s e , this low-viscosity silicone e m u l s i o n can be u s e d a s s u p p l i e d , or r e d u c e d w i t h water t o a n y desired c o n c e n ­ tration. Little or no stirring is r e ­ quired.

4. C. T . DECK, E. EICHLER, G. P. LANG, J. C. SHEPPARD, A. C. W A H L . Kinetics of

Some Rapid Electron-Transfer Exchange Reactions. 5. R.

A. MARCUS.

On the Theory of

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Kinetics of the Ex­

change Reaction Between N p ( V ) and Np(VI) Ions. 7. H. TAUBE. Bridging Groups in Elec­ tron'Transfer Reactions. and Inorganic Chemistry

1. C. H. SIHITH, J. D . ROBINSON.

Position

Name_ , Firm, Street

The

Raman and Infrared Spectra of Formamide-2V—d2. 2. W. J. SVTKBELY. Kinetics of Cyanohydrin Formation. 3. R. IE. PENNINGTON, K. A. KOBE.

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Thermodynamic Properties of Acetone. 4. O.

D. B O N N E R ,

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L.

SMITH.

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Selectivity Scale for Some Divalent Cat­ ions on Oowex 50.

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ASSOCIATIONS 5 . S. A . B R O W N ,

J. E . JLAND.

The

Niean Activity Coefficients of Mercurous Sulfate in Sulfuric Acid Solutions a n d t h e Nature of the Complex Formed Between Mercurous Sulfate a n d Sulfuric Acid i n Solutions as Determined from Solubility Measurements a t 2 5 ° C . β , Η . C U R R Y , W . R. GILEERSOÎ?.

The

Conductance o f Several Electrolytes in a Dichlorobenzene as a Function o f Temperature. 7 . J. L. R A N D A L L , J. L . KASSNER, E . L .

SULFIDES

OLEFINS RHC=CHR

H I R-N-R

R-S-R

GROVE. T h e Dielectric Constant Measurem e n t for a Species o f Ketones. 8 . J. C . POSEY,

H . A . SMITH.

The

Eqxiilibriuxn Distribution of Light a n d H e a v y Waters in a Freezing Mixture. 9 . J. W . B L A I R ,

E . S. A M I S .

Flow

Chromatography on Silicic Acid. 10. K. FAJANS. Dipole Moment a n d D e g r e e o f Polarity of Salt Molecules. 11.

F. ΛΥ. B U R T C H , T. E . M O O R E .

Ac­

tivity Relations in t h e System M n C L - H C l . 12.

H.

A. S M I T H ,

J. C. POSEY.

The

Separation of Hydrogen and Deuterium by the Reaction of Iron with Steam. FRIDAY

R I R-N-R

Ο t R-S-R SULFOXIDES

R H C - f l s — CHR

Ο ÀMUŒ OBOES

MORNING

Analytical Chemistry 1. M A R T H A

STEWART,

GRANVTL

C.

KYKER. Standardization of Beta Emitting Radioisotopes. 2 . S. F . TENG, E . L . G R O V E , JAJMES L .

KASSNER. T h e High-Frequency Titrations of Organic Acids a n d Salts w i t h the Alkali Methoxides. 3. E. W . LARD,

[ RCHO ]

Ο t

RO 1

RHC-0—0-CHR

R-S-R

OXY-PEROXIDES

SULFONES

1 OR

ALDEHYDES

4 Ο

G. T . GRIESHEIMER,

R. C. HORN. T h e Determination of Trace Quantities of Acetylene, Methane, Carbon Monoxide, and Carbon Dioxide. 4. JACK L . LAMBERT, VERNON E. CATES. T h e Use of Polyanion-Stabilized

Diazoniurn agents.

Cations

as Analytical R e ­

5. W. D . B o x , P. F. SHORTEN.

Deter­

mination of "Water b y Pyridine Distilla­ tion and Xarl Fischer Titration. 6. W. S. Ρ A P P A S , C. W . W E B E R .

RCH,OH PtlllAlY ALCOHOLS

RCOOH ACIDS

RCOOOH PERACOS

RCHtNH. AMIMES

Con­

tinuous Analysis b y Boiling Point D etermination. 7. C. A. KIENBERGER. Automatic Sol­ vent Extraction Apparatus a n d Method. 8. C. R . S P E L L , E . C. M A R K H A M , C. N .

REILLEY. η Value Determinations b y Means o f a Constant Current Micropolarographic Method.

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T. T R U E M P E R ,

EUGENE W .

Biochemistry 1. J. W . W O O D S , D . B R I C E , D. H A R R I ­

SON. Ainalogs of Thyroxine: The Synthe­ sis of β- [3,5-Diiodo-4- ( 3-Iodophenoxy ) ] phenylpropionic Acid. 2. R. S. S H A P I R A , D . G. D O H E R X Y , J. X. KHYM. Mercaptoalkylguanidines as P o ­

WELSBACH OZONE

T H E WELSBACH CORPORATION

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9. JOSEPH

BERG. T h e Separation of Zinc, Cadmium, and Mercury by I o n Exchange Chroma­ tography.

tential Radiation-Protective Agents. 3. J. X . K H Y M , R. S. SHAPIRA, D . G.

LABORATORY UNITS PLANT INSTALLATIONS

OZONE PROCESSES 0 1 VISION—I 8 0 2 W A L N U T ST.. PHILADELPHIA 2. PA. .

N O V . 12. 1 9 5 6

DOHERTY. Intramolecular Rearrange­ ments o f 2-Aminoethyl-isothiuronium Br· HBr(AKT). 4. L. L. R O G E R S , R. B. P E L T O N .

Be­

havior-Altering Drugs and Alcohol Con­ sumption by Rats.

ο. G . C. MMLLS. olism. 6. A .

S.

Hemoglobin Catab-

Y^ÎU),

H.

McXsstNis, JR.

Studies of ther Synthesis and Biological Action of o-j3-X>âaminosuccinic Acids. 7. J . SACKS,

G. J. D E X O N .

Differential

Turnover of Adenine Nucleotide Phosphate Groups h o Muscle. S. ÏC, K, Wc'SC, J . D . rEagfNsoN, JR. Effect of Phospihorus-32 on Adenosine Tripliosphatase Activities of Rat Tissues. 9. J . H. WcrarcHiK, J. D . PERKHNSON, JR.

Effect of Internal Irradiation of Rat Liver and Kidney A m i n o Acid Oxidases. Chemical Engineering Mass Transfer Symposium 1. J . C. BRJSSEE, D . C.

O'BRIEN.

An

Orifice Plate l?ulse Column f o r LiquidL i q u i d Extraction, 2. W .

M. NÎEWTON,

L.

J. E N G E L .

A

Study of Gas AJbsorption b y Liquid Drops. 3. W . LIGHT-, C, E>. L A N E .

A Study of

trie Meehanisiras of Solute Transfer from Single Drops. 4. N .

F.

IVIURPHY,

J.

E.

LASTOVICA.

Correlation o f Mass Transfer Coefficients for Liquid-Liquid, Countercurrent Extractions with Three Component Systems. 5. N . F. MUJRPHY, J. E . LASTOVICA, J.

G . FALLIS. Eifect o f Interfacial Tension o n t h e Rate of: Mass Transfer i n a Horizontal Tube. 6. M . W. BESLAGA, J. E . BIGETLOW.

Ef-

fect o f Pulse Column Operating Variables o n H.T.U. Instrumentation Symposium o m Laboratory Analytical Instrumentation (Instrument Society of America ) 1. M . T. KE3LLEY, D . J. F I S H E R .

Stud-

i e s in Derivative Polarography. I. High Sensitivity, Recording, Derivative Polarograph. 2. H . E. Zrr-TEi, M . T. KELLEY. Studies in Derivative Polarography. II. A p plications and Limitations. 3. T . H. LO-TZE, E>. N . GRUNTS.

Redox

Potentials in S e w a g e Anaerobiosis. 4. J.

P. S T R A N C E ,

R.

A.

MORRIS,

R.

HEINE-GELDER3ST. Detection a n d Analysis of Gases b y Ioii Current Measurements. 5. E . B. W A G N E R , D . J. FISHER, M. T.

KELLEY. A Versatile Automatic, Recordi n g Potentionaestric Titrator. Organic Chemistry 1. C . K.BRAVDSHEB, SIDNEY T. W E B S T E R .

A New Reaction.

Base-Catalyzed

2. PEYTON

C.

TEAGUE,

Cyclization T.

GLENN

ROBERTS. Bexizoin Condensations. II. l-Methylcyclohrutane Carboxaldehyde. 3. EDMUND T. KJTTLENXAN, DARTHON V . W E L L S , SAZMUEL F. CLARK. A n Iso-

topic Study oxf the Alkaline Rearrangement of Benzalacetophenone Oxides. 4. DAVID B .

RICHARDSON, A R T H U R F R Y .

A n Isotope E f f e c t Study of the Mechanism o f the Wolff Rearrangement. 5. JAMES

G-.

TRAYNHA*,!,

MERLE

BATTISTE. Solvolyses of Some Hindered Aliplbatic Esters. 6. GAESAR

VAUGHAN.

A

B.

GARAVELLI,

A.

Sterically GEORGE

Kinetic Study o f the D e -

NOV.

12,

19 56

C&EN

5555

ASSOCIATIONS^

OLDBURY

hydrochlorination of Some α,/3-Dichloroketones.

1896

7 . CHARLES E . BOOZER, ANTHONY S O L -

PHOSPHORUS CYeilow or White)

PHOSPHOROUS ACID

PHOSPHORUS OXYCHLORIDE

HYP0PH0SPH0ROUS ACID

PHOSPHORUS TRICHLORIDE PHOSPHORUS PENTACHLORIDE

ALKYL ACID PHOSPHATES (Alkyl Phosphoric Acids)

PHOSPHORUS PENTASULFIDE

SODIUM CHXORATE

PHOSPHORUS SESQUISULPHIDE

POTASSIUM: CHLORATE

AMORPHOUS PHOSPHORUS

POTASSIUM PERCHLORATE

PHOSPHORIC ANHYDRIDE

HYTOPHOSPHITES

PHOSPHORIC ACID

OXALIC ACID

F.

EASTHÀM,

matic Compounds Reagents.

10. BARTON MILLIGAN.

A Kinetic Study o f

1. N . S. GINGRICH.

COMPANY

T h e Diffraction of

2. D .

G.

HENSHAW,

D.

G.

HURST.

Atomic Distributions in Liquid Helium and Liquid Argon by Neutron Diffraction. 3. R. W . ZWANZIG.

A Statistical M e -

chanical Theory of the Thermodynamic Properties of Liquid Metals. 4. O. K. RICE. Elementary Theory of Liquid Helium. 5. H . L . RITTER. X-Ray Studies of Metal Halides in the Melt and i n Solution.

COLUMBUS, MISS.

e

Chamber

A Free-

X-Rays and Neutrons by Liquids.

FRIDAY

Test

Halogen Inter-

change in Aromatic Compounds. Radical Substitution.

Symposium on the Structure of Liquids a n d Vitreous Materials

for o m b l e n t t o m p e r o f u r i tests In th·'* LABORATORY o r on t h e PRODUCTION. LINE, the": Mode ï-TC-2 Temperature Test/ Chamber i s ideal! Interchangeable extra*test trays may- be ordered to elimiriatejoading' delays in continuousproduction'tests, or. lor convenience in special t e s t work:

Temperature

Free-Radical

Physical and Inorganic Chemistry

Soles Office: 19 RECTOR STREET, NEW YORK! 6, Ν. Υ.

Versatile ...

R.

Reactions of Aro-

with

11. JOHN L. KICE.

Executive Offices: NIAGARA FALLS, NEW YORK

Portable...

DONALD

t h e Reactivity of Some Fulvenes Toward Free Radicals.

OLDBURY Plants: NIAGARA FALLS, N.Y.

β. JEROME

LARKIN. T h e Rate of Isomerization o£ 1,4-Dihydronaphthalene a n d I t s Derivatives t o the Corresponding 1,2-Dihydronaphthalenes. 9. BRIAN M. L Y N C H .

ZINC PHOSPHIDE

ELECTRO-CHEMICAL

DATOS. Deuterium Isotope Effects o n t h e Reaction of *-ButyI Bromide with Carboxylic Acids.

Range: — 65 .toJ:-f 3 S O \ F . . Heater· Electric.strip Neater . Coolant: Dryjce; 15 l b s : capacity Control: Adjustable thermostat & selectable heat inputs'-; Load Capacity: 6 0 0 cubic Inches of test materials?;" Power: 115V,- 5 amp: 50-60 cycle Overall Size: 48Τ χ 16 Viz" χ 12" Weight: 62Vz Ib'sV *

AFTERNOON

Analytical Chemistry 1. S A M U E L B. KNIGHT, ROSS L. PARKS, S A R A H C. L E I D T . T h e Colorimetric D e -

termination of Ruthenium. 2. ROBERT L . M A U T E , R A U L W . T n > W E L L , M. L . O W E N S , JR. Application a n d

Versatility of Nonaqueous Titration. 3. T . H. W H I T E H E A D , JAMES F . H I N T O N .

A Study of the Color of Basic LanthanumAcetate-Iodine Systems. 4. R. A. D A Y , J R . , FREDERICK N E L S O N ,

KURT A. KRAUS.

Separation of a Number

of Elements b y Anion Exchange in Ethylenediaminetetraacetic Acid Solutions. 5. W. J. Ross, A. S. M E Y E R , JR., J. C.

W H I T E . Determination o f Boron i n Fluoride Salts. 6. OSCAR M E N I S ,

H. P . H O U S E , I.

RUBIN. Spectrophotometric tion of Titanium.

B.

Detennina-

7. OSCAR M E N I S , D . L. MANNING, R. G.

BALL. Automatic Titrations. MODEL TC-2 TEMPERATUR Ε TEST CHAMBER

8. C. A . HORTON.

Analytical Method nary Gas Mixtures. 9. B,

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C&EN

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I 2.

I956

D.

Spectrophotometric T h e Choice of an

for Analysis

BRENEMAN,

C.

of Bi-

R.

NEIT.

Rapid Determination of Carbon Black in Natural and Synthetic Rubbers. 10. ROBERT T. O'CONNOR, E L S I E F. E>UPRE, ELIZABETH: R. MCGAXL. An Infrared

Spectrophotometric Procedure Analysis of Cellulose and Cellulose.

for the Modified

Biochemistry 1. G, a n d presentation of the society's medal awa/d.

1956

ACS LOCAL S E C T I O N S PLACE

Alabama, Room 333, Basic Sci­ ence Bldg., University of Alabama Medical Center, Bir­ mingham Cleveland, Cleveland Engineer­ ing Society Columbus, Room 100, MacPherson Chemical Laboratory, Ohio State University Lehigh. Valley, Lafayette College, Easton, Pa. Michigan State University, Kedzie Chemical Laboratory, East Lansing Mid-Hudson, Lecture Room, San­ ders Chemical Laboratory, Vassar College, Poughkeepsie, Ν. Y . Midland, Auditorium, D o w Chemical Company itfew York (Chemical Marketing and Economics Group), Mosaic Room, Hotel New Yorker New York (Staten Island Sub­ section), Old Mill Restaurant, Staten Island North Jersey (Lackawanna Sub­ section), Celanese Corp. of America, Summit, N. J. Rochester, Hotel Rochester (Har­ rison Howe Lecture) South Jersey, Woodbury Coun­ try Club, Woodbury, N . J . "University ot Arkansas, Chem­ istry Bldg., Fayetteville Western N e w York, University of Buffalo Wooster (Ohio), Chemistry Bldg., College of Wooster

Nov.

SUBJECT

SPEAKER

James T. MacKenzie

The Chemistry of the Cast Irons

21

G. L . Clark

19

G. L . Clark

Instrumental Techniques in Ana­ lytical Chemistry Chemical Order from Solid State Disorder

23

C. E . Schildknecht

20

Hubert N . Alyea

Recent Advances in Polymeriza­ tion Atomic Energy: Weapon for Peace

19

David NTachmansohn

Chemical Mechanisms of Nerve Activity

19

Hubert N . Alyea

20

Charles H . Clark

Atomic Energy: Weapon for Peace Creative Thinking Through Brainstorming

20

Morgan Sparks

The Transistor from the Chemi­ cal Point of View

19

H. F . Mark

Stereospecifie Olefins

19 20 19

V. H . Cheldelin Charles S. Stokes I. C . Gcrasalus

20

M. J. Kelly

20

G. L . Clark

19

Polymerization of

Pathways of Carbohydrate M e ­ tabolism Production of High Temperatures by Chemical Means The Microbe as a ChemicalBiological Model: Multiple Patterns of Organic Acid Metabolism The Nature of Research X-Ray Testing and Research in Industry